• 제목/요약/키워드: Effective permeability

검색결과 533건 처리시간 0.021초

EDTA와 붕산 혼합용출제를 이용한 중금속으로 오염된 토양의 처리에 관한 연구(I): 납 (A Study of Heavy Metal-Contaminated Soil Remediation with a EDTA and Boric acid Composite(I): Pb)

  • 이종열;김용수;권영호;공성호;박신영;이창환;성혜련
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제9권4호
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    • pp.1-7
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    • 2004
  • 납으로 오염된 토양을 정화하는 방법인 토양수세기법에 가장 효율적인 용출제를 선정하기 위해서 여러 가지 유기산의 납 제거효율을 측정한 결과 0.01M의 EDTA 주입 시 납 제거효율은 $69.4\%$로 같은 농도의 다른 유기산과 비교해서 가장 높은 효율을 보였다. 또한 0.01M의 EDTA에 0.1M의 여러 가지 무기산을 혼합한 후 납 제거효율을 비교한 결과 EDTA와 붕산 혼합용출제가 pH5에서 $68.8\%$로 가장 높았다. EDTA와 붕산 혼합용출제의 경우 0.01M의 EDTA에 붕산의 주입농도를 0.1M에서 0.4M로 증가시킬 경우 납의 탈착/제거율은 $68\%$에서 $45\%$로 감소하였다. 그러나 0.1M의 붕산에 EDTA의 주입농도를 0.01M에서 0.04M로 증가시킬 경우 투수율은 $6.98{\times}10^{-4}cm/sec$에서 $5.99{\times}10^{-4}cm/sec$로 감소하였다. 이처럼 EDTA는 납의 탈착/제거율을 증가시키는 반면 투수율를 감소시키는 단점이 있다. 그러나 0.03M EDTA에 0.1M 붕산을 첨가한 경우 EDTA만을 주입한 경우와 비교해서 투수율이 $4.41{\times}10^{-4}cm/sec$에서 $6.26{\times}10^{-4}cm/sec$로 약 $30\%$ 증가되었다. 실제 중금속 오염토양에서 납의 제거효율은 납의 탈착/제거율과 오염토양 내 용출제의 투수율의 함수로 정의할 수 있으며, 최적의 [EDTA]/[붕산] 몰비는 [0.01M]/[0.1M]로 조사되었다.

노출시간과 열강도에 따른 복사열 노출후의 소방보호복의 물리적 특성과 역학적 특성변화 (Changes of Physical and Mechanical Properties of Firefighter Protective Clothing After Radiant Heat Exposure)

  • 유화숙
    • 한국의류학회지
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    • 제23권6호
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    • pp.853-863
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    • 1999
  • the change of physical properties (thickness, weight, air permeability) and mechanical properties(abrasion resistance breaking load and displacement) of samples were determined after heat exposure by a RPP tester. The effect of exposure time and heat flux intensity on the changes and the relationship between physical properties and mechanical properties were investigated. FR treated cotton Kevlar/PBI and Nomex with different structureal characteristics were chosen for specimens. The changes of physical properties and mechanical properties were calculated based on their initial values before heat exposure. The longer exposure time and the high heat flux intensity the more changes of those properties. Heat flux intensity was more effective on the changes, The showed to be affected by an interplay of shrinkage and pyrolysis products loss. The changes of thickness and abrasion resistance showed to be higher for plain weave fabric and those of air permeabiliyt and breaking load and displacement for twill weave fabric. While FR treated cotton which have high RPP value experienced serious and detrimental changes after heat exposure Kevlar/PBI which has low RPP value showed no high changes. In conclusion it could be confirmed that when total performance of a protective clothing is estimated retention capability of physical and mechanical properties after heat exposure as well as RPP value must be considered.

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Permalloy를 이용한 효율적 인 무선 전력송신 기술 (An Effective Wireless Power Transfer Technique using Permalloy)

  • 황재영;정연호
    • 한국정보통신학회논문지
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    • 제14권3호
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    • pp.678-683
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    • 2010
  • 일반적으로 무선(비접촉식) 충전 장치는 Ferrosilicon 혹은 Ferrite 와 같은 코어를 사용하여 충전 효율을 높이고 있다. 본 논문에서는 무선충전 장치에 있어서 투자율이 더 높은 Permalloy를 이용하여 비접촉방식 충전 효율을 극대화한 무선 전력송신 기술을 제안한다. 기존의 Ferrosilicon 혹은 Ferrite 코어 재료보다 Permalloy를 이용할 경우 높은 효율의 투자율을 얻을 수 있으며 기존 비접촉식 충전 기술과의 비교 실험을 통해 더 높은 충전 효율과 무선 충전 거리를 확보할 수 있었다. 본 연구에서 개발된 무선 전력송신 기술은 향후 소형 휴대용 충전기기에 유용하게 적용 할 수 있을 것이다.

