• Journal of Korean Society on Water Environment
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• v.23 no.1
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• pp.27-32
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• 2007

This study focused on estimating the feasibility of a strong basic anion exchanger (PA312OH) as a sorbent for the removal of residual reactive dye and saving chemicals and water. Cellulose reactive dye C.I.RB49 was tested because reactive dye is the largest single group of dyes and that dye needs larger amount of inorganic salts as dyeing agent but nearly 50% of reactive dyes may be lost to the effluent. The adsorption characteristics of PA312OH for C.I.RB49 were as follows. Ion-selectivity among the dye and inorganic salts was Dye > ${SO_4}^{2-}$ > ${CO_3}^{2-}$ > $Cl^-$. C.I.RB49 was exchanged more than 3 times ${SO_4}^{2-}$ and ${CO_3}^{2-}$ and $Cl^-$ was not exchanged absolutely. The exchanging velocity was increased exponentially with increasing temperature. This result is positive effect on treating the high temperature dyeing process wastewater. The exchanged dye percents to initial were 96.8% and 99% at flow rate 20.5 mL/min. and 3.7 mL/min.. The exchanging capacity of PA312OH for C.I.RB49 was 215.2 mg/g at conc.=369.2 mg/L, Temp.=$25^{\circ}C$. 74% inorganic salts were recrystallized from real dark reactive color dyeing wastewater treated with PA312OH.

• Journal of Korean Society on Water Environment
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• v.33 no.6
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• pp.650-660
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• 2017

In this study, pollutant emission characteristics by water damage period analyzed 11 items (water temperature, pH, DO, EC, BOD, COD, TOC, SS, T-N, T-P and flow) with load duration curve, time series load curve and factor analysis for three years (2014-2016). Load duration curve is applied to judge the level of impaired waterbody and estimate impaired level by pollutants such as BOD and T-P in this study depending on variation of stream flow. Water quality standard exceeded the flow of mid-range and low-range by flow condition evaluation using load duration curve. This watershed was influenced by point source more than non-point source. Cumulative excess rate of BOD and T-P kept water quality standard for all seasons (spring, summer, autumn and winter) except BOD 59% in spring. Water quality changes were influenced by pollutants of basic environmental treatment facilities and agricultural areas during spring and summer. Results of factor analysis were classified commonly first factor (BOD, COD, and TOC) and second factor (flow, water temperature and SS). Therefore, effects of artificial pollutants and maintenance water must be controlled seasonally and reduced relative to water damage caused by point pollution sources with effluent standard strengthened in the target watershed.

• Journal of Wetlands Research
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• v.12 no.3
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• pp.39-47
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• 2010

Annually, the scale of agricultural areas in Korea were being reduced as the lands were converted to other land uses. While the rate of productivity were either being maintained or increased, the pollution load from these areas were still greater in magnitude. Although the levels of pollutant concentration released in the agricultural watersheds were minimal, the combined quantities mostly from diffuse sources were high. As a consequence, the Ministry of Environment (MOE) in Korea adopted the use of free water surface (FWS) flow constructed wetlands to reduce the pollutant loadings emitted from agricultural watersheds for the improvement of water quality and protection of aquatic ecosystems. In this study, a constructed wetland treating stream water in an agricultural watershed was monitored since April 2009 subsequent to its completion in December 2008. Satisfactory performance was achieved for TSS, BOD and TP with 26%, 28% and 39% pollutant removal rates, respectively. In addition, the effluent water quality was improved and achieved compliance the national water quality criteria. Results of this study can be useful to establish design parameters and employ proper removal techniques of similar natural treatment systems for future implementation in the country.

