• Title/Summary/Keyword: Effluents

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Fenton난s Reagent Oxidation of Refractory Organics in Petrochemical Plant Effluent (석유화학공장 방류수내 난분해성 유기물의 Fenton 산화처리)

  • Lee, Kyu-Hoon;Jung, Dae-Young;Park, Tae-Joo
    • Journal of Environmental Science International
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    • v.5 no.1
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    • pp.51-59
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    • 1996
  • The purpose of this study was to evaluate the partial oxidation of the biological treatment plant effluents using Fenton's reagent as a pretreatment step prior to a tertiary biological oxidation of these effluents. Fenton's reagent was evaluated as a pretreatment process for inhibitory or refractory organics. Based on the Fenton oxidation system, the petrochemical wastewater treatment plant effluent was shown to have significant improvement in toxicity after oxidation with hydrogen peroxide. For example, at ranee of 42 ∼ 184 mg/L COD of petrochemical plant effluents, the COD removal efficiencies were from 38.2% to 60.1% after reaction with hydrogen peroxide 200 mg/L and Fe2+ 100 mg/L and reaction time was 30 minutes. The total TOC reduction were about 15.8∼22.4% with same test condition and difference between the overall removal rate and BOD/COD ratio after Fenton's oxidation estabilished in the biodegradation and otherwise meets the discharge standard or reuse for cooling tower make-up water.

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Bleaching of Oak Kraft Pulp by O, Eo and C/D Stage (O, Eo 및 C/D단계를 이용한 신갈나무 크라프트펄프표백)

  • 김동호;백기현
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.29 no.3
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    • pp.43-50
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    • 1997
  • The purpose of this study was to decrease pollutants of effluents from KP bleaching. Multistage bleaching that combined with O, Eo, and C/D stage was conducted, after optimum bleaching conditions of O, Eo, and C/D stage were determined. Moreover the properties for bleached pulps and pollution level of bleaching effluent were measured by each standard method. Due to increase on the brightness and delignification of pulps by O, Eo, and C/D stage bleaching. It was possible that bleaching sequences were reduced from five stage to four stage. In addition to, OC/DEoD and OC/DEopD bleaching sequences had higher brightness than CEDED bleaching sequence. The pulps bleached by O and Eo stage had higher in tensile index than conventional bleaching sequences with the similar results in burst and tear index. While each bleaching sequences had little differences, bleaching sequences with Eo stage had higher in physical properties than with Eop stage. The pollution level measured by Chemical Oxygen Demand(COD), Biochemical Oxygen Demand(BOD) and Color of bleaching effluents were much lower in combined bleaching sequences of O, Eo and C/D stage than that of CEDED sequence. Particularly, a pollution index of bleaching effluents generated by C/DEoDEB and OC/DEopDED bleaching sequences were lower than that from the other bleaching sequences.

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New methodologies to derive discharge limits considering operational flexibility of radioactive effluents from Korean nuclear power plants based on historical discharge data

  • Kang, Ji Su;Cheong, Jae Hak
    • Nuclear Engineering and Technology
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    • v.54 no.3
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    • pp.1003-1015
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    • 2022
  • The new methodologies to derive discharge limits considering operational flexibility according to international safety standards were developed to help reduce the environmental releases of radioactive effluents from nuclear power plants (NPPs). To overcome the limitations of the two existing methods to set up discharge limits assuming a specific statistical distribution of the effluent discharge, two modified equations were newly proposed to directly derive a particular discharge limits corresponding to the target 'compliance probability' based on the actual annual discharge data for a specific NPP and radionuclide groups. By applying these to the actual yearly discharge data of 14 Korean NPPs for 7 radionuclide groups for the past 20 years, the applicability of two new methodologies to actual cases was demonstrated. The 'characteristic value' with approximately a 90% compliance probability for each Korean NPP and radionuclide group was proposed based on the results. The new approaches for setting up the discharge limits and the characteristic values developed in this study are expected to be effectively utilized to foster operator's efforts to progressively reduce the environmental releases of radioactive effluents of NPPs relative to the previous discharge data considering operational flexibilities.

