• Journal of Powder Materials
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• v.25 no.3
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• pp.213-219
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• 2018

We report a method for preparing rare earth oxides ($Re_xO_y$) from the recycling process for spent Ni-metal hydride (Ni-MH) batteries. This process first involves a leaching of spent Ni-MH powders with sulfuric acid at $90^{\circ}C$, resulting in rare earth precipitates (i.e., $NaRE(SO_4)_2{\cdot}H_2O$, RE = La, Ce, Nd), which are converted into rare earth oxides via two different approaches: i) simple heat treatment in air, and ii) metathesis reaction with NaOH at $70^{\circ}C$. Not only the morphological features but also the crystallographic structures of all products are systematically investigated using field-emission scanning electron microscopy (FESEM) and X-ray diffraction (XRD); their thermal behaviors are also analyzed. In particular, XRD results show that some of the rare earth precipitates are converted into oxide form (such as $La_2O_3$, $Ce_2O_3$, and $Nd_2O_3$) with heat treatment at $1200^{\circ}C$; however, secondary peaks are also observed. On the other hand, rare earth oxides, RExOy can be successfully obtained after metathesis of rare earth precipitates, followed by heat treatment at $1000^{\circ}C$ in air, along with a change of crystallographic structures, i.e., $NaRE(SO_4)_2{\cdot}H_2O{\rightarrow}RE(OH)_3{\rightarrow}RE_xO_y$.

• Proceedings of the SAREK Conference
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• 2008.06a
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• pp.294-298
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• 2008

The major threats that human being is facing nowadays are the Climate change, depletion of the fossil fuels at a rapid rate and energy costs. A significant portion of world energy consumption is consumed by domestic heating and cooling. And heat pumps, due to their higher utilization efficiencies as compared to conventional heating and cooling systems, offer an attractive solution to this problem. Among the types of heat pumps, the Geothermal heat pump or Ground-source heat pump is a highly efficient, renewable energy technology for space heating and cooling. The Ground-source heat pump uses the Earth as a heat sink in the summer and a heat source in the winter. And the Earth, having a relatively constant temperature, warmer than the air in winter and cooler than the air in summer, offers an excellent heat source in winter and heat sink in summer.. This paper will discuss an overview of the types of heat pumps, its operation, benefits of using geothermal heat pumps, soil characteristics, and overview of some experimental works. Finally it will briefly discuss the opportunity of using these energy efficient systems (EES) in the HVAC market of South Korea.

• Journal of the Korean Society for Geothermal and Hydrothermal Energy
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• v.13 no.2
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• pp.22-29
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• 2017

This study is performed to performance of the combined system the GSHP (Ground Source Heat Pump) system with the Earth tube system using EnergyPlus program. The Earth tube system using fan is characteristics as supply lower (higher) air temperature than outdoor air temperature in cooling and heating seasons, the GSHP system is characteristics as small indoor air temperature variation range. As the results of Earth tube + GSHP system simulation, GSHP power can be reduced than the GSHP single operation as 17.3% in cooling seasons and 32.5% in heating seasons, the GSHP design capacity can be replaced more small size.

• Atmosphere
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• v.22 no.4
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• pp.429-436
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• 2012

The performances of the Seoul National University Urban Canopy Model (SNUUCM) under different meteorological conditions (clear, cloudy, and rainy conditions) in summertime are compared using observation dataset obtained at an urban site. The daily-averaged net radiation, sensible heat flux, and storage heat flux are largest in clear days and smallest in rainy days, but the daily-averaged latent heat flux is similar among clear, cloudy, and rainy days. That is, the ratio of latent heat flux to net radiation increases in order of clear, cloudy, and rainy conditions. In general, the performance of the SNUUCM is better in clear days than in cloudy or rainy days. However, the performance in simulating sensible heat flux in clear days is as poor as that in rainy days. For all the meteorological conditions, the performance in simulating latent heat flux is worst among the performances in simulating net radiation, sensible heat flux, and latent heat flux. The normalized mean error for latent heat flux is largest in rainy days in which the relative importance of latent heat flux in the surface energy balance becomes greatest among the three conditions. This study suggests that improvements to the parameterization of processes that are related to latent heat flux are particularly needed.

• 한국신재생에너지학회:학술대회논문집
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• 2005.06a
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• pp.684-687
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• 2005

Ground source heat pump systems are used for heating, ventilating and air-conditioning systems in commercial buildings, schools, and factories because of low operating and maintenance costs. These systems use the earth as a heat source in heating mode and a heat sink in cooling mode. Ground heat exchangers are classified by a horizontal type and vertical type according to the installation method. A horizontal type means that a heat exchanger is laid in the trench bored in 1.2 to 1.8 m depth. The solar heat and the rainwater are affected by the performance of heat exchanger and causes mutual influence among heat exchangers. In this study, to evaluate the performance of straight type, slinky type, and spiral type of horizontal ground heat exchangers designed on 1 RT scale, test sections are buried on the earth and experimental apparatus is installed. Therefore the performance of these is estimated.

