• 분석과학
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• 제6권3호
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• pp.247-254
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• 1993

스트론튬을 비롯한 알칼리 토금속의 전기화학적 분석의 적용은 수용액상에서 DME(Drop Mercury Electrod)에 대한 환원이 어렵기 때문에 그 연구가 많지 않다. 본 연구에서는 지금까지 UV-VIS 흡광광도법에서 스트론튬의 분석에 이용되어 온 o-Cresolphthaleoxon을 가지고 이들 사이의 착물형성에 따른 전자이동을 이용하여 전기화학적 분석에 적용시켰다. 이 때 지지전해질의 선택, Accumulation Potential 등 전기화학적 분석에 영향을 미치는 실험조건 등을 조사하여 정량범위를 결정짓고, 분석시 공존 이온의 영향을 조사하였다. UV-VIS 흡광광도법의 경우 $100{\mu}g/L$로 검출감도가 좋지 못하였으나, 전기화학적 방법을 이용할 경우 $5{\sim}30{\mu}g/L$ 범위까지의 정량이 가능하였다.

• 전기학회논문지
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• 제60권5호
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• pp.955-964
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• 2011

In renewable energy system such as flywheel energy storage system, wind power and solar power, the motor/generator is the important key for offering the electric energy to the electric loads. For example, the heavy and large flywheel is rotated by electromagnetic torque of pemanent magnet synchronous motor (PMSM) and, in case of a breakdown of electric current, the PMSM used as generator supplies electric energy for the various electric utilities using mechanical rotation energy of the flywheel. Thus, design of a motor/generator should be performed in effort to reduce cogging torque and electromagnetic loss for high efficiency. In our paper, a slotless permanent magnet synchronous motor/generator (SPMSM/G) with output power 15kW at the rotor speed 18000rpm is designed from electromagnetic analysis and dynamic performance analysis. In analytical approach, design parameters such as back electro-motive force (back EMF), inductance and electromagnetic torque are derived from analytical method which is one of the electromagnetic analysis method. And using the design parameters, this paper deal with system design considering the driving characteristics and electric load in required power. Finally, the analytical results are verified by the experiment and finite element method (FEM).

• Advances in materials Research
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• 제5권4호
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• pp.279-298
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• 2016

Present disquisition proposes an analytical solution method for exploring the buckling characteristics of porous magneto-electro-elastic functionally graded (MEE-FG) plates with various boundary conditions for the first time. Magneto electro mechanical properties of FGM plate are supposed to change through the thickness direction of plate. The rule of power-law is modified to consider influence of porosity according to two types of distribution namely even and uneven. Pores possibly occur inside FGMs due the result of technical problems that lead to creation of micro-voids in these materials. The variation of pores along the thickness direction influences the mechanical and physical properties. Four-variable tangential-exponential refined theory is employed to derive the governing equations and boundary conditions of porous FGM plate under magneto-electrical field via Hamilton's principle. An analytical solution procedure is exploited to achieve the non-dimensional buckling load of porous FG plate exposed to magneto-electrical field with various boundary condition. A parametric study is led to assess the efficacy of material graduation exponent, coefficient of porosity, porosity distribution, magnetic potential, electric voltage, boundary conditions, aspect ratio and side-to-thickness ratio on the non-dimensional buckling load of the plate made of magneto electro elastic FG materials with porosities. It is concluded that these parameters play remarkable roles on the dynamic behavior of porous MEE-FG plates. The results for simpler states are confirmed with known data in the literature. Presented numerical results can serve as benchmarks for future analyses of MEE-FG plates with porosity phases.

• 한국자동차공학회논문집
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• 제16권4호
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• pp.173-178
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• 2008

Electro-hydraulic brake system has many advantages. It provides improved braking performance and stability functions. It also removes complex mechanical parts for freedom of design, improves maintenance requirements and reduces unit weight. However, the EHB system should be dependable and have back-up redundancy in case of a failure. In this paper, the model-based fault diagnosis system is developed to monitor the brake status using the analytical redundancy method. The performance of the model-based fault diagnosis system is verified in real-time simulation. It demonstrates the effectiveness of the proposed system in various faulty cases.

• 분석과학
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• 제8권4호
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• pp.469-475
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• 1995

Di-2-pyridylmethanon 2-thiophenecarboxylie hydrazone(DPMTCH) was synthesized and used as a chromogenic reagent in the spectrophotometric determination of nickel in steel. The proton disc spectrophotometrically, were $pK_{a1}= 2.66$ and $pK_{a2}= 10.98$ ${\mu}=0.5(NaCl)$. Nickel(II) reacts with DPMTCH to form a 1:2 metal-2-ligand ratio complex, the xylene solution of which has an absorption maximum at 417 nm. Beer's law is obeyed over the range $0-1.17\;mg\;ml^{-1}$ of nickel(II). The molar absorptivity of the nickel(II) complex is $4.17{\times}10^4l\;mol^{-1}\;cm^{-1}$. The precision of the method was estimated for 4.7 mg of nickel(II), the coefficient of variation for 15 replicate determinations being 0.34%.

