• 제목/요약/키워드: Electrochemical Simulation

검색결과 144건 처리시간 0.02초

고체산화물 연료전지의 유동방향에 따른 온도 균일성 영향 (Effect of Flow Direction on Temperature Uniformity in Solid Oxide Fuel Cell)

  • 전동협;신동열;유광현;송락현
    • 대한기계학회논문집B
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    • 제41권10호
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    • pp.667-673
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    • 2017
  • 공개소스 전산유체 해석 라이브러리인 OpenFOAM을 이용하여 음극 지지체형 고체산화물 연료전지의 온도균일성에 관한 연구를 수행하였다. 3가지 유형의 유동흐름(병행류, 대향류, 직교류)에 대하여 수치해석이 이루어졌다. 다공성 물질내에서의 기체의 흐름은 유효확산계수를 이용하여 계산하였고 분리판의 리브 영향도 고려하였다. 전기화학반응의 계산을 위하여 실험식으로부터 얻은 집중내부저항 모델이 사용되었다. 수치해석 결과 대향류가 가장 균일한 온도분포를 나타내었다.

In-process Truing of Metal-bonded Diamond Wheels for Electrolytic In-process Dressing (ELID) Grinding

  • Saleh, Tanveer;Biswas, Indraneel;Lim, Han-Seok;Rahman, Mustafizur
    • International Journal of Precision Engineering and Manufacturing
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    • 제9권3호
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    • pp.3-6
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    • 2008
  • Electrolytic in-process dressing (ELID) grinding is a new technique for achieving a nanoscale surface finish on hard and brittle materials such as optical glass and ceramics. This process applies an electrochemical dressing on the metal-bonded diamond wheels to ensure constant protrusion of sharp cutting grits throughout the grinding cycle. In conventional ELID grinding, a constant source of pulsed DC power is supplied to the ELID cell, but a feedback mechanism is necessary to control the dressing power and obtain better performance. In this study, we propose a new closed-loop wheel dressing technique for grinding wheel truing that addresses the efficient correction of eccentric wheel rotation and the nonuniformity in the grinding wheel profile. The technique relies on an iterative control algorithm for the ELID power supply. An inductive sensor is used to measure the wheel profile based on the gap between the sensor head and wheel edge, and this is used as the feedback signal to control the pulse width of the power supply. We discuss the detailed mathematical design of the control algorithm and provide simulation results that were confirmed experimentally.

Hydrodynamic Effect on the Inhibition for the Flow Accelerated Corrosion of an Elbow

  • Zeng, L.;Zhang, G.A.;Guo, X.P.
    • Corrosion Science and Technology
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    • 제16권1호
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    • pp.23-30
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    • 2017
  • The inhibition effect of thioureido imidazoline inhibitor (TAI) for flow accelerated corrosion (FAC) at different locations for an X65 carbon steel elbow was studied by array electrode and computational fluid dynamics (CFD) simulations. The distribution of the inhibition efficiency measured by electrochemical impedance spectroscopy (EIS) is in good accordance with the distribution of the hydrodynamic parameters at the elbow. The inhibition efficiencies at the outer wall are higher than those at the inner wall meaning that the lower inhibition efficiency is associated with a higher flow velocity, shear stress, and turbulent kinetic energy at the inner wall of the elbow, as well as secondary flow at the elbow rather than the mass transport of inhibitor molecules. Compared to the static condition, the inhibition efficiency of TAI for FAC was relatively low. It is also due to a drastic turbulence flow and high wall shear stress during the FAC test, which prevents the adsorption of inhibitor and/or damages the adsorbed inhibitor film.

