• Title/Summary/Keyword: Earth Material

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An Information Management Strategy Over Entire Life Cycles of Hazardous Waste Streams (유해폐기물 생애 전주기 흐름 기반 정보 관리 전략)

  • Lee, Sang-hun;Kim, Jungeun
    • Clean Technology
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    • v.26 no.3
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    • pp.228-236
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    • 2020
  • Korea has an economy based on manufacturing industrial fields, which produce high amounts of hazardous wastes, in spite of few landfill candidates, and a significant concern for fine airborne particulates; therefore, traditional waste management is difficult to apply in this country. Moreover, waste collection and accumulation have recently been intensified by the waste import prohibitions or regulations in developing nations, the universalization of delivery services in Korea, and the global COVID-19 crisis. This study thus presents a domestic waste management strategy that aims to address the recent issues on waste. The contents of the strategy as the main results of the study include the (1) improvement of the compatibility of the classification codes between the domestic hazardous waste and the international ones such as those of the Basel Convention; (2) consideration of the mixed hazard indices to represent toxicity from low-content components such as rare earth metals often contained in electrical and electronic equipment waste; (3) management application based on risks throughout the life cycles of waste; (4) establishment of detailed material flow information of waste by integrating the Albaro system, Pollutant Release and Transfer Register (PRTR) system, and online trade databases; (5) real-time monitoring and prediction of the waste movement or discharge using positional sensors and geographic information systems, among others; and (6) selection and implementation of optimal treatment or recycling practices through Life Cycle Assessment (LCA) and clean technologies.

Residual Liquid Behavior Calculation for Vacuum Distillation of Multi-component Chloride System (다성분 염화물계 진공 증류의 잔류 액체 거동 계산)

  • Park, Byung Heung
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.12 no.3
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    • pp.179-189
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    • 2014
  • Pyroprocessing has been developed for the purpose of resolving the current spent nuclear fuel management issue and enhancing the recycle of valuable resources. An electrolytic reduction of the pyroprocessing is a process to reduce oxides into metals using LiCl as an electrolyte and requires a post-treatment process due to the inclusion of residual salt in porous metal products. A vacuum distillation has been adopted for various molten salt systems and could be applied to the post-treatment process of the electrolytic reduction. The residual salt in the metal products includes LiCl, alkali chlorides, and alkaline earth chlorides. In this paper, vapor pressures of chlorides have been estimated and the composition changes on the residual liquid during the vacuum distillation process have been calculated. A model combining a material balance and vapor-liquid equilibrium relations has been proposed under a constant vapor discharging flow rate and liquid composition changes have been calculated using the vapor pressures with respect to a dimensionless time. The behaviors have been compared with temperature and molten salt composition changes to simulate the process condition variation. The distillation of the residual salt has been dominated by LiCl which is the main component of the salt and CsCl of which vapor pressure is higher than that of LiCl would be readily removed. RbCl exhibits similar vapor pressure with LiCl and maintains its composition. However, $SrCl_2$ and $BaCl_2$ of which vapor pressures are much lower than that of LiCl are concentrated with time and expected to be possibly precipitated during the distillation when the initial compositions are increased.

Study on the immersion test of geopolymers made by recycling of coal ash (석탄회를 재활용한 지오폴리머 침지실험에 관한 연구)

