• 한국전기전자재료학회논문지
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• 제15권5호
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• pp.429-434
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• 2002

In this paper, multiheterostructure white organic light-emitting device was fabricated by vacuum evaporation. The structure of white organic light-emitting device is ITO/CuPc/TPD/DPBi:DPA/$Alq_3/Alq_3$:DCJTB/BCT/$Alq_3$/Ca/Al. Three primary colors are implemented with DPVBi, Alq$_3$and DCJTB. The maximum EL wavelength of the fabricated white organic light-emitting device is 647nm. And the CIE coordinate is (0.33, 0.33) at 13 V. In the fabrication of white organic light-emitting devices with DCJTB, $Alq_3$, DPVBi, the EL spectrum has two peaks at 492nm, 647nm. Two peaks appeared because the blue light is combined with green light. The maximum wavelength of red light is not changed with applied voltage. After voltage applied, for the first time, the electrons met the holes in the red emission layer and emitted red light. And then the electrons moved to the green emission layer, and blue emission layer continuously. Finally, when all of the emission layer activated, the white light is emitted.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2000년도 하계학술대회 논문집
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• pp.332-335
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• 2000

We fabricated organic electroluminescent (EL) devices with single layer of poly(3-dodeoylthiophene) (P3DoDT) hlended with different amounts of poly(N-vinylcarbazole) (PVK) as a emitting layer. The molar ratio between P3DoDT and PVK changed with 1:0, 2:1 and 1:1. To improve the external quantum efficiency of EL devices, we applied insulating layer, LiF layer, between polymer emitting layer and Al electrode. All of the devices emit orange-red light and it's can be explained that the energy transfer occurs from PVK to P3DoDT. In the voltage-current and voltage-brightness characteristics of devices applied LiF layer, current and brightness increased with increasing applied voltage. The brightness of the device have a molar ratio 1:1 with LiF layer was about 10 times larger than that of the device without PVK at 6V. Electrical impedance properties of ITO/emitting layer/LiF/Al devices were investigated. In the Cole-Cole plots of impedance data, one semicircle was observed. Therefore, the equivalent circuit for the devices can be designed as a single parallel resistor and capacitor network with series resistor.

• 한국생물공학회:학술대회논문집
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• 한국생물공학회 2000년도 추계학술발표대회 및 bio-venture fair
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• pp.520-523
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• 2000

Phenol and other phenolic compounds are common constituents of aqueous effluents from processes such as polymeric resin production, oil refining and cokeing plants. Phenol is a both toxic and lethal of fish at relatively low concentrations e.g. 5-25 mg/L and imparts objectionable tastes to drinking water at far lower concentration. Therefore, the treatment of phenol effluent is important. Among the various techniques of phenol wastewater treatment, microbial teratment is a popular process. The breakdown of phenols by microorganisms has recived considerable attention, because of its biochemical interest and its industrial importance in effluent treatment. This research was performed to investigate the dynamics of microbial community, biofilm growth and the comparison of phenol removal efficiency by RBC (Rotating Biological Contactor) using Rhodococcus sp. EL-GT The experiment was carried out at rotating speed of 10ppm and hydraulic retention time of 7 hours. As time passed, phenol removal efficiency was gained highly. The RBC using Rhodococcus sp. EL-GT completely degraded 15 mM.

• Journal of Information Display
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• 제7권4호
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• pp.9-12
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• 2006

This paper reports the synthesis and electroluminescent properties of new aromatic compounds as hole-transporting materials based on phenothiazine, such as 1,4-diphenothiazyl-benzene [DPtzB], 1,4-diphenothiazyl-xylene [DPtzX] and 9,10-diphenothiazyl-anthracene [DPtzA]. DPtzB thin film exhibited photoluminescence (PL) maximum emission peak and emission shoulder at 450 and 475 nm, and a maximum emission at 447 nm without emission shoulder was obtained in DPtzX thin film. When DPtzA was excited by incident light of 359 nm, DPtzA showed strong PL emission at 417 nm and weak emission at 600 nm. Luminance efficiency of DPtzB, DPtzX and DPtzA-based electroluminescence (EL) devices was 3.57, 3.46 and 0.47 cd/A, and power efficiency of DPtzB, DPtzX and DPtzA-based EL devices was 1.48, 1.26 and 0.201 m/W.

• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2001년도 International Meeting on Information Display
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• pp.209-212
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• 2001

We report the synthesis and characterization of new alkoxy substituted spirobifluorene derivatives. The spiro compounds having alkoxy hydrocarbon chains were readily soluble in common organic solvents, having improved film-forming properties and had a significantly reduced tendency to crystallize, resulting in increasing their service lifetime. The results of DSC showed that it was amorphous. The optical and electroluminescent spectra were characterized. Electroluminescence (EL) properties of three-layer light emitting diodes (LED) of $ITO/TPD/spirobifluorene/Alq_3/LiF/Al$ as the active layer were characterized. Blue emission peaking of the EL spectrum of the three-layer device at 402 nm and a luminance of 3,125 $cd/m^2$ were achieved at a drive voltage 12.8 V. The luminous efficiency was obtained to be 1.7 lm/W. The color coordinate in CIE chromaticity is (0.16, 0.09), which is in a pure blue region. The external quantum efficiency was obtained to be 2.0%. The results indicate that the spirobifluorene compounds having alkoxy hydrocarbon chains are strongly potential blue emitters for LED applications.

• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2006년도 6th International Meeting on Information Display
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• pp.1054-1058
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• 2006

We report the synthesis and electroluminescent properties of new aromatic compounds as hole-transporting materials based on phenothiazine, such as 1,4-diphenothiazyl-benzene [DPtzB], 1,4-diphenothiazyl-xylene [DPtzX] and 9,10-diphenothiazyl-anthracene [DPtzA]. DPtzB thin film exhibited photoluminescence (PL) maximum emission peak and emission shoulder at 450 and 475nm, and maximum emission at 447nm without emission shoulder was found in DPtzX thin film. When DPtzA was excited by incident light of 359nm, DPtzA showed strong PL emission at 417nm and weak emission at 600nm. Luminance efficiency of DPtzB, DPtzX and DPtzA-based electroluminescence (EL) devices was 3.57, 3.46 and 0.47cd/A, and power efficiency of DPtzB, DPtzX and DPtzA-based EL devices was 1.48, 1.26 and 0.20lm/W.

• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2006년도 6th International Meeting on Information Display
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• pp.1583-1586
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• 2006

All non-dopant white organic light-emitting diodes (WOLEDs) have been realized by using solid state highly fluorescent red bis(4-(N-(1- naphthyl)phenylamino)phenyl)fumaronitrile (NPAFN) and amorphous bipolar blue light-emitting 2-(4- diphenylamino)phenyl-5-(4-triphenylsilyl)phenyl- 1,3,4-oxadiazole (TPAOXD), together with well known green fluorophore tris(8- hydroxyquinolinato)aluminum $(Alq_3)$. The fabrication of multilayer WOLEDs did not involve the hard-tocontrol doping process. Two WOLEDs, Device I and II, different in layer thickness of $Alq_3$, 30 and 15 nm, respectively, emitted strong electroluminescence (EL) as intense as $25,000\;cd/m^2$. For practical solid state lighting application, EL intensity exceeding $1,000\;cd/m^2$ was achieved at current density of $18-19\;mA/cm^2$ or driving voltage of 6.5-8 V and the devices exhibited external quantum efficiency $({\eta}_{ext})$ of $2.6{\sim}2.9%$ corresponding to power efficiency $({\eta}_P)$ of $2.1{\sim}2.3\;lm/W$ at the required brightness.

• Bulletin of the Korean Chemical Society
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• 제25권5호
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• pp.652-656
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• 2004

A new luminescent polymer, poly{1,4-phenylene-1,2-ethenediyl-2'-[2"-(4'"-octyloxyphenyl)-(5"-yl)-1",3",4"-oxadiazole]-1,4-phenylene-1,2-ethenediyl-2,5-bis-dodecyloxy-1,4-phenylene-1,2-ethenediyl} (Oxd-PPV), was synthesized by the Heck coupling reaction. Electron withdrawing pendant, conjugated 1,3,4-oxadiazole (Oxd), is on the vinylene unit. The band gap of the polymer figured out from the UV-visible spectrum was 2.23 eV and the polymer film shows bright yellow emission maximum at 552 nm. The electroluminescence (EL) maximum of double layer structured device (ITO/PEDOT:PSS/Oxd-PPV/Al) appeared at 553 nm. Relative PL quantum yield of Oxd-PPV film is 3.6 times higher than that of MEH-PPV film. The HOMO and LUMO energy levels of Oxd-PPV figured out from the cyclic voltammogram and the UV-visible spectrum are -5.32 and -3.09 eV, respectively, so that more balanced hole and electron injection efficiency can be expected compared to MEH-PPV. A double layer EL of Oxd-PPV has an maximum efficiency of 0.15 cd/A and maximum brightness of 464 cd/$m^2$.

• 한국응용과학기술학회지
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• 제18권3호
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• pp.186-190
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• 2001

By fabricating the organic light-emitting devices (OLEDs) based on phosphorescent material, the internal quantum efficiency can reach 100%, compared to 25% in the case of the fluorescent material. Thus, the phosphorescent OLEDs have recently been extensively studied and showed higher internal quantum efficiencies then the conventional OLEDs. In this study, we investigated the characteristics of the phosphorescent OLEDs, with the green emitting phosphor, $Ir(ppy)_{3}$, (tris(2-phenylpyridine)iridium). The devices with a structure of $ITO/TPD/Ir(ppy)_{3}$ doped in the host material $/BCP/Alq_{3}/Li:Al/Al$ were fabricated, and its electrical and optical characteristics were studied. By changing the doping concentration of $Ir(ppy)_{3}$, we fabricated several devices and investigated the device characteristics. OLEDs doped into BCP by 10% showed the best characteristics. For 10% doped OLEDs, the maximum luminance of was over 10000 $cd/m^{2}$, and the maximum power efficiency was 7.14 lm/W.

• 한국전기전자재료학회논문지
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• 제16권9호
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• pp.816-825
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• 2003

Current-voltage-luminance characteristics of organic light-emitting diodes (OLEDs) were measured in the temperature range of 10 K～300 K. Indium-tin-oxide (ITO) was used as an anode and aluminum as a cathode in the device. Organic of N,N'-diphenyl-N,N'-di(m-tolyl)-benzidine (TPD) was used for a hole transporting material, and tris (8-hydroxyquinolinato) aluminum (Alq$_3$) for an electron transporting material and emissive material. And copper phthalocyanine (CuPc), poly(3,4-ethylenedi oxythiophene);poly(styrenesulfonate) (PEDOT:PSS), and poly(N-vinylcarbazole) (PVK) were used for hole-injection buffer layers. From tile analysis of electroluminescence (EL) and photoluminesccnce (PL) spectra of the Alq$_3$, the EL spectrum is more greenish then that of PL. And the temperature-dependent current-voltage characteristics were analyzed in the double and multilayer structure of OLEDS. Electrical conduction mechanism was explained in the region of high-electric and low-electric field. Temperature-dependent luminous efficiency and operating voltage were analyzed from the current-voltage- luminance characteristics of the OLEDS.