• Smart Structures and Systems
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• 제20권6호
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• pp.709-728
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• 2017

This disquisition proposes a nonlocal strain gradient beam theory for thermo-mechanical dynamic characteristics of embedded smart shear deformable curved piezoelectric nanobeams made of porous electro-elastic functionally graded materials by using an analytical method. Electro-elastic properties of embedded curved porous FG nanobeam are assumed to be temperature-dependent and vary through the thickness direction of beam according to the power-law which is modified to approximate material properties for even distributions of porosities. It is perceived that during manufacturing of functionally graded materials (FGMs) porosities and micro-voids can be occurred inside the material. Since variation of pores along the thickness direction influences the mechanical and physical properties, so in this study thermo-mechanical vibration analysis of curve FG piezoelectric nanobeam by considering the effect of these imperfections is performed. Nonlocal strain gradient elasticity theory is utilized to consider the size effects in which the stress for not only the nonlocal stress field but also the strain gradients stress field. The governing equations and related boundary condition of embedded smart curved porous FG nanobeam subjected to thermal and electric field are derived via the energy method based on Timoshenko beam theory. An analytical Navier solution procedure is utilized to achieve the natural frequencies of porous FG curved piezoelectric nanobeam resting on Winkler and Pasternak foundation. The results for simpler states are confirmed with known data in the literature. The effects of various parameters such as nonlocality parameter, electric voltage, coefficient of porosity, elastic foundation parameters, thermal effect, gradient index, strain gradient, elastic opening angle and slenderness ratio on the natural frequency of embedded curved FG porous piezoelectric nanobeam are successfully discussed. It is concluded that these parameters play important roles on the dynamic behavior of porous FG curved nanobeam. Presented numerical results can serve as benchmarks for future analyses of curve FG nanobeam with porosity phases.

• 분석과학
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• 제8권4호
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• pp.865-868
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• 1995

The method of matrix-assisted laser desorption ionization mass spectrometry has been used to solve some bioanalytical problems, which is difficult to analyse by general methods. For the selection of proper laser wavelength and matrices, eight matriees was used with laser wavelength of 226 and 355nm. The result shows that with wavelength of 355nm better results could be obtained with most of the matrices. The molecular weight of eytochrome C, which was seperated by gel electrophoresis and electro-blotted onto NC membrane is determined by MALDI. The accuracy is better than 0.1%, which is much higher than that of SDS-PAGE. Protein mixture extracted from crude peanut oil is directly determined by MALDI. The molecuiar weight of its three components are determined, and the result also demonstrated that these proteins are in free manner. As proteins arc in 2S bond, with the traditional method, SDS-PAGE, it is not able to decide whether protein exists in combination mode or in free manner. In the technique of two phase aquesous solution, which is used for separating biomaterials, water soluble polymers stained with dyes are used in this technique. By the use of MALDI the number or the dye molecules react with the polymer PEG molecule are determined, and that is difficult to determined by other methods.

• 한국소음진동공학회:학술대회논문집
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• 한국소음진동공학회 2005년도 추계학술대회논문집
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• pp.247-250
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• 2005

Underwater acoustic transducers are widely used for SONAR application, whose important design parameters are shapes, materials, dimensions and supporting structures. Practical design method of transducers consists of manufacturing, experiments and modifications so that It requires much time and expenses. In this study, an analytical method was developed for the Tonpilz type transducers using the commercial finite element analysis code ATILA which can solve the electro-mechanical coupling Problems. A finite element model was established including the transducer elements such as ceramic stack, head mass, tall mass, tensile bolt, and molding layers. The proposed model was verified and modified by comparing the in-air and in-water test results of prototypes. The developed analysis method will be effectively used for the sensitivity analysis of design parameters in transducer design process.

• Structural Engineering and Mechanics
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• 제53권6호
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• pp.1167-1182
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• 2015

In this study, the stresses and electric potential redistributions of a cylinder made from functionally graded piezoelectric material (FGPM) are investigated. All the mechanical, thermal and piezoelectric properties are modeled as power-law distribution of volume fraction. Using the coupled electro-thermo-mechanical relations, strain-displacement relations, Maxwell and equilibrium equations are obtained including the time dependent creep strains. Creep strains are time, temperature and stress dependent, the closed form solution cannot be found for this constitutive differential equation. A semi-analytical method in conjunction with the Mendelson method of successive approximation is therefore proposed for this analysis. Similar to the radial stress histories, electric potentials increase with time, because the latter is induced by the former during creep deformation of the cylinder, justifying industrial application of such a material as efficient actuators and sensors.

• Advances in nano research
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• 제10권3호
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• pp.235-251
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• 2021

In the current study, the free vibrational behavior of a Porous Micro (PM) beam which is integrated with Functionally Graded Piezoelectric (FGP) layers with initial curvature is considered based on the two trigonometric shear deformation theories namely SSDBT and Tan-SDBT. The structure's mechanical properties are varied through its thicknesses following the given functions. The curved microbeam is exposed to electro-mechanical preload and also is rested on a Pasternak type of elastic foundation. Hamilton's principle is used to extract the motion equations and the MCST is used to capture the size effect. Navier's solution method is selected as an analytical method to solve the motion equations for a simply supported ends case and by validating the results for a simpler state with previously published works, effects of different important parameters on the behavior of the structure are considered. It is found that although increasing the porosity reduces the natural frequency, but enhancing the volume fraction of CNTs increasing it. Also, by increasing the central angle of the curved beam the vibrations of the structure increases. Designing and manufacturing more efficient smart structures such as sensors and actuators are of the aims of this study.