연료전지 모델링 및 부스트 컨버터 출력 특성 (Fuel Cell Modeling with Output Characteristics of Boost Converter)

  • 박봉희;최주엽;최익;이상철;이동하
    • 한국태양에너지학회 논문집
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    • 제34권1호
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    • pp.91-97
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    • 2014
  • This paper proposes a modeling of fuel cell which replaces dc source during simulation. Fuel cells are electrochemical devices that convert chemical energy in fuels into electrical energy. This system has high efficiency and heat, no environmental chemical pollutions and noise. Proton exchange membrane fuel cells (PEMFC) are commonly used as a residential generator. These fuel cells have different electrical characteristics such as a low voltage and high current compared with solar cells. And there are different behaviors in the V-I curve in the temperature and pressure. Therefore, the modeling of fuel cell should consider wide voltage range and slow current response and the resulting electrical model is applied to boost converter with fuel cell as an input source.

조기화재 감시시스템을 위한 CO센서의 시그널컨디셔너 성능개선 (Performance Improvement of CO Sensor Signal Conditioner for Early Fire Detection System)

  • 박종찬;손진근
    • 전기학회논문지P
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    • 제66권2호
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    • pp.82-87
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    • 2017
  • This paper presents performance improvement of CO gas sensor signal conditioner for early fire warning system. The warning system is based on the CO sensor and its advanced signal conditioning modules network that employ electochemical gas sensor. The electochemical has advantage of having a linear output and operating with a low consumption and fast response. This electrochemical gas sensor contains a gas membrane and three electrodes(working, counter, reference electrode) in contact with an electrolyte. To use a three-electrode sensor, a voltage has to be applied between the working and the reference electrode according to the specification of the sensor. In this paper, we designed these requirements that should be considered in temperature compensation algorithm and electrode measurement of CO sensor modules by using advanced signal conditioning method included 3-electrode. Simulation and experimental results show that signal conditioner of CO sensor module using 3-electrode have a advantage linearity, sensitivity and stability, fast response etc..

가습조건이 사형유로를 채택한 고분자 전해질 연료전지의 성능에 미치는 영향에 대한 전산유체역학 해석 연구 (Computational Fluid Dynamics Study on Performance Variation of PEMFC with Serpentine Flow Fields According to Humidity Condition)

  • 오규환;이규진;남진현;김찬중
    • 대한기계학회논문집B
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    • 제33권8호
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    • pp.604-612
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    • 2009
  • Water management has been recognized as a crucial factor for achieving better performance and stability in polymer electrolyte membrane fuel cells (PEMFCs). Proper water management should provide favorable water conditions, including the local humidity, membrane water content, and liquid water saturation in PEMFCs, thereby leading to more uniform electrochemical reaction and current generation. In this study, computational fluid dynamics (CFD) simulation was conducted to investigate the effects of the cathode relative humidity (RH) on the performance of a 3 by $3\;cm^2$ PEMFC with serpentine flow fields. The CFD results showed that the best performance of the PEMFC was obtained for the cathode RH of 80%, but the performance variation was small for the cathode RH range of $60{\sim}100%$. However, the loss of the PEMFC performance was significant when the cathode RH was reduced below 40%. The reason for such performance variation was investigated through the detailed inspection of ohmic loss, activation and concentration overpotential, and water and current distributions.

GDL Permeability에 따른 고분자 전해질 연료전지의 물질전달 및 열전달 특성에 관한 연구 (Mass Transfer and Heat Transfer Characteristics of PEM fuel cell by Permeability of GDL)

  • 한상석;이필형;박창수;이재영;황상순
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2008년도 추계학술대회B
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    • pp.2822-2827
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    • 2008
  • Among the main components of PEM fuel cell, the functions of GDL are to transport reactants from the channel to the catalyst and remove reaction products from the catalyst and transport heat from the catalyst to the channels in the flow filed plate. Permeability of GDL is known to make it possible to enhance the gas transport through GDL, devoting to get better performance. In this paper, three dimensional numerical simulation of the fuel cell by the permeability of GDL is presented by using a FLUENT modified to include the electrochemical behavior. Results show that as permeability is higher than $10^{-12}m^2$, gradients of temperature distribution, oxygen molar concentration and current density distribution in MEA were decreased. Although heat generation was increased as high permeability, MEA's temperature was lower than the low permeability of GDL. This seems because that convection was higher affects in mass and heat transfer process than diffusion as permeability of GDL is increases.

