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Review of Domestic Research Trends on Layered Double Hydroxide (LDH) Materials: Based on Research Articles in Korean Citation Index (KCI) (이중층수산화물(layered double hydroxide, LDH) 소재의 국내 연구동향 리뷰: 한국학술지인용색인(KCI)에 발표된 논문을 대상으로)

  • Seon Yong Lee;YoungJae Kim;Young Jae Lee
    • Economic and Environmental Geology
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    • v.56 no.1
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    • pp.23-53
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    • 2023
  • In this review paper, previous studies on layered double hydroxides (LDHs) published in the Korean Citation Index (KCI) were examined to investigate a research trend for LDHs in Korea. Since the first publication in 2002, 160 papers on LDHs have been published until January 2023. Among the 31 academic fields, top 5 fields appeared in the order of chemical engineering, chemistry, materials engineering, environmental engineering, and physics. The chemical engineering shows the highest record of published paper (71 papers) while around 10 papers have been published in the other four fields. All papers were reclassified into 15 research fields based on the industrial and academic purposes of using LDHs. The top 5 in these fields are in order of environmental purification materials, polymer catalyst materials, battery materials, pharmaceutical/medicinal materials, and basic physicochemical properties. These findings suggest that researches on the applications of LDH materials in the academic fields of chemical engineering and chemistry for the improvement of their functions such as environmental purification materials, polymer catalysts, and batteries have been being most actively conducted. The application of LDHs for cosmetic and agricultural purposes and for developing environmental sensors is still at the beginning of research. Considering a market-potential and high-efficiency-eco-friendly trend, however, it will deserve our attention as emerging application fields in the future. All reclassified papers were summarized in our tables and a supplementary file, including information on applied materials, key results, characteristics and synthesis methods of LDHs used. We expect that our findings of overall trends in LDH research in Korea can help design future researches with LDHs and suggest policies for resources and energies as well as environments efficiently.

Potential Study for the Sedimentary Exhalative Pb-Zn Mineralization in Dyusembay Area, Kazakhstan (카자흐스탄 듀셈바이지역의 퇴적분기형 연-아연 광화작용에 대한 잠재력 연구)

  • No, Sang-gun;Lee, Seung-han;Park, Ki-woong;Jeong, Hyeon-guk;Yun, Ji-seong;Kim, Sun-ok;Park, Maeng-eon
    • Economic and Environmental Geology
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    • v.51 no.3
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    • pp.213-222
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    • 2018
  • Metasediment-hosted Pb-Zn mineralized zone has been found in Dyusembay of Kazakhstan. Its petrological properties, metal index, alteration index and redox-sensitivity are compared with those of SEDEX type deposit. Mineralization is developed along foliation of host rock (graphitic phyllite) and controlled by folds and faults; major ore minerals including pyrite, pyrrhotite, sphalerite, and galena are disseminated or interlayered with fine-grained quartz. The margin of the mineralized zone is metamorphosed accompanying sericite and chlorite. Hydrothermal brecciation and Pb-Zn mineralization formed in quartz-calcite stockworks are confirmed at the around of Maytyubin granitoid intrusions. The mineralization is classified into three types according to those of occurrence, paragenesis, chemical composition and isotopic characteristics. Type 1 whose fine-grained pyrite, pyrrhotite and sphalerite are formed in parallel yet discontinuous to well-developed foliations of the host rock; its geochemistry is similar to those of the earlier stage in SEDEX-type mineralization. In case of type 2, the ore minerals of which are concentrated being parallel to a foliation by regional metamorphism, and most of them associated with quartz and muscovite (${\pm}$ biotite) paragenetically. Type 3 is formed in the hydrothermal breccia zone whose ore minerals are controlled by foliation and breccia and developed in quartz ${\pm}$ calcite veins having a form such as stratification, stockwork or veinlets. Host rocks in the mineralized zone indicate homogeneous metamorphic grade and there is no specific alteration zonation. Also, all types (type 1, type 2, and type 3) represent similar REEs patterns, it can be interpreted that these are originated from a same source. Sulphides occurred in mineralized zone indicate a limited range of sulphur isotope values (type 2, ${\delta}^{34}S=-13.3{\sim}-11.7$‰; type 3, ${\delta}^{34}S=-13.9{\sim}-8.2$‰), and a result of geothermometry presents different temperature ranges: type 2($251{\pm}38^{\circ}C{\sim}277{\pm}40^{\circ}C$); type 3($360{\pm}2^{\circ}C$ to $537{\pm}29^{\circ}C$). It is estimated to be due to the effect of metamorphism and Maytyubin granitoid intrusions, respectively. In addition, ternary chart of thorium, scandium, and zircon for discrimination of tectonic setting and redox sensitivity using V/Mo values indicate that hydrothermal sediments put on reduction environment after precipitation, before being affected by metamorphism and intrusion activity. Geochemical data are plotted on a distal trend of SEDEX-type with discrimination plot using SEDEX index. As a result, petrological-geochemical properties demonstrate that Dyusembay Pb-Zn mineralized zone is comparable to distal-type of SEDEX deposit.

