• Title/Summary/Keyword: Effect Modifier

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Toughening of PLA stereocomplex by Impact modifiers (충격보강제에 의한 PLA stereocomplex의 강인화 연구)

  • Nam, Byeong-Uk;Lee, Bum-Suk
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.13 no.2
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    • pp.919-925
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    • 2012
  • We tried to blend PLLA and PDLA at overall compositions to form PLA stereocomplexes (SC). The presence of the SC crystalline phase in the PLLA matrix was verified by differential scanning calorimetry (DSC). As a result, a various PDLA composition of the PLA SC blends can influence PLA SC formation. And the largest amount of PLA SC crystallites was formed when PLLA/PDLA ratio is 50/50. In addition, we have tried to do PLA SC toughening with two impact modifiers in 92/8, 85/15 ratio of PLLA/PDLA to enhance the mechanical properties such as impact strength. Thermal and mechanical properties of PLA SC were investigated by DSC, HDT, Izod impact tester and UTM. PLA SC formation decreased when 10-20 wt% of Strong120 (impact modifier) was added. On the other hand, there is no effect on PLA SC formation when 10-20% of Elvaloy (impact modifier) was added. HDT values dramatically increased over $100^{\circ}C$ with the addition of PDLA. However, HDT decreased as Strong120 and Elvaloy content increased. Finally, we could find well balanced composition of toughened PLA SC with 10wt% of impact modifier in flexural modulus and impact strength.

The Sijo Strained by the Preceding Line: Focusing on the Works of Bang-yeon Wang (선행하는 행(行)에 의해 긴장되는 시조: 왕방연의 작품들을 중심으로)

  • Park, In-kwa
    • The Journal of the Convergence on Culture Technology
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    • v.4 no.2
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    • pp.149-153
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    • 2018
  • The purpose of this study is to actively utilize the type of tension of Sijo in literary therapy programs. I will examine the Sijo of the Bang-yeon Wang. The Sijo of the Bang-yeon Wang is not known much yet, so we will discuss it. The Sijo of the Bang-yeon Wang has the effect of conveying the meaning while the modifier tensions the next sentence. This literary framework can be useful for literary therapy programs.

Effect of surface modifiers on the nano porous silica aerogels prepared by ambient drying process (상압건조 나노다공성 실리카 에어로젤에 대한 개질제 효과)

  • Kim, Tae-Jung;Oh, Young-Jei
    • Journal of Sensor Science and Technology
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    • v.16 no.1
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    • pp.77-83
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    • 2007
  • Nanoporous silica aerogels with various surface modifiers were prepared by ambient drying process. Tetraethylorthosilicate (TEOS) were used a raw material. Ambient drying process for various surface modifier was studied in the point of view of a crack-free monolith and thin films and low cost. Various kinds of surface modifiers like as hexamethyldisilazane (HMDSZ), trimethlychlorosilane (TMCS), methlytriethoxylsilane (MTES), and methlytrimethoxysilane (MTMS) were studied in order to enhance hydrophobicity for the silica aerogel. Surface modified aerogels were evaluated by FT-IR, TG, BET, SEM and wetting angle measurement. Homogeneous and crack-free aerogels were obtained by modifying the HMDSZ and the TMCS. However silica xerogel was obtained when modified with MTMS, MTES.

Experimental Study on the Development of Fuel-Efficient Gasoline Engine Oil (가솔린 엔진오일의 개선을 통한 연비절감에 관한 연구)

  • Moon, W.S.;Lee, J.H.;Kim, S.H.;Lee, D.H.;Ryoo, S.C.
    • Transactions of the Korean Society of Automotive Engineers
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    • v.1 no.3
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    • pp.46-54
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    • 1993
  • In order to develop a fuel-efficient gasoline engine oil, an experimental study was conducted using an engine dynamometer, a passenger car and the SRV machine. Oil samples with different viscosity were prepared by adding several friction modifiers to select the best one and also to investigate the effect of the viscosity grade. From the study, we have developed engine oils which result in good fuel economy. The viscosity grade of 7.5W/30 was best among the oils investigated with respect to fuel economy and a fatty amine type friction modifier had the good fuel-economy property.

