• Title/Summary/Keyword: Electro-osmotic

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Effect of electrochemical treatment on consolidation of soft clay

  • Li, Xiaobing;Yuan, Guohui;Fu, Hongtao;Wang, Jun;Cai, Yuanqiang
    • Geomechanics and Engineering
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    • v.15 no.4
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    • pp.957-964
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    • 2018
  • In this study, a method of electrochemical consolidation is applied. This method utilizes electro-osmosis, which is an effective ground improvement technique for soft clays, and soil treatment using lime, which is the oldest traditional soil stabilizer. The mechanism of lime treatment for soil involves cation exchange, which leads to the flocculation and agglomeration. Five representative laboratory tests-an electro-osmotic test and four electrochemical tests with various proportions of lime-were performed on dredged marine clay. The objectives of this study are to investigate the effect of electrochemical treatment and to determine the optimum dose for optimal consolidation performance of dredged marine clay. The results show that a better consolidation effect was achieved in terms of current, temperature, and vane shear strength by using electrochemical treatment. The best results were observed for the electrochemical test using 4% lime content.

Transport of Water through Polymer Membrane in Proton Exchange Membrane Fuel Cells (고분자전해질 연료전지에서 고분자막을 통한 물의 이동)

  • Lee, Daewoong;Hwang, Byungchan;Lim, Daehyun;Chung, Hoi-Bum;You, Seung-Eul;Ku, Young-Mo;Park, Kwonpil
    • Korean Chemical Engineering Research
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    • v.57 no.3
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    • pp.338-343
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    • 2019
  • The water transport and water content of the electrolyte membrane greatly affect the performance of the membrane in PEMFC(Proton Exchange Membrane Fuel Cell). In this study, the parameters (electroosmotic coefficient, water diffusion coefficient) of polymer membranes for water transport were measured by a simple method, and water flux and ion conductivity were simulated by using a model equation. One dimensional steady state model equation was constructed by using only the electro-osmosis and diffusion as the driving force of water transport. The governing equations were simulated with MATLAB. The electro-osmotic coefficient of $144{\mu}m$ thick polymer membranes was measured in hydrogen pumping cell, the value was 1.11. The water diffusion coefficient was expressed as a function of relative humidity and the activation energy for water diffusion was $2,889kJ/mol{\cdot}K$. The water flux and ion conductivity results simulated by applying these coefficients showed good agreement with the experimental data.

Comparison of Electro-Osmotic Pumps with Two Different Types of Porous Glass Frits (두 종류의 다공성 유리막을 이용한 전기삼투 펌프의 비교 연구)

  • Kwon, Kil-Sung;Park, Chul-Woo;Kim, Dae-Joong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.35 no.4
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    • pp.379-383
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    • 2011
  • Electro-osmotic pumps were fabricated by using two types of porous glass frits. The performance of these pumps was characterized in terms of maximum flow rate, current, and pressure using deionized water and 1 mM sodium tertraborate decahydrate buffer. Maximum flow rate and current when ROBU porous glass frits were used were higher than those when DURAN porous glass frits were used because of the high porosity of the ROBU glass frits. However, the maximum pressure when ROBU glass frits were used was similar to that when DURAN glass frits were used. The therrmodynamic efficiency of a pump with ROBU porous glass frits is approximately twice that of a pump with DURAN porous glass frits. Further, the maximum flow rate at maximum current in the case of ROBU porous glass frits is high. However, it is lower than the maximum pressure at maximum current in the case of DURAN porous glass frits. Further, in this study, we also verified the effectiveness of ROBU glass frits when high flow rate is required and of DURAN glass frits when a high pressure is required.

A STUDY ON CHARACTERISTICS OF Ac ELECTRO-OSMOTIC FLOWS IN THE MICROCHANNEL WITH COPLANAR ELECTRODES (마이크로 채널 내 동일 평면 전극에 교류인가로 인한 유동특성 연구)

  • Heo, H.S.;Kang, S.M.;Suh, Y.K.
    • 한국전산유체공학회:학술대회논문집
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    • 2006.10a
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    • pp.163-166
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    • 2006
  • This paper presents numerical results of fluid flows and mixing in a microfluidic device for AC electroosmotic flow (AC-EOF) with coplanar electrodes on top and bottom walls. Differently from previous EOF a channel which attached a couple of coplanar electrodes can be utilized to mix a target liquid with a reagent. In this study we propose a method of controlling fluid flows and mixing enhancement. To obtain the flow and mixing characteristics, numerical computations are performed by using a commercial code, CFX10. It was found that the flow near the coplanar electrodes is of 3-D complex flows and vortices between the other electrodes, and as a consequence the AC-electroosmotic flow on the electrodes plays an important role in mixing the liquid.

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Electro-osmotic pump in osteo-articular tissue engineering: A feasibility study

  • Lemonnier, Sarah;Naili, Salah;Lemaire, Thibault
    • Advances in biomechanics and applications
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    • v.1 no.4
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    • pp.227-237
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    • 2014
  • The in vitro construction of osteo-articular large implants combining biomaterials and cells is of great interest since these tissues have limited regeneration capability. But the development of such organoids is particularly challenging, especially in the later time of the culture, when the extracellular matrix has almost filled the initial porous network. The fluid flow needed to efficiently perfuse the sample can then not be achieved using only the hydraulic driving force. In this paper, we investigate the interest of using an electric field to promote mass transport through the scaffold at the late stage of the culture. Based on the resolution of the electrokinetics equations, this study provides an estimation of the necessary electric driving force to reach a sufficient oxygen perfusion through the sample, thus analyzing the feasibility of this concept. The possible consequences of such electric fields on cellular activities are then discussed.

