• 제목/요약/키워드: Effective Heat of Formation

검색결과 138건 처리시간 0.026초

THE FORMATION MECHANISM OF GROWN-IN DEFECTS IN CZ SILICON CRYSTALS BASED ON THERMAL GRADIENTS MEASURED BY THERMOCOUPLES NEAR GROWTH INTERFACES

  • Abe, Takao
    • 한국결정성장학회:학술대회논문집
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    • 한국결정성장학회 1999년도 PROCEEDINGS OF 99 INTERNATIONAL CONFERENCE OF THE KACG AND 6TH KOREA·JAPAN EMG SYMPOSIUM (ELECTRONIC MATERIALS GROWTH SYMPOSIUM), HANYANG UNIVERSITY, SEOUL, 06월 09일 JUNE 1999
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    • pp.187-207
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    • 1999
  • The thermal distributions near the growth interface of 150mm CZ crystals were measured by three thermocouples installed at the center, middle (half radius) and edge (10m from surface) of the crystals. The results show that larger growth rates produced smaller thermal gradients. This contradicts the widely used heat flux balance equation. Using this fact, it si confirmed in CZ crystals that the type of point defects created is determined by the value of the thermal gradient (G) near the interface during growth, as already reported for FZ crystals. Although depending on the growth systems the effective lengths of the thermal gradient for defect generation are varied, were defined the effective length as 10mm from the interface in this experiment. If the G is roughly smaller than 20C/cm, vacancy rich CZ crystals are produced. If G is larger than 25C/cm, the species of point defects changes dramatically from vacancies to interstitial. The experimental results which FZ and CZ crystals are detached from the melt show that growth interfaces are filled with vacancy. We propose that large G produces shrunk lattice spacing and in order to relax such lattice excess interstitial are necessary. Such interstitial recombine with vacancies which were generated at the growth interface, next occupy interstitial sites and residuals aggregate themselves to make stacking faults and dislocation loops during cooling. The shape of the growth interface is also determined by the distributions of G across the interface. That is, the small G and the large G in the center induce concave and convex interfaces to the melt, respectively.

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공동주택 단지 내 지반 특성 및 지반 구성에 따른 열적 특성에 관한 연구 (The Effect of the Ground Composition on Thermal Environment in Multi -residential Building Block)

  • 황효근;송두삼
    • 한국태양에너지학회 논문집
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    • 제29권5호
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    • pp.88-97
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    • 2009
  • In these days, it attracts our attention to create a green outdoor environment around the building block in urban area. Green space and permeable ground covering are increased by laws and regulations. According to these trends, variety researches for improving outdoor environment are accomplished at this moment. However, the problems for outdoor environment such as heat island effect and air contaminant in urban area are still reported. The purpose of this study is to examine the variables to affect the formation of outdoor thermal environment by quantitative analysis. As a initial study, in this paper, the effect of ground composition on changes of surface temperature and heat flux in multi-residential building were analyzed by field measurement and numerical simulation. Through field measurement, the surface temperature and heat flux of artificial ground in multi-residential building in Suwon city were measured. The result showed that the surface temperature was decreased by about $20^{\circ}C$ with afforestation of artificial ground compared with those of concrete covering. Moreover, the inner temperature of artificial ground was changed as same behaviors of outdoor temperature changes to depths of 20cm. In simulation, the effect of soil types and depth of artificial ground on the changes of the surface temperature and heat flux were analyzed. As results, the natural soil ground was more effective against lowering the surface temperature than any other cases in the analyzed cases.

The effects of Hydroxyapatite nano-coating implants on healing of surgically created circumferential gap in dogs

  • Chae, Gyung-Joon;Lim, Hyun-Chang;Choi, Jung-Yoo;Chung, Sung-Min;Lee, In-Seop;Cho, Kyoo-Sung;Kim, Chong-Kwan;Choi, Seong-Ho
    • Journal of Periodontal and Implant Science
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    • 제38권sup2호
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    • pp.373-384
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    • 2008
  • Purpose: The aim of this study is to compare the healing response of various Hydroxyapatite(HA) coated dental implants by Ion-Beam Assisted Deposition(IBAD) placed in the surgically created circumferential gap in dogs. Materials and methods: In four mongrel dogs, all mandibular premolars and the first molar were extracted. After an 8 weeks healing period, six submerged type implants were placed and the circumferential cylindrical 2mm coronal defects around the implants were made surgically with customized step drills. Groups were divided into six groups : anodized surface, anodized surface with 150nm HA and heat treatment, anodized surface with 300nm HA and heat treatment, anodized surface with 150nm HA and no heat treatment, and anodized surface with 150nm HA, heat treatment and bone graft, anodized surface with bone graft. The dogs were sacrificed following 12 weeks healing period. Specimens were analyzed histologically and histomorphometrically. Results: During the healing period, healing was uneventful and implants were well maintained. Anodized surface with HA coating and $430^{\circ}C$ heat treatment showed an improved regenerative characteristics. Most of the gaps were filled with newly regenerated bone. The implant surface was covered with bone layer as base for intensive bone formation and remodeling. In case that graft the alloplastic material to the gaps, most of the coronal gaps were filled with newly formed bone and remaining graft particles. The bone-implant contact and bone density parameters showed similar results with the histological findings. The bone graft group presented the best bone-implant contact value which had statistical significance. Conclusion: Within the scope of this study, nano-scale HA coated dental implants appeared to have significant effect on the development of new bone formation. And additional bone graft is an effective method in overcoming the gaps around the implants.

