• Journal of Technology Innovation
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• v.20 no.2
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• pp.161-187
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• 2012

Recently, environmentally friendly technology are becoming important due to reconsideration about climate change and environmental pollution. In addition, as well as technical skills and social interaction through an analysis of the nonlinear transition management and policy implementation are emerging. This study of the development of photovoltaic industry in Korea 10 years analyze with strategic niche management (SNM) based on the theoretical and multi-layered perspective (MLP) is used as the analytical framework. Choose the gerverment-support project for niche technology, through a process of quantifying and alnalyze the phase transition to Regime with the numerical method and policy vision, learning effects, and network that key elements of SNM, MLP. Through the analysis of the photovoltaic industry technology-commercialization phase was investigated. This conventional overall and step-by-step model for technical management is proposed to replace exiting linear and narrow method and through the case study its validity was confirmed.

• 한국신재생에너지학회:학술대회논문집
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• 2011.11a
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• pp.49.1-49.1
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• 2011

집광채광 설비는 건축물의 조명에너지 절감 및 자연광의 실내 유입을 위해 적용 가능한 태양에너지설비로써 다른 신 재생 에너지 설비와 다르게 연간에너지생산에 대한 정량적 데이터가 아직까지 부재하다. 집광채광 설비의 설치효과를 판단하기 위해서는 집광채광 설비 설치에 따른 연간 에너지생산량 산출이 필요하며, 이를 위해서는 각 구성부분(집광부, 전송부 및 산광부)의 광전송 효율에 대한 데이터가 구축되어야 한다. 본 연구는 집광채광 설비의 효율 분석에 관한 첫 번째 단계로써 외부광속에 대한 집광부 통과 직후의 내부광속의 비율을 예측하였다. 국내에 보급된 집광채광 설비는 대부분 프리즘형과 광덕트형이며, 우선적으로 집광부 입사면의 경사각과 방위각이 다양하여 내부광속 산출방법론이 매우 복잡한 프리즘형을 분석대상으로 삼았다. 전일사량, 외부조도 및 집광부 내부조도가 측정되었으며, 외부광속으로부터 내부광속을 산출하는 공식을 유도하기 위해 천공상태에 따라 전일사량 측정치가 직산분리 되었다. Perez model과 Liu and Jordon에 의해 제시된 계산식과 입사면 및 집광부 면적을 고려하여 수평면 외부조도 측정치로부터 외부광속이 그리고 내부조도로부터 내부광속이 산출되었다. 입사면의 투과율이 동일하다는 전제 하에 천공상태에 따른 태양광 투과 비율을 도출한 결과, 담천공(Kt ${\leq}$ 0.3)에서 0.39, 부분담천공(0.3${\geq}$ 0.78)에서 1.0으로 나타났다. 도출된 투과비율을 외부광속에 적용하여 내부광속을 계산한 결과치와 측정치는 약 ${\pm}9%$ 정도의 차이를 보였다. 연간 기상데이터에 위와 같은 방법론이 적용되면 프리즘형 집광부의 연간 내부광속이 산출될 수 있다. 또한 기존 연구에서 제시된 발광효율 산출식과 일사 파장에 따른 시감도를 고려하면 매 시간별 외부조도도 산출이 가능하다. 일사량 측정치와 외부조도 측정치 사이의 상관관계를 분석한 결과 결정계수 $R^2$이 0.99인데 반해 일사량 측정치와 외부조도 계산치 사이의 상관관계 결정계수는 0.95로 측정치 보다 약간 작은 값을 갖는다. 이렇게 산출된 외부조도는 각 입사면의 면적을 반영하여 외부광속으로 변환되고, 앞서 산출된 천공상태별 투과비율이 적용됨으로써 내부광속이 도출될 수 있다. 이와 같은 집광부에 대한 연구를 바탕으로 향후 전송부와 산광부 효율을 도출하고 궁극적으로 집광채광 설비를 통해 실내에 전달되는 연간 빛에너지를 예측할 수 있을 것이다. 또한 본 연구의 방법론은 다른 형태의 집광채광 설비에도 적용이 가능할 것으로 판단되며, 국내 집광채광 설비의 연간 에너지생산량에 대한 폭 넓은 데이터 구축이 가능할 것으로 기대된다.

• Journal of Wetlands Research
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• v.16 no.4
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• pp.477-486
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• 2014

Integrated sand control including sediment discharge from hinterland rivers is necessary to maintain coastal sand resources over a long term. In this regard, the following subjects should be considered; efficient ways to transfer discharged sand from a river to the neighboring coast, measures to improve storage efficiency of the discharged sand at the river delta and/or river terrace, measures to prevent the sand resources from being discharged into the deep sea during flooding. From the 1997 to January 2004, the jetty of 156 m length was constructed the Heoya-river mouth to protect the blockade of river mouth. Several tests were carried out to investigate the characteristics of sediment transport and morphological change due to the construction of the jetty at the Heoya-river mouth. Firstly, The sand discharge from Heoya river is quantified by one-dimensional numerical analysis assuming the mixed sand of three different particle diameters. Also the numerical mode system, which predicts the sea bed changes obtained from the Bailard's energy model(1981), was combined with the wave, wave-induced currents and sediment transport models. Then, to understand the changes to the blockade of the river mouth, several aerial photographs were compared, which showed that the changes were significant.

