• Journal of Korean Society on Water Environment
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• v.21 no.1
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• pp.1-6
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• 2005

The effect of ozone oxidation on biodegradability of leachate was studied. Ozone oxidation process was used as pre-treatment process to enhance performance of biological process in treating landfill leachate. Optimum ozone dosing rate and contact time in this experiment was $160mg\;O_3/L$ hr and 45 minutes, respectively. Biodegradability was enhanced 5.08% by ozone oxidation. The ratio of ozone demand/DOC concentration was $0.049{\sim}0.091mg\;O_3/mg$ DOC. The increase of biodegradability depending on ozone dosing rate(D) and contact time(T) can be expressed as follows ; ${\Delta}E=0.00479{\cdot}D^{0.773}{\cdot}T^{0.800}$ The biodegradation rate of DOC was increased proportionally with the increase of ozone dosing rate and contact time irrespective of landfill site age. The increase of biodegradability by ozone addition was not satisfactory. It is hard to expect significant increase in biodegradability by ozone treatment only. Thus, it is evaluated that ozone oxidation can not increase biodegradability significantly in concentrated wastewater composed of complex organic compound such as leachate.

• Bulletin of the Korean Chemical Society
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• v.21 no.12
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• pp.1217-1221
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• 2000

L-alanine dehydrogenase from Bacillus subtilis exhibits allosteric kinetic properties in the presence of $ZN^{2+}$. $ZN^{2+}$ induces the binding of substrate (L-alanine) to be cooperative at pH 8.0. The effect of pH variation between pH 7.0 and pH 10.0 on the inhibition by $ZN^{2+}$ correlates with the pH effect on the $K_m$ values for L-alanine within these pH range indicating that $ZN^{2+}$ and substrate compete for the same site. No such cooperativity is induced by $ZN^{2+}$ when the reaction is carried out at pH 10. At this higher pH, $ZN^{2+}$ binds with the enzyme with lower affinity and noncompetitive with respect to L-alanine. Inhibition of L-alanine dehydrogenase by $ZN^{2+}$ depends on the ionic strength. Increase in KCI concentration reduced the inhibition, but allosteric property in $ZN^{2+}$ binding is conserved. A model for the regulatory mechanism of L-alanine dehydrogenase as a noncooperative substrate-cooperative cofactor allosteric enzyme, which is compatible in both concerted and the sequential allosteric mechanism, is proposed.

• Nuclear Engineering and Technology
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• v.54 no.10
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• pp.3949-3956
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• 2022

Kori Unit 1 is planning a system decontamination project to reduce radiation exposure of decommissioning workers, prevent the spread of contamination and down-grade the level of classification of radioactive waste. The system decontamination range for Kori Unit 1 will be the entire primary system, including RCS, CVCS and RHRS. Some system design modifications are required for the system decontamination operation. In this paper, major system design modifications were evaluated based on the conditions that system restoration is needed after completion of system decontamination. The major system design modifications are CIDF connection location to system, system decontamination operating pressure control, RCP seal water injection and formation of letdown flow. It was evaluated that there was no negative effect on the system due to the system design modifications. However, as the RCP seal water is injected into the system in the oxidation process, the concentration of the oxidizing agent is diluted. Therefore, the oxidizing agent injection and system decontamination operation procedures should be developed to address the dilution effect of the oxidizing agent. The system design modifications dealt in this paper will be finally confirmed through on-site investigation in the future, and if necessary, the system design modifications will be re-evaluated.

• Journal of Korean Society of Water and Wastewater
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• v.23 no.6
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• pp.743-752
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• 2009

One of the major problems associated with operation of domestic sewer lines involves hydraulic problems such as insufficient conveyance capacity, exceeding maximum velocity, and deficiency of minimum velocity. It has also been pointed out that influent concentration lower than design concentration of pollutants, which is mainly caused by unidentified inflow and infiltration, degrades the operational efficiency of many sewage treatment plants (STPs). A computer-added analysis method supporting a coupled simulation of sewage quality and quantity is essentially required to evaluate the status of existing STPs and to improve their efficiency by a proper sewer rehabilitation work. In this study, dynamic water quality simulations were conducted using MOUSE TRAP to investigate the principal parameters that governs the changes of BOD, ${NH_4}^+$, and ${PO_4}^{3-}$3- concentrations within the sewer networks based on data acquired through on-site and laboratory measurements. The BOD, ${NH_4}^+$ and ${PO_4}^{3-}$3- concentrations estimated by MOUSE TRAP was lower than theoretical pollution loads because of sedimentation and decomposition in the sewer. The results revealed that sedimentation is a most important factor than other biological reactions in decreasing pollutant load in the sewers of C-city. The sensitivity analysis of parameters pertaining to water quality changes indicated that the effect of the BOD decay rate, the initial DO concentration, the half-saturation coefficient of dissolved BOD, and the initial sediment depth is marginal. However, the influence of settling rate and temperature is relatively high because sedimentation and precipitation, rather than biological degradation, are dominant processes that affect water quality in the study sewer systems.

