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Properties for the $CdIn_2Te_4$ Single Crystal

  • Hong, Kwang-Joon
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2004년도 추계학술대회 논문집 Vol.17
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    • pp.179-182
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    • 2004
  • The $p-CdIn_2Te_4$ single crystal was grown in the three-stage vertical electric furnace by using Bridgman method. The quality of the grown crystal has been investigated by the x-ray diffraction and the photoluminescence measurements. From the Photoluminescence spectra of the as-grown $CdIn_2Te_4$ crystal and the various heat-treated crystals, the $(D^{o},X)$ emission was found to be the dominant intensity in the photoluminescence spectrum of the $CdIn_2Te_4:Cd$, while the $(A^{o},X)$ emission completely disappeared in the $CdIn_2Te_4:Cd$. However, the $(A^{o},X)$ emission in the photoluminescence spectrum of the $CdIn_2Te_4:Te$ was the dominant intensity like an as-grown $p-CdIn_2Te_4$ crystal. These results indicated that the $(D^{o},X)$ is associated with $V_{Te}$ acted as donor and that the $(A^{o},X)$ emission is related to $V_{Cd}$ acted as acceptor, respectively. The $p-CdIn_2Te_4$ crystal was found to be obviously converted into the n-type after annealing in the Cd atmosphere. The origin of $(D^{o},\;A^{o})$ emission and its TO Phonon replicas is related to the interaction between donors such as $V_{Te}$ or $Cd_{int}$, and accepters such as $V_{Cd}$ or $Te_{int}$. Also, the In in the $CdIn_2Te_4$ was confirmed not to form the native defects because it existed in the stable form of bonds.

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다층배선 인터커넥트 구조의 기생 인덕턴스 추출 연구 (A Study on the Extraction of Parasitic Inductance for Multiple-level Interconnect Structures)

  • 윤석인;원태영
    • 대한전자공학회논문지SD
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    • 제39권7호
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    • pp.16-25
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    • 2002
  • 본 논문에서는 반도체 집적 회로의 다층 배선 인터커넥트 사이의 기생 인덕턴스를 수치 해석적으로 계산하여 추출하는 방법과 그 적용 예를 보고한다. 기생 인덕턴스를 추출하기 위하여, 3차원 다층배선 구조물에 대해 유한요소법을 이용하여 다층 배선내에서의 전위 분포 및 전류 밀도를 계산하고, 계산된 전류 밀도로부터 자계 에너지를 계산하여 상호 인덕턴스 및 셀프 인덕턴스를 계산하였다. 시뮬레이션 결과의 정확도를 검증하기 위하여 해석적 방법으로 해석이 가능한 간단한 구조에 대하여 시뮬레이션을 수행하여 결과를 비교하였으며, 또다른 응용으로, $13{\times}10.25{\times}8.25\;{\mu}m^3$ 크기의 4비트 룸 구조에 대하여 시뮬레이션을 수행하였다. 3차원 4비트 룸 구조물의 기생 인덕턴스 추출을 위해서, 유한요소법 적용을 위한 6,358개의 노드와 31,941개의 사면체 메쉬를 생성하였으며, ULTRA 10 워크스테이션에 대해서 소요된 CPU 시간은 약 2분 30초이었으며, 20 메가바이트의 메모리를 사용하였다.

양극산화처리를 통한 다공성 임플랜트 표면의 표면거칠기 증대에 대한 연구 (STUDY ON THE ENHANCING MICRO-ROUGHNESS OF POROUS SURFACED DENIAL IMPLANT THROUGH ANODIZATION)