• Applied Chemistry for Engineering
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• v.23 no.5
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• pp.450-455
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• 2012

The paper includes the utlization of an activated carbon as a potential adsorbent to remove a hazardous fluorescein dye from an aqueous solution. Batch adsorption experiments were carried out for the removal of fluorescein dyes using a granular activated carbon as an adsorbent. The effects of various parameters such as pH, amount of adsorbent, contact time, initial concentration and temperature of the adsoprtion system were investigated. The experimental results revealed that activated carbon exhibit high efficiencies to remove fluorescein dyes from the aqueous solution. The equilibrium process can be well described by Freundlich isotherm in the temperature range from 298 K to 318 K. From adsorption kinetic experiments, the adsorption process followed a pseudo second order kinetic model, and the adsorption rate constant ($k_2$) decreased with increasing the initial concentration of fluorescein. The free energy of adsorption ${\Delta}G^0$), enthalpy ${\Delta}H^0$), and entropy (${\Delta}S^0$) change were calculated to predict the nature adsorption. The estimated values for ${\Delta}G^0$ were -17.11~-20.50 kJ/mol over an activated carbon at 250 mg/L, indicated toward a spontaneous process. The positve value for ${\Delta}H^0$, 33.2 kJ/mol, indicates that the adsorption of fluorescein dyes on an activated carbon is an endothermic process.

• Proceedings of the Korean Vacuum Society Conference
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• 2011.02a
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• pp.27-27
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• 2011

For the design of real applicable molecular devices, current-voltage properties through molecular nanostructures such as metal-molecule-metal junctions (molecular junctions) have been studied extensively. In thiolate monolayers on the gold electrode, the chemical bonding of sulfur to gold and the van der Waals interactions between the alkyl chains of neighboring molecules are important factors in the formation of well-defined monolayers and in the control of the electron transport rate. Charge transport through the molecular junctions depends significantly on the energy levels of molecules relative to the Fermi levels of the contacts and the electronic structure of the molecule. It is important to understand the interfacial electron transport in accordance with the increased film thickness of alkyl chains that are known as an insulating layer, but are required for molecular device fabrication. Thiol-tethered RuII terpyridine complexes were synthesized for a voltage-driven molecular switch and used to understand the switch-on mechanism of the molecular switches of single metal complexes in the solid-state molecular junction in a vacuum. Electrochemical voltammetry and current-voltage (I-V) characteristics are measured to elucidate electron transport processes in the bistable conducting states of single molecular junctions of a molecular switch, Ru(II) terpyridine complexes. (1) On the basis of the Ru-centered electrochemical reaction data, the electron transport rate increases in the mixed self-assembled monolayer (SAM) of Ru(II) terpyridine complexes, indicating strong electronic coupling between the redox center and the substrate, along the molecules. (2) In a low-conducting state before switch-on, I-V characteristics are fitted to a direct tunneling model, and the estimated tunneling decay constant across the Ru(II) terpyridine complex is found to be smaller than that of alkanethiol. (3) The threshold voltages for the switch-on from low- to high-conducting states are identical, corresponding to the electron affinity of the molecules. (4) A high-conducting state after switch-on remains in the reverse voltage sweep, and a linear relationship of the current to the voltage is obtained. These results reveal electron transport paths via the redox centers of the Ru(II) terpyridine complexes, a molecular switch.

• Journal of Applied Biological Chemistry
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• v.63 no.1
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• pp.1-8
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• 2020

This study investigated the processing characteristics of soybean (HaePum) sprouts based on temperature (5, 15 and room temperature), period (0, 6 and 12 mon) and relative humidity (20, 40, 60, and 80%) during storage. The initial germination rate of soybean sprouts was 76.02±6.32%, which significantly reduced to 57.18±8.51%, and 0% as the storage temperature of soybean increased for a period of 12 mon. The germination rate of soybean sprouts with 30 ℃ and 80% RH decreased after 4 mon of storage to 4.94%. The yellowness of cotyledon of soybean sprouts was not significantly changed during the 12 mon period of storage at 5 ℃, whereas, soybean sprouts stored at 15 ℃ and room temperature demonstrated decreased yellowness. However, the stress of cotyledon decreased with an increase in both storage temperature and time, and the hardness of hypocotyl decreased with an increase of storage time. The stress of cotyledon affected by high temperature (30 ℃) and humidity (80%) during 4 mon was reduced to 44.39±9.38 g/㎟. The asparagine content of soybean sprouts showed a similar result with the germination rate due to the amount of hypocotyl. Therefore, lower temperatures and shorter storage times are suitable for soybean sprout processing. The first order kinetic model and Arrhenius equation (activation energy =29.56 kJ/mol) were able to predict the yield of sprout at various storage temperatures and periods.

