• Title/Summary/Keyword: Electrical charge

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Tuning of Electro-optical Properties of Nano-structured SnO2:Ga Powders in a Micro Drop Fluidized Reactor

  • Lim, Dae Ho;Yang, Si Woo;Yoo, Dong June;Lee, Chan Gi;Kang, Yong
    • Korean Chemical Engineering Research
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    • v.57 no.2
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    • pp.259-266
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    • 2019
  • Tuning of electro-optical properties of nano-structured $SnO_2:Ga$ powders in a micro drop fluidized reactor (MDFR) was highly effective to enhance the activities of powders to be used as sensor materials. The tuning was conducted continuously in a facile one-step process during the formation of powders. The microscopic hydrodynamic forces affected the band gap structure and charge transfer of $SnO_2:Ga$ powders through the oxygen and interfacial tin vacancies by providing plausible pyro-hydraulic conditions, which resulted in the decrease in the electrical resistance of the materials. The analyses of room-temperature photoluminescence (PL) spectra and FT-IR exhibited that the tuning could improve the surface activities of $SnO_2:Ga$ powders by adjusting the excitation as well as separation of electrons and holes, thus maximizing the oxygen vacancies at the surface of the powders. The scheme of photocatalytic mechanism of $SnO_2:Ga$ powders was also discussed.

Top-emission Electroluminescent Devices based on Ga-doped ZnO Electrodes (Ga-doped ZnO 투명전극을 적용한 교류무기전계발광소자 특성 연구)

  • Lee, Wun Ho;Jang, Won Tae;Kim, Jong Su;Lee, Sang Nam
    • Journal of the Semiconductor & Display Technology
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    • v.16 no.2
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    • pp.44-48
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    • 2017
  • We explain optical and electrical properties of top and bottom-emission structured alternating-current powder electroluminescent devices (ACPELDs) with Ga-doped ZnO(GZO) transparent electrode. The top-emission ACPELDs were layered as the metal electrode/dielectric layer/emission layer/top transparent electrode and the bottom-emission ACPELDs were structured as the bottom transparent electrode/emission layer/dielectric layer/metal electrode. The yellow-emitting ZnS:Mn, Cu phosphor and the barium titanate dielectric layers were layered through the screen printing method. The GZO transparent electrode was deposited by the sputtering, its sheet resistivity is $275{\Omega}/{\Box}$. The transparency at the yellow EL peak was 98 % for GZO. Regardless of EL structures, EL spectra of ACPELDs were exponentially increased with increasing voltages and they were linearly increased with increasing frequencies. It suggests that the EL mechanism was attributed to the impact ionization by charges injected from the interface between emitting phosphor layer and the transparent electrode. The top-emission structure obtained higher EL intensity than the bottom-structure. In addition, charge densities for sinusoidal applied voltages were measured through Sawyer-Tower method.

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A Three-layered Optical Waveguide of Second-order Orbital Angular Momentum Mode Guiding for Photonic Integrated Circuit (3층 구조를 가지는 광 집적회로용 2차 궤도 각운동량 광 도파로)

  • Lee, In-Joon;Kim, Sang-In
    • The Journal of the Korea institute of electronic communication sciences
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    • v.14 no.4
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    • pp.645-650
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    • 2019
  • In this paper, a specifically designed waveguide structure that can carry first, and second-order orbital angular momentum(: OAM) mode is proposed. The proposed optical waveguide consists of three Si stripes embedded in $SiO_2$, which is suitable for implementing on-chip integration and fabrication by standard thin film deposition and etching processes. The second-order OAM mode was generated by combining two eigenmodes, which are calculated by finite difference method(: FDM). The topological charge number of the first, and second-order OAM mode was calculated as l=0.9642 and 1.8766 respectively, which is close to the theoretical value.