  • 윤태호;송광엽
    • 대한치과보철학회지
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    • 제44권5호
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    • pp.617-627
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    • 2006
  • Statement of problem: HA has been used as a coating material on Ti implants to improve osteoconductivity. However. it is difficult to form uniform HA coatings on implants with complex surface geometries using a plasma spraying technique. Purpose : To determine if Ti6Al4V sintered porous-surfaced implants coated with HA sol-gel coated and hydrothermal treated would accelerate osseointegration. Materials and Methods : Porous implants which were made by electric discharge were used in this study. Implants were anodized and hydrothermal treatment or HA sol-gel coating was performed. Hydrothermal treatment was conducted by high pressure steam at $300^{\circ}C$ for 2 hours using a autoclave. To make a HA sol, triethyl phosphite and calcium nitrate were diluted and dissolved in anhydrous ethanol and mixed. Then anodized implant were spin-coated with the prepared HA sols and heat treated. Samples were soaked in the Hanks solution with pH 7.4 at $37^{\circ}C$ for 6 weeks. The microstructure of the specimens was observed with a scanning electron microscope (SEM), and the composition of the surface layer was analyzed with an energy dispersive spectroscope (EDS). Results : The scanning electron micrographs of HA sol-gel coated and hydrothermal treated surface did not show any significant change in the size or shape of the pores. After immersion in Hanks' solution the precipitated HA crystals covered macro- and micro-pores The precipitated Ca and P increased in Hanks' solution that surface treatment caused increased activity. Conclusion : This study shows that sol-gel coated HA and hydrothermal treatment significantly enhance the rate of HA formation due to the altered surface chemistry.

선박용 디젤엔진의 배기가스에 적용된 3 변 사이클의 열역학적 분석 (Thermodynamic Analysis of Trilateral Cycle Applied to Exhaust Gas of Marine Diesel Engine)

  • 최병철;김영민
    • 대한기계학회논문집B
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    • 제36권9호
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    • pp.937-944
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    • 2012
  • 선박의 주 추진용 디젤엔진에서 배출되는 배기가스의 폐열을 회수하는 발전시스템에 대하여, 작동유체로서 물이 적용된 3 변 사이클에 대한 열역학적 특성을 이론적으로 조사하였다. 그 결과로, 하나의 열원이 주어지면, 에너지 및 엑서지 효율은 터빈입구에서 작동유체에 대한 압력 및 온도의 특정한 조건에 의하여 최대화될 수 있었다. 그러한 조건에 대하여 응축온도의 증가에 따라, 터빈의 체적 팽창비를 적절하게 감소시킬 수 있었는데, 열원의 엑서지 손실률 및 응축기에서 엑서지 파괴율이 크게 증가되었다. 따라서, 상부 사이클에서 버려지는 엑서지를 회수하기 위하여, 저온 열원에 적합한 유기랭킨사이클을 하부 사이클로 적용하는 복합 사이클이 유용할 수 있다.

The Effect of Annealing Heat Treatment by Anodic Polarization Impedance Experiments for Cu-10%Ni Alloy

  • Lee, Sung-Yul;Moon, Kyung-Man;Jeong, Jae-Hyun;Lee, Myeong-Hoon;Baek, Tae-Sil
    • Journal of Advanced Marine Engineering and Technology
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    • 제39권5호
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    • pp.536-541
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    • 2015
  • Copper has been used extensively as an electric wire or as a base material in various types of machineries owing to its good electrical and thermal conductivity and good fabricating property, as well as its good corrosion resistance compared to iron. Furthermore, the copper-nickel alloy has significant corrosion resistance in severely corrosive environments. Although, cupro-nickel alloy shows better corrosion resistance than the brass and bronze series, this alloy also corroded in severely corrosive environments, including aggressive chloride ions, dissolved oxygen, and condition of fast flowing seawater. In this study, and annealing treatment at various annealing temperatures was carried out on the cupro-nickel (Cu-10%Ni) alloy, and the effects of annealing were investigated using electrochemical methods, such as measuring the polarization and impedance behaviors under flowing seawater conditions. The corrosion resistance increased by annealing compared to non heat treatment in the absence of flowing seawater. In particular, the sample annealed at $200^{\circ}C$ exhibited the best corrosion resistance. The impedance in the presence of flowing seawater showed higher values than in the absence of flowing seawater. Furthermore, the highest impedances was observed in the sample annealed at $800^{\circ}C$, irrespective of the present of flowing seawater. Consequently, the corrosion resistance of cupro-nickel (Cu-10%Ni) alloy in a severely corrosive environment can be improved somewhat by annealing.

