• 제목/요약/키워드: Effective Heat of Formation

검색결과 138건 처리시간 0.027초

Synthesis of Fe-TiB2 Nanocomposite by a combination of mechanical activation and heat treatment

  • ;;김지순;강태훈;김진천;권영순
    • 한국재료학회:학술대회논문집
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    • 한국재료학회 2012년도 춘계학술발표대회
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    • pp.91.2-91.2
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    • 2012
  • The TiB2-reinforced iron matrix nanocomposite (Fe-TiB2) was in-situ fabricated from titanium hydride (TiH2) and iron boride (FeB) powders by a simple and cost-effective process that combines the mechanical activation (MA) and a subsequent heat treatment (HT). Effect of milling factors and synthesized temperatures on the formation of the nanocomposite were presented and discussed. A differential thermal analyser (DSC-TG) was employed for examination of thermal behavior of MAed powders. Phases of the nanocomposite were confirmed by X-ray diffraction analysis (XRD). The morphologies and microstructure of nanocomposite were investigated by field emission-scanning electron microscopy (FE-SEM) and energy-dispersive X-ray spectroscopy (EDS). Phase composition and distribution were analyzed by electron probe X-ray microanalysis (EPMA). Results showed that TiB2 particles formed in nanoscale were uniformly distributed in alloyed Fe matrix.

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냉각 평판에서 서리 성장 모델링 (Modeling for Frost Growth on a Cold Plate)

  • 양동근;이관수
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2004년도 춘계학술대회
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    • pp.1546-1551
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    • 2004
  • This paper presents a mathematical model to predict the frost properties and heal and mass transfer within the frost layer formed on a cold plate. The laminar flow equations for the air-side are analyzed. and the empirical correlations of local frost properties are employed in order to predict the frost layer growth. The correlations of local frost density and effective thermal conductivity of frost layer, obtained from various experimental conditions, are derived as functions of various frosting parameters (Reynolds number, frost surface temperature, absolute humidity and temperature of moist air, cooling plate temperature, and frost density). The numerical results are compared with experimental data and the results of various models to validate the present model, and agree well with experimental data within a maximum error of 10%. The heat and mass transfer coefficients obtained from the numerical analyses are presented, as the results, it is found that the model for frost growth using the correlation of heat transfer coefficient without solving air flow have a limitation in its application.

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고강도 이온질화 기어의 개발 (Development of high-strength ion nitrided gear)

  • 김영훈;선철곤;김한군
    • 열처리공학회지
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    • 제7권3호
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    • pp.184-189
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    • 1994
  • The heat treatment charaterristic of SCM 440 and B 16 steels has been investigated in various condition(A, B and C) to the effect of heat treatment on mechanical properties, and the following results were obtained. 1. We are obtained a good nitriding characteristic in bainitic structure than other heat treatment cycle in our experiment. 2. Fatigue characteristic has shown in order of B)C)A condition as heat treatment cycle. 3. The effective hardening depth and fatigue characteristic has been excellented in B 16 than SCM 440 after the nitriding and Q. T for Band C condition. 4. Nitriding depth has been increased in addition of Cr, V and the nitriding efficiency is increased as easiness of banite formation to wide range of cooling rate by addition of Mo. 5. The depth of compound layer in parallel surface, notched slop plane and notched bottom has been varied to the nitriding depth of 5, 4 and 3 ${\mu}$ in relatively uniform pattern after 10h nitriding treatment for SCM 440 into A condition.

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기계적 합금화법으로 제조된 과포정 Al-Ti 합금에서 Al3Ti 형성에 관한 연구 (Formation of Al3Ti From Mechanically Alloyed Hyper-Peritectic Al-Ti Powder)

  • 김혜성;서동수;김긍호;금동화
    • 열처리공학회지
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    • 제9권1호
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    • pp.1-11
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    • 1996
  • Mechanical alloying is an effective process to finely distribute inert dispersoids in an Al-TM(TM is a transition metal) system. It has been considered that high melting point aluminides are formed by precipitation from supersaturated Al(Ti) powder. This analysis is based on the fact that much higher content of TM than the solubioity can be dissolved in alpha aluminum during the high energy ball milling. Thus, decomposition behavior of Ti in the Al(Ti) was considered very important. But it is confirmed that the higher portion of Ti than Al(Ti) solid solution is existed as nano-sized Ti particles in the MA powders by high energy ball nilling from the XRD spectrum and TEM analysis in this study. Therefore, the role of undissolved TM particles affect the formation of aluminides should be suitably considered. In this study, we present experimental observation on the formation of $Al_3Ti$ fron mechanical alloyed Al-Ti alloys in the hyperperitectic region. This study showed that, in the mechanically alloyed Al-20wt%Ti specimen, intermediate phase of cubic $Al_3Ti$ and tetragonal $Al_{24}Ti_8$ formed at $300{\sim}400^{\circ}C$ and $400{\sim}500^{\circ}C$, respectively, before the MA state reaches to equilibrium at higher temperatures. The formation behavior of $Ll_2-Al_3Ti$ is interpreted by interdiffusion of Al and Ti in solid state based on the fact that large amount of nano-sized Ti particles exist in the milled powder. Present analysis indicated undissolved Ti particles of nanosize should have played an important role initiation the formation of $Al_3Ti$ phase during annealing.