• Journal of Korean Society of Coastal and Ocean Engineers
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• v.26 no.2
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• pp.81-95
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• 2014

In the present study, the statistical analysis on the storm waves in the East Sea have been carried out, and the several storm waves were reproduced by the modified WAM as a first step for the accurate and prompt forecasting and warning against the swell waves in East Sea. According to the present study, the occurrences of the storm waves from the North were the most probable, while the waves from the Northeast were most frequently observed. It was found that the significant wave heights of storm waves from the North and Northern northeast were larger than those of storm waves from the Northeast. But due to long fetch distance, the significant wave periods of storm waves from the Northesast were longer than those of North and Northern northeast. In addition to the wave analysis, the numerical experiments for the storm waves in East Sea were carried out using the modified WAM, and three periods of storm waves in 2013 were calculated. The numerical results were well agreed with wave measurements. However the numerical simulation results in shallow water region showed lower accuracies compared to deep water, which might be due to lower resolution of wind field and bottom topography caused by large grid size, 5 minute, adopted in the present study. Overall computational efficiency of the modified WAM found to be excellent compared to original WAM. It is because the modified WAM adopted the implicit scheme, thereby the present model performed 10 time faster than original WAM in computation time.

• Journal of the Korea institute for structural maintenance and inspection
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• v.13 no.2 s.54
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• pp.215-222
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• 2009

In this study, steel and FRP jackets are used to confine concrete cylinders. The FRP jacket behaviors compositely with concrete since there is bonding between them. However, the used steel jacket in this study do not behavior compositely with concrete since there is not an adhesive between them. The steel jackets are attached by external forces and the welding. This study suggests the measuring method of the axial strain for the confined concrete cylinders showing noncomposite behavior with the jackets and the correcting method of the measured strain for the composite-behavior jackets. For the noncomposite-behavior steel jacket, the axial strain of the steel surface does not represent the axial strain of the concrete inside. Also, a compressormeter can not be used. Thus, the two rigid plates at the top and bottom of a cylinder are placed and the distance of the two plates are measured and used for estimating the axial strain of the concrete. For the composite-behavior FRP jacket, the vertical strain measured on the FRP surface can be used for estimating the axial strain of the concrete. However, the vertical strain on the FRP surface contains the tensile strain due to the bulge of the concrete and, thus, the tensile strain should be corrected from the vertical strain. The corrected verticals strains compared with the measured strain or a existing constitute model; the result is satisfactory. The uncorrected stress-strain curves have the potential to under estimate the ductile behavior and the energy-dissipation-capacity of the composite-behavior FRP jackets.

• Fire Science and Engineering
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• v.24 no.2
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• pp.106-113
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• 2010

Fire characteristics can be analyzed more realistically by using more accurate material properties related to the fire dynamics and one way to acquire these fire properties is to use one of the inverse property analyses. In this study the genetic algorithm which is frequently applied for the inverse heat transfer problems is selected to demonstrate the procedure of obtaining fire properties of the solid charring material with relatively simple chemical structure. The thermal decomposition on the surface of the test plate is occurred by receiving the radiative energy from external heat sources, and in this process the heat transfer through the test plate can be simplified by an unsteady 1-D problem. The inverse property analysis based on the genetic algorithm is then applied for the estimation of the properties related to the reaction pyrolysis. The input parameters for the analysis are the surface temperature and mass loss rate of the char plate which are determined from the unsteady 1-D analysis with a givenset of 8 properties. The estimated properties using the inverse analysis based on the genetic algorithm show acceptable agreements with the input properties used to obtain the surface temperature and mass loss rate with errors between 1.8% for the specific heat of the virgin material and 151% for the specific heat of the charred material.

• Journal of the Korean GEO-environmental Society
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• v.14 no.5
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• pp.57-63
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• 2013

In this study, the characteristics of degradation and mineralization of diazinon using a statistical approach based on Box-Behnken design (BBD, one of response surface method) was investigated in an E-beam process, and also the main factors with diazinon concentration ($X_1$), irradiatin intensity ($X_2$) and pH ($X_3$) which consisted of 3 levels in each factor was set up to determine the effects of factors and optimization. At first, effects of pH and diazinon concentration were investigated to determine the proper range of application on response surface method(RSM). In statistical approach, the regression analysis and analysis of variance (ANOVA) were applied to evaluate the quantitative comparison of each factors in order to obtain the effects were irradiation intensity>diazinon concentration>pH. The regression model predicted the optimization point using the response optimizer to consider the effects of operation conditions were $Y_1=81.73-5.58X_1+23.69X_2-14.23X{_2}^2+4.22X{_3}^2(R^2=99.7%)$, $Y_2=35.23-3.01X_1+10.79X_2-7.58X_2{^2}(R^2=97.9%)$ and 95.7% of diazinon degradation, 41.8% of TOC reduction at 12.75mg/L and 4.26kGy, respectively. The pH condition was not significantly affects on E-beam process than other advanced oxidation processes (AOPs).