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F316 오스테나이트 스테인리스강의 상변태 및 입계부식저항성에 미치는 입열의 영향 (Effects of Heat Inputs on Phase Transformation and Resistance to Intergranular Corrosion of F316 Austenitic Stainless Steel)

  • 정규석;이인성;김순태
    • Corrosion Science and Technology
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    • 제19권3호
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    • pp.146-155
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    • 2020
  • To elucidate the effect of heat inputs on phase transformation and resistance to intergranular corrosion of F316 austenitic stainless steel (ASS), thermodynamic calculations of each phase and time-temperature-transformation diagram were conducted using JMaPro simulation software, oxalic acid etch test, double-loop electrochemical potentiokinetic reactivation test (DL-EPR), field emission scanning electron microscopy with energy dispersive spectroscopy, and transmission electron microscopy analyses of Cr carbide (Cr23C6), austenite phase and ferrite phase. F316 ASS containing a relatively low C content of 0.043 wt% showed a slightly sensitized microstructure (acceptably dual structure) due to a small amount of Cr carbide precipitated at heat affected zone irrespective of heat inputs. Based on results of DL-EPR test, although heat input was increased, the ratio of Ir to Ia was only increased very slightly due to a slight sensitization. Therefore, heat inputs have little influences on resistance to intergranular corrosion of F316 austenitic stainless steel containing 0.043 wt% C.

PEMFC 발전시스템용 고효율 PCS 개발에 관한 연구 (A Study on Development of High Efficiency PCS using in PEMFC Generation System)

  • 곽동걸;정원석;정도영;김춘삼;심재선
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2009년도 춘계학술대회 논문집 에너지변화시스템부문
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    • pp.266-268
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    • 2009
  • In this paper, authors deal with a power conditioning system (PCS) of high efficiency for a proton exchange membrane fuel cell (PEMFC) generation system. Fuel cells are a direct current (DC) power generators. They generate electricity through an electrochemical process that converts the energy stored in a fuel directly into electricity. Fuel cells have many benefits, which produce no particulate matter, nitrogen or sulfur oxides. And they have few moving parts and produce little or no noise. When fueled by hydrogen, they yield only heat and water as byproducts. Their wide application can reduce our dependence on fossil fuels and foreign sources of petroleum. This paper studies on a novel PCS circuit topology of high efficiency using in PEMFC generation system The controlling switches in the PCS is operated to soft switching. Some digital simulation results and experimental results for the proposed PCS is confirmed to the validity of the analytical results.

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Intermodulation 방법에 의한 자동차용 연료전지 스택의 실시간 진단방법 개발 (Development of Real-time Diagnosis Method for PEMFC Stack via Intermodulation Method)

  • 이용현;유승열;김종현
    • 한국자동차공학회논문집
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    • 제22권7호
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    • pp.76-83
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    • 2014
  • During PEMFC(Proton Exchange Membrane Fuel Cell) operation monitoring and diagnosis are important issues for reliability and durability. Stack defect can be followed by a critical cell voltage drop in the stack. One method for monitoring the cell voltage is CVM(Cell Voltage Monitoring), where all cells in the stack are electrically connected to a voltage measuring system and monitored these voltages. The other methods are based on the EIS(Electrochemical Impedance Spectroscopy) and on nonlinear frequency response. In this paper, intermodulation(IM) method for diagnosis PEMFC stack is introduced. To detect one or more critical PEMFC cell voltage PEMFC stack is excited by two or more test sinusoid current, and the frequency response of the stack voltage is analyzed. If one or more critical cell voltage exists, higher harmonics on the voltage frequency spectrum will appear. For the proposed IM method, stack simulation and experiments are conducted.