• Journal of the Korea Organic Resources Recycling Association
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• v.26 no.2
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• pp.19-32
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• 2018

This study has been carried out to analyze the effects of leachate recirculation on methane gas concentration in the Landfill. The monthly average on precipitation of the landfill area during the period from 2010 to 2016 has been recorded at 130.9 mm and the total precipitation was recorded at 73.7 mm for the month of June in 2017. And based on the Korea meterological administration data obtained, the water content has been anticipated to be at low level. And for the control environment testing on the effects of leachate recirculation, the reading has been carried out in relation to the methane gas concentration with the landfill site tested with average reading of 30.14%. Once the reading has been established 5 tones of leachate has been injected and the readings carried out respectively with the first reading recorded at 24.66% on June with subsequent readings carried out, 31.51 (6/24), 36.88% (7/1) and final reading carried out on 7/25 registered at 52.47%. Based on the leachate recirculation, the test showed increase of methanate concentrations with the concentration percentage showing between 50~65%.

• BMB Reports
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• v.31 no.4
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• pp.391-398
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• 1998

In vitro effects of acetone, methanol, and dimethylsulfoxide (DMSO) on liver microsomal cytochrome P450 (P450) content, and P450-dependent arylhydrocarbon hydroxylase (AHH) and 7-ethoxycoumarin O-deethylase (ECOD) activities were studied in rats. Acetone at 1% (v/v) enhanced the content ofP450, assayed spectrally in 3-methylcholanethrene (MC)- and ${\beta}-naphthoflavone$ (BNF)-inducible microsomes by 18 and 7%, respectively. Methanol, up to 5% (v/v) applied, also showed enhancement effects on P450 content in liver microsomes from rats treated with phenobarbital (PB), MC, and BNF, as well as uninduced microsomes with similar but low strength. DMSO, however, did not show such enhancing effects at the ranges of the concentrations applied. AHH and ECOD activities in MC-inducible microsomes were also enhanced by acetone at 1%, which was in proportion to the increase in P450 content by the same concentration. However, the P450 content, and AHH and ECOD activities, were decreased by increasing the concentration of acetone. Methanol at the same concentration with acetone also enhanced ECOD activity but not AHH activity in MCinducible microsomes. The enhancing effect of acetone on the enzymes was negligible when the microsomes were pretreated with a specific monoclonal antibody of MC-inducible isozyme. The difference in the effects of these solvents on P450 system might be due to their different properties that cause the P450 active site to be exposed in milieu.

• Journal of Environmental Impact Assessment
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• v.15 no.2
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• pp.121-127
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• 2006

The conventional water quality measurements by point sampling provide only site specific temporal water quality information but not the synoptic geographic coverage of water quality distribution. To circumvent these limitations in temporal and spatial measurements, the use of remote sensing is increasingly involved in the water quality monitoring research. In other to assess a trophic state of Yongdam reservoir using satellite imagery data, I obtained Landsat ETM data and water quality data on 16th September and 18th October 2001. The approach involved acquisition of water quality samples from boats at 33 sites on 16th September and 30 sites on 18th October 2001, simultaneous with Landsat-7 satellite overpass. The correlation coefficients between the DN values of the imagery and the concentrations of chlorophyll-a were analyzed. The visible bands(band 1,2,3) and near infrared band(band 4) data of September image showed the correlation coefficient values higher than 0.9. The October image showed the correlation coefficient values about 0.7 due to the atmospheric effect and low variation of chlorophyll-a concentration. Regression models between the chrophyll-a concentration and DN values of the Landsat imagery data have been developed for each image. The regression model was determined based on the spectral characteristics of chlorophyll, so the green band(band 2) and near infrared band(band 4) were selected to generate a trophic state map. The coefficient of determination(R2) of the regression model for 16th September was 0.95 and that of the regression model for 18th October was 0.55. According to the trophic state map made based on Aizaki's TSI and chlorophyll-a concentration, the trophic state of Yongdam reservoir was mostly eutrophic state during this study.

