• Journal of Korean Society of Environmental Engineers
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• v.39 no.1
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• pp.9-18
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• 2017

Arsenic (As) has been considered as the most toxic one among various hazardous materials and As contamination can be caused naturally and anthropogenically. Major forms of arsenic in groundwater are arsenite [(As(III)] and/or arsenate [(As(V)], depending on redox condition: arsenite and arsenate are predominant in reduced and oxidized environments, respectively. Because arsenite is much more toxic and mobile than arsenate, there have been a number of studies on the reduction of its toxicity through oxidation of As(III) to As(V). This study was initiated to develop photocatalytic oxidation process for treatment of groundwater contaminated with arsenite. The performance of two types of light sources (UV lamp and UV LED) was compared and the feasibility of goethite as a photocatalyst was evaluated. The highest removal efficiency of the process was achieved at a goethite dose of 0.05 g/L. Based on the comparison of oxidation efficiencies of arsenite between two light sources, the apparent performance of UV LED was inferior to that of UV lamp. However, when the results were appraised on the basis of their emitting UV irradiation, the higher performance was achieved by UV LED than by UV lamp. This study demonstrates that environmentally friendly process of goethite-catalytic photo-oxidation without any addition of foreign catalyst is feasible for the reduction of arsenite in groundwater containing naturally-occurring goethite. In addition, this study confirms that UV LED can be used in the photo-oxidation of arsenite as an alternative light source of UV lamp to remedy the drawbacks of UV lamp, such as long stabilization time, high electrical power consumption, short lifespan, and high heat output requiring large cooling facilities.

• Journal of the Korean earth science society
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• v.42 no.5
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• pp.536-555
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• 2021

Sea-surface wind is an important variable in ocean-atmosphere interactions, leading to the changes in ocean surface currents and circulation, mixed layers, and heat flux. With the development of satellite technology, sea-surface winds data retrieved from scatterometer observation data have been used for various purposes. In a complex marine environment such as the Korean Peninsula coast, scatterometer-observed sea-surface wind is an important factor for analyzing ocean and atmospheric phenomena. Therefore, the validation results of wind accuracy can be used for diverse applications. In this study, the sea-surface winds derived from ASCAT (Advanced SCATterometer) mounted on MetOp-A/B (METeorological Operational Satellite-A/B) were validated compared to in-situ wind measurements at 16 marine buoy stations around the Korean Peninsula from January to December 2020. The buoy winds measured at a height of 4-5 m from the sea surface were converted to 10-m neutral winds using the LKB (Liu-Katsaros-Businger) model. The matchup procedure produced 5,544 and 10,051 collocation points for MetOp-A and MetOp-B, respectively. The root mean square errors (RMSE) were 1.36 and 1.28 m s^-1, and bias errors amounted to 0.44 and 0.65 m s^-1 for MetOp-A and MetOp-B, respectively. The wind directions of both scatterometers exhibited negative biases of -8.03° and -6.97° and RMSE values of 32.46° and 36.06° for MetOp-A and MetOp-B, respectively. These errors were likely associated with the stratification and dynamics of the marine-atmospheric boundary layer. In the seas around the Korean Peninsula, the sea-surface winds of the ASCAT tended to be more overestimated than the in-situ wind speeds, particularly at weak wind speeds. In addition, the closer the distance from the coast, the more the amplification of error. The present results could contribute to the development of a prediction model as improved input data and the understanding of air-sea interaction and impact of typhoons in the coastal regions around the Korean Peninsula.

• Journal of the Korean earth science society
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• v.21 no.1
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• pp.22-22
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• 2000

To search out the characteristics of the lower and the upper atmospheric vertical structure, we selected the island(Oeyoundori Ochun-myen Poryeng city Chung-Nam) as an observation site, which is thought to represent the characteristics of ocean well, and observed the vertical structure of the atmosphere by Radiosonde. By using the results of the observation, we analyzed the changes of relative humidity(RH), temperature and wind when the cyclone and the anticyclone passed and compared the results in case of each event. To compare the vertical structure of the ocean atmosphere with those of the continent, we analyzed the values observed with using Radiosonde at Osan site.Through this study, we found that relative humidity changed as the cyclone and the anticyclone passed. That is, when the cyclone came, RH increased first in the upper atmosphere than in the lower and when the high came, RH in the upper decreased sharply to 10%. And the variations of relative humidity in ocean are bigger than those in continent. In the future, we plan to find out the relation between the vapor water in ocean and continent seasonally and daily through the observation in ocean and continent at same time.