폐폴리에틸린/폐에틸렌 비닐아세테이트공중합체 블렌드 발포체의 난연 및 발포 특성에 관한 연구 (Flame Retardancy and Foaming Properties of the Waste-Polyethylene(W-PE)/Waste-Ethylene vinyl acetate copolymer(W-EVA) Blend Foams)

  • 문성철;조병욱;최재곤
    • Elastomers and Composites
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    • 제38권4호
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    • pp.316-325
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    • 2003
  • 본 연구에서는 폐폴리에틸렌 (W-PE)/폐에틸렌비닐아세테이트공중합체 (W-EVA) 블렌드계에 무기계 및 인계 난연제 등을 첨가하여 난연폴리올레핀 발포체를 제조하고, 수지대비 난연제, 특히 무기계 난연제의 종류 및 함량 변화에 따른 발포 및 난연특성의 변화를 조사하였다. 그 결과 W-PE/W-EVA 블렌드계의 조성비가 50/50 (w/w)이고, 수지 대비 난연제의 함량이 220phr의 범위 내에서 가교반응을 쉽게 이룰 수 있을 것으로 생각되는 폐고분자재료를 사용함으로써 가교 및 발포가 효과적으로 이루어져 V-PE 난연 발포체와 비교해 비교적 균일한 독립기포를 갖고, 발포율이 오히려 증가 (100 % 이상)함을 알 수 있었으며, 난연특성 (limiting oxygen index; LOI, heat release rate; HRR, total heat release; THR, effective heat of combustion; EHC등) 또한 높음을 확인할 수 있었다. 그리고 난연제의 종류 및 함량이 발포 및 난연특성에 미치는 영향이 큼을, 그리고 무기계 난연제의 난연 및 연기발생억제 효과를 확인하였다. 무기계 난연제 중 수산화알루미늄은 LOI 상승에, 수산화마그네슘은 발포율 상승 및 HRR, COY를 낮추는 데 효과적임을 알 수 있었고, 수산화알루미늄과 수산화마그네슘을 동시에 사용했을 때 상호작용에 따른 시너지 효과로 난연성을 보다 향상시킴을 확인하였다.

분무건조된 세라믹 과립분말의 압축강도가 에어로졸 데포지션 공정에 미치는 효과 (The Effect of the Spray-Dried Ceramic Granules' Compressive Strength on the Aerosol Deposition method)

  • 김종우;류정호;한병동;최종진;윤운하;안철우;최준환;박동수
    • 한국입자에어로졸학회지
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    • 제9권3호
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    • pp.127-132
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    • 2013
  • Recently, Aerosol Deposition method has attracted considerable attention because of its advantages to produce ceramic coatings on various substrates at room temperature. This method is strongly dependent on the raw powder, which should have high mobility with carrier gas and moderate mechanical strength to be crushed onto the substrate. In this report, the effects of the ceramic granules' compressive strength on the ceramic coating formation are discussed. The ceramic granules were prepared by spray-drying method and heat treated at various temperatures. It was found that at the moderate mechanical strength of ceramic granules gave more effective film formation behavior during Aerosol Deposition method.

열처리조건이 초전도벌크의 임계특성에 미치는 영향 (The effects of heat treatment condition on critical characteristics of HTSC bulk)

  • 임성훈;한태희;박경국;조동언;이중근;한병성
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1997년도 추계학술대회 논문집
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    • pp.356-359
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    • 1997
  • The Effects of different melting temperature and holding time in the melting temperature on J$\sub$c/ of YBa$_2$Cu$_3$O$\sub$x/ based superconducting bulk using MPMG process were investigated. the value of critical current density was the largest at l120$^{\circ}C$, the melting temperature which is appointed to the mid point of (Y$_2$BaCuO$\sub$5/ + Liquid)region. With the melting temperature in which the value of J$\sub$c/ is the largest, J$\sub$c/ was again measured to see whether the holding time at this proper melting temperature has the effect on the critical characteristics. From the result above it was concluded that the melting temperature and holding time were important to improve the J$\sub$c/ and the formation of the Y$_2$BaCuO$\sub$5/. In this paper, the melting temperature obtained was l120$^{\circ}C$ and propel holding time could be obtained as 20 minute and the more holding time was not effective in the J$\sub$c/ improvement as well as the formation of Y$_2$BaCuO$\sub$5/.