Practical Radiation Safety Control: (II) Application of Numerical Guidance for the Discharges of Radioactive Gaseous and Liquid Effluents (방사선안전관리 실무: (II) 배기중 및 배수중 배출관리기준의 적용)

  • Kim, Hyun Kee
    • Journal of Radiation Protection and Research
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    • v.39 no.1
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    • pp.61-64
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    • 2014
  • Radioactive materials are in use and have many applications from the generation of electricity to the purposes of research, industry and medicine such as diagnosis and therapy. In the course of their use some of radioactive substances may be discharged into the environment from facilities using the unsealed radioactive materials, which are main artificial sources occurring the public exposure. Discharges are in the form of gases, particles or liquids. This paper provides procedures to estimate the level of the public exposure based on the conservative assumptions and simple calculations in the facility using unsealed liquid sources. They consist of two processes; (1) to calculate maximum concentration of gaseous effluents discharged through the exhaust pipe and average concentration of liquid effluents discharged through the drain of the storage tank, (2) to compare each of them to numerical guidances for the discharges of radioactive gaseous and liquid effluents mentioned in the related notification. For this purpose followings are assumed properly; daily usage, form and dispersion rate of radionuclides, daily amount of radioactive liquid waste and exhaust and drainage equipment. The procedures are readily applicable to evaluate environmental effects by planned effluent discharges from facilities using the unsealed radioactive materials. In addition they may be utilized to obtain practical requirements for radiation safety control necessary for the reductions of the public exposure.

Influences of Thermal Effluents on the Epilithic Algal Community in Small Stream Originating from the Seokjung Hot Spring (온천 배수 유입에 따른 소형 하천의 생태계 변화와 회복에 관한 연구 -소형 하천에서 온천 배수가 부착조류 군집에 미치는 영향)

  • 정연태;문연자;김미연;최민규;길봉섭
    • Korean Journal of Environmental Biology
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    • v.17 no.3
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    • pp.345-358
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    • 1999
  • To study the influences of thermal effluents flowing from hot spring on epilithic algal community, seasonal survey was carried out at stream and its watersheds from Seokjeong hot spring in Chollabuk-Do, Korea. Totally 7 points were divided into three regions fur sampling of water and epilithic algae, such as the direct effected, uneffected and the mixed region, respectively. At the discharging points of effluents, a dark-green cyanobacterial mat were remarkably constructed, mainly by two cyanobacteria, Oscillatoria and Phormidium. The mat formation were more obvious at low temperature than any other season, and even result in disappear with downstream and season. Totally, one hundred and fifty-three taxa of epilithic algae were classified with 15 unidentified species. Among the, diatoms occupied 58% of total species, whereas cyanobacteria was 67% of total biomass, comparatively. In terms of stream direction, relative abundance of cyanobacteria was only limited in the upstream in cold season, and result in this pattern disappeared with season change. Although all physicochemical variables at the discharging points, was very high, compare to other points, they were quickly decreased downstream. Among them, some heavy metals were not detected or below the detection levels at downstream. Nitrate nitrogen increased with downstream, as well as phosphorus and sulfate have a similar trend throughout, while ammonia quickly decreased in the initial period of discharging effluents. This suggest that although the thermal effluent with high temperature and organic compounds could polluted the small study stream, various contributions such as flowing water, intake of uneffected streawater and collaboration of cyanobacterial mat and stream bottom gradually induces a stable water system.

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Characteristics of Organics and Ammonia Nitrogen Discharged by Pollution Source from Human Living (생활계 오염원의 유기물 및 암모니아성 질소 배출특성 평가)

  • Han, Song-Hee;Kim, Yo-Yong;Sung, Yeon-Gook;Park, Ik-Beom;Cho, Deok-Hee;Nam, Woo-Kyung;Kim, Chang-Gyu;Oh, Jo-Kyo
    • Journal of Korean Society on Water Environment
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    • v.31 no.4
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    • pp.377-386
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    • 2015
  • The purpose of this research was to suggest the water quality improvement in streams by evaluating the distribution characteristics of organics and ammonia nitrogen discharged by pollution sources from human living. The public sewage treatment plants'(PSTPs) effluents and the waters from streams in Gyeonggi-do were sampled and analyzed. Nitrogenous oxygen demand (NOD) was measured for the stream waters as well as the PSTPs effluents, and the correlations of NOD and $NH_3$-N, $NH_3$-N and water temperature in the PSTPs effluents were confirmed. In the case of the stream waters, the ratios of NOD to BOD and $NH_3$-N increased in the downstream sites after discharging the PSTPs effluents. As a result of statistical analysis of $NH_3$-N concentrations for the national water quality monitoring streams in Gyeonggi-do, $NH_3$-N showed the non-normal distribution which were biased to the left, but showed the considerable level because of higher coefficient of variation. Therefore, it is required to establish the water quality standard for the $NH_3$-N as a new parameter for judging the quality of the streams. In addition, inducing complete nitrification and introducing a logical standard setting system are needed to improve the water quality of streams by identifying distribution of the nitrogen components from PSTPs effluents.