Fabrication and Characterization of a Flexible PVDF Fiber-based Polymer Composite for High-performance Energy Harvesting Devices

  • Nguyen, Duc-Nam;Moon, Wonkyu
    • Journal of Sensor Science and Technology
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    • v.28 no.4
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    • pp.205-215
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    • 2019
  • A flexible polyvinylidene fluoride (PVDF)/polydimethylsiloxane (PDMS) composite prototype with high piezoelectricity and force sensitivity was constructed, and its huge potential for applications such as biomechanical energy harvesting, self-powered health monitoring system, and pressure sensors was proved. The crystallization, piezoelectric, and electrical properties of the composites were characterized using an X-ray diffraction (XRD) experiment and customized experimental setups. The composite can sustain up to 100% strain, which is a huge improvement over monolithic PVDF fibers and other PVDF-based composites in the literature. The Young's modulus is 1.64 MPa, which is closely matched with the flexibility of the human skin, and shows the possibility for integrating PVDF/PDMS composites into wearable devices and implantable medical devices. The $300{\mu}m$ thick composite has a 14% volume fraction of PVDF fibers and produces high piezoelectricity with piezoelectric charge constants $d_{31}=19pC/N$ and $d_{33}=34pC/N$, and piezoelectric voltage constants $g_{31}=33.9mV/N$ and $g_{33}=61.2mV/N$. Under a 10 Hz actuation, the output voltage was measured at 190 mVpp, which is the largest output signal generated from a PVDF fiber-based prototype.

2D Layered Ti3C2Tx Negative Electrode based Activated Carbon Woven Fabric for Structural Lithium Ion Battery (카본우븐패브릭 기반 2D 구조의 Ti3C2Tx 배터리음극소재)

  • Nam, Sanghee;Umrao, Sima;Oh, Saewoong;Oh, Il-Kwon
    • Composites Research
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    • v.32 no.5
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    • pp.296-300
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    • 2019
  • Two dimensional transition metal carbides and/or nitrides, known as MXenes, are a promising electrode material in energy storage due to their excellent electrical conductivity, outstanding electrochemical performance, and abundant functional groups on the surface. Use of $Ti_3C_2$ as electrode material has significantly enhanced electrochemical performance by providing more chemically active interfaces, short ion-diffusion lengths, and improved charge transport kinetics. Here, we reports the efficient method to synthesize $Ti_3C_2$ from MAX phase, and opens new avenues for developing MXene based electrode materials for Lithium-Ion batteries.

Charging of Sensor Network using Multiple Mobile Robots (다중 이동 로봇을 이용한 센서 네트워크의 충전)

  • Moon, Chanwoo
    • The Journal of the Convergence on Culture Technology
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    • v.7 no.2
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    • pp.345-350
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    • 2021
  • The maintenance of sensor networks, installed in a wide area has been an issue for a long time. In order to solve this problem, studies to supply energy to a sensor network using a robot has been carried out by several researchers. In this study, for a sensor network consisting of power nodes supplied with energy by multiple robots and sensor nodes around them, we propose a method of allocating a work area using a modified k-means algorithm so that the robots move the minimum distance. Through the simulation study using the energy transfer rate of the robot as a variable, it is shown that nodes of each allocated area can maintain survival, and the validity of the proposed modified k-means algorithm is verified.

Surface observation of Ni(OH)2 nanosheets fabricated by electrodeposition method (전착법에 의해 제작된 Ni(OH)2 나노 시트의 표면 관찰 및 분석)

  • Kim, Dong Yeon;Son, Injoon;Choi, Mun-Hyun
    • Journal of Surface Science and Engineering
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    • v.54 no.3
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    • pp.152-157
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    • 2021
  • The pseudocapacitor has a high energy density characteristic because it accumulates charges through a paradic redox reaction. However, due to its strong insulation properties, metal hydroxides should be designed as structural systems optimized for charge transfer to support fast electron transport. Also, Nickel material is weak to heat and is easily deformed when used as a cathode material, so stability must be secured. In this study, nickel hydroxide was produced by electrodeposition to secure the stability of nickel. Electrodeposition is a synthetic method suitable for growing optimized nickel hydroxide because it allows fine control. Nickel hydroxide (Ni(OH)2) is a metal hydroxide used as a pseudocapacitor anode due to its high capacitance, electrical conductivity and resistance. Therefore, in order to determine how Ni(OH)2 nanosheets are formed and what are the optimization conditions, various measurement methods were used to focus on structural growth of nanosheets produced by electrodeposition.