프레스 금형 마모에 대한 음-초음파 신호 특성 분석 (Characterization of Acousto-ultrasonic Signals for Stamping Tool Wear)

  • 김용연
    • 한국소음진동공학회논문집
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    • 제19권4호
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    • pp.386-392
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    • 2009
  • This paper reports on the research which investigates acoustic signals acquired in progressive compressing, hole blanking, shearing and burr compacting process. The work piece is the head pin of the electric connector, whose raw material is the preformed steel bar. An acoustic sensor was set on the bed of hydraulic press. Because the acquired signals include the dynamic characteristics generated for all the processes, it is required to investigate signal characteristics corresponding to unit process. The corresponding dynamic characteristics to the respective process were first studied by analyzing the signals respectively acquired from compressing, blanking and compacting process. The combined signals were then periodically analyzed from the grinding to the grinding in the sound frequency domain and in the ultrasonic wave. The frequency of around 9 kHz in the sound frequency domain was much correlated to the tool wear. The characteristic frequency in the acoustic emission domain between 100 kHz and 500 kHz was not only clearly observed right after tool grinding but its amplitude was also related to the wear. The frequency amplitudes of 160 kHz and 320 kHz were big enough to be classified by the noise. The noise amplitudes are getting bigger, and their energy was much bigger as coming to the next regrinding. The signal analysis was based on the real time data and its frequency spectrum by Fourier Transform. As a result, the acousto-ultrasonic signals were much related to the tool wear progression.

이차전지 음극용 탄소 전극을 이용한 리튬이온 커패시터 연구 (Study of Lithium Ion Capacitors Using Carbonaceous Electrode Utilized for Anode in Lithium Ion Batteries)

  • 오례경;홍정의;양원근;류광선
    • 공업화학
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    • 제24권5호
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    • pp.489-493
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    • 2013
  • 기존의 EDLC용 활성탄소 대신 리튬이차전지용 탄소류 음전극(천연흑연, 인조흑연, 하드카본, MCMB)을 이용해 리튬이온 커패시터를 구성하면 리튬의 층간 삽입반응으로 인해 기존의 물질보다 에너지 밀도가 큰 전극소재를 개발할 수 있을 것이다. 이 실험에서는 기존 리튬이차전지 음극용 탄소 물질을 대칭 전극으로 사용하여 코인형 커패시터를 제조하여 성능을 측정하였다. 또한 리튬을 미리 삽입시킨 탄소류 전극을 이용한 커패시터를 제조한 후 성능을 측정한 결과, 축전현상이 일어나는 것을 알 수 있었다. 즉 전해액에서 전하분리에 의한 리튬이온의 이동을 보충할 수 있다면 기존의 리튬이온은 탄소류 전극의 층간으로 확산되어 들어가 기존의 대칭성 탄소류 전극의 경우에 비해 축전 용량이 증가한다. 또한 표면적이 매우 큰 graphene oxide를 사용하여 위와 같이 실험한 결과 용량이 크게 나왔으며 이로부터 슈퍼커패시터 전극용 물질에는 높은 비표면적이 중요한 요소로 작용한다는 것을 알 수 있었다.

