• Title/Summary/Keyword: Electro-chemistry

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A Four-Channel Laser Array with Four 10 Gbps Monolithic EAMs Each Integrated with a DBR Laser

  • Sim, Jae-Sik;Kim, Sung-Bock;Kwon, Yong-Hwan;Baek, Yong-Soon;Ryu, Sang-Wan
    • ETRI Journal
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    • v.28 no.4
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    • pp.533-536
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    • 2006
  • A distributed Bragg reflector (DBR) laser and a high speed electroabsorption modulator (EAM) are integrated on the basis of the selective area growth technique. The typical threshold current is 4 to 6 mA, and the side mode suppression ratio is over 40 dB with single mode operation at 1550 nm. The DBR laser exhibits 2.5 to 3.3 mW fiber output power at a laser gain current of 100 mA, and a modulator bias voltage of 0 V. The 3 dB bandwidth is 13 GHz. A 10 Gbps non-return to zero operation with 12 dB extinction ratio is obtained. A four-channel laser array with 100 GHz wavelength spacing was fabricated and its operation at the designed wavelength was confirmed.

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Dyamic Modeling and Analysis of Air Supply System for Vehicular PEM Fuel Cell (고분자 전해질형 연료전지 자동차의 급기 시스템의 동적 모델링 및 분석)

  • Jang, HyunTak
    • Journal of Hydrogen and New Energy
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    • v.15 no.3
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    • pp.175-186
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    • 2004
  • In this paper, we developed the dynamic model of a fuel cell system suitable for controller design and system operation. The transient phenomena captured in the model include the flow characteristics and inertia dynamics of the compressor, the intake manifold filling dynamics, oxygen partial pressures and membrane humidity on the fuel cell voltage. In the simulations, we paid attention to the transient behavior of stack voltage and compressor pressure, stoichiometric ratio. Simulation results are presented to demonstrate the model capability. For load current following, stack voltage dynamic characteristics are plotted to understand the Electro-chemistry involved with the fuel cell system. Compressor pressure and stoichiometric ratio are strongly coupled, and independent parameters may interfere with each other, dynamic response, undershoot and overshoot.

Synthesis and Properties of Non-chiral Liquid Crystalline Molecules with Semi-Fluorinated Alkyl Chains

  • Choi, E-Joon;Sim, Hoo-Sik;Zin, Wang-Cheol;Kim, Dae-Cheol;Lee, Chong-Kwang;Chien, Liang-Chy
    • 한국정보디스플레이학회:학술대회논문집
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    • 2002.08a
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    • pp.933-935
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    • 2002
  • In this paper, new non-chiral molecules with semi-fluorinated alkyl chains were synthesized varying the structure of central bent core unit. Their mesomorphic properties were investigated by DSC and polarized microscopy. The compound with 1,3-dihydroxy phenylene unit could form an enantiomeric smectic phase, but the remaining compounds with bent-core mesogenic unit were not liquid crystalline. In this presentation, their x-ray measurement and electro-optical property will be also described.

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Light Induced Structural Transition in $B_7$ phase of Bent-shaped Liquid Crystals containing Azo dye

  • Kim, Hee-Kyung;Shin, S.T.;Lee, C.K.;Jang, Chi-Woong;Lim, Tong-Kun
    • 한국정보디스플레이학회:학술대회논문집
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    • 2002.08a
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    • pp.494-497
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    • 2002
  • The influence of isomeric state of doped azo dye on the $B_7$ phase of bent-shaped liquid crystal (LC) is studied. It was found that modulating the isomeric trans-cis state of azo dye can change the molecular arrangement of the bent-shaped LCs. To identify these phenomena the observations of microscopic texture, electro-optic response, second harmonic wave generation (SHG) and switching current were carried out..

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Enhancement of electro-optic performance in dyesensitized solar sell using homeotropically aligned liquid crystal molecular

  • Kim, Hyeon-Kyung;Jin, Sung-Ho;Lee, Gi-Dong
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.1130-1132
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    • 2009
  • We propose a novel way for enhancement of efficiency on a quasi solid-state dye-sensitized solar cell (DSSC). It contained gel type electrolyte mixing the liquid crystal (LC) of specific concentration and applied voltage for alignment of the LC. Aligned LC is supported charge transfer inside electrolyte and efficiency is increased in DSSC. We made a quasi solid-state DSSC which applied DC voltage or not and have measured the power conversion efficiency (PCE) and the fill factor. From measurement, we obtain high performances in case of cell applied voltage compare to reference cell.

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Study on the Electrodyalisis Using Ion Exchange Membrane (이온交換樹脂膜을 利用한 電氣透析의 檢討)

  • Chin Taik Lee
    • Journal of the Korean Chemical Society
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    • v.18 no.1
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    • pp.58-65
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    • 1974
  • The relation between the concentration of concentrated solution, the quantity of electromigrated solute/electricity and the increasing volume of concentrated solution/the quantity of electromigrated ion to the concentration of solution and the applied current density in the electrodyalisis using ion exchange membranes are studied. It is found that the experimental results on the above mentioned quantities can be understood by the ionic concentration in the membrane phase, the mobility of electrolytes and the flux of electro-osmosis.

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Novel Smart Polymeric Composites for Thermistors and Electromagnetic Wave Shielding Effectiveness from TiC Loaded Styrene-Butadiene Rubber

  • Sung, Yong-Kiel;Farid EI-Tantawy
    • Macromolecular Research
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    • v.10 no.6
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    • pp.345-358
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    • 2002
  • The electrical conductivity during vulcanization process was measured as a function of time for the system of TiC loaded styrene-butadiene rubber (SBR) composites. The phenomenon of negative and positive temperature coefficients of conductivity and its conduction mechanism were also studied for the SBR polymeric composites. The current-voltage characteristics of the polymeric composites were non-linear in high voltage and showed a switching effect. The effects of temperature on the thermal conductivity and effective dielectric constant were measured. The measured parameters were found to be dependent on TiC concentration. The electromagnetic wave shielding (EMS) of the SBR-TiC polymeric composite was also examined. The SBR filled with TiC could be expected to be promising novel smart polymeric composites for self-electrical heating, temperature sensor, time delay switching, and electro-magnetic wave shielding effectiveness.

Chloride ion removal effect for the ACF electrochemically treated with silver

  • Oh, Won-Chun;Park, Choung-Sung;Bae, Jang-Soon
    • Analytical Science and Technology
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    • v.19 no.4
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    • pp.316-322
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    • 2006
  • The removal efficiencies of silver-ACFs were associated with their surface properties such as surface area, porosity, and the electro-chemical reaction time for the silver treatments. X-ray diffraction patterns of fibers electrochemically treated with silver display diffraction peaks for metallic silver and kinds of silver chloride complexes on the fiber surface after electrochemical adsorption. The results of SEM and EDX indicate that surface reaction motive of silver-ACF prepared by electrochemical reaction are depend on time function for the chloride ion removal efficiency. Finally, Cl ion adsorbed by the silver-ACFs from the ICP analysis seems to show an excellent removal effect.