• Proceedings of the Korean Geotechical Society Conference
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• 2008.10a
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• pp.3-32
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• 2008

The potential deep geothermal resources span a wide range of heat sources from the earth, including not only the more easily developed, currently economic hydrothermal resources; but also the earth's deeper, stored thermal energy, which is present anywhere. At shallow depths of 3,000~10,000m, the coincidence of substantial amounts heat in hot rock, fluids that heat up while flowing through the rock and permeability of connected fractures can result in natural hot water reservoirs. Although conventional hydrothermal resources which contain sufficient fluids at high temperatures and geo-pressures are used effectively for both electric and nonelectric applications in the world, they are somewhat limited in their location and ultimate potential for supplying electricity. A large portion of the world's geothermal resource base consists of hot dry rock(HDR) with limited permeability and porosity, an inadquate recharge of fluids and/or insufficient water for heat transport. An alternative known as engineered or enhanced geothermal systems(EGS), to dependence on naturally occurring hydrothermal reservoirs involves human intervention to engineer hydrothermal reservoirs in hot rocks for commercial use. Therefore EGS resources are with enormous potential for primary energy recovery using an engineered heat mining technology, which is designed to extract and utilize the earth's stored inexthermal energy. Because EGS resources have a large potential for the long term, United States focused his effort to provide 100GW of 24-hour-a-day base load electric-generating capacity by 2050.

• Resources Recycling
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• v.27 no.1
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• pp.55-63
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• 2018

Physical property changes of printed circuit board (PCB) according to heat treatment conditions were investigated. The heat treatment was carried out in air and nitrogen atmosphere at temperature range from $200^{\circ}C$ to $325^{\circ}C$. Thermogravimetric analysis showed that the PCB was pyrolyzed in two steps. The thickness of PCB expanded by 11~28% at about $300^{\circ}C$ in both air and nitrogen atmosphere as layer disintegration occurred. Mechanical strength of PCB decreased from 338.4 MPa to 20.3~40.2 MPa due to the delamination caused by the heat treatment. The heated printed circuit boards were crushed and sieved for analysis of density distribution and liberation degree of copper according to particle size. As a result of the density distribution measurement, non metallic particles and copper particles were concentrated into different size range, respectively. The liberation degree of copper was improved from 9.3% to 100% at size range of $1,400{\sim}2,000{\mu}m$ by heat treatment.

• 한국신재생에너지학회:학술대회논문집
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• 2007.06a
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• pp.466-469
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• 2007

Heat pumps are used for air-conditioning systems in commercial buildings, schools, and factories because of low operating and maintenance costs. These systems use the earth as a heat source in heating mode and a heat sink in cooling mode. Ground heat exchangers are classified by a horizontal type and vertical type according to the installation method. A horizontal type means that a heat exchanger is laid in the trench bored in 1.2 to 1.8 m depth. And a vertical type is usually constructed by placing small diameter high density polyethylene tube in a vertical borehole. Vertical tube sizes range from 20 to 40 mm nominal diameter. Borehole depth range between 100 and 200 m depending on local drilling conditions and available equipment. In this study, to evaluate the performance of single u-tube with bentonite grouting, single u-tube with broken stone grouting and double n-tube bentonite grouting of vertical ground heat exchangers, test sections are buried on the earth and experimental apparatus is installed. Therefore the heat transfer performance and pressure loss of these are estimated.

• Proceedings of the KSME Conference
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• 2007.05b
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• pp.2102-2107
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• 2007

GSHP systems are used for air-conditioning systems in commercial buildings, schools, and factories because of low operating and maintenance costs. These systems use the earth as a heat source in heating and a heat sink in cooling mode. Ground heat exchangers are classified by a horizontal and vertical type according to the installation method. Vertical type is usually constructed by placing small diameter high density polyethylene tube in a vertical borehole. Vertical tube sizes range from 20 to 40 mm nominal diameter. Borehole depth range between 100 and 200 m depending on local drilling conditions and available equipment. In this study, to evaluate the performance of single u-tube with bentonite grouting, single u-tube with broken stone grouting and double u-tube bentonite grouting of vertical ground heat exchangers, test sections are buried on the earth and experimental apparatus is installed. Therefore the heat transfer performance and pressure loss of these are estimated.

• Atmosphere
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• v.17 no.2
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• pp.195-205
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• 2007

The influences of ice microphysical processes on urban heat island-induced convection and precipitation are numerically investigated using a cloud-resolving model (ARPS). Both warm- and cold-cloud simulations show that the downwind upward motion forced by specified low-level heating, which is regarded as representing an urban heat island, initiates moist convection and results in downwind precipitation. The surface precipitation in the cold-cloud simulation is produced earlier than that in the warm-cloud simulation. The maximum updraft is stronger in the cold-cloud simulation than in the warm-cloud simulation due to the latent heat release by freezing and deposition. The outflow formed in the boundary layer is cooler and propagates faster in the cold-cloud simulation due mainly to the additional cooling by the melting of falling hail particles. The removal of the specified low-level heating after the onset of surface precipitation results in cooler and faster propagating outflow in both the warm- and cold-cloud simulations.