Analysis of the Physiological Healing Effects by Forest Types - Focused on Hypertensive and Diabetic - (숲의 종류에 따른 생리적 치유효과 분석 - 고혈압과 당뇨병 환자를 중심으로 -)

  • Jeong, Na-Ra;Ahn, Deug-Soo
    • Journal of the Korean Institute of Landscape Architecture
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    • v.43 no.5
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    • pp.1-12
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    • 2015
  • This study analyzes the physiological healing effects on users according to forest types. Forest types are classified into Chamaecyparis obtusa, Quercus serrata and Pinus densiflora and the subjects of this study, 64 hypertensives, 59 diabetics and 59 ordinary people, were tested to observe their physiological effects. The index of physiological reaction comprises electroencephalogram(EEG), heart rate variability(HRV), blood pressure and cortisol level. An analysis of the stress-buffering effect from the physiological reactions of the overall subjects indicates that Quercus serrata forests have a higher stress-buffering effect than others in terms of central nervous, endocrine and autonomic nervous systems. Chamaecyparis obtusa forests are contributory to soothing stress in the central nervous and endocrine systems. Pinus densiflora forests contribute in some indexes of the endocrine and autonomic nervous systems. In contrast, Pinus densiflora forests are less influential on a stress-buffering effect than the other two. In the level of the effect for lowering blood pressure, Chamaecyparis obtusa and Quercus serrata forests are more effective than Pinus densiflora forests. Therefore, staying in the first two forests can heighten the healing effect of the lowering of blood pressure for hypertensive patients. Every forest is efficacious to lowering diabetic blood glucose levels. Spending time in Quercus serrata forests is more effective for hypoglycemic.

Mineral Medicine Described in the Oriental Medicine Book and Mineral Medicines Applicable to Atopic Dermatitis Treatment (한의서에 기재된 광물(鑛物) 약재 및 아토피피부염 활용 외용성 광물(鑛物) 약재)

  • Bak, Jiwon;Kim, Donghee
    • Economic and Environmental Geology
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    • v.48 no.3
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    • pp.231-240
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    • 2015
  • A total of 93 mineral medicines are mentioned in the Chinese Bonchodogam(本草圖鑑). In Donguibogam(東醫寶鑑), 77 mineral medicines are listed, where 18 are from soil origin, 4 from gem origin, and 55 mineral medicines were originated from stone. In the Herblogy(本草學), which is the textbook used in most oriental medicine colleges in Korea, a total of 23 mineral medicines are listed. Of those, Cinnabaris, Alumen, Melanteritum, Realgar, Orpimentum, Sulfur, Lime from Donguibogam, additional eight which are Talcum, Calomelas, Minium, Calamina, Stannum, Hydrargyrum, Lithargyrum, Hydrargyrum Chloratum from Bonchodogam and Gypsum, Natrii Sulfas, Talcum, Cinnabaris, Sulfur, Arsenicum Sublimatum, Realgar, Calomelas, Minium, Calamina, Borax, Aurum, Glauberitum from Herblogy were selected as the mineral medicine applicable as external atopic dermatitis treatment. Most of the mineral medicines were generally regarded as toxic materials, and therefore, they were elaborately processed to remove toxicity before use. In accordance, it is necessary to discuss how to effectively remove toxicity from toxic mineral medicines. In addition, detoxification can be applied to those mineral medicines classified based on the index material or high content compounds, and if efficacy can be evaluated through various analytical methods, this can be applied to diverse inflammatory diseases as well as atopic dermatitis.

