• Title/Summary/Keyword: Electreochemical impedance spectroscopy(EIS)

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An Experimental Study of the Corrosion Behavior Evaluation of Rebar in Concrete by Using Electrochemical Impedance Spectroscopy (EIS) Method (EIS를 이용한 콘크리트 내부 철근의 부식거동평가에 관한 실험적 연구)

  • Park, Jang-Hyun;Lee, Han-Seung
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.21 no.1
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    • pp.83-90
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    • 2017
  • The corrosion behavior of a rebar in concrete according to the amount of NaCl and $LiNO_2$ was observed by using Electrochemical Impedance Spectroscopy. The corrosion was accelerated in a short time by using dry/wet cycles method, which is one of the corrosion acceleration methods, and though the value of measured impedance, equivalent circuit can be introduced. It was confirmed that the passive film of a embedded rebar in concrete with NaCl was broken quickly, and when $0.6M\;LiNO_2$ was added, the velocity of ongoing corrosion was declined considerably compared to the amount of NaCl. However, when $1.2M\;LiNO_2$ was added, it was confirmed that the passive film was not broken and its performance remained, compared to the amount of NaCl.

An Experimental Study on Corrosion Behavior in Steel of Concrete Applied with Arc Metal Spray Method Surface Treatment Technology Using EIS (EIS를 이용한 아크 금속용사 표면처리기법이 적용된 강재의 콘크리트 내 부식 거동에 관한 실험적 연구)

  • Yoon, Chang-Bok;Park, Jang hyun;Lee, Han-Seung
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.24 no.3
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    • pp.87-95
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    • 2020
  • As an experimental study on the corrosion behavior of steel materials to which ATMS method using EIS was applied in concrete, immersion of Ca(OH)2 saturated aqueous solution and NaCl aqueous solution simulating the environment inside concrete The corrosion behavior was tested. The equivalent circuit was derived through the analysis of the Nyquist plot, and the interfacial resistance and the polarization resistance of the Ca(OH)2 aqueous solution were compared, and Al ATMS was the best interfacial resistance and Zn ATMS was the best polarization resistance. After burying ATMS steel material of cement mortar, the initial immersion impedance measurement value was the highest in the Zn ATMS test body in the impedance measurement by the immersion time by immersing it in the NaCl aqueous solution. Al ATMS test piece has the highest impedance and is highly reliable. This is because Al, which has a high ionization tendency, is continuously oxidized in a strong alkaline environment to form a film and protect the steel from permeation of chlorine ions.