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고농도 침탄강의 탄화물 형성과 피팅 피로강도에 미치는 탄소 포텐셜의 영향 (Effect of Carbon Potential on the Carbide Formation and Pitting Fatigue Strength of Supercarburized Steel)

  • 소상진;신정호;임재원;이석재
    • 열처리공학회지
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    • 제29권3호
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    • pp.113-123
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    • 2016
  • In the present work, we investigated the effects of the carbon potential on the formation of carbide at the carburized surface and anti-pitting fatigue strength in the supercarburized steels. Two low carbon steels with different Cr concentrations were adopted and the repeated supercarburizing treatment carried out with the different carbon potential conditions. The microstructure and carbides at the supercarburized surface were observed by using optical microscope and scanning electron microscope. The microhardness test was performed and the hardness distribution and the effective case depth at the supercarburized surface were discussed. The roller pitting fatigue test was carried out and the fatigue strength was evaluated with different the carbon potential conditions. The microstructure of the fatigue specimen surface was observed by means of scanning electron microscope and scanning transmission electron microscope. Depending on the chemical composition of the steels and the carbon potential condition, the resistance of temper softening and pitting failure was influenced due to the carbide distribution and the formation of coarse network carbide. Thus, it was confirmed that the control of the carbide formation is a key factor to improve the anti-pitting fatigue strength in the supercarburized steels.

포제한약재의 최종당화산물 생성 억제 활성 및 항산화 효과 (Inhibitory Activity of Advanced Glycation Endproducts (AGEs) Formation and Antioxidant Activity of Processed Korean Medicines)

  • 이아름;권오준;최준영;노성수
    • 대한본초학회지
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    • 제32권3호
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    • pp.63-69
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    • 2017
  • Objectives : Advanced glycation end product (AGEs) is combine formation of glucose and protein. AGEs and reactive oxygen species are potential therapeutic targets for the various disease such as diabetic complications, renal injury, skin damage. The aim of this study was investigated the AGEs inhibitory activity and antioxidant activity of water extracts from 40 Korean medicines and 5 heating-processed Korean medicines. Methods: AGEs formation inhibitory activities of Korean medicines measured using bovine serum albumin (BSA), glucose, and fructose. Then, five effective Korean medicines were selected and heated with 30% ethanol. The AGEs inhibitory activities of heated Korean medicine were measured compared with not-heated Korean medicines. The antioxidant activities were evaluated through radical scavenging assays using 1,1-diphenyl-2-picrylhydrazyl (DPPH) and 2,2'-azino-bis (3-ethylbenzothiazoline-6-sulphonic acid) (ABTS) radicals. Furthermore, we examined total phenol and flavonoids contents. Results: Scutellariae Radix, Corni Fructus, Persimmon Fruit, Paeoniae Radix, Mori Folium respectively reduced AGEs production. Morever, heating-processed Scutellariae Radix has AGEs inhibitory activities better than not-processed Scutellariae Radix. Heating- processed Scutellariae Radix scavenged DPPH and ABTS effectively and $IC_{50}$ of DPPH and ABTS radical scavenging activity of Heat processed Scutellariae Radix were $15.47{\pm}0.26{\mu}g/m{\ell}$ and $12.07{\pm}1.23{\mu}g/m{\ell}$. It caused heat processing methods of Scutellariae Radix up regulated total phenol and flavonoids contents ($26.68{\pm}0.01$ to $46.15{\pm}0.10$, $20.30{\pm}0.38$ to $64.20{\pm}0.52$). Conclusion: It has AGEs inhibitory activities that 20 kind of medicinal plants of 40 medicinal plants. Especially, heat processed Scutellariae Radix has excellent AGEs inhibitory activities and antioxidant effect.

