• Title/Summary/Keyword: Eco-process

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Fe(II)/과황산/전기화학적 산화 공정에 의한 2,4-D의 제거 (Removal of 2,4-D by an Fe(II)/persulfate/Electrochemical Oxidation Process)

  • 현영환;최지연;신원식
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제26권1호
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    • pp.45-53
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    • 2021
  • The removal of 2,4-dichlorophenoxyacetic acid (2,4-D) in aqueous solution by coupled electro-oxidation and Fe(II) activated persulfate oxidation process was investigated. The electrochemical oxidation was performed using carbon sheet electrode and persulfate using Fe(II) ion as an activator. The oxidation efficiency was investigated by varying current density (2 - 10 mA/㎠), electrolyte (Na2SO4) concentration (10 - 100 mM), persulfate concentration (5 - 20 mM), and Fe(II) concentration (10 - 20 mM). The 2,4-D removal efficiency was in the order of Fe(II) activated persulfate-assisted electrochemical oxidation (Fe(II)/PS/ECO, 91%) > persulfate-electrochemical oxidation (PS/ECO, 51%) > electro-oxidation (EO, 36%). The persulfate can be activated by electron transfer in PS/ECO system, however, the addition of Fe(II) as an activator enhanced 2,4-D degradation in the Fe(II)/PS/ECO system. The 2,4-D removal efficiency was not affected by the initial pHs (3 - 9). The presence of anions (Cl- and HCO3-) inhibited the 2,4-D removal in Fe(II)/PS/ECO system due to scavenging of sulfate radical. Scavenger experiment using tert-butyl alcohol (TBA) and methanol (MeOH) confirmed that although both sulfate (SO4•-) and hydroxyl (•OH) radicals existed in Fe(II)/PS/ECO system, hydroxyl radical (SO4•-) was the predominant radical.

Combination of ultrasonic assisted liquid phase exfoliation process and oxidation-deoxidation method to prepare large-sized graphene

  • Qi, Lei;Guo, Ruibin;Mo, Zunli;Wu, Qijun
    • Carbon letters
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    • 제25권
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    • pp.50-54
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    • 2018
  • Large-size graphene samples are successfully prepared by combining ultrosonic assisted liquid phase exfoliation process with oxidation-deoxidation method. Different from previous works, we used an ultrasound-treated expanded graphite as the raw material and prepared the graphene via a facile oxidation-reduction reaction. Results of X-ray diffraction and Raman spectroscopy confirm the crystal structure of the as-prepared graphene. Scanning electron microscopy images show that this kind of graphene has a large size (with a diameter over $100{\mu}m$), larger than the graphene from graphite powder and flake graphite prepared through single oxidation-deoxidation method. Transmission electron microscopy results also reveal the thin layers of the prepared graphene (number of layers ${\leq}3$). Furthermore, the importance of preprocessing the raw materials is also proven. Therefore, this method is an attractive way for preparing graphene with large size.

바이오디젤부산물인 폐글리세롤을 이용한 친환경 가소제의 개발 (Development of an Eco-friendly Plasticizer using Crude Glycol Derived from the Biodiesel Process)

  • 강수정;배성재;진대언;김진환
    • 한국산업보건학회지
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    • 제24권3호
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    • pp.365-370
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    • 2014
  • Objectives: The major objective is development of an eco-friendly non-phthalate plasticizer using crude glycol derived from the biodiesel process. Methods: Glycerol monolaurate(GML) was synthesized from glycol and triglyrcerides. Glycerol diacetomonolaurate(GDAL) was synthesized from GML and acetic acid. Results: The synthesis of the GDAL plasticizer was measured with nuclear magnetic resonance spectroscopy(NMR). Mechanical properties were measured by universal testing machine(UTM) and the experimental values were compared with phthalate plasticizers such as dioctyl phthalate(DOP). In particular, the values for tensile strength and elongations with GDAL were higher than with DOP. Conclusions: We confirmed the development of an eco-friendly non-phthalate plasticizer by NMR. Based on our results, applicability for food and drug packaging materials was found.