• KSBB Journal
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• v.20 no.2 s.91
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• pp.100-105
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• 2005

Removal of nitrogen compound from waste water is essential and often accomplished by biological process. Denitrification bacterium, Paracoccus denitrificans (KCTC 2350) is employed to estimate the denitrification ability and the characteristics. In the immobilized biological reactor system, the measurement of absolute amount of active strain in the reactor is comparatively difficult or impossible. In this. study, a reactor was designed with the unwoven texture wrapped peep holed plastic tube to calculate the absolute amount of active strain by comparing the activity of the permeabilized and or immobilized reactor and the free cell reactor The reactor system was continuous stirred tank reactor and the reaction rate of substrate consumption was assumed to satisfy the Michaelis-Menten equation. The effluent concentration of nitrate and nitrite was measured to estimate the apparent parameter of Michaelis-Menten equation. As a result, we found that the amount of immobilized active strain was figured out to be half of the total active strain in the reactor and the time required to be reached in the equilibrium state in the permeabilized and or immobilized reactor system was figured out to be shorter than that of the free cell reactor system.

• Solar Energy
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• v.18 no.3
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• pp.197-203
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• 1998

A 5 ton/day pilot scale two-phase anaerobic digester was constructed and tasted to treat Korean food wastes in Anyang city. The process was developed based on 3 years of lab-scale experimental results on am optimim treatment method for the recovery of biogas and humus. Problems related to food waste are ever Increasing quantity among municipal solid wastes(MSW) and high moisture and salt contents. Thus our food waste produces large amounts of leachate and bed odor in landfill sites which are being exhausted. The easily degradable presorted food waste was efficiently treated in the two-phase anaerobic digestion process. The waste contained in plastic bags was shredded and then screened for the removal of inert material such as fabrics and plastics, and subsequently put into the two-stage reactors. Heavy and light inerts such as bones, shells, spoons and plastic pieces were again removed by gravity differences. The residual organic component was effectively hydrolyzed and acidified in the first reactor with 5 days space time at pH of about 6.5. The second, methanization reactor part of which is filled with anaerobic fillters, converted the acids into methane with pH between 7.4 to 7.8. The space time for the second reactor was 15 days. The effluent from the second reactor was recycled to the first reactor to provide alkalinities. The process showed stable steady state operation with the maximum organic rate of 7.9 $kgVS/m^3day$ and the volatile solid reduction efficiency of about 70%. The total of 3.6 tons presorted MSW containing 2.9 tons of food organic was treated to produce about $230m^3$ of biogas with 70% of methane and 80kg humus. This process is extended to full scale treating 15 tons of food waste a day in Euiwang city and the produced biogas is utilized for the heating/cooling of adjacent buildings.

• Journal of Korean Society on Water Environment
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• v.24 no.1
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• pp.91-98
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• 2008

This work was performed to develop a model possible to predict the influent flow and influent components, which are one of main disturbances causing process problems at the operation of municipal wastewater treatment plant. In this study, artificial neural network (ANN) was used in order to develop a model that was able to predict the influent flow, $COD_{Mn}$, SS, TN 1 day-ahead, 2day-ahead and 3 day ahead. Multi-layer feed-forward back-propagation network was chosen as neural network type, and tanh-sigmoid function was used as activation function to transport signal at the neural network. And Levenberg-Marquart (LM) algorithm was used as learning algorithm to train neural network. Among 420 data sets except missing data, which were collected between 2005 and 2006 at field plant, 210 data sets were used for training, and other 210 data sets were used for validation. As result of it, ANN model for predicting the influent flow and components 1-3day ahead could be developed successfully. It is expected that this developed model can be practically used as follows: Detecting the fault related to effluent concentration that can be happened in the future by combining with other models to predict process performance in advance, and minimization of the process fault through the establishment of various control strategies based on the detection result.

• Journal of Wetlands Research
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• v.22 no.4
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• pp.321-327
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• 2020

Recently The amount of wastewater and linked wastewater is being increased every year due to industrial development, population growth, and improvement in living standards. Linked wastewater shows the feature-low flow rate and high concentration. Therefore, it has been shown that it has a great impact on the operation of the sewage treatment plant and costs a lot for treating linked wastewater. In this study, a scenario with low increase of water quality when the total amount of the inflow of linked wastewater was entered into individual reactors is obtained. According to the result of modeling, The effluent water quality get the least increment once the water was introduced into the influent and anoxic tank. We generated the various scenarios Based on these results. scenarios are varying according to inflow from linked waste water's distribution ration. As a result of modeling through various scenarios, it was found that the increment of TN and TP were at the least when the inflow of linked water was distributed with ratio between sewage (80%) and oxygen-free tank (20%).