• Journal of the Korean earth science society
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• v.21 no.1
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• pp.23-39
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• 2000

To search out the characteristics of the lower and the upper atmospheric vertical structure, we selected the island(Oeyoundori Ochun-myen Poryeng city Chung-Nam) as an observation site, which is thought to represent the characteristics of ocean well, and observed the vertical structure of the atmosphere by Radiosonde. By using the results of the observation, we analyzed the changes of relative humidity(RH), temperature and wind when the cyclone and the anticyclone passed and compared the results in case of each event. To compare the vertical structure of the ocean atmosphere with those of the continent we analyzed the values observed with using Radiosonde at Osan site. Through this study, we found that relative humidity changed as the cyclone and the anticyclone passed. That is, when the cyclone came, RH increased first in the upper atmosphere than in the lower and when the high came, RH in the upper decreased sharply to 10%. And the variations of relative humidity in ocean are bigger than those in continent. In the future, we plan to f d out the relation between the vapor water in ocean and continent seasonally and daily through the observation in ocean and continent at same time.

• Journal of the Korean earth science society
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• v.38 no.6
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• pp.395-404
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• 2017

In this study, we classified observed fog events in the Middle Nakdong River near Gumi and analyzed the meteorological characteristics before and after the fog formation. The observation was performed from 2013 to 2015 using visibility meter. A total of 74 fog events were observed and most of them were classified as steam fog. The duration of observed steam fogs was longer than that of typical inland fogs because the nocturnal evaporation from the water surface was enhanced by the topographical characteristics. In order to analyze the effect of evaporation from the stream on the fog duration, the evaporation was estimated using the Penman-Monteith and the Bulk aerodynamic methods. The estimated evaporation by the Bulk method was similar to the actual evaporation from the water surface. Therefore, the Bulk method is suitable for estimating the evaporation from water surface. The evaporation amount, estimated by using the Bulk method was higher on fog days than non-fog days at 06 LST and 07 LST. The added evaporation of fog days released latent heat to the atmosphere and provided energy to maintain the turbulence in the fog. This phenomenon was confirmed by the increase of wind speed, temperature and turbulent kinetic energy within the fog.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.10 no.10
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• pp.2786-2793
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• 2009

Recently, the development and spread of the new recyclable energy becomes urgent because of the depletion of fossil fuel and strengthening the environmental regulation. To recovery from the waste out of the many new recyclable energies has been proved as the most favorable when the potential value of energy source is compared. The RDF from the waste has been approved as the most economical method out of the other methods. However, the toxic gases (HCl, Dioxin etc) and heavy metals generated during the burning of the industrial wastes have been pointed out as problems. The PVC, alkali metal chloride, and alkaline earth metal chloride are major materials for emitting the chlorine and chlorine compounds have the problem such as the erosion on the heat collection device. This research has analyzed the heavy metal components containing in the industrial waste, and the concentration of Cl and S in the industrial waste generated in B industrial complex are slightly high than that of the A industrial complex. The results can be used to discuss the origin of inorganic components in industrial waste and utilized as a base data to improve the performance of the RDF as fuel.

• Journal of the Korean earth science society
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• v.33 no.3
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• pp.219-232
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• 2012

The intensive observation (ProbeX-2010) was performed to investigate an urban effect on summer rainfall over the Seoul metropolitan area from 13 August to 3 September 2010. Two kinds of urban effect were detected. First, weak rainfall (${\leq}1\;mm\;hr^{-1}$) was observed more frequently in the downwind area of Seoul than any other area of the country. The high frequency of weak rainfall in the downwind area was also confirmed from the recent five years of observational data (2006-2010). Because the high frequency was more apparent in mountainous regions during nighttime, the weak rainfall seems to be caused by a combined effect of urbanization and topography. Second, sporadically, a convective system was developed rapidly in the downwind area of Seoul, causing heavy rainfall (${\geq}10\;mm\;hr^{-1}$). It can be most clearly seen in series of radar images around 1300-1500 KST 27 August 2010. We investigated in detail the synoptic and local weather and upper air conditions. As a result, not only urban-induced high sensible heat but also conditionally unstable atmosphere (especially unstable in low level) and low level moisture were pointed out as important factors that contributed to urban-induced heavy rainfall.

