• Applied Chemistry for Engineering
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• v.35 no.4
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• pp.341-345
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• 2024

Common adhesives contain harmful chemicals, posing risks to humans and the environment. Basil seeds, an underutilized resource, can offer a solution. We extracted mucilage from basil seeds and found that altering the basil seed mucilage (BSM) to water ratio allowed us to control the adhesive strength. As the concentration of BSM increased and the water evaporated, adhesive strength improved. BSM can serve as both an adhesive and pressure-sensitive adhesive. This research showcases BSM's impressive strength and stability, making it a promising eco-friendly industrial adhesive option from plant-based sources, revolutionizing the adhesive industry.

• Korean Chemical Engineering Research
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• v.62 no.4
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• pp.335-343
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• 2024

This study was conducted to confirm the potential of adhesive resins formulated with rapeseed flour (RSF), which is a residue in the production of edible oil, for the manufacture of medium-density fiberboards (MDF). The RSF-based adhesive resins were formulated with the weight ratio of RSF hydrolyzates (80, 70, 60 wt%) to PF prepolymer(20, 30, 40 wt%), MDF was fabricated in accordance with its resin content and target density using the RSF-based adhesive resin, and then the physical properties(density, moisture content, bending strength, internal bonding strength and thickness swelling) and formaldehyde emission of the MDF were measured. The effect of the weight ratio of RSF hydrolyzate to PF prepolymer was the greatest, followed by that of target density and resin content. The values of MDF fabricated with RSF-based adhesive resins exceeded those with urea-formaldehyde resins, which is mostly used as a resin in the manufacture of MDF. Based on the results of MDF per experimental factors, the optimal conditions were determined to target density of 0.7 g/cm³, resin content of 5% and PF-prepolymer weight ratio of 40 wt% in RSF-based adhesive resin, and physical properties and formaldehyde emission of the MDF fabricated with the conditions satisfied the requirements for MDF and E₀ grade, which was designated by National Institute of Forest Science, except for thickness swelling. In conclusion, the potential of RSF-based adhesive for the production of MDF could identify on the basis of the results of this study. However, the stable securement of RSF through the development of bio-refinery process for rape plant is required to commercialize RSF-based adhesive resins for MDF production.

• Journal of the Korean Wood Science and Technology
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• v.40 no.3
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• pp.164-176
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• 2012

In the present study, rapeseed flour (RSF), which is a by-product from the production of edible oil and biodiesel extracted from rapeseed, was used to develop alternative adhesives for the production of plywood panels. To examine the effects of the enzyme on the adhesive properties and formaldehyde emission of the RSF-based adhesive resins, three enzymes, such as cellulase (CEL), pectinase (PEC) and protease (ALC), were used either separately or together. As a crosslinking agent, PF prepolymers, which were prepared with 1.5, 1.8 and 2.1 mole formaldehyde and 1 mol phenol (1.8-, 2.1- and 2.4-PF), were added into the RSF hydrolyzates. The adhesive resins formulated with CEL- or CEL-PEC-RSF hydrolyzates and 1.8-F/P PF prepolymers exhibited excellent adhesive strengths and formaldehyde emission. The tensile shear strength and formaldehyde emission of the plywood panels bonded with the formulate resins were satisfied with the minimum requirement of the KS standard for ordinary plywood panels (0.6 N/$mm^2$). In addition, formaldehyde emissions of the plywood panels approached to that of E0 specified in the KS standard (0.5 mg/${\ell}$), and even had much better than those of commercial UF glue mixes. Overall, the use of RSF-based adhesive resins for the production of plywood panels might provide durable adhesive properties and an environmentally friendly substitute for petroleum-based adhesive resins. However, further researches - the increase of solid content of RSF-based adhesives for reducing press time and the microscopic observation of plywood specimen for identifying the relationship between tensile shear strength and the penetration of adhesives into wood structure - are required to commercialize the RSF-based adhesives.