농도 성층화된 유체의 아랫면 가열에 의한 이중확산대류에 관한 연구 (Double-Diffusive Convection in a Salt-Stratified Fluid Heated From Below)

  • 강신형;김무현;이진호
    • 대한기계학회논문집
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    • 제18권12호
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    • pp.3297-3304
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    • 1994
  • Experimental investigation have been made to study the double-diffusive nature of convection of an initially stratified salt-water solution heated from below in a cylindrical cavity. The objective is to examine the process of mixed-layer formation, the flow phenomena, the heat transfer characteristics, and temperature and concentration distribution according to the changes in the effective Rayleigh number based on the reference height which represents the relation of temperature and concentration gradient. The types of initially formed flow pattern are categorized in three regimes depending on the effective Rayleigh number ; stagnant flow regime, single mixed-layer flow regime and successively formed multiple mixed-layer flow regime. The temperature and concentration profiles are both uniform in each layer due to convective mixing in the layered flow regime, but both linear in stagnant flow regime and single mixed-layer flow regime. At the interface between adjacent layers, the temperature changes smoothly but the concentration changes rapidly. The layers expand by diffusion of concentration through the interface along with its random fluctuation.

경계층 이론을 이용한 고효율 열교환기 설계를 위한 이론적 접근법 (Theoretical approach on the effective heat exchanger design using boundary layer theory)

  • 이동연;이무연
    • 한국산학기술학회논문지
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    • 제13권12호
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    • pp.5655-5660
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    • 2012
  • 본 연구의 목적은 경계층 해석법을 이용하여 고효율 열교환기 설계를 위한 이론적 접근법을 제시하고 기존 열교환기에 많이 사용되고 있는 사각 평판 핀과 이를 대체할 수 있는 원형 평판 핀에 대하여 경계층 형성과 간섭에 대하여 설명하고 속도 및 온도 경계층 성장에 따른 열전달계수의 변화를 나타내고자 한다. 더불어 한 개의 핀에서의 유동은 외부유동으로 간주할 수 있으나 다수의 핀 사이의 유동은 내부유동으로 간주하였고 이론적인 결과를 도출하였다. 결과적으로 열교환기의 고효율화 및 컴팩트화를 실현하기 위하여 경계층 간섭을 회피할 수 있는 방안을 이론적으로 제시하였고, 이러한 관점에서 원형 평판 핀이 사각 평판 핀에 비하여 열전달성능이 우수함을 알 수 있었다.

BiSrCaCuO계의 Pb첨가 효과 (Effect of Pb dopped on BiSrCaCuO system)

  • 한태회;박성진;황종선;김동필;한병성
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1991년도 추계학술대회 논문집 학회본부
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    • pp.269-273
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    • 1991
  • High Tc oxide superconductor with a Tc above 100 K has been successfully prepared by solid state reaction method in added-Pb BiSrCaCuO system. As compared with 123 compound, the formation reaction of the high Tc requires long time heat treatment. It is due to the transformation from the low Tc phase to high Tc phase. The sintering just below the melting point of the calcined powder mixture is effective on the formation of the high Tc phase in BiSrCaCuO system to be added with Pb. The growth of the high Tc superconducting phase has a thin plate shape, which is characterized by the c parameter of 37${\AA}$. The formation kinetics is also investigated in the samples with different Bi/Pb ratio and the 30% Pb addition is most preferable for the formation of the high Tc phase. The formation of the high Tc phases is delayed by the excessive addition of Pb. The lattice parameter(c) of the unit cell(both the low and high Tc phases) is increased with increase of Pb.

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가스하이드레이트 제조성능 향상을 위한 영향인자 검토 연구 (An experimental study on the factors to improve the formation performance of gas hydrate)

  • 신창훈;김유나;권옥배;박승수;한정민;이정환
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2007년도 춘계학술대회B
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    • pp.2989-2994
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    • 2007
  • Gas hydrates are ice-like crystalline compounds that form under low temperature and elevated pressure conditions. Although hydrate formation can pose serious flow-assurance problems in the gas pipelines or facilities, gas hydrates present a novel means for natural gas storage and transportation with potential applications in a wide variety of areas. An important property of hydrates that makes them attractive for use in gas storage and transportation is their very high gas-to-solid ratio. In addition to the high gas content, gas hydrates are remarkably stable. The main barrier to development of gas hydrate technology is the lack of an effective method to mass produce gas hydrate in solid form. The first objective of this study is investigating the characteristics of gas hydrate formation related to several factors such as pressure, temperature, water-to-storage volume ratio, concentration of SDS, heat transfer and whether stirred or not respectively. And the second objective is clarifying the relation between the formation efficiency and each factor in order to find the proper way or direction to improve the formation performance.

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