• Title/Summary/Keyword: EHC

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Flame Retardancy and Foaming Properties of the NBR/Ground Tire Rubber Foams Containing Expandable Graphite (팽창 흑연을 포함한 NBR/GTR 발포체의 난연 및 발포특성)

  • Moon Sung-Chul;Choi Jae-Kon;Jo Byung-Wook
    • Polymer(Korea)
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    • v.28 no.5
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    • pp.412-425
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    • 2004
  • The influence of expandable graphite (EG) on flame retardancy and foaming properties of the NBR/GTR foams was studied. The foaming properties were similar to those of NBR/GTR foams without EG when the EG contents were 10$\~$30 phr. The LOI values were increased with the EG content. For cone-calorimeter test, the data showed the trend similar to that from experiment. When the composition ratios of the compounds of NBR/GTR were 100$\~$0/80$\~$20 (w/w), and the EG contents were 10$\~$30 phr, we obtained high flame retardancy foams with low heat release rate (HRR), total heat release (THR), effective heat of combustion (EHC) and carbon monoxide yield (COY). The smoke density is similar to CO yield values obtained by the cone-calorimeter test. TGA analysis also showed the results approximately similar to those from the LOI and cone-calorimeter experiments.

Combustion-Retardation Properties of Low Density Polyethylene and Ethylene Vinyl Acetate Mixtures with Magnesium Hydroxide (수산화마그네슘이 첨가된 저밀도 폴리에틸렌과 에틸렌 비닐 아세테이트 혼합물의 난연성)

  • Chung, Yeong-Jin;Lim, Hyung Mi;Jin, Eui;Oh, JungKyoo
    • Applied Chemistry for Engineering
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    • v.22 no.4
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    • pp.439-443
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    • 2011
  • It was performed to test the combustive properties of low density polyethylene and ethylene vinyl acetate (LDPE-EVA) mixture by the addition of magnesium hydroxide. Flame retardant of natural magnesium hydroxide was added to the mixture of LDPE-EVA in 40 to 80 wt% concentration. The composite was compounded to prepare specimen for combustive analysis by cone calorimeter (ISO 5660-1). Comparing with virgin LDPE-EVA, the specimens including the magnesium hydroxide had lower combustive properties. It is supposed that the combustion-retardation properties in the composites improved due to the endothermic decomposition of magnesium hydroxide. The specimens with magnesium hydroxide showed both the lower peak heat release rate (PHRR) and lower effective heat of combustion (EHC) than those of virgin polymer. As the magnesium hydroxide content increases, time to ignition increased and the peak heat release rate decreased.

An Experimental Study for Reducing the Exhaust Hydrocarbon Emission at SI Engine Using Timed Secondary Air Injection (2차 공기 분사에 의한 스파크 점화 가솔린 엔진의 배기 Hydrocarbon 저감에 관한 실험적 연구)

  • 심현성;김세준;정석호
    • Transactions of the Korean Society of Automotive Engineers
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    • v.7 no.7
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    • pp.104-112
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    • 1999
  • An experimental study for reducing the exhaust hydrocarbon emission at spark ignition engine using timed secondary air injection is carried out . In this study, secondary air injection timings and durations are controlled to decrease the hydrocarbon emission and to increase exhaust gas temperature at cold and warm-up engine conditions. The hydrocarbon reduction rate and exhaust gas temperature are compared between timed secondary air injection and continuous air injection. The optimum secondary air injection timing for reducing the hydrocarbon emission is at the exhaust valve open timing. At some engine conditions , the hydrocarbon emissions are decreased to 10% of engine raw values and exhaust gas temperatures increase by 20$0^{\circ}C$ with times secondary air injection . Timed secondary air injection has more hydrocarbon reduction rate that continuous secondary air injection except some engine conditions.

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A comparative study on corrosion behavior of WC-CoCr and WC-CrC-Ni coatings by HVOF

  • Ju, Yun-Gon;Jo, Jae-Yeong;Jang, Si-Hong;Song, Gi-O;Jo, Dong-Yul;Yun, Jae-Hong
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2008.11a
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    • pp.155-157
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    • 2008
  • High velocity oxy-fuel (HVOF) thermal spraying coating has been used widely throughout the last 60 years mainly in defense, aerospace, and power plants. Recently this coating technique is considered as a promising candidate for the replacement of the traditional electrolytic hard chrome plating (EHC) which pollutes the environment and causes lung cancer by toxic hexa-valent $Cr^{6+}$. In this study, two kinds of cermet coatings, WC-CoCr and WC-CrC-Ni, are formed by HVOF spraying. The corrosion and electrochemical properties are evaluated by polarization tests in 3.5 wt% solutions.

