• Elastomers and Composites
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• v.44 no.1
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• pp.22-33
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• 2009

Recently, elastomer-nanocomposites reinforced with low volume fraction of nanofillers have attracted great interest due to their fascinating properties. The incorporation of nanofillers, such as, layered silicate clays, carbon nanotubes, nanofibers, calcium carbonate, metal oxides or silica nanoparticles into elastomers improves significantly their mechanical, thermal, dynamic mechanical, barrier properties, flame retardancy, etc. The properties of nanocomposites depend greatly on the chemistry of polymer matrices, nature of nanofillers, and the method in which they are prepared. The uniform dispersion of nanofillers in elastomer matrices is a general prerequisite for achieving desired mechanical and physical characteristics. In this paper, current developments in the field of elastomer nanocomposites reinforced with layered silicates, silica, carbon nanotubes, nanofibers and various other nanoparticles have been addressed.

• Textile Coloration and Finishing
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• v.35 no.3
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• pp.159-168
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• 2023

Polyolefin elastomer (POE) is widely used in a variety of applications, particularly in the manufacture of composites, due to its excellent mechanical properties, chemical resistance, and flexibility. However, POE has a high processing temperature, which causes damage to the fiber during the manufacturing process when impregnating the fiber. Therefore, ethylene vinylacetate (EVA), which has a low melting point and excellent adhesion properties, is blended with POE to reduce the processing temperature, and POE-g-MAH (Polyolefin elastomer-grafted-maleic anhydride) is used as a compatibilizer to further improve the POE/EVA blend properties. The compatibility of POE/EVA blends is observed by SEM, and the interaction between each polymer is confirmed by DSC and FT-IR. In addition, the effect of adding the compatibilizer is analyzed through mechanical properties such as tensile strength and elongation. The optimal content of compatibilizer for POE/EVA blends considering physical properties and moldability is sought, and 20 phr is determined to be the most appropriate.

• Nuclear Engineering and Technology
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• v.53 no.12
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• pp.4142-4149
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• 2021

In the radiation protection application, the metal-polymer composites have been developed for their radiation shielding properties. In this research, the elastomer composites doped by 10 ㎛ and 100nm size of lead, bismuth and tungsten particles as filler with 30 and 60 wt percentages were prepared. To survey the shielding properties of the polymer composites using gamma-ray emitted from 152Eu and 137Cs sources, the gamma flux was measured by using NaI(Tl) detector, then the linear attenuation coefficient was calculated. Also, the Monte Carlo simulation (MCs) method was used. The results showed a direct relationship between the linear attenuation coefficients of the absorbent and filler ratio. Also, the decrease in the particle size of the shielding material in each weight percentage improved the radiation shielding features. When the dimension of the particles was in the order of nano-size, more attenuation was achieved. At low energies used for medical diagnostic X-ray applications due to the predominance of the photoelectric effect, bismuth and lead were suitable selection as filler.

• Proceedings of the Korean Fiber Society Conference
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• 2001.10a
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• pp.320-323
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• 2001

일반적으로 고분자 재료는 그 자체로는 전기가 통하지 않는 전기절연체이나 여기에 카본블랙, 카본파이버, 금속분말 등 전도성을 가지는 입자들을 가지고 도핑할 경우 전기가 통하는 반도체 특성을 지니는 재료로 변화를 한다. 특히, 전기ㆍ전자재료 분야에서 이러한 특성을 이용한 재료 중 하나인 PTC 소자는 나노 크기를 가지는 카본 블랙과 고분자 재료의 복합화를 바탕으로 하여 과전류에 의한 발열의 감지 및 전류를 차단함으로서 회로를 보호하는 소자를 말하는 것으로서 현재 그 수요량이 급격히 증대하고 있는 기능성 재료중 하나이다. (중략)

• Polymer(Korea)
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• v.36 no.6
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• pp.721-726
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• 2012

Thermoplastic polyurethane (TPU) elastomer is used as an encapsulant in undersea sonar devices. A new material for sonar encapsulant exhibiting better mechanical strength than TPU along with a lower swelling ratio for seawater and oil is required to prolong its application. TPU grafted silica nanoparticles (TPU-g-silica) were prepared and then they were melt mixed with TPU to fabricate desirable composites for underwater applications. The composite containing silica nanoparticles exhibited better tensile strength and lower swelling ratios in the seawater and oil than TPU regardless of the surface treatment of the silica particles. At fixed silica content in the composite, the TPU/TPU-g-silica composite exhibited better tensile strength and lower swelling ratio than the TPU composite with the pristine silica particles. Furthermore, the TPU/TPU-g-silica composite exhibited enhanced tensile strength as compared to TPU after being impregnated with oil.