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Effect $\beta$-Cyclodextrin on the Taste Quality of Neohesperidin Dihydrochalcone

  • Chung, Hai-Jung
    • Preventive Nutrition and Food Science
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    • v.1 no.2
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    • pp.186-189
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    • 1996
  • Neohesperidin dihydrochalcone(NHDC) is an intense sweetener with lingering aftertaste, which limits NHDC to use as a sweetener in food products. This study was conducted to examine the changes of teste quality of NHDC when using $\beta$-cyclodextrin($\beta$-CD) as a taste modifier. A series of $\beta$-CD(0.01%, 0.03%, 0.1%, 0.176%) was added to NHDC solution (100ppm) and the taste quality was evaluated by magnitude estimation. It was found that $\beta$-CD produced a significant effect in the reduction of aftertaste of NHDC(p<0.01) and sweetness as well.(p<0.001). Linear regression(log mean magnitude estimate versus $\beta$-CD concentration) analysis showed that the intensity of sweetness(n=-0.31) decreased more rapidly than that of aftertaste(m=-0.17). This result suggests the possibility that $\beta$-CD may form inclusion complex with NHDC, so that the hydrophobic portion is encapsulated in the cavity of $\beta$-CD and the carbohydrate moiety is oriented to the outside of the cavity. Or it may be that $\beta$-CD competes with the NHDC molecule for binding to the taste receptor, resulting in reduced perceived intensity.

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Effect of Organic Processing Parameters in Non-aqueous Tape-casting on Dispersion Stability of Barium Titanate-Borosilicate Glass Based Suspensions (비수계 테잎성형공정의 유기공정변수의 변화에 따른 티탄산바륨-붕규산염유리계 현탁액의 분산안정성)

  • Yeo, Jeong-Gu;Choi, Sung-Churl
    • Korean Journal of Materials Research
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    • v.13 no.11
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    • pp.725-731
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    • 2003
  • The effect of organic processing parameters on the dispersion stability of the BaTiO$_3$-based dielectric particles and borosilicate glass particulate suspensions was investigated in a system where organic solvents, dispersant, binder and modifier were used as processing additives in a low temperature cofired ceramic fabrication processes. Two- and three-component organic solvents were used to disperse ceramic particles and it was found the better stability in the particulate suspension prepared in a bi-solvent, which was consists of toluene and ethanol in a non-azeotropic composition. The addition amount of organic additives had a great impact on dispersion in the present investigation. The flow curves of the suspensions prepared with binder and modifier were fitted according to the power-law equation, which indicates that the internal structure of the suspension could be disturbed under the applied shear stress. Finally, the LTCC green tapes were successfully tape-cast based upon the optimum formulation of LTCC suspension and its microstructure was compared with that of the hard-agglomerates.

Laboratory Evaluation of the Properties of Sulfur Modified Asphalt Mixtures (황이 첨가된 개질 아스팔트 혼합물의 실내 물성 평가)

  • Yang Sung-Lin;Kim Boo-Il;Kim Nam-Ho;Rhee Suk-Keun
    • International Journal of Highway Engineering
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    • v.8 no.3 s.29
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    • pp.163-172
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    • 2006
  • This study evaluated the laboratory properties of asphalt binder and mixture modified with SPC(Sulfur Polymer Cement), which consists of sulfur as a main ingredient that is an industrial by-product made from refining process of crude oil and carbon-black as an additive. Four levels of SPC modifier ratios(0, 10, 30, 50%) were evaluated in the laboratory. Superpave(Superior Performing Asphalt Pavements) system was used to determine the PG(Performance Grade) and evaluate the property of SPC modified binder at the different temperatures. IDT(Indirect Tensile Test) was performed to evaluate the resistance of fatigue and low-temperature cracking at $10^{\circ}C\;and\;-10^{\circ}C$. Wheel-tracking test was also performed to evaluate the rutting-resistance of SPC modified asphalt mixtures. Test results showed that the more SPC modifier ratios, the better rutting-resistance and the more potential of low-temperature cracking resistance. However, SPC modifier did not show the effect on the fatigue cracking resistance.