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A Study of Audio Interface Development based on In-Vehicular Multimedia Network (차량 내 멀티미디어 네트워크 기반 오디오 인터페이스 개발에 관한 연구)

  • Jeon, Young-Joon;Kim, Tae-Jun;Yu, Yun-Sik
    • Proceedings of the Korea Information Processing Society Conference
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    • 2009.11a
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    • pp.51-52
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    • 2009
  • 본 논문에서는 차량 내의 네트워크 가운데에서 대용량의 멀티미디어 데이터를 전송할 수 있는 MOST(Media Oriented Systems Transport) 네트워크 기반의 오디오 인포테인먼트 인터페이스 개발에 관한 연구를 수행하였다. 구현한 오디오 인포테인먼트 인터페이스는 MOST 네트워크 인터페이스 컨트롤러로 OS81050A INIC 칩을 사용하였으며, EHC 부분은 ATmega128L 8bit 마이크로컨트롤러를 사용하였다. 오디오 동작과 관련된 기능 블록(FBlock) 및 애플리케이션 작성에는 NetServices API를 활용하였다. 구현된 인터페이스는 MOST 네트워크 분석 도구인 OptoLyzer G2를 이용하여 정확한 동작여부를 확인하였다.

Autothermal Reforming Reaction at Fuel Process Systems of 1Nm3/h (1 Nm3/h급 연료 변환시스템에서 메탄의 자열 개질반응)

  • Koo, Jeong-Boon;Sin, Jang-Sik;Yang, Jeong-Min;Lee, Jong-Dae
    • Korean Chemical Engineering Research
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    • v.50 no.5
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    • pp.802-807
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    • 2012
  • The autothermal reforming of methane to syngas has been carried out in a reactor charged with both a Ni (15 wt%)-Ru (1 wt%)/$Al_2O_3$-MgO metallic monolith catalyst and an electrically-heated convertor (EHC). The standalone type reactor has a start-up time of less than 2 min with the reactant gas of $700^{\circ}C$ fed to the autothermal reactor. The $O_2/CH_4$ and $H_2O/CH_4$ ratio governed the methane conversion and temperature profile of reactor. The reactor temperature increased as the reaction shifted from endothermic to exothermic reaction with decreasing $H_2O/CH_4$ ratio. Also the amount of $CO_2$ in the products increases with increasing $H_2O/CH_4$ ratio due to water gas shift reaction. The 97% of $CH_4$ conversion was obtained and the reactor temperature was maintained $600^{\circ}C$ at the condition of $GHSV=10,000\;h^{-1}$ and feed ratio ($H_2O/CH_4=0.6$ and $O_2/CH_4=0.5$). In this condition, the maximum flow rate of the syngas generated from the reactor charged with 170 cc of the metallic monolith catalyst is $0.94\;Nm^3/h$.

The Characteristic Study on the Extraction of a Co Ion in the Metal Ion Implanter (금속이온 주입기에서의 Co 이온의 인출 특성 연구)

  • Lee, Hwa-Ryun;Hong, In-Seok;Trinh, Tu Anh;Cho, Yong-Sub
    • Journal of the Korean Vacuum Society
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    • v.18 no.3
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    • pp.236-243
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    • 2009
  • Proton Engineering Frontier Project (PEFP) has supplied the metal ions to users by using an installed metal ion implanter of 120 keV. At present a feasibility study is being performed for a cobalt ion implantation. For a cobalt ion extraction we studied to sustain the high temperature($648^{\circ}C$) for metal ions vaporization from a cobalt chloride powder by using an alumina crucible in the ion source. The temperature condition of the crucible was satisfied with the plasma generation at the arc current of 120V and EHC power of 250W. The extracted beam current of $Co^+$ ions was dependent on the arc current in the plasma. The maximum beam current was $100{\mu}A$ at 0.18A of the arc current. The 3 peak currents of the extracted ions such as $Co^+$, $CoCl^+$ and $Cl^+$ were obtained by adjusting a mass analyzing magnet and the $Co^+$ ion beam peak current fraction as around 70% in the sum of the peak currents. The fluence of the implanted cobalt ions at the $10{\mu}A$ of the beam current and 90 minutes of the implantation time into an aluminum sample as measured around $1.74{\times}10^{17}#/cm^2$ by a quantitative analysis method of RBS (Rutherford Backscattering Spectrometry).