친환경 가스개폐기 개폐성능 향상을 위한 유동해석 및 실험 (Fluid Dynamics Analysis and Experimental Trial to Improve the Switching Performance of Eco-friendly Gas Insulated Switch)

  • 유련;안길영;김영근;조해용
    • 한국기계가공학회지
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    • 제21권9호
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    • pp.42-49
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    • 2022
  • An underground electric switch is a high-voltage switch used in distribution network systems for a reliable power supply. Many studies are being conducted to expand the switch to use an eco-friendly gas using dry air instead of SF6 gas to reduce greenhouse gas emissions. In this study, a flow analysis model was established to improve the performance of an eco-friendly gas switch. The results were compared and reviewed through experiments. For the optimal arc grid design applied to the switch, the flow characteristics based on the flow path configuration and the changes in arcing time for each configuration were compared. Flow analysis can predict the switch flow distribution, and a comparative review of the flow path configurations of various methods is possible.

김환기 회화를 응용한 에코티셔츠의 모티브 디자인 개발 (Eco T-shirt designs inspired by paintings of Whan-ki Kim)

  • 이경희;김래연;김새봄
    • 복식문화연구
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    • 제21권2호
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    • pp.195-205
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    • 2013
  • Eco T-shirts have become a part of environmental campaigns following social trends toward eco-friendly designs. With the demand for such designs expected to grow, there has arisen a need for higher product variety. In the past, eco T-shirts were designed to convey messages about the protection of nature through the use of environmentally friendly text or images. However, in order to respond to the preferences and emotional needs of Koreans, designs should cater to their characteristics and tastes. To this end, this study used a Whan-ki Kim-inspired motif to develop an eco-friendly design tailored to Korean perspectives. It is believed that this process can not only result in a distinctive eco T-shirt design, but also make it globally competitive. With regard to research methodology, a total of 41 paintings of Whan-ki Kim were analyzed and classified into four major themes or key values expressed in modern eco-friendly fashion designs: naturalness, indigenousness, harmony between nature and man, and harmony between natural and artificial beauty. Employing a wide range of CAD techniques and varying forms, the themes were developed into 28 T-shirt designs after their forms, tones, and textures were fully explored. This study demonstrates the possibility of designing creative, aesthetic, and high value-added eco T-shirts through motif development. In addition, it successfully integrates Korean paintings in the development of T-shirt designs aimed at communicating environmentally friendly messages.

성능, 사용성, 환경성 평가를 통한 소형온풍기 설계안 개발 사례 (A Case Study of Eco-Design for a Small-Size Electric Heater by Performance, Usability, and Life-Cycle Assessments)

  • 이백희;유희천
    • 대한산업공학회지
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    • 제40권2호
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    • pp.223-232
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    • 2014
  • Life-cycle assessment (LCA) is often employed to quantify the environmental impact of a product in a comprehensive manner. The aspects of performance and usability as well as that of eco-friendliness should be considered in an integrated manner for the market competitiveness of an eco-friendly product. The present study developed a product improvement plan for an eco-friendly electric heater by benchmarking two small-size electric heaters (companies 'H' and 'T') in terms of performance, usability, and eco-friendliness. The performance measurements such as temperature, humidity, wind speed, noise, and power consumption were collected while the two heaters were operated in a laboratory setting. Then, the usability evaluations such as aesthetics, operation satisfaction, performance satisfaction, and overall satisfaction were surveyed for the two heaters using a 5-point scale (1 for very unsatisfied and 5 for very satisfied). Lastly, the LCA analysis was conducted by following the six-step process of eco-friendly product design provided by KEITI. The analysis results of the two products being integrated with the aspects of product, service, and user, four design improvement directions such as eco-efficient, smart, modularized, and user-support were recommended for an eco-friendly electric heater. These proposed concepts would be useful to develop an eco-friendly electric heater design with a high level of market competitiveness.

전과정 분석을 통한 자동차엔진 재제조시 온실가스 저감효과 분석 (An Analysis of Greenhouse Gas Reduction effect of Automotive Engine Re-manufacturing throug Whole Process Analysis)

  • 박지형;이한솔;황용우;김영춘;이충근
    • 자원리싸이클링
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    • 제32권2호
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    • pp.43-51
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    • 2023
  • 본 연구에서는 자동차엔진의 신품제조시와 재제조시 발생하는 환경영향을 전과정 관점에서 산정하고 이를 기반으로 온실가스 저감효과를 산정하였다. 자동차엔진 원부자재 원료취득 및 제조공정에서 배출되는 온실가스량은 신품제조시 약 3,473 kg, 재제조시 약 872 kg으로 재제조를 통해 저감되는 온실가스량은 약 2,601kg으로 나타나 폐기 단계를 제외한 전과정 측면에서 저감효과가 있는 것으로 분석되었다. LCA 가중화 분석 결과 신품 제조시 환경영향은 1.07E+03 Eco-point, 재제조시 2.67E+02 Eco-point로 나타났으며, 주요 6대 영향 범주 중 지구온난화 점유비율이 99.72%, 99.68%로 높게 나타났다.