친환경 하이브리드 동력 시스템 개발 및 농기계 응용 (Development of an Environmental Friendly Hybrid Power System and its Application to Agricultural Machines)

  • 김상철;홍영기;김국환
    • 제어로봇시스템학회논문지
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    • 제21권5호
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    • pp.447-452
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    • 2015
  • A hybrid power system was developed for agricultural machines with a 20kW output capacity, and it was attached to a multi-purpose cultivator to improve the performance of the cultivator. The hybrid system combined heterogeneous sources: an internal-combustion engine and an electric power motor. In addition, a power splitter was developed to simplify the power transmission structure. The cultivator using a hybrid system was designed to have increased fuel efficiency and output power and reduced exhaust gas emissions, while maintaining the functions of existing cultivators. The fuel consumption for driving the cultivator in the hybrid engine vehicle (HEV) mode was 341g/kWh, which was 36% less than the consumption in the engine (ENG) mode for the same load. The maximum power take off output of the hybrid power system was 12.7kW, which was 38% more than the output of the internal-combustion engine. In the HEV mode, harmful exhaust gas emissions were reduced; i.e., CO emissions were reduced by 36~41% and NOx emissions were reduced by 27~51% compared to the corresponding emissions in the ENG mode. The hybrid power system improved the fuel efficiency and reduced exhaust gas emissions in agricultural machinery. The hybrid system's lower exhaust gas emissions have considerable advantages in closed work environments such as crop production facilities. Therefore, agricultural machinery with less exhaust gas emissions should be commercialized.

$Cu_2ZnSnSe_4$ 태양전지의 적용을 위한 최적화 된 CdS 버퍼층 연구 (Optimization of CdS buffer layers for $Cu_2ZnSnSe_4$ thin-film applications)

  • 김지영;정아름;조윌렴
    • 한국태양에너지학회:학술대회논문집
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    • 한국태양에너지학회 2012년도 춘계학술발표대회 논문집
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    • pp.400-403
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    • 2012
  • $Cu_2ZnSnSe_4$(CZTSe) is emerged as a promising material for thin-film solar cells because of non-toxic, inexpensive and earth abundant more than $Cu(In,Ga)Se_2$ materials. For fabricating compound semiconductor thin-film solar cells, CdS is widely used for a buffer layer which fabricated by a chemical bath deposition method (CBD). Through the experiment, we controlled deposition temperature and mol ratio of solution conditions to find the proper grain 크기 and exact composition. The optimum CdS layers were characterized in terms of surface morphology by using a scanning electron microscope (SEM) and atomic force microscope (AFM). The optimized CdS layer process was applied on CZTSe thin-films. The thickness of buffer layer related with device performance of solar cells which controlled by deposition time. Local surface potential of CdS/CZTSe thin-films was investigated by Kelvin probe force microscopy (KPFM). From these results, we can deduce local electric properties with different thickness of buffer layer on CZTSe thin-films. Therefore, we investigated the effect of CdS buffer layer thickness on the CZTSe thin-films for decreasing device losses. From this study, we can suggest buffer layer thickness which contributes to efficiencies and device performance of CZTSe thin-film solar cells.

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더블 레이어 흡수기를 이용한 고온 태양열 메탄-이산화탄소 개질반응 (Solar CO2-Reforming of Methane Using a Double-Layer Absorber)

  • 김동연;이진규;이주한;서태범
    • 한국태양에너지학회:학술대회논문집
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    • 한국태양에너지학회 2012년도 춘계학술발표대회 논문집
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    • pp.267-273
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    • 2012
  • Solar reforming of methane with CO2 was successfully tested with a direct irradiated absorber on a parabolic dish capable of 5kWth solar power. And the new type of double-layer absorber-the front layer, porous metal foam which absorbs the radiation and transfers the heat from material to gas, and the back layer, catalytically-activated metal foam-was prepared, and its activity was tested by using electric furnace. Ni was applied as the active metal on the gamma-Al2O3 coated Ni metal foam for the preparation of the catalytically-activated metal foam layer. Compared to conventional direct irradiation of the catalytically activated metal foam absorber, this new type of double layer absorber is found to exhibit a superior reaction and thermal storage performance at the fluctuating incident solar radiation. In addition, unlike direct irradiation of the foam absorber, double layer absorber has better thermal resistance, which prevents the emergence of cracks caused by mechanical or thermal shock. The total solar power absorbed reached up to 3.25kW and the maximum CH4 conversion was almost 59%.

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