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Manganese removal by KMnO4: Effects of bicarbonate and the optimum conditions (과망간산칼륨을 이용한 용해성 망간 제거: 중탄산염 영향 및 최적조건)

  • Lee, Yong-Soo;Do, Si-Hyun;Kwon, Young-Eun;Hong, Seong-Ho
    • Journal of Korean Society of Water and Wastewater
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    • v.30 no.2
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    • pp.207-213
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    • 2016
  • This study is focused on manganese (Mn(II)) removal by potassium permanganate ($KMnO_4$) in surface water. The effects of bicarbonate on Mn(II) indicated that bicarbonate could remove Mn(II), but it was not effectively. When 0.5 mg/L of Mn(II) was dissolved in tap water, the addition of $KMnO_4$ as much as $KMnO_4$ to Mn(II) ratio is 0.67 satisfied the drinking water regulation for Mn (i.e. 0.05 mg/L), and the main mechanism was oxidation. On the other hand, when the same Mn(II) concentration was dissolved in surface water, the addition of $KMnO_4$, which was the molar ratio of $KMnO_4/Mn(II)$ ranged 0.67 to 0.84 was needed for the regulation satisfaction, and the dominant mechanisms were both oxidation and adsorption. Unlike Mn(II) in tap water, the increasing the reaction time increased Mn(II) removal when $KMnO_4$ was overdosed. Finally, the optimum conditions for the removals of 0.5 - 2.0 mg/L Mn(II) in surface water were both $KMnO_4$ to Mn(II) ratio is 0.67 - 0.84 and the reaction time of 15 min. This indicated that the addition of $KMnO_4$ was the one of convenient and effective methods to remove Mn(II).

Synthesized and Characterization of high density cathode materials for Lithium Secondary Batteries (리튬이온이차전지용 고밀도 양극활물질의 합성 및 평가)

  • Kwon, Yong-Jin;Choi, Byung-Hyun;Ji, Mi-Jung;Sun, Yang-Kuk
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.429-429
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    • 2008
  • Li$[Ni_{1/2}Co_{1/2}]O_2$ powder were synthesized from co-precipitation spherical metal oxide, $[Ni_{1/2}Co_{1/2}](OH)_2$. The preparation of metal hydroxide was significantly dependent on synthetic conditions, such as pH, amount of chelating agent, stirring speed, etc. The optimized condition resulted in $[Ni_{1/2}Co_{1/2}](OH)_2$, of which the particle size distribution was uniform and the particle shape was spherical, as observed by scanning electron microscopy. Calcination of the uniform metal hydroxide with LiOH at higher temperature led to a well-ordered layer-structured Li$[Ni_{1/2}Co_{1/2}]O_2$, as confirmed by X-ray diffraction pattern. Also these materials have ${\alpha}-NaFeO_2$ ($R\bar{3}m$) structure. Due to the homogeneity of the metal hydroxide, $[Ni_{1/2}Co_{1/2}](OH)_2$, the final product, Li$[Ni_{1/2}Co_{1/2}]O_2$, was also significantly uniform, i.e., the average particle size was of about 10 to 15 ${\mu}m$ in diameter and the distribution was relatively narrow. As a result, the corresponding tap-density was also high approximately 2.41 $gcm^{-3}$, of which the value is comparable to that of commercialized $LiCoO_2$.

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Effects of flushing techniques on water quality at extremity with low chlorine residuals in drinking water distribution systems (수질 취약지역 및 관말에서 플러싱 적용 먹는물 수질 개선 효과)

  • Ko, Kyung-Hoon;Kweon, Ji-Hyang;Kim, In-Ja;Lim, Woo-Hyuk
    • Journal of Korean Society of Water and Wastewater
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    • v.25 no.3
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    • pp.313-324
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    • 2011
  • Several complaints from consumers on red or turbid waters were often filed at the same places although various efforts were made to improve water quality in the drinking water plant. The red water problems were occurred due to corrosion of main water pipe, especially at extremity. The low concentrations of chlorine indicating poor water quality were detected at the problematic location. To solve the poor water quality at the extremity, flushing techniques, i.e., conventional flushing, unidirectional flushing, and continuous flushing, were recently practiced. In this study, effects of conventional flushing on water qualities were examined by comparing turbidity and residual chlorine before and after flushing. In addition, more detailed analyses on water qualities at the tap water were conducted to learn a reduction pattern during flushing. Five items from geographic information system of water distribution were used to obtain a relationship with water quality, washing duration or amounts of washing water. The flushing was effective to meet the National Drinking Water Quality Standard with simple and relatively short time operation. The key operational parameter in flushing was amounts of washing water which should be estimated based on water quality of the consumer's tap water. The positive relationship between the residual chlorine and pipe length implied that detention time in the pipeline was the main cause of the complaints. More experiments on effectiveness of flushing are needed to determine reasonable strategies of flushing.

A Study on the Hardening Characteristics of Ground Injection Grout under Various Curing Conditions (다양한 양생조건에서 지반주입 그라우트의 경화특성에 대한 연구)

  • Heo, Hyungseok;Park, Innjoon
    • Journal of the Korean GEO-environmental Society
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    • v.21 no.11
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    • pp.11-20
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    • 2020
  • For water barrier and reinforcing grout in soft ground, the verification of durability was conducted over the initial and long-term ages under various curing conditions. The grout was made of water glass system, fast-hardening mineral (FHM) system, and acrylic polymer system. There were three types of curing conditions that were tab water curing, artificial seawater curing, and atmospheric curing. And the various tests were performed for each sample by age, uniaxial compressive strength, length change, and weight change. As artificial seawater, MgCl2 and MgSO4 aqueous solutions were prepared and used, respectively. As the test results, the fast-hardening mineral system and acrylic polymer system were cured stably without significant change in durability in tap water and artificial sea water, whereas water glass system showed a very rapid drop in durability under artificial sea water conditions compared to tap water. In atmospheric curing conditions, durability is lowered compared to water curing in all cases, and in particular, the weight loss in the FHM system and water glass system is about 62% and 60%, respectively, resulting in a significant decrease in durability.