• Journal of Korean Society for Atmospheric Environment
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• v.10 no.2
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• pp.90-97
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• 1994

PIXE( Proton Induced X- ray Emission ) analysis has been applied to the analysis of aerosol for the Purpose of pollution monitoring. Coarse and fine Particle fractions were sampled selectively, using Nuclepore filter in stacked filter units, once a month from February to September in 1993 at urban and rural sites. Concentration of 9 elements, Si, S, K, Ca, Mn, Fe, Cu, Zn and Pb was determined without Pretreatment of Samples. Comparison of data between urban and rural site revealed higher elemental concentration level in urban aerosol. From April to May aerosol sampling was carried out daily to observe the effect of Yellow Sand on the composition of aerosol in the Korean Peninsula. During the Yellow Sand period, Si, Ca, Fe content level in aerosol became more than 5 times higher than normal. The elemental concentration of the aerosol samples of Daejeon City was compared with that of two foreign cities. S and Pb( which are fuel- derived elements) levels in Daejeon City aerosol appeared to be lower than those of foreign cities. And it may be due to the leaded-fuel restriction policy of Korean government since 1987.

• Journal of Dental Anesthesia and Pain Medicine
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• v.23 no.1
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• pp.19-28
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• 2023

Background: Fearful and anxious patients who find dental treatment intolerable without sedative and analgesic support may benefit from moderate sedation. Target controlled infusion (TCI) pumps are superior to bolus injection in maintaining low plasma and effect-site concentration variability, resulting in stable, steady-state drug concentrations. We evaluated the safety and efficacy of moderate sedation with remifentanil and propofol using TCI pumps in non-hospital dental settings. Methods: A prospective chart review was conducted on 101 patients sedated with propofol and remifentanil using TCI pumps. The charts were completed at two oral surgeons and one general dentist's office over 6 months. Hypoxia, hypotension, bradycardia, and over-sedation were considered adverse events and were collected using Tracking and Reporting Outcomes of Procedural Sedation (TROOPS). Furthermore, patient recovery time, sedation length, drug dose, and patient satisfaction questionnaires were used to measure sedation effectiveness. Results: Of the 101 reviewed sedation charts, 54 were of men, and 47 were of women. The mean age of the patients was 40.5 ±18.7 years, and their mean BMI was 25.6 ± 4.4. The patients did not experience hypoxia, bradycardia, and hypotension during the 4694 min of sedation. The average minimum Mean Arterial Pressure (MAP) and heartbeats were 75.1 mmHg and 60.4 bpm, respectively. 98% of patients agreed that the sedation technique met their needs in reducing their anxiety, and 99% agreed that they were satisfied with the sedation 24 hours later. The average sedation time was 46.9 ± 55.6 min, and the average recovery time was 12.4 ± 4.4 min. Remifentanil and propofol had mean initial effect-site concentration doses of 0.96 µ/.ml and 1.0 ng/ml respectively. The overall total amount of drug administered was significantly higher in longer sedation procedures compared to shorter ones, while the infusion rate decreased as the procedural stimulus decreased. Conclusion: According to the results of this study, no patients experienced adverse events during sedation, and all patients were kept at a moderate sedation level for a wide range of sedation times and differing procedures. The results showed that TCI pumps are safe and effective for administering propofol and remifentanil for moderate sedation in dentistry.

• Journal of Soil and Groundwater Environment
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• v.20 no.1
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• pp.1-6
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• 2015

The objectives of this study were to calculate the radius of influence (ROI) of well for an air-sparging (AS)/soil vapor extraction (SVE) system and to evaluate the applicability of the system applied for the remediation of the petroleum contaminated rail site. For air permeability test, three monitoring wells were installed at a location of 1.3 m, 2.3 m, 3.0 m from the extraction well. And the pressure of each monitoring well was measured by extracting air from the extraction well with the pressure and flow of $(-)2,600mmH_2O$ and $1.58m^3/min$. The ROI for an extraction well was calculated as 4.31 m. Air was injected into the injection well with the pressure and flow of $3,500mmH_2O$ and $0.6m^3/min$ to estimate the radius of influence for oxygen transfer. Oxygen concentrations of air from three monitoring wells were measured. The ROI of an injection well for oxygen transfer was calculated as 3.46 m. The 28 extraction wells and 19 injection wells were installed according to the ROI calculated. The AS/SVE system was operated eight hours a day for five months. The rail site was contaminated with the petroleum and concentrations of benzene, toluene, and xylene were over the 'Worrisome Standard' of the 'Soil Environment Conservation Act'. The contaminated area was estimated as $732m^2$ and contaminants were dispersed up to (-)3 m from the ground. During the operation period, soil samples were collected from 5 points and analyzed periodically. With the AS/SVE system operation, concentrations of benzene, toluene, and xylene were decreased from 7.5 mg/kg to 2.0 mg/kg, from 32.0 mg/kg to 23.0 mg/kg, from 35.5 mg/kg to 23.0 mg/kg, respectively. The combined AS/SVE system applied to the rail site contaminated with volatile organic compounds (VOCs) exhibited a high applicability. But the concentration of contaminants in soil were fluctuated due to the heterogeneous of soil condition. Also the effect of the remediation mechanisms was not clearly identified.