• Journal of Korean Society for Atmospheric Environment
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• v.14 no.E
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• pp.19-25
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• 1998

Adsorption characteristics of DMMP and IMPF were investigated using dynamic adsorption method. Adsorbate vapor was forced to Pass at fixed flow rate of 4 mg/I through Cu Cr impregnated activated carbon column at several different flow velocities until the effluent concentrations exceeded 4.0$\times$10$^{-5}$ mg/I. The kinetic adsorption capacity, adsorption kinetic constant, and critical bed weight of the activated carbon were determined for DMMP and IMPF vapors by plotting breakthrough time as a function of carbon weight. A mathematical expression was deduced from our experimental data to represent the relationships between kinetic adsorption capacity and flow velocity. According to our experimental results, the lifetime of DMMP was longer than that of IMPF under the same conditions. Their relationship can be expressed empirically as follows: Tb(DMMP) ＝ 0.9825$\times$Tb(IMPF)-15.368

• YAKHAK HOEJI
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• v.42 no.5
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• pp.473-479
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• 1998

Lovastatin (LOVA), a fungal metabolite isolated from cultures of Aspergillus terreus, is a competitive HMG-CoA reductase inhibitor used for the treatment of primary hyper cholesterolemia, and has also been shown to suppress growth in a variety of non-glioma tumor cell lines. A sensitive reversed-phase high-perfonnance liquid chromatographic method with ultraviolet (UV) absorbance detection has been developed to quantitate LOVA in human plasma and urine samples using liquid-liquid extraction procedure. Baseline separation of LOVA and internal standard, simvastatin was achieved on a Novapak $C_{18}$ analytical column with a mobile phase containing 0.025M $NaH_2PO_4$: CAN (35:65, v/v%), adjusted pH to 4.5. The flow rate was set at 1.5ml/min, and the column effluent was monitored by a UV detection at 238nm. The limit of quantification was determined to be 0.5${\mu}$g/ml while extraction efficiency of LOVA ranged from 73.4-82.9% at LOVA concentrations of 0.5 to 10${\mu}$g/ml. Good linearity with correlation coefficients greater than 0.999 was obtained in the range of LOVA concentrations from 0.5 to 10${\mu}$g/ml. The accuracy and the precision were proven excellent with relative standard deviation (RSD, %) and relative error (RE, %) of less than 4.2 and 4.0, respectively. Intraday precision, evaluated at five LOVA concentrations (0.5, 1, 2, 5, 10${\mu}$g/ml) and expressed as RSD ranged from 0-1.82% while the interday precision at the same concentrations ranged from 0.7-10.5%. The analytical method described was then successfully employed for the determination of LOVA concentrations in plasma samples obtained during a phase II clinical trial using high doses of LOVA (30-40mg/kg/day). This method could be further utilized for the ongoing pharmacolkinetic studies and therapeutic drug monitoring of the high-dose LOVA therapy in adenocarcinoma patients.

• Journal of Aquaculture
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• v.13 no.2
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• pp.137-145
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• 2000

Capacity of water treatment of the three phase fluidized bed reactor as a biofilter in the seawater recirculating system was evaluated. The water treatment system consists of fluidized bed reactor for ammonia removal, cartridge filter for solid removal and ozone contactor for disinfection. Mean concentration of water quality parameters: COD, TAN, $NO_2$-N, $NO_3$-N, SS and alkalinity were 9.0, 0.22, 0.05, 20.0, 9.5 and 70.0 mg/l, respectively; the relevant values were 7.6 for pH and 3.64 NTU for turbidity. These indicate the maintenance of good water quality by the treatment system. The influent TAN loading rate in to the fluidized bed reactor ranged from 4.3 to 32.9 g/$m^3$/day, and averaged to 20 g/$m^3$/day. TAN removal efficiency of each phase of the fluidized bed reactor was 47-60%, indicating the effective ammonia removal. During operation the effluent of fluidized bed reactors also maintained the unionized ammonia nitrogen level below 0.002 mg/l.