• Composites Research
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• v.26 no.5
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• pp.289-294
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• 2013

A thinner is used to improve the multi-walled carbon nano-tube (CNT) and carbon black (CB) dispersion in a polymer matrix and to make a soft electrode. The electrical and mechanical properties of the soft electrodes are investigated as functions of CNT, CB and thinner content. The optimal mixing condition for the electrode is thinner 80, CNT 3.5, CB 18 (phr) on the basis of matrix (KE-12). The specific resistance of that is 73 (${\Omega}{\cdot}cm$), and tensile strength, tensile modulus, and elongation of that is 0.45 MPa, 0.21 MPa, and 184%, respectively. Also, a simple structure of the actuator with an optimized electrode and elastomer is fabricated and its characteristic is evaluated. At the operating voltage 25 kV, the displacement of an elastomer KE-12 is 2.24 mm, and that of an elastomer KE-12 with thinner 50 (phr) is 4.05 mm. It shows a higher displacement compared to that of 3M 4910 which has similar modulus. The actuator made with elastomer and electrode of the same material (KE-12) may have advantages for fatigue life and application.

• Elastomers and Composites
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• v.43 no.2
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• pp.63-71
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• 2008

Up to now, most of researches and practical applications of polymeric elastomers have been focused on rubber, a type of elastomeric materials. Therefore, it has been widely accepted that rubber industry is tire industry. In this review, we would like to illuminate new emerging technologies of elastomers. Among many examples, there are actuators which can transform their mechanical shapes with respect to the surrounding environments. Paper folding (so called "origami" in Japanese) technology can be another good example. Utilizing paper folding technology, three-dimensional (3D) architectures containing multi-functions can be constructed from programmed 2D structures. Elastomer microlens can also be fabricated using lithography technologies combined with chemical reactions.

• Elastomers and Composites
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• v.38 no.2
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• pp.122-127
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• 2003

Compounding, using such thermoplastic elastomer as styrene-ethylene-butadiene-styrene (SEBS) blended with polypropylene(PP), oil, and other ingredients, was studied to develop a new material with excellent impact resistance and resilience for the replacement of environmentally toxic PVC sheet. Hardness decreased linearly with oil content in the SEBS/oil blend, and the tensile strength increased with PP content whereas elongation showed no effects over 50 phr of PP in SEBS/oil/PP blend. In the practical SEBS composition, proposed to replace the PVC sheet material, tensile and tear strength, as well as hardness, increased proportionally with PP content, while melt index decreased.

• Elastomers and Composites
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• v.36 no.2
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• pp.86-93
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• 2001

For solving the environmental problem of the waste EPDM and for new TPE blend materials, we developed a new kind of TPE material using a co-rotating twin screw extruder. To improve the mechanical properties of TPE material such as tensile strength, elongation at break, and modulus of the blend, PP and waste EPDM powder were blended with different screw configurations. The mechanical properties of the blends and morphology of the TPE were investigated. As the number of kneading disc and left-handed screw element increased, dynamic vulcanization of the material was increased because the shear stress and residence time of blends increased.

• Elastomers and Composites
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• v.46 no.1
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• pp.2-9
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• 2011

Permeability to gases and vapors is an important function in tires, rubber tubes and diaphragms. It mainly depends on the rubber material. Generally, permeability increases in the following order: silicone rubber > NR > EPDM > SBR > NBR > FPM > ECO > IIR. And, for an elastomer permeability is also very much dependent on compounding. Many research works are reported in the area of gas permeability for formed rubber,$^{1-7}$ however, few studies are found for unformed elastomer products. Incorporation of nano-particles, use of thermoplastic elastomers and applying high barrier multilayer coatings are the main approaches to obtain a high barrier elastomeric product. In this paper, barrier article for vehicle is introduced.