NFC 통신거리 확장을 위한 페라이트 시트의 설계 (The Design of a Ferrite Sheet for NFC Communication Distance Extension)

  • 박양재
    • 디지털융복합연구
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    • 제12권8호
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    • pp.303-308
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    • 2014
  • 본 논문은 스마트폰의 후면에 페라이트 시트를 종류별, 패턴별, 두께별로 부착하여 NFC의 인식거리를 시뮬레이션을 통하여 최적의 페라이트 시트를 설계하였다. 패턴별 특징은 I-type보다는 Full- type의 통신거리가 1~2mm 정도 더 확장되었다. 적용한 페라이트 시트는 금속에 의한 NFC 안테나의 특성을 개선하는 효과를 확인하였으며, 패턴 C의 경우 투자율이 140, 두께가 0.1mm, Full-type 인 페라이트 시트를 적용하였을 때 NFC 통신거리가 일반 전자파 흡수제의 경우 45mm에서 59mm로 증대되었음을 확인하였다.

CIP 부피비에 따른 이방성 MRE의 전단계수 변화율 (The Variation Rate of Shear Modulus for Anisotropic Magneto-rheological Elastomer due to Volume Fraction of CIP)

  • 정운창;윤지현;양인형;이유엽;오재응
    • 한국소음진동공학회논문집
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    • 제21권12호
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    • pp.1132-1137
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    • 2011
  • MRE(magneto-rheological elastomers) is a material which shows reversible and various modulus in magnetic field. Comparing to conventional rubber vibration isolator, MREs are able to absorb vibration of broader frequency range. These characteristic phenomena result from the orientation of magnetic particles named carbonyl iron powder(CIP) in rubber matrix. In this paper, simulation on variation rate of shear modulus for anisotropic MRE due to volume fraction of CIP and an effective permeability model was applied to predict the field-induced shear modulus of MREs. Also, the variation rate of shear modulus for anisotropic MRE was derived using magneto-mechanical theory. Based on Maxwell-Garnett mixing rule, the increment of shear modulus was calculated to evaluate the shear modulus of MREs with column structure of CIP due to induced current. The simulation results on variation rate of shear modulus can be applied to the variable mechanical system of MRE such as tunable vibration absorber, stiffness variable bush and mount.

Anti-inflammatory functions of purpurogallin in LPS-activated human endothelial cells

  • Kim, Tae-Hoon;Ku, Sae-Kwang;Lee, In-Chul;Bae, Jong-Sup
    • BMB Reports
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    • 제45권3호
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    • pp.200-205
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    • 2012
  • Enzymatic oxidation of commercially available pyrogallol was efficiently transformed to an oxidative product, purpurogallin. Purpurogallin plays an important role in inhibiting glutathione S-transferase, xanthine oxidase, catechol O-methyltransferase activities and is effective in the cell protection of several cell types. However, the anti-inflammatory functions of purpurogallin are not well studied. Here, we determined the effects of purpurogallin on lipopolysaccharide (LPS)-mediated proinflammatory responses. The results showed that purpurogallin inhibited LPS-mediated barrier hyper-permeability, monocyte adhesion and migration and such inhibitory effects were significantly correlated with the inhibitory functions of purpurogallin on LPS-mediated cell adhesion molecules (vascular cell adhesion molecules, intracellular cell adhesion molecule, E-selectin). Furthermore, LPS-mediated nuclear factor-${\kappa}B$ (NF-${\kappa}B$) and tumor necrosis factor-${\alpha}$ (TNF-${\alpha}$) releases from HUVECs were inhibited by purpurogallin. Given these results, purpurogallin showed its anti-inflammatory activities and could be a candidate as a therapeutic agent for various systemic inflammatory diseases.