• Journal of the Korean earth science society
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• v.32 no.6
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• pp.629-639
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• 2011

Based on Maxwell-Eucken(ME) model, which is one of structural models, a new model for predicting the effective thermal conductivity of variably saturated porous materials is proposed. The new model is a linear combination of three ME models having matrix, water, and air as a continuous phase. The coefficient of the corresponding linear equation is defined by a parameter referred to as 'the continuity coefficient', which provides a relative degree of continuity of each phase. The continuity coefficient of matrix is assumed to be linearly proportional to porosity. The model can be linear or nonlinear depending on how the continuity coefficients of water and air vary with water saturation. The feasibility of the proposed model was examined by both numerical and experimental results. Both linear and nonlinear models showed a high accuracy of prediction with $R^2$ values of 0.86-0.98 and 0.88-0.99, respectively. The numerical and experimental results also showed that the continuity coefficient of matrix was linearly proportional to porosity. Therefore, the proposed prediction model can be effectively used to estimate effective thermal conductivity of unsaturated porous materials by measuring porosity, water content and mineralogical compositions of matrix.

• Journal of the korean society of oceanography
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• v.39 no.2
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• pp.119-135
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• 2004

A three-dimensional numerical model using POM (the Princeton Ocean Model) is established in order to understand the dispersion processes of the Yangtze River water in the Yellow and East China Seas. The circulation experiments for the seas are conducted first, and then on the bases of the results the dispersion experiments for the river water are executed. For the experiments, we focus on the tide effects and wind effects on the processes. Four cases of systematic experiments are conducted. They comprise the followings: a reference case with no tide and no wind, of tide only, of wind only, and of both tide and wind. Throughout this study, monthly mean values are used for the Kuroshio Current input in the southern boundary of the model domain, for the transport through the Korea Strait, for the river discharge, for the sea surface wind, and for the heat exchange rate across the air-sea interface. From the experiments, we obtained the following results. The circulation of the seas in winter is dependent on the very strong monsoon wind as several previous studies reported. The wintertime dispersion of the Yangtze River water follows the circulation pattern flowing southward along the east coast of China due to the strong monsoon wind. Some observed salinity distributions support these calculation results. In summertime, generally, low-salinity water from the river tends to spread southward and eastward as a result of energetic vertical mixing processes due to the strong tidal current, and to spread more eastward due to the southerly wind. The tide effect for the circulation and dispersion of the river water near the river mouth is a dominant factor, but the southerly wind is still also a considerable factor. Due to both effects, two major flow directions appear near the river mouth. One of them is a northern branch flow in the northeast area of the river mouth moving eastward mainly due to the weakened southerly wind. The other is a southern branch flow directed toward the southeastern area off the river mouth mostly caused by tide and wind effects. In this case, however, the tide effect is more dominant than the wind effect. The distribution of the low salinity water follows the circulation pattern fairly well.

• Journal of Microbiology and Biotechnology
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• v.17 no.5
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• pp.721-727
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• 2007

Stability-enhanced mutants, H44, 11-94, 5A2-84, and F8, of L-threonine aldolase(L-TA) from Streptomyces coelicolor A3(2)(SCO1085) were isolated by an error-prone PCR followed by a high-throughput screening. Each of these mutant, had a single amino acid substitution: H177Y in the H44 mutant, A169T in the 11-94 mutant, D104N in the 5A2-84 mutant and F18I in the F8 mutant. The residual L-TA activity of the wild-type L-TA after a heat treatment for 20 min at $60^{\circ}C$ was only 10.6%. However, those in the stability-enhanced mutants were 85.7% for the H44 mutant, 58.6% for the F8 mutant, 62.1% for the 5A2-84 mutant, and 67.6% for the 11-94 mutant. Although the half-life of the wild-type L-TA at $63^{\circ}C$ was 1.3 min, those of the mutant L-TAs were longer: 14.6 min for the H44 mutant, 3.7 min for the 11-94 mutant, 5.8 min for the 5A2-84 mutant, and 5.0 min for the F8 mutant. The specific activity did not change in most of the mutants, but it was decreased by 45% in the case of mutant F8. When the aldol condensation of glycine and 3,4-dihydroxybenzaldehyde was studied by using whole cells of Escherichia coli containing the wild-type L-TA gene, L-threo-3,4-dihydroxyphenylserine(L-threo-DOPS) was successfully synthesized with a yield of 2.0 mg/ml after 20 repeated batch reactions for 100 h. However, the L-threo-DOPS synthesizing activity of the enzyme decreased with increased cycles of the batch reactions. Compared with the wild-type L-TA, H44 L-TA kept its L-threo-DOPS synthesizing activity almost constant during the 20 repeated batch reactions for 100 h, yielding 4.0 mg/ml of L-threo-DOPS. This result showed that H44 L-TA is more effective than the wild-type L-TA for the mass production of L-threo-DOPS.