  • Bang, John J.;Kang, Seunggu
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.28 no.5
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    • pp.199-205
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    • 2018
  • A geopolymer was produced from coal ash generated from an integrated gasification combined cycle (IGCC) plant and its water resistance was evaluated. For this purpose, the geopolymer specimens were immersed in water for 30 days to measure changes in microstructure and alkalinity of the immersion liquid. Particularly, the experiment was carried out with foaming status of the geopolymers and parameters of room temperature aging condition, and immersion time. The foamed geopolymer containing 0.1 wt% Si-sludge had pores with a diameter of 1 to 3 mm and exhibited excellent foamability. Also, the calcium-silicate-hydrate crystal phase appeared in the foamed geopolymer. In the geopolymer immersion experiment, the pH of the immersion liquid increased with time, because the un-reacted alkali activator remained was dissolved in the immersion liquid. From the pH change of the immersion liquid, it was found that geopolymer reaction in the foamed specimen was completed faster than the non-foamed specimen. Through this study, it was possible to successfully produce foamed and non-foamed geopolymers recycled from IGCC coal ash. Also the necessary data for the safe application of IGCC coal ash-based geopolymers to areas where water resistance is needed were established; for example, the process conditions for room temperature aging time, effect of foaming status, immersion time and so on.

Analysis on Cloud-Originated Errors of MODIS Leaf Area Index and Primary Production Images: Effect of Monsoon Climate in Korea (MODIS 엽면적지수 및 일차생산성 영상의 구름 영향 오차 분석: 우리나라 몬순기후의 영향)

  • Kang, Sin-Kyu
    • The Korean Journal of Ecology
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    • v.28 no.4
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    • pp.215-222
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    • 2005
  • MODIS (Moderate Resolution Image Spectrometer) is a core satellite sensor boarded on Terra and Aqua satellite of NASA Earth Observing System since 1999 and 2001, respectively. MODIS LAI, FPAR, and GPP provide useful means to monitor plant phonology and material cycles in terrestrial ecosystems. In this study, LAI, FPAR, and GPP in Korea were evaluated and errors associated with cloud contamination on MODIS pixels were eliminated for years $2001\sim2003$. Three-year means of cloud-corrected annual GPP were 1836, 1369, and 1460g C $m^{-2}y^{-1}$ for evergreen needleleaf forest, deciduous broadleaf forest, and mixed forest, respectively. The cloud-originated errors were 8.5%, 13.1%, and 8.4% for FPAR, LAI, and GPP, respectively. Summertime errors from June to September explained by 78% of the annual accumulative errors in GPP. This study indicates that cloud-originated errors should be mitigated for practical use of MODIS vegetation products to monitor seasonal and annual changes in plant phonology and vegetation production in Korea.

Investigation of Pyroprocessing Concept and Its Applicability as an Alternative Technology for Conventional Fuel Cycle (고온전해분리 기술의 개요 및 기존 핵연료주기 대체 기술로서의 적합성 검토)

  • Yoo, Jae-Hyung;Lee, Byung-Jik;Lee, Han-Soo;Kim, Eung-Ho
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.5 no.4
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    • pp.283-295
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    • 2007
  • The technical feasibility of a pyroprocessing of PWR spent fuels to recover nuclear fuel materials, uranium and transuranic elements group(TRU), was examined in this study. Also its applicability as a new fuel cycle technology in terms of non-proliferation was investigated. First, various unit processes were combined to a pyroprocess. Then the flow aspects of such materials of issue as uranium, transuraniums, rare earth, noble metals and heat generating elements were examined on the flowsheet, which was obtained by the assumptions on the basis of various experimental results in this work or separation data collected from literatures. Consequently, the calculated results of the material balance for the whole process showed that uranium and TRU could be recovered as products by 98.0 % and 97.0 %, respectively, from a PWR spent fuel while removing the other elemental groups into radioactive wastes. On the one hand, the TRU product was found to emit a considerable amount of ${\gamma}$-ray as well as neutrons favorably contributing to the strategy of proliferation resistance.

