• 제목/요약/키워드: Effective Heat of Formation

검색결과 137건 처리시간 0.028초

Arginyl-fructosyl-glucose and Arginyl-fructose, Compounds Related to Browning Reaction in the Model System of Steaming and Heat-drying Processes for the Preparation of Red Ginseng

  • Suzuki, Yukio;Choi, Kang-Ju;Uchida, Kei;Ko, Sung-Ryong;Sohn, Hyun-Joo;Park, Jong-Dae
    • Journal of Ginseng Research
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    • 제28권3호
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    • pp.143-148
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    • 2004
  • Brown color intensity has been a major factor to estimate the quality of red ginseng and its products. This study deals with the relationship between the browning reaction of ginseng root and two compounds, arginyl-fructosyl-glucose(Arg-fru-glc) and arginyl-fructose (Arg-fru), in the model system of steaming and heat-drying processes for the preparation of red ginseng. During the steaming process, a marked decrease of starch and a considerable formation of maltose occurred in main roots of raw ginseng, but the formation of glucose was scarcely observed. After the heat-drying process, the brown color intensity of the powdered preparation of steamed main roots was 3 to 4 times higher than that of the powdered preparation of raw main roots. Also, when the heat- drying process was done with the addition of L-arginine, brown color intensity of the powdered preparation of steamed main roots was 12 to 13 times higher than that of the powdered preparation of raw main roots. The amount ratios of browning reaction products formed from sugar compounds and amino acids in the model system of steaming and heat-drying treatments in vitro were in order of xylose > glucose > fructose > maltose > dextrin (DE 9) > sucrose > dextrin (DE 8) and soluble starch. Each solution of Arg-fru-glc and Arg-fru that were synthesized chemically from maltose plus L-arginine and glucose plus L-arginine, respectively, changed from colorless to brown color during the heat-drying treatment. Amino acids or sugars were effective on the acceleration of each browning reaction of Arg-fru-gIc and Arg-fru during the heat-drying treatment.

비후성 반흔 각질세포와 정상 각질세포의 유전자 비교분석 (Difference of Gene Expression between Hypertrophic Scar Keratinocytes and Normal Keratinocytes)

  • 최성원;정호윤;임영국;김훈남;오지원;김문규;전세화;홍용택
    • Archives of Plastic Surgery
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    • 제37권4호
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    • pp.317-322
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    • 2010
  • Purpose: There is no clear evidence of the original cause of hypertrophic scar, and the effective method of treatment is not yet established. Recently the steps of searching in gene and molecular level are proceeding. we are trying to recognize the difference between keratinocytes of hypertrophic scar and normal skin. Then we do support the comprehension of the scar formation mechanism and scar management. Methods: Total RNAs were extracted from cultured keratinocytes from 4 hypertrophic scars and normal skins. The cDNA chips were prepared. A total of 3063 cDNAs from human cDNA library were arrayed. And the scanning data were analyzed. Results: On microarray, heat shock protein, pyruvate kinase, tumor rejection antigen were more than 2 fold intensity genes. Among them, heat shock 70 kd protein showed the strongest intensity difference. Conclusion: In this study, it can be concluded that heat shock proteins play an important role in the process of wound healing and scar formation. This study provides basic biologic information for scar research. The new way of the prevention and treatment of scar formation would be introduced with further investigations.

Effects of the Preheating Treatments of Raw Ginseng in the Model System on the Synthesis of the Maillard Type-Browning Reaction Products of Red Ginseng

  • Suzuki, Yukio;Choi, Kang-Ju;Uchida, Kei;Ko, Sung-Ryong
    • Journal of Ginseng Research
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    • 제28권3호
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    • pp.136-142
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    • 2004
  • During our investigations on the relationship between the browning reaction of ginseng root and two compounds (arginyl-fructosyl-glucose and arginyl-fructose) in the model system of steaming and heat-drying processes for the preparation of red ginseng, the preheating treatment of main roots of raw ginseng at 60∼70$^{\circ}C$ prior to the steaming and heat-drying processes was found to bring about the gelatinization of starch granules. The enzymatic hydrolysis of gelatinized starch to maltose, a marked formation of maltose, and the increase of both free arginine and total amino acids, resulting the acceleration of the Maillard type-browning reaction of ginseng root during the steaming and heat-drying processes, and the rise of brown color intensity of red ginseng. These results show that the preheating treatment may be effective for the decrease of inside white of red ginseng.