Reduction of eco-toxicity risk of heavy metals in the rotary drum composting of water hyacinth: Waste lime application and mechanisms

  • Singh, Jiwan;Kalamdhad, Ajay S.;Lee, Byeong-Kyu
    • Environmental Engineering Research
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    • 제20권3호
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    • pp.212-222
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    • 2015
  • Experiments were conducted on the immobilization of eight heavy metals (HMs) (Zn, Cu, Mn, Fe, Ni, Pb, Cd, and Cr) during 20-day rotary drum composting of water hyacinth. The Tessier sequential extraction procedure was used to investigate the fractionation of HMs. The eco-toxicity risk of HMs was assessed by risk assessment code (RAC). In the results, the bioavailability factor (BAF) for different HMs presented in the following order: Mn > Zn = Fe > Cu > Cr > Cd = Pb > Ni. The total concentration of Pb was higher than that of Zn, Cu, Mn, Cd and Cr; however, its BAF was the lowest among these HMs. These results confirmed that the eco-toxicity of HMs depends on bioavailable fractions rather than on the total concentration. The greatest reduction in bioavailability and eco-toxicity risk of HMs occurred in lime 1% and 2% as compared to control and lime 3%. The eco-toxicity risk of Fe, Ni, Pb, Cd and Cr was reduced from low risk to zero risk by rotary drum composting. These studies demonstrated the high efficiency of the rotary drum for degrading compost materials and for reducing the bioavailability and eco-toxicity risk of HMs during the composting process.

에코센터의 생태건축기술에 관한 연구 - 건축재료와 태양에너지활용시스템을 중심으로 - (A Study on the Eco-Tecnique of EcoCenter - Focused on the Building Material and Solar System -)

  • 최영호;심우갑
    • KIEAE Journal
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    • 제4권2호
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    • pp.65-72
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    • 2004
  • Ecological architecture enables people to recycle and reuse architectural resources within the category of ecosystem and also to minimize the effect on environment in a whole process, including architectural planning, usage and exhaustion to use sustainable energies. Rammed earth wall construction method utilized in EcoCenter located in Crystalwaters ecological village in Austrailia is a good example, which maximizes its advantages and also covers its limits to use soil and wood as structural resources. In a case of wood, they used non-treated timber to minimize environmental load and utilized used materials in openings. In the roofs, aluminum coated steel which is plated with zinc collects rain effectively even though it is not regenerable. Nontoxic finishes and insulation in floor and ceiling with used papers are able to minimize its environmental load. Solar energy system applied in EcoCenter enables them to market extra energy with electricity companies as well as support needs of its own buildings to utilize photovoltaic panel system with PV panels. Passive solar system is planned effectively in heating and cooling to apply regenerative walls in a use of rammed earth wall construction and natural ventilation systems through openings.

상호상관법에 의한 간질 초점부 피질뇌파 전파의 가시화 (Visualization of propagating process in the seizure discharge by use of cross-correlation analysis)

  • 김진우
    • 한국정보통신학회논문지
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    • 제10권8호
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    • pp.1471-1477
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    • 2006
  • 뇌파 기록은 난치성 간질 환자인 성인을 대상으로 하였다. 경막하 전극으로 부터 기록된 피질뇌파를 위상차해석에 의해서 간질 초점의 동정 및 발작파 전파의 가시화를 행하였다. 발작파의 세밀한 시간변화를 조사하기 위해서 자기 회귀모델, 웨이브렛해석을 이용하여 발작파 성분을 구하고, 상호상관법에 의해 각 전극 간의 위상차를 해석했다. 그 결과, 발작파의 초점은 적어도 2종류가 존재하였고, 각각의 전파방법도 달랐다. 이로 부터 발작파의 출현 기구는 동시에 적어도 2종류 존재하는 것을 확인할 수 있었다. 또한, 발작파 출현의 변화를 경시적으로 해석할 수 있기 때문에 발작파 전파의 가시화에 유효하다고 생각되어 진다.