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Survey on distribution and vegetation environment of Tricholoma matsutake in Kyonggi province, Korea (경기도지역 송이버섯 분포 및 식생환경조사)

  • Ha, Tai-Moon;Kim, Young-Ho;Chi, Jeong-Hyun;Ju, Young-Cheuol;Kim, Hee-Dong;Sung, Jae-Mo
    • Journal of Mushroom
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    • v.2 no.4
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    • pp.175-183
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    • 2004
  • We carried out survey of a pine mushroom picking district and its vegetation environment for increase and maintainment of its production in Kyonggi province. The district which we could pick up pine mushroom among the nineteen surveyed district were sixteen such as Geoleun ri Gangcheon myeon Yeoju gun Kyonggi do, etc. and total yields were 470~600 kg in Kyonggi province. The temperature of atmosphere and earth in Yeoju and Bonghwa were droped to $19^{\circ}C$ at 5~7th september and maintained from $12^{\circ}C{\sim}18^{\circ}C$ during the a pine mushroom picking period. The density of a pine tree per $100m^2$ was 5.1~27.1 trees, the years of it was 15~50years old and height was 4~11 meter. The pine tree in a pine mushroom picking district was competed with oak trees, azaleas, lacquers, etc. The depth of organic materials accumulated on the pine mushroom mycelium layer was 4.5 cm in Yeoju. The soil texture of a pine mushroom picking district was almost sandy, soil pH was 4.3~5.1 and organic material content was 3.91~8.28%.

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Field Application of a Precast Concrete-panel Retaining Wall Adhered to In-situ Ground (원지반 부착식 판넬옹벽의 현장 적용성 평가)

  • Min, Kyoung-Nam;Lee, Jae-Won;Lee, Jung-Gwan;Kang, In-Kyu;Ahn, Tae-Bong
    • The Journal of Engineering Geology
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    • v.26 no.1
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    • pp.51-61
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    • 2016
  • New building methods are needed to aid increased inner-city redevelopment and industrial construction. A particular area of improvement is the efficient use of cut slopes, with the minimization of associated problems. A retaining wall of precast panels can resist the horizontal earth pressure by increasing the shear strength of the ground and reinforcing it through contact with the panels. Precast panels allow quick construction and avoid the problem of concrete deterioration. Other problems to be solved include the digging of borrow pits, the disposal of material cut from the slope, and degradation of the landscape caused by the exposed concrete retaining wall.This study suggest the methods of improvement of an existing precast panel wall system by changing the appearance of the panels to that of natural rock and improving the process of adhering the panel to a vertical slope. The panels were tested in the laboratory and in the field. The laboratory test verified their specific strength and behavior, and the field test assessed the panels' ground adherence at a vertical cutting. Reinforcement of the cutting slope was also measured and compared with the results of 3D numerical analysis. The results of laboratory test, identified that the shear bar increase the punching resistance of panel. And as a results of test construction, identified the construct ability and field applicability of the panel wall system adhered to in-situ ground. In addition to that, extended measurement and numerical analysis, identified the long-term stability of panel wall system adhered to in-situ ground.

Sulfur Isotope Composition of Seafloor Hydrothermal Vents in the Convergent Plate Boundaries of the Western Pacific: A Role of Magma on Generation of Hydrothermal Fluid (서태평양 지판소멸대의 해저열수분출구에서 관찰되는 황동위원소 조성변화: 열수 생성의 다양성과 마그마의 역할)

  • Kim, Jong-Uk;Moon, Jai-Woon;Lee, Kyeong-Yong;Lee, In-Sung
    • Economic and Environmental Geology
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    • v.45 no.2
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    • pp.145-156
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    • 2012
  • Seafloor hydrothermal system occurs along the volcanic mid-ocean ridge, back-arc spreading center, and other submarine volcanic regions. The hydrothermal system is one of the fundamental processes controlling the transfer of energy and matter between crust/mantle and ocean; it forms hydrothermal vents where various deepsea biological communities are inhabited and precipitates metal sulfide deposits. Hydrothermal systems at convergence plate boundaries show diverse geochemical properties due to recycle of subducted material compared to simple systems at mid-ocean ridges. Sulfur isotopes can be used to evaluate such diversity in generation and evolution of hydrothermal system. In this paper, we review the sulfur isotope composition and geochemistry of hydrothermal precipitates sampled from several hydrothermal vents in the divergent plate boundaries in the western Pacific region. Both sulfide and sulfate minerals of the hydrothermal vents in the arc and backarc tectonic settings commonly show low sulfur isotope compositions, which can be attributed to input of magmatic $SO_2$ gas. Diversity in geochemistry of hydrothermal system suggests an active role of magma in the formation of seafloor hydrothermal system.