Highly ordered TiO2 nanotubes; Synthesis and applications (고도로 정렬된 TiO2 나노튜브의 제조와 활용)

  • Yoo, JeongEun;Lee, Kiyoung
    • Journal of Surface Science and Engineering
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    • v.55 no.1
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    • pp.1-8
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    • 2022
  • Titanium dioxide (TiO2) is one of the most intensively investigated materials in materials science. Mostly, TiO2 has been used in the form of nanoparticles, but recently new highly ordered TiO2 nanotubes (U-tube) has been introduced and applied to various applications due to their one-dimensional charge path way. In the present paper, we described the formation process and physical properties of U-tube then, gave examples of applications in sequence. Firstly, in photocatalysis, U-tube was used with Au/Pt co-catalysts and showed enhanced photogenerated H2 efficiency compared to bare TiO2. Secondly, photoelectrochemical performance of U-tube was evaluated with different heat-treatment temperatures. As a further application, two different types of electrical cell (Ti-TiO2-Pt and Ti-TiO2-PtNP) was configurated to observe memristive behavior of U-tube. Both cells behaved as switching electrodes and follow a memristive movement in the high and low resistance state extremely well with high reproducibility.

Spherical Silicon/CNT/Carbon Composite Wrapped with Graphene as an Anode Material for Lithium-Ion Batteries

  • Shin, Min-Seon;Choi, Cheon-Kyu;Park, Min-Sik;Lee, Sung-Man
    • Journal of Electrochemical Science and Technology
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    • v.13 no.1
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    • pp.159-166
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    • 2022
  • The assembly of the micron-sized Si/CNT/carbon composite wrapped with graphene (SCG composite) is designed and synthesized via a spray drying process. The spherical SCG composite exhibits a high discharge capacity of 1789 mAh g-1 with an initial coulombic efficiency of 84 %. Moreover, the porous architecture of SCG composite is beneficial for enhancing cycling stability and rate capability. In practice, a blended electrode consisting of spherical SCG composite and natural graphite with a reversible capacity of ~500 mAh g-1, shows a stable cycle performance with high cycling efficiencies (> 99.5%) during 100 cycles. These superior electrochemical performance are mainly attributed to the robust design and structural stability of the SCG composite during charge and discharge process. It appears that despite the fracture of micro-sized Si particles during repeated cycling, the electrical contact of Si particles can be maintained within the SCG composite by suppressing the direct contact of Si particles with electrolytes.

Gird Connected Modeling of Primary Frequency Recovery Reserve Provided by Electric Vehicle Considering Characteristics of Electric Vehicle Charge/Discharge Control Integrated Environment (전기자동차 충·방전제어 통합 환경을 고려한 전기차 1차 주파수 회복예비력의 계통연계형 모델링)

  • Kook, Kyung Soo;Lee, Jihoon;Moon, Jonghee;Choi, Wooyeong;Park, Kijun;Jang, Dongsik
    • KEPCO Journal on Electric Power and Energy
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    • v.7 no.2
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    • pp.249-254
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    • 2021
  • As the spreading speed of electric vehicles increases rapidly, those are expected to be able to use them as flexible resources in the power system beyond the concern for the supply of its charging power. Especially when the Renewable Energy sources (RES) which have no intrinsic control capability have replaced the synchronous generators more and more, the power system needs to secure the additional frequency control resources to ensure its stability. However, the feasibility of using electric vehicles as the frequency control resources should be analyzed from the perspective of the power system operation and it requires the existing simulation frameworks for the power system. Therefore, this paper proposes the grid connected modeling of the primary frequency control provided by electric vehicles which can be integrated into the existing power system model. In addition, the proposed model is implemented considering technical performances constrained by the characteristics of the Vehicle-Grid Integration (VGI) system so that the simulation results can be accepted by the power utilities operating the power system conservatively.