Stratigraphy of the BP-1 well from Sora Sub-basin (소라소분지 BP-1공의 층서연구)

  • Oh, Jaeho;Kim, Yongmi;Yun, Hyesu;Park, Eunju;Yi, Songsuk;Lee, Minwoo
    • Economic and Environmental Geology
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    • v.45 no.5
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    • pp.551-564
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    • 2012
  • This study carried out palynological analysis and seismic interpretation to establish a stratigraphic and environmental reconstruction mainly based on fossil palynomorphs and seismic reflection data correlated with the oil exploation well (BP-1) located in the Sora Sub-basin. There were frequent environmental and floral changes due to sea level change in the Sora Sub-basin. The palynomorph assemblages found in the well sediments enabled paleoecological zonation of the well sediment sequence resulting in 4 zones: Ecozone III, Ecozone IV, Ecozone V, Ecozone VI. Index fossils among palynomorphs indicate geological ages of the units within the well ranging from Eocene to Pleistocene, and paleoenvironment varies from freshwater to inner neritic marine. Previous studies suggest that the marine deposits were slightly different in stratigraphic range from well to well. It is considered the difference is credited to geomorphological setting. This study also shows stratigraphic correlation between existing wells and BP-1 well to establishes a standard stratigraphy of the Domi Basin.

Characteristics and Provenance of Heavy Minerals in the Yellow Sea and Northern East China Sea (황해 및 동중국해 북부의 중광물 특성과 기원)

  • Koo, Hyo Jin;Lee, Bu Yeong;Cho, Hyen Goo
    • Economic and Environmental Geology
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    • v.53 no.5
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    • pp.505-515
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    • 2020
  • The Yellow Sea and northern East China Sea contain a transgressive sand layer. Numerous sedimentary studies have been carried out in these sand deposits using seismic exploration and core sediment techniques, but few mineralogical studies have been reported. The major purposes of this study are to describe the distributions of heavy minerals throughout the Yellow sea and northern East China Sea and to identify the provenance of coarse sediments using the mineral chemistry. Eight heavy mineral species were identified in the study area (epidote, amphibole, garnet, zircon, sphene, rutile, apatite, and monazite). The study region was divided into six areas (areas A to F) based on heavy mineral distributions and sampling locations. In mineral chemistry, the amphiboles present are classified as edenite and hornblende in the calcic amphibole group, and the garnets are identified primarily as almandine in the pyralspite group. A combined data set of heavy mineral distributions and mineral chemistry showed clear differentiation of the characteristics of the six classified areas, enabling determination of provenance and sedimentary environment. Area A and B in the eastern Yellow Sea were originated from the Korean peninsula, and these regions showed different heavy mineral characteristics by tidal current and coastal current. In addition, monazite was only found in the area B and could be used as an indicator from the southwestern Korean peninsula. Area D and E in the western Yellow Sea showed the characteristics of sediments originating from the Huanghe, and sediment in the area E was derived from the Changjiang. Area C in the northern East China Sea appeared to have Changjiang-origin sediment, and abundant apatite indicated that area C was formed close to the Last Glacial Maximum.

Stratigraphy and Paleoenvironment of Domi-1 and Sora-1 Wells, Domi Basin (도미분지 도미-1, 소라-1공의 층서와 고환경)

  • Yun, Hye-Su;Byun, Hyun-Suk;Oh, Jin-Yong;Park, Myong-Ho;Lee, Min-Woo
    • Economic and Environmental Geology
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    • v.45 no.4
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    • pp.407-429
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    • 2012
  • There has been much debates on the geologic age of the sediments of the Domi Basin, since age results varied after research methods and fossil groups. This study carried out palynological analysis and seismic interpretation to establish a stratigraphy and environmental reconstruction mainly based on fossil dinoflagellates and Seismic data from the Domi-1 and Sora-1 wells. The dinocyst assemblages found enabled zonation of the well sediment sequence resulting in 4 ecozones. Index fossils among dinocysts and palynomorphic substances indicate geologic age of the well ranges from Eocene to Pleistocene, and paleoenvironment varies from freshwater to inner-neritic marine. The fossil association also suggests strong relationship to Japanese Tertiary basins in Kyushu area in terms of stratigraphy and basin developmental history.

Qualitative Analysis of Research Papers of KIGAM World Class Laboratories (WCL) Candidates (논문 질적평가를 통한 KIGAM 세계수준 후보연구실 기술수준 평가)