단조품의 등온 어닐링에 따른 미세조직 변화 (The Effect of Isothermal Annealing on Microstructure of Forged Parts)

  • 김동배;이종훈
    • 열처리공학회지
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    • 제13권5호
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    • pp.303-308
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    • 2000
  • The ring gears of automobile parts are manufactured generally process chart of which is as follows : forging ${\rightarrow}$ annealing or normalizing ${\rightarrow}$ rough machining ${\rightarrow}$ hardening(Quenching-Tempering or carburizing process) ${\rightarrow}$ finish machining. Isothermal annealing process after forging is most effective in the side of improvment of machinability. On this study we selected two kinds of steel;SCM415, SCM435 of most universal and investigated microstructures to find out most suitable condition of heat treatment in proportion continuous cooling and isothermal annealing. As the cooling rate is $5^{\circ}C$ per minute in continuous cooling process, martensite and bainite are coexisted with ferrite and pearlite in SCM435 steel. If the cooling rate is slower than $5^{\circ}C$ per minute, microstructure were only ferrite and pearlite but formation of band structure can't be avoid. On the other hand, microstructure is only ferrite and pearlite regardless of cooling rate because carbon content of SCM415 steel is low. Moreover formation of band structure isn't exposed by faster cooling rate. Most optimal temperature of the isothermal annealing is from $650^{\circ}C$ to $680^{\circ}C$ in SCM435 steel. When holding time is 60 minute with $650^{\circ}C$, the identical ferrite and pearlite microstructures can be obtained.

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도시 가로수의 증산 작용으로 인한 불쾌지수 변화 분석 (Analyzing Change of Discomfort Index for Transpiration of Street Tree)

  • 윤석환;이동근;박채연
    • 한국환경복원기술학회지
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    • 제23권5호
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    • pp.29-43
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    • 2020
  • Thermal environment of city is getting worse due to severe urban heat island caused by climate change and urbanization. The cooling effect of street tree is regarded as a effective way to ameliorate the urban heat environment. The effect is largely made up of shadow formation and transpiration. This study aims to identify how the transpiration affects the discomfort index by analyzing comprehensive impact of the transpiration on the air temperature and relative humidity. The changes in the amount of transpiration, air temperature, and relative humidity were estimated for Seogyo-dong area which has a lot of floating population in Seoul, at 2 p.m. in dry day in July and August. On average, the transpiration of the street tree decreased the temperature 0.3℃ and increased the relative humidity 2.6% in an hour. As a result of these changes in temperature and humidity, the discomfort index rose mostly(0.036 on average). It was always get rise especially on the day when the discomfort index was above 80(0.05 on average). However, compared with the significant change in temperature and humidity, the variation of the discomfort index itself was very slight(up to 0.107). Therefore, the effect of transpiration by the street trees might not be effective in the planning to improve the thermal environment(especially on the day when the discomfort index is high). It is necessary to select the species of trees and planting location considering the cooling effect of shade formation synthetically.

Inhibition of methane formation and improvement of $H_2$ production by adding nitrate to anaerobic reactor

  • Kim, Jeong-Ok;Kim, Yong-Hwan;Ryu, Jeong-Yong;Song, Bong-Keun;Kim, In-Ho
    • 한국생물공학회:학술대회논문집
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    • 한국생물공학회 2003년도 생물공학의 동향(XIII)
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    • pp.129-134
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    • 2003
  • Anaerobic hydrogen production was executed using mixed anaerobic sludge. pH control (pH $5.5^{\sim}6.2)$ and heat treatment of anaerobic sluge at $92^{\circ}C$ was not effective for repressing the methane formation. The addition of $nitrate(500^{\sim}2,000\;mg/L\;KNO_3)$ made it possible to repress the methane formation, which resulted in the improvement of hydrogen production. By using SEM(Scanning Electron Microscope), less methane forming microbial with spagetti shape was observed when nitrate was supplied to anaerobic reactor.