Selection of Binder and Solid Materials for Pelleting Welsh Onion(Allium fistulosum L.) Seeds (파 펠렛종자 생산을 위한 접착제 및 피복재료 선발)

  • 강점순
    • Journal of Life Science
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    • v.12 no.6
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    • pp.721-730
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    • 2002
  • This study was carried out to select new pelleting binder and material for Welsh onion seeds. The optimum treatments of the various plant growth regulators to improve seed germination of the Welsh onion was also estimated. There were no significant effects of growth regulators on the germination percentage, but germination was faster according to the number of days to 50% of the final germination ($T_{50}$) and the mean number of days to germination (MDG) than those of the control. Germinability was increased when the seeds were soaked in gibberellic acid ($GA_3$) solution for 24hrs, even though there was no synergy effect on the germinability when $GA_3$ was mixed with 6-benzylaminopurine (BAP). The optimum treatment for improving germination of Welsh onion was observed when the tested seeds was soaked in 500 $\mu$M of $GA_3$ at $20^{\circ}C$ for 24hrs. Also, when the seeds soaked in the aforementioned treatment, the rate of germination was increased at lower temperature than at $20^{\circ}C$, the optimal temperature. The percentage and the speed of seed germination depended on the kinds of pelleting binder and their concentration. It showed that the higher the concentration of the binder for seeds pelleting, the lower the percentage of seed germination. Among the pelleting binder, polyvinyl alcohol (PVA) and polyvinyl pyrrolidone (PVP) were the best binders for seed pelleting, because seed germination using those binder did not affect on the concentration of binder. On the other hand, Carboxymethy cellulose (CMC) and methyl cellulose (MC) severely inhibited the seed germination The germinability was also different arcording to the pelleting materials. Among the different 58 pelleting materials, kaoline alone, the mixture of bentonite and kaoline, the mixture of bentonite, calcium carbonate and diatomaceous earth #300 were found as the best pelleting materials for welsh onion seeds.

The relation of structural transition, thermal and electrical stability deintercalation of Li- CICs(II) : For Li-EaGDICs and Li-EGDICs (Li-CICs의 Deintercalation에 따른 구조변이와 열적, 전기적 안정성과의 관계(II) : Li-EaGDICs와 Li-EGDICs에 관하여)

  • Oh, Won-Chun;Park, Chung-Oh;Back, Dae-Jin;Ko, Young-Shin
    • Analytical Science and Technology
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    • v.9 no.1
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    • pp.43-51
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    • 1996
  • We have discussed on the deintercalation process of Li-EaGICs and Li-EGICs synthesized under pressure and temperature by spontaneous oxidation reaction of those compounds based on the results of X-ray diffraction, thermal analysis and electrical specific resistivity analysis. According to the results of the X-ray analysis for the intercalation process, we have found that the stage 1 for Li-EaGICs and Li-EGICs were not completly formed, but their lower stages were formed mainly. And from this results of the deintercalation process, we have found that the deintercalation process did not occur any more after 4 weeks, and the Li-EGDICs have more residual lithium metals than LiEaGDICs between the graphite interlayers. According to the thermal decomposition analysis, Li-two compounds had included very hard exothermic reaction. And we have found that these compounds did not occrurred deintercalation reaction above $400^{\circ}C$. According to the results of the electrical specific resistivity measurements, Li-EGDICs have relatively lower electrical specific resistivity than Li-EaGDICs, and Li-EaGDICs showed a formation of the ideal curve. From these results, we can suggest that Li-EaGDICs have a better properties as an anode material secondary than Li-EGICs.

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