  • Ahn, Eun-Young
    • Economic and Environmental Geology
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    • v.47 no.3
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    • pp.227-235
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    • 2014
  • For technology level assessment of KIGAM World Class Laboratories (WCL) candidates, bibliometric and qualitative analysis was conducted on their research papers listed on the SCIE database during 2009-2012. For the six research areas of geoscience and mineral resources, a research excellence indicator was applied using a Modified Rank Normalized Impact Factor (mrnIF), which was introduced by Heo et al. (2008) and Cho (2013). The KIGAM research department in rare metals utilization had the highest score for Impact Factor (IF) per paper in 2012 but the groundwater department or the exploration geophysics department came first based on the position and the mrnIF. Applying the mrnIF, the KIGAM research department in groundwater achieved excellent results in 2009 and 2011 and the urban mine department or exploration geophysics department came first place in other years. In the groundwater area, the percentage of research papers over 80 or 90 mrnIF, using Cho (2013)'s research excellence index, was the highest in 2011. The Cho (2013)'s excellent research indicator, 20%, the ratio of over 90 mrnIF was matched in the urban mining area for the whole research period, 2009-2012, and in the groundwater area for several years except 2010. Qualitative analysis of research papers can show the technology level of research departments. KIGAM World Class Laboratories (WCL) candidates should focus on increasing the quality and the quantity of their research papers.

Slope Stability and Development of Debris Flow Deposit in the Ulleung Basin, East Sea (동해 울릉분지의 사면안정성 및 쇄설류 퇴적체의 발달)

  • Lee, Sun-Jong;Lee, Jeong-Min;Yoo, Dong-Geun;Lee, Go-Eun;Park, Soo-Chul
    • Economic and Environmental Geology
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    • v.50 no.2
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    • pp.129-143
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    • 2017
  • The shallow sediments in the southwestern Ulleung Basin consist of mass flow deposits such as slide/slump and debris flow deposits (DFD), caused by slope failure. These sediments are proven to be important in studying geological disaster and stability of the seafloor. In this paper, we analysised the flow accumulation and slope failure susceptibility of the Ulleung Basin on the basis of multi-beam data, collected in this area. We also studied the distribution pattern and the seismic characteristics of the DFD in the uppermost layer of the Ulleung Basin on the basis of seismic data. The slope susceptibility was calculated as the frequency ratio of each factors including slope, aspect, curvature and stream power index (SPI), which causes the slope failure. These results indicate that the slope failure is frequently to occur in the southern and western continental slope of the Ulleung Basin. The sediment flow (mass flow) caused by the slope failure converges to the north and northwest of the Ulleung Basin. According to the seismic characteristics, the uppermost layer in study area can be divided into four sedimentary unit. These sedimentary units develop from the south and southwest to the north and northwest in association with slope susceptibility and flow accumulation.

The Neuroanatomy and Psychophysiology of Attention (집중의 신경해부와 정신생리)

  • Lee, Sung-Hoon;Park, Yun-Jo
    • Sleep Medicine and Psychophysiology
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    • v.5 no.2
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    • pp.119-133
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    • 1998
  • Attentional processes facilitate cognitive and behavioral performance in several ways. Attention serves to reduce the amount of information to receive. Attention enables humans to direct themselves to appropriate aspects of external environmental events and internal operations. Attention facilitates the selection of salient information and the allocation of cognitive processing appropriate to that information. Attention is not a unitary process that can be localized to a single neuroanatomical region. Before the cortical registration of sensory information, activation of important subcortical structures occurs, which is called as an orienting response. Once sensory information reaches the sensory cortex, a large number of perceptual processes occur, which provide various levels of perceptual resolution of the critical features of the stimuli. After this preattentional processing, information is integrated within higher cortical(heteromodal) systems in inferior parietal and temporal lobes. At this stage, the processing characteristics can be modified, and the biases of the system have a direct impact on attentional selection. Information flow has been traced through sensory analysis to a processing stage that enables the new information to be focused and modified in relation to preexisting biases. The limbic and paralimbic system play significant roles in modulating attentional response. It is labeled with affective salience and is integrated according to ongoing pressures from the motivational drive system of the hypothalamus. The salience of information greatly influences the allocation of attention. The frontal lobe operate response selection system with a reciprocal interaction with both the attention system of the parietal lobe and the limbic system. In this attentional process, the search with the spatial field is organized and a sequence of attentional responses is generated. Affective, motivational and appectitive impulses from limbic system and hypothalamus trigger response intention, preparation, planning, initiation and control of frontal lobe on this process. The reticular system, which produces ascending activation, catalyzes the overall system and increases attentional capacity. Also additional energetic pressures are created by the hypothalamus. As psychophysiological measurement, skin conductance, pupil diameter, muscle tension, heart rate, alpha wave of EEG can be used. Event related potentials also provide physiological evidence of attention during information process. NI component appears to be an electrophysiological index of selective attention. P3 response is developed during the attention related to stimulus discrimination, evaluation and response.

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