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Study on the Effects of Hydrogen Decrepitation on the Formation of Sm2Fe17Nx-type Material

  • Kwon, H.W
    • Journal of Magnetics
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    • 제4권2호
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    • pp.55-59
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    • 1999
  • In an attempt to find an effective production way of the$ Sm_2Fe_{17}N_{x-}type material, the Sm_2Fe_{17-}$type alloy with chemical composition of Sm 22.7 wt.%, Fe72.3 wt.% Nb 5.0wt.% was subjected to a HD (hydrogen decrepitation) treatment prior to a nitrogenation, and its effect on the formation of the nitride material was investigated. The nitrogenation behaviours of the alloy were investigated using a TPA(thermopiezic analysis), TMA, and DTA under nitrogen gas, and XRD. It has been found that the previous HD treatment significantly facilitated the formation of $Sm_2Fe_{17}N_{x-}$type nitride, and this was accounted for by the clean surface and the finer particle size of the powder caused by the HD treatment. It has also been found that the hydrogen atoms existing in the initial HD-treated alloy were removed almost completely during the nitrogenation. The heat output associated with the nitrogenation of the previously HD-treated alloy was found to be significantly smaller than that of the as-cast alloy.

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1차원 모델에 의한 보어홀 열거동 해석 및 현지측정 (A Study of Borehole Thermal Behavior with 1-Dimensional Model;Field Test Analysis included)

  • 김대기;우정선;노정근;이세균
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2007년도 추계학술대회 논문집
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    • pp.550-554
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    • 2007
  • A one-dimensional heat transfer model coupled with parameter estimation is developed in this study to predict the effective thermal conductivities of soil formation and borehole resistances from in situ field test data. In this application a new method of using initial ignoring time(IIT) obtained from error estimation is tried and turned out to be successful in determining soil thermal conductivities. The validity of this model is accomplished through comparison of the predicted temperature profiles of the model with the data from laboratory scale experimental setting. Eleven test boreholes were constructed in Ochang, Chungcheong Buk Do, and thermal response test was carried out with each borehole. The results of the in situ tests were analyzed with our 1-D numerical model and compared with the results of line source method. The comparison shows that the thermal properties from line source method is a little lower (${\sim}95%$)than those from numerical method. The reason of such result seems to be the lower thermal conductivity of grout material, which is not counted in line source method.

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CW Nd:YAG레이저를 이용한 금형 재료의 표면열처리 (Surface Heat treatment of Die material by means of CW Nd:YAG Laser)

  • 유영태;신호준;장우양
    • 한국공작기계학회논문집
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    • 제13권5호
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    • pp.67-74
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    • 2004
  • Laser heat treatment is an effective technique used to improve the tribological properties and also to increase the service life of automobile components such as camshafts, crankshatfs, lorry brake drums and gears. High power $CO_2$ lasers and Nd:YAG lasers are employed for localized hardening of materials and hence are of potential application in the automobile industries. The heat is conducted rapidly into the bulk of the specimen causing self-quenching action to occur and the formation of matrensitic structure. In this investigation, the microstructrual features occurring in Nd:YAG laser hardening SM45C and $STD_11$ steel are discussed with the use of optical microscopic and scanning electron microscopic analysis. Moreover, This paper describes the optimisation of the processing parameters for maximum hardened depth of SM45C and $STD_11$ steel specimens of 10mm thickness by using CW:YAG laser.

자동차 경량 부품 제조를 위한 Al-Cu-Mg 분말 합금의 소결 및 열처리 특성 (Sintering and Heat Treatment Characteristics of Al-Cu-Mg Powder Metallurgy Alloy for Lightweight Automotive Parts)

  • 안병민
    • 한국생산제조학회지
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    • 제23권2호
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    • pp.152-156
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    • 2014
  • Lightweight materials such as aluminum and magnesium have recently received much attention in the automotive industries because of environmental and fuel-efficiency concerns. Using the powder metallurgy (PM) process for these materials creates significant opportunities for the cost-effective manufacture of lightweight automotive parts. In the present study, an Al-Cu-Mg alloy was fabricated using conventional PM processes. Primarily, the effects of the alloying elements on the sintering characteristics and mechanical behavior after heat treatment were investigated. A microstructural analysis was performed using an optical microscope and a scanning electron microscope to investigate the behavior of liquid phase sintering, including the formation of precipitates. The dependence of the mechanical behavior on the alloying elements was evaluated based on the transverse rupture strength.