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Separation of Functionalized Heterocyclic Compounds by High Performance Liquid Chromatography(I) (고성능 액체 크로마토그래피에 의한 기능성 헤테로고리화합물의 분리(I))

  • Lee, Kwang-PilI;Cho, Yun Jin;Lee, Young Cheol
    • Analytical Science and Technology
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    • v.10 no.6
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    • pp.408-417
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    • 1997
  • Normal phase or reversed phase liquid chromatographic separation of some structural isomers of functionalized heterocyclic compounds has been carried out by using several different columns and various mobile phases. The optimal experimental conditions for separation of structural isomers were found on a ternary solvent system including alcohol as a modifier. This polar modifier is preferentially adsorbed onto strong adsorption site, leaving a more uniform population of weaker site that then serve to retain the sample. This 'deactivation' of the adsorbent leads to a number of improvements in subsequent separations. The optimal mobile phase system of separation were found on normal phase on structural isomers. Retention mechanism of normal phase system was also studied depending on adsorption strength between solute and stationary phase of column. However, retention factors of reversed phase system were found on hydrophobic interaction with solvophobic effect.

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Evaluation of the Effect of PE Wax on Asphalt Binder Properties (PE Wax를 첨가한 아스팔트 바인더의 물리적 특성)

  • Kim, Boo-Il;Jeon, Sung-Il;Lee, Moon-Sup;Cho, Yoon-Ho
    • International Journal of Highway Engineering
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    • v.8 no.4 s.30
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    • pp.101-113
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    • 2006
  • Generally, asphalt binder modifier increases the viscosity at high temperature as well as at mixing and paving temperature, so that higher temperature is required to produce the hot-mix asphalt. Otherwise, wax is able to improve workability by means of decreasing the viscosity of asphalt binder. In this study, the effect of PE wax used to modify the asphalt binder was evaluated in laboratory. The properties of PE wax modified binder were compared with those of SBS and Crumb Rubber Modified binders. The results showed that wax type I has an effect on strengthening rut resistance as well as improving workability. However, wax type I weaken crack resistance due to making binder harder at intermediate temperature. The results also showed that wax type II has an effect on improving workability and on strengthening crack resistance due to making binder softer.

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The Study on Prepare Water Proof Agent by Acryl Copolymer and Oleic Acid Mixed Emulison (아세트화 아크릴 공중합체-올레인산 혼합 에멀젼계 방수제 제조연구)

  • Kim, Young-Geun;Hwang, Yong-Hyun
    • Journal of the Korean Applied Science and Technology
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    • v.13 no.3
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    • pp.83-94
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    • 1996
  • EMA-co-DAMA were synthesized from 2-diethylaminoethyl metacrylate and ethylhexyl metacrylate in acrylmonomer. To facilitate water emulsification, acrylic copolymer was cationized by acetic acid to produce acetated acrylic copolymer. The structures of the synthesized copolymer and acetated copolymers were confirmed by IR, NMR, and molecular weight was measure by GPC, and C.H.N elemental analysis. Acetated acrylic copolymers were perfectly emulsified in water and showed increased emulsion stability. Polymer dispersion for cement modifier[(PDCM-PED) water proof agent of cement for concrete in building construction] was prepared by blending of the guaternized acrylic copolymer syndisized above, sodium silicate, sodium gluconate and oleic acid emulsion. The result with prepared polymer dispersion of cement modifier was examined, and it was found that excellent waterprooffing effect ; Water permeability ratio is 0.50 under the water pressure of $100g/cm^2$ and 0.60 under $3kg/cm^2$, and water absorption ratio is $0.42{\sim}0.50$ and $1.0{\sim}1.02$ compressive strength ratio at mixed of water/PDCM-PED is 50 times.