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가시화 엔진을 이용한 직분식 예혼합 압축착화 디젤엔진의 화염 및 연소특성 (Flame and Combustion Characteristics of D.I. HCCI Diesel Engine using a Visualization Engine)

  • 권오영;류재덕;이기형;이창식
    • 한국자동차공학회논문집
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    • 제10권6호
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    • pp.100-107
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    • 2002
  • Combustion characteristics of diesel engine depends on mixture formation process during Ignition delay and premixed flame region. Fuel and air mixture formation has a great influence on the exhaust emission. Therefore, the present study focused on the combustion mechanism of Homogeneous Charge Compression Ignition (HCCI) engine. This study was carried out to investigate the combustion characteristics of direct injection type HCCI engine using a visualization engine. To investigate the combustion characteristics, we measured cylinder pressure and calculated heat release rate. In addition, we investigated the flame development process by using visualization engine system. From the experimental result of HCCI engine, we observed that cool flame was always appeared in HCCI combustion and magnitude of cool flame was proportional to magnitude of hot flame. And we also found that fuel injection timing is more effective to increase lean homogeneous combustion performance than intake air temperature. Since increasing the intake air temperature improved fuel vaporization before the fuel atomizes, we concluded that increasing the temperature has disadvantage fur homogeneous premixed combustion.

Mg-5Al-2Si 합금의 조직 및 부식특성에 미치는 Sb, Sr 첨가의 영향 (Effect of Sb and Sr Addition on Corrosion Properties of Mg-5Al-2Si Alloy)

  • 전종진;이상원;김병호;박봉규;박용호;박익민
    • 대한금속재료학회지
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    • 제46권5호
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    • pp.304-309
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    • 2008
  • Magnesium alloys containing $Mg_2Si$ particles, as a promising cheap heat-resistant magnesium alloy for automobile power train parts applications, are attracting more attention of both material scientists and design engineers. Modification of the Chinese script shape $Mg_2Si$ particle is a key for using this alloy in sand or permanent mould casting. In the present work, the modification effect of Sr and Sb on the corrosion properties of the Mg-5Al-2Si alloy was investigated. Sr or Sb addition promoted the formation of fine polygonal shape $Mg_2Si$ particles by providing the nucleation sites. Sr was more effective element than Sb for shape modification of Chinese script shape $Mg_2Si$. Such improved microstructure of the modified alloy resulted in large improvement in corrosion resistance as compared to unmodified Mg-5Al-2Si alloy.

GMA 용접에서 비드형상을 고려한 수평필릿용접부의 온도해석에 관한 연구 (A Study of the Thermal Analysis of Horizontal Fillet Joints by Considering the Bead Shape in GMA Welding)

  • 조시훈;김재웅
    • 한국정밀공학회지
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    • 제18권8호
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    • pp.71-78
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    • 2001
  • In GMA(Gas Metal Arc)Welding, the weld size that is a locally melted area of a workpiece is one of the most important considerations in determining the strength of a welded structure. Variations in the weld power and the welding heat flux may affect the weld pool formation and ultimately the size of the weld. Therefore, an accurate prediction of the weld size requires a precise analysis of the weld thermal cycle. In this study, a model which can estimate the weld bead geometry and a method for thermal analysis, including the model, are suggested. In order to analyze the weld bead geometry, a mathematical model was developed with transformed coordinates to apply to the horizontal fillet joints. A heat flow analysis was performed with a two dimensional finite element model that was adopted for computing the base metal melting zone. The reliability of the proposed model and the thermal analysis was evaluated through experiments, and the results showed that the proposed model was very effective for predicting the weld bead shape and good correspondence in melting zone of the base metal.

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비대칭 압연과 시효 시퀀스가 Al-Zn-Mg-Cu합금의 미세조직과 기계적 특성에 미치는 영향 (Effects of Asymmetric Rolling and Aging Sequence on Microstructure and Mechanical Properties of Al-Zn-Mg-Cu Aluminum Alloys)

  • 정민경;이종범;김수현;한준현
    • 열처리공학회지
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    • 제36권5호
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    • pp.285-297
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    • 2023
  • The effects of aging treatment sequence, specifically pre-aging and post-aging, on the microstructure and mechanical properties of Al-Zn-Mg-Cu aluminum alloys has been studied in comparison to symmetrically rolled specimens. In symmetrically rolled specimens, a straight-band precipitation distribution was observed, whereas asymmetrically rolled specimens exhibited a curved-band microstructure of fine precipitates. Notably, the asymmetrically rolled specimens displayed higher strengths. In the case of post-aging, the aging process occurred after rolling, and the dislocations generated during rolling acted as nucleation sites for precipitates during aging. This resulted in the formation of fine precipitates, contributing to improved mechanical properties compared to symmetric rolling. To enhance strength of the Al-Zn-Mg-Cu aluminum alloys, asymmetric rolling proves to be more effective than symmetric rolling, with post-aging showing greater efficacy than pre-aging.