Mixing in a Microchannel by using Induced-charge Electro-osmosis (마이크로 채널 내 유도-전하 전기삼투에 의한 혼합)

  • Jeon, Young-Hun;Heo, Young-Gun;Jung, Won-Hyuk;Alapati, Suresh;Suh, Yong-Kweon
    • Journal of the Korean Society of Visualization
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    • v.8 no.4
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    • pp.13-18
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    • 2010
  • This paper presents an experimental study on the performance of a micro-mixer using AC electro-osmotic flow. The microchannel is made of PDMS for the side and top walls and glass patterned with ITO for the bottom wall. We first investigated the effect of the applied potential as well as the frequency on the slip velocity. We have found that the slip velocity is roughly proportional to the applied voltage in line with the Helmholtz-Smoluchowski equation and there is an optimum frequency at which the slip velocity becomes maximized. To find the optimum parameters for mixing device we tested our device for various design parameters. It turned out that the best mixing effect is obtained approximately when the electrode angle is $30^{\circ}$, electrode width $200\;{\mu}m$, and the frequency of power supply 700 Hz.

Ion Conductivity of Membrane in Proton Exchange Membrane Fuel Cell (고분자전해질 연료전지에서 고분자 막의 이온 전도도)

  • Hwang, Byungchan;Chung, Hoi-Bum;Lee, Moo-Seok;Lee, Dong-Hoon;Park, Kwonpil
    • Korean Chemical Engineering Research
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    • v.54 no.5
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    • pp.593-597
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    • 2016
  • The effects of relative humidity, current density and temperature on the ionic conductivity were studied in PEMFC (Proton Exchange Membrane Fuel Cell). Water contents and water flux in the electrolyte membrane largely affected ion conductivity. The water flux was modelled and simulated by only electro-osmotic drag and back-diffusion of water. Ion conductivities were measured at membrane state out of cell and measured at MEA (Membrane and Electrode Assembly) state in condition of operation. The water contents in membrane increase as relative humidity increased in PEMFC, as a results of which ion conductivity increased. Current enhanced electro-osmotic drag and back diffusion and then water contents linearly increased. Enhancement of current density results in ion conductivity. Ion conductivity of about 40% increased as the temperature increased from $50^{\circ}C$ to $80^{\circ}C$.

Measurement of Humidity Distribution in a Proton Exchange Membrane Fuel Cell Using Channel Embedded Humidity Sensors (채널 내장형 습도 센서를 이용한 고분자 전해질 연료전지의 습도분포 측정)

  • Lee, Yongtaek;Yang, Gyung Yull
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.39 no.5
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    • pp.397-403
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    • 2015
  • In this study, water distribution inside a proton exchange membrane fuel cell (PEMFC) was measured experimentally. Water distribution is non-uniform because of vigorous chemical reaction and mass transport and has been difficult to measure experimentally. Therefore, much research relied on indirect measuring methods or numerical simulations. In this study, several mini temperature-humidity sensors were installed at the channel for measuring temperature and humidity of the flowing gas throughout the channel. Only one of two electrode channels was humidified externally, and the humidity distribution on the other side was measured, enabling the observation of water transport characteristics under various conditions. Diffusion through the membrane became more vigorous as the temperature of the humidifier rose, but at high current density, electro-osmotic drag became more effective than diffusion.

Studies on the Transport of Acetic Acid by Electrodialysis (전기투석에 의한 초산의 이동특성 연구)

  • 최동민;구윤모
    • KSBB Journal
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    • v.11 no.3
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    • pp.360-366
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    • 1996
  • Electrodialysis of acetic acid was studied to find out the trend of the transport of organic acids through ultrafiltration and ion exchange membranes. The net transport rate of acetic acid was determined from the electro-migration velocity relative to the electro-osmotic flow rate through the membrane. Electro-osmosis flows through ultrafiltration membranes were from the anodic side to the cathodic side in the presence of electric field. The surface of ultrafiltration membrane was measured by the electro-osmotic flow to be charged negatively. Different transport behaviors of acetic acid were found with the ultrafiltration membranes of different materials. In general, regenerated cellulose membranes (YM series) were more effective than polysulfone membranes (PM series) for the transport of acetic acid. The transport of acetic acid was affected by electric strength, distance between the electrodes, surface area of electrode, temperature, and pore size of membrane. The transport rate through the ion exchange membrane was 1.5 to 3 times of those through the ultrafiltration membranes at the constant current of 150 mA in the experimental ranges. The transport rate of acetic acid through the ion exchange membrane increased by 10% with a pulse electric field of 10 sec/hr.

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EFFECT OF THE ZETA POTENTIAL CONTROL BY THE TRAPEZOIDAL ELECTRODES IN A MICROCHANNEL ON ENHANCEMENT MIXING-PERFORMANCE (마이크로 채널 내 사다리꼴 전극의 제타 포텐셜 변화에 따른 혼합효과 증대에 대한 수치해석적 연구)

  • Suh, Y.K.;Heo, H.S.;Kang, J.F.
    • Journal of computational fluids engineering
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    • v.11 no.3 s.34
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    • pp.46-51
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    • 2006
  • This paper presents the numerical results of fluid flow and mixing in a microfluidic device for electro-osmotic flow (EOF) with an trapezoidal electrode array on the bottom wall (ETZEA). Differently from previous EOF in a channel which only transports fluid in colloidal system. ETZEA can also be utilized to mix a target liquid with a reagent. In this study we propose a method of controlling fluid flow and mixing enhancement. To obtain the flow and mixing characteristics, numerical computations are performed by using a commercial code, CFX-10, and a self-made code LBM-D. It was found that the flow near the trapezoidal electrode in the ETZEA is of 3-D complex flows due to the zeta potential difference between the trapezoidal electrode and channel walls, and as a consequence the hetrogeneous zeta potential on the electrodes plays an important role in mixing the liquid.