Seasonal Variation of Thermal Effluents Dispersion from Kori Nuclear Power Plant Derived from Satellite Data (위성영상을 이용한 고리원자력발전소 온배수 확산의 계절변동)

  • Ahn, Ji-Suk;Kim, Sang-Woo;Park, Myung-Hee;Hwang, Jae-Dong;Lim, Jin-Wook
    • Journal of the Korean Association of Geographic Information Studies
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    • v.17 no.4
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    • pp.52-68
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    • 2014
  • In this study, we investigated the seasonal variation of SST(Sea Surface Temperature) and thermal effluents estimated by using Landsat-7 ETM+ around the Kori Nuclear Power Plant for 10 years(2000~2010). Also, we analyzed the direction and range of thermal effluents dispersion by the tidal current and tide. The results are as follows, First, we figured out the algorithm to estimate SST through the linear regression analysis of Landsat DN(Digital Number) and NOAA SST. And then, the SST was verified by compared with the in situ measurement and NOAA SST. The determination coefficient is 0.97 and root mean square error is $1.05{\sim}1.24^{\circ}C$. Second, the SST distribution of Landsat-7 estimated by linear regression equation showed $12{\sim}13^{\circ}C$ in winter, $13{\sim}19^{\circ}C$ in spring, and $24{\sim}29^{\circ}C$ and $16{\sim}24^{\circ}C$ in summer and fall. The difference of between SST and thermal effluents temperature is $6{\sim}8^{\circ}C$ except for the summer season. The difference of SST is up to $2^{\circ}C$ in August. There is hardly any dispersion of thermal effluents in August. When it comes to the spread range of thermal effluents, the rise range of more than $1^{\circ}C$ in the sea surface temperature showed up to 7.56km from east to west and 8.43km from north to south. The maximum spread area was $11.65km^2$. It is expected that the findings of this study will be used as the foundational data for marine environment monitoring on the area around the nuclear power plant.

Production of Bleach-Stable and Halo-Tolerant Alkaline Protease by an Alkalophilic Bacillus pumilus JB05 Isolated from Cement Industry Effluents

  • Johnvesly, B.;Naik, Gajanan R.
    • Journal of Microbiology and Biotechnology
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    • v.11 no.4
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    • pp.558-563
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    • 2001
  • A new alkalophilic strain of Bacillus pumilus JB¬05 producing bleach-stable and halo-tolerant alkaline protease was isolated from cement industry effluents in Karnataka, India. The effects of carbon and nitrogen sources on protease production by this alkalophilic strain were observed after a 30-h incubation. A high level of alkaline protease activity was obtained in the presence of starch as the carbon and peptone as the nitrogen sources. The partially purified enzyme showed an optimum temperature and pH activity at $58^{\circ}C$ and 10.5, respectively. The enzyme was completely inhibited by PMSF (95.0%) indicating it as a serine protease. It is bleach-stable as it retained 35% original activity in the presence of 10% (v/v) hydrogen peroxide at $30^{\circ}$C after 2 h and is halo-tolerant as it retained 70% original activity in the presence of 2.5 M sodium chloride at $30^{\circ}C$ after 2 h incubation.

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Adsorptive Removal of Acid Green 20 from Aqueous Solutions by Biomass Ash and Activated Carbon

  • Purai, Abhiti;Rattan, V.K.
    • Carbon letters
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    • v.10 no.2
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    • pp.131-138
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    • 2009
  • Study on the removal of Acid Green 20 by adsorption on indigenously prepared activated carbons from cow dung, mango stone, parthenium leaves and commercial activated carbon have been carried out with an aim to obtain information on treating effluents from tanneries. The effects of various experimental parameters have been investigated by following the batch adsorption technique. Adsorption data was modeled with the Freundlich and Langmuir isotherms. Removal of Acid Green 20 was found to be favorable using Biomass ash and could be considered as alternatives to commercial activated carbon for the treatment of tannery effluents, especially for the removal of dye(s).