Hydrogen Diffusion in APX X65 Grade Linepipe Steels

  • Park, Gyu Tae;Koh, Seong Ung;Kim, Kyoo Young;Jung, Hwan Gyo
    • Corrosion Science and Technology
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    • 제5권4호
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    • pp.117-122
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    • 2006
  • Hydrogen permeation measurements have been carried out on API X65 grade linepipe steel. In order to study the effect of steel microstructure on hydrogen diffusion behavior in linepipe steel, the accelerated cooling condition was applied and then three different kinds of microstructures were obtained. Hydrogen permeation measurement has been performed in reference to modified ISO17081 (2004) and ZIS Z3113 method. Hydrogen trapping parameters in these steels were evaluated in terms of the effective diffusivity ($D_{eff}$), permeability ($J_{ss}L$) and the amount of diffusible hydrogen. In this study, microstructures which affect both hydrogen trapping and diffusion were degenerated pearlite (DP), acicular ferrite (AF), bainite and martensite/austenite constituents (MA). The low $D_{eff}$ and $J_{ss}L$ mean that more hydrogen can be trapped reversibly or irreversibly and the corresponding steel microstructure is dominant hydrogen trapping site. The large amount of diffusible hydrogen means that corresponding steel microstructure is predominantly reversible. The results of this study suggest that the hydrogen trapping efficiency increases in the order of DP, bainite and AF, while AF is the most efficient reversible trap.

준설매립지반의 압밀침하에 대한 쌍곡선 침하예측기법의 적용성 연구 (A Study on the Applicability of Hyperbolic Settlement Prediction Method to Consolidation Settlement in the Dredged and Reclaimed Ground)

  • 유남재;전상현;전진용
    • 산업기술연구
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    • 제28권A호
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    • pp.11-17
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    • 2008
  • Applicability of hyperbolic settlement prediction method to consolidation settlement in the dredged and reclaimed ground was assessed by analyzing results of centrifuge tests modelling self-weight consolidation of soft marine clay. From literature review about self-weight consolidation of soft marine clays located in southern coast in Korea, constitutive relationships of void ratio - effective stress - permeability and typical self-weight consolidation curves with time were obtained by analyzing centrifuge model experiments. For the condition of surcharge loading, exact solution of consolidation settlement curve obtained by using Terzaghi's consolidation theory was compared with results predicted by the hyperbolic method. It was found to have its own inherent error to predict final consolidation settlement. From results of analyzing thc self-weight consolidation with time by using this method, it predicted relatively well in error range of 0.04~18% for the case of showing the linearity in the relationship between T vs T/S in the stage of consolidation degree of 60~90 %. However, it overestimated the final settlement with large errors if those relation curves were nonlinear.

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Edible Packaging Film Derived from Mechanically Deboned Chicken Meat Proteins: Effect of Transglutaminase on Physicochemical Properties

  • Yayli, Damla;Turhan, Sadettin;Saricaoglu, Furkan Turker
    • 한국축산식품학회지
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    • 제37권5호
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    • pp.635-645
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    • 2017
  • In this study, effect of transglutaminase (TGase) addition on physical, water barrier, optical and mechanical properties of mechanically deboned chicken meat protein (MDCM-P) films was investigated. When TGase was added to the films, the thickness increased, but the solubility decreased. Films treated with TGase exhibited higher water vapor permeability than control film (p<0.05). When TGase concentration increased, the $L^*$ values of films decreased, but $a^*$ and $b^*$ values increased. All films showed very good barrier properties against UV light. The highest tensile strength was obtained in MDCM-P films containing 3% TGase (p<0.05). The elongation at break values increased with the TGase concentration increasing from 1 to 3%, but decreased at higher enzyme concentration (p<0.05). The addition of TGase altered molecular organization and intermolecular interaction in the film matrix. TGase treated films showed smoother and ordered surface structure and homogeneous and compact microstructure. The results indicated that TGase use can be an effective approach in improving the solubility and mechanical properties of MDCM-P films.

Borehole stability analysis in oil and gas drilling in undrained condition

  • Wei, Jian-Guang;Yan, Chuan-Liang
    • Geomechanics and Engineering
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    • 제7권5호
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    • pp.553-567
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    • 2014
  • Borehole instability during drilling process occurs frequently when drilling through shale formation. When a borehole is drilled in shale formation, the low permeability leads to an undrained loading condition. The pore pressure in the compressed area near the borehole may be higher than the initial pore pressure. However, the excess pore pressure caused by stress concentration was not considered in traditional borehole stability models. In this study, the calculation model of excess pore pressure induced by drilling was obtained with the introduction of Henkel's excess pore pressure theory. Combined with Mohr-Coulumb strength criterion, the calculation model of collapse pressure of shale in undrained condition is obtained. Furthermore, the variation of excess pore pressure and effective stress on the borehole wall is analyzed, and the influence of Skempton's pore pressure parameter on collapse pressure is also analyzed. The excess pore pressure decreases with the increasing of drilling fluid density; the excess pore pressure and collapse pressure both increase with the increasing of Skempton's pore pressure parameter. The study results provide a reference for determining drilling fluid density when drilling in shale formation.