Foaming Properties and Flame Retardancy of the Foams Based on NBR/GTR Compounds (니트릴고무/타이어고무분말(GTR)를 이용한 발포체의 발포 및 난연 특성에 관한 연구)

  • Moon, Sung-Chul;Jo, Byung-Wook;Choi, Jae-Kon
    • Elastomers and Composites
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    • v.37 no.3
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    • pp.159-169
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    • 2002
  • The improvement of flame retardancy of the foams based on NBR/GTR compounds was conducted by formulating various materials i.e. NBR, GTR, inorganic and phosphorus containing flame retardants, foaming agent, cross-linking agent and activator. The foaming properties, morphology, smoke density and flame retardancy of the specimens were investigated using SEM, LOI tester, smoke density control system and cone calorimeter. The phosphorus containing flame retardant reduces heat release rate, increases the limiting oxygen index and a char formation. The inorganic flame retardant increases the limiting oxygen index and reduces heat release rate with an increased CO yield by char formation, and smoke suppressing effect. The formed char seemed to intercept the oxygen transport and heat transfer into the core area. When the composition ratios of the compounds of NBR/GTR were $100{\sim}80/0{\sim}20 wt.%$, and the ratios of the rubbers/flame retardants were $1/1.55{\sim}3.60 wt.%$, we could developed foams with low heat release rate, high limiting oxygen index($28.0{\sim}39.3$), closed or semi-closed cell of uniformity and reasonable expandability($225{\sim}250 %$).

Flame Retardancy and Foaming Properties of the Waste-Polyethylene(W-PE)/Waste-Ethylene vinyl acetate copolymer(W-EVA) Blend Foams (폐폴리에틸린/폐에틸렌 비닐아세테이트공중합체 블렌드 발포체의 난연 및 발포 특성에 관한 연구)

  • Moon, Sung-Chul;Jo, Byung-Wook;Choi, Jae-Kon
    • Elastomers and Composites
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    • v.38 no.4
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    • pp.316-325
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    • 2003
  • The blends of waste-polyethylene (W-PE)/waste-ethylene vinyl acetate copolymer (W-EVA) with inorganic and phosphorous flame retardants (i.e., aluminium hydroxide, magnesium hydroxide, and so on) were prepared by melt mixing techniques at different compositions and foamed. The flame retardancy and foaming properties of the blends, limiting oxygen index (LOI), heat release rate (HRR), carbon monoxide yield (COY), total heat release (THR), effective heat of combustion (EHC), expandability and cell structure were investigated using cone calorimeter, SEM, LOI tester and polarizing microscope. When the composition ratios of the W-PE/W-EVA blends were 50/50 (w/w), and the ranges of the flame retardants contents were $175{\sim}220 phr$, we could obtain foams with the uniform and closed cell, high expandability (1900 % or more), high LOI, and low HRR values. These results depend on crosslinking and loaming conditions, a char formation and smoke suppressing effect. Aluminium hydroxide had more effect in the increase of LOI than magnesium hydroxide, while magnesium hydroxide considerably affected the decrease of HRR and COY.

Wear Property of HVOF WC-CoCr Coating Manufactured by Optimal Coating Process (최적 고속화염용사코팅 공정기술에 의하여 제조된 WC-CoCr 코팅의 마모 특성)

  • Song, Ki O;Cho, Tong Yul;Yoon, Jae Hong;Fang, W.;Youn, Seok Jo;Youn, Kuk Tae;Suh, Chang Hee;Hwang, Soon Young;Ha, Sung Sik
    • Korean Journal of Metals and Materials
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    • v.46 no.6
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    • pp.351-356
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    • 2008
  • Thermally sprayed tungsten carbide-based powder coatings are being widely used for a variety of wear resistance applications. The coating deposited by high velocity processes such as high velocity oxy-fuel (HVOF) thermal spraying is known to provide improved wear resistant property. In this study, optimal coating process (OCP) is obtained by the study of coating properties such as surface hardness, porosity, surface roughness and microstructure of 9 coatings prepared by Taguchi program for 3 levels of four spray parameters. The Friction and wear behaviors of HVOF WC-CoCr coating prepared by OCP, electrolytic hard chrome (EHC) plating and Inconel718 (In718) are investigated by reciprocating sliding wear test at $25^{\circ}C$, $450^{\circ}C$. Friction coefficients (FC) of all of the 3 samples are decreased as increasing sliding surface temperature from $25^{\circ}C$ to $450^{\circ}C$. FC of WC-CoCr decreases as increasing the surface temperature from $0.33{\pm}0.02$ at $25^{\circ}C$ to $0.26{\pm}0.02$ at $450^{\circ}C$, showing the lowest FC among the 3 samples. Wear trace (WT) and wear depth (WD) of WC-CoCr are smaller than those of EHC and In718 both at $25^{\circ}C$ and $450^{\circ}C$. These show that WC-CoCr is highly recommendable for protective coating on In718 and other metal components.