Ability of children to perform touchscreen gestures and follow prompting techniques when using mobile apps

  • Yadav, Savita;Chakraborty, Pinaki;Kaul, Arshia;Pooja, Pooja;Gupta, Bhavya;Garg, Anchal
    • Clinical and Experimental Pediatrics
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    • v.63 no.6
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    • pp.232-236
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    • 2020
  • Background: Children today get access to smartphones at an early age. However, their ability to use mobile apps has not yet been studied in detail. Purpose: This study aimed to assess the ability of children aged 2-8 years to perform touchscreen gestures and follow prompting techniques, i.e., ways apps provide instructions on how to use them. Methods: We developed one mobile app to test the ability of children to perform various touchscreen gestures and another mobile app to test their ability to follow various prompting techniques. We used these apps in this study of 90 children in a kindergarten and a primary school in New Delhi in July 2019. We noted the touchscreen gestures that the children could perform and the most sophisticated prompting technique that they could follow. Results: Two- and 3-year-old children could not follow any prompting technique and only a minority (27%) could tap the touchscreen at an intended place. Four- to 6-year-old children could perform simple gestures like a tap and slide (57%) and follow instructions provided through animation (63%). Seven- and 8-year-old children could perform more sophisticated gestures like dragging and dropping (30%) and follow instructions provided in audio and video formats (34%). We observed a significant difference between the number of touchscreen gestures that the children could perform and the number of prompting techniques that they could follow (F=544.0407, P<0.05). No significant difference was observed in the performance of female versus male children (P>0.05). Conclusion: Children gradually learn to use mobile apps beginning at 2 years of age. They become comfortable performing single-finger gestures and following nontextual prompting techniques by 8 years of age. We recommend that these results be considered in the development of mobile apps for children.

Retention of BioAggregate and MTA as coronal plugs after intracanal medication for regenerative endodontic procedures: an ex vivo study

  • Amin, Suzan Abdul Wanees;Gawdat, Shaimaa Ismail
    • Restorative Dentistry and Endodontics
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    • v.43 no.3
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    • pp.18.1-18.12
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    • 2018
  • Objectives: This study compared the retention of BioAggregate (BA; Innovative BioCeramix) and mineral trioxide aggregate (MTA; Angelus) as coronal plugs after applying different intracanal medications (ICMs) used in regenerative endodontic. Materials and Methods: One-hundred human maxillary central incisors were used. The canals were enlarged to a diameter of 1.7 mm. Specimens were divided into 5 groups (n = 20) according to the ICM used: calcium hydroxide (CH), 2% chlorhexidine (CHX), triple-antibiotic paste (TAP), double-antibiotic paste (DAP), and no ICM (control; CON). After 3 weeks of application, ICMs were removed and BA or MTA were placed as the plug material (n = 10). The push-out bond strength and the mode of failure were assessed. The data were analyzed using 2-way analysis of variance, the Tukey's test, and the ${\chi}^2$ test; p values < 0.05 indicated statistical significance. Results: The type of ICM and the type of plug material significantly affected bond strength (p < 0.01). Regardless of the type of ICM, BA showed a lower bond strength than MTA (p < 0.05). For MTA, CH showed a higher bond strength than CON, TAP and DAP; CHX showed a higher bond strength than DAP (p < 0.01). For BA, CH showed a higher bond strength than DAP (p < 0.05). The mode of failure was predominantly cohesive for BA (p < 0.05). Conclusions: MTA may show better retention than BA. The mode of bond failure with BA can be predominantly cohesive. BA retention may be less affected by ICM type than MTA retention.

Homologous Expression and Quantitative Analysis of T3SS-Dependent Secretion of TAP-Tagged XoAvrBs2 in Xanthomonas oryzae pv. oryzae Induced by Rice Leaf Extract

  • Kim, S.H.;Lee, S.E.;Hong, M.K.;Song, N.H.;Yoon, B.;Viet, P.T.;Ahn, Y.J.;Lee, B.M.;Jung, J.W.;Kim, K.P.;Han, Y.S.;Kim, J.G.;Kang, L.W.
    • Journal of Microbiology and Biotechnology
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    • v.21 no.7
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    • pp.679-685
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    • 2011
  • Xanthomonas oryzae pv. oryzae (Xoo) produces a putative effector, XoAvrBs2. We expressed XoAvrBs2 homologously in Xoo with a TAP-tag at the C-terminus to enable quantitative analysis of protein expression and secretion. Addition of rice leaf extracts from both Xoo-sensitive and Xoo-resistant rice cultivars to the Xoo cells induced expression of the XoAvrBs2 gene at the transcriptional and translational levels, and also stimulated a remarkable amount of XoAvrBs2 secretion into the medium. In a T3SS-defective Xoo mutant strain, secretion of the TAPtagged XoAvrBs2 was blocked. Thus, we elucidated the transcriptional and translational expressions of the XoAvrBs2 gene in Xoo was induced in vitro by the interaction with rice and the induced secretion of XoAvrBs2 was T3SSdependent. It is the first report to measure the homologous expression and secretion of XoAvrBs2 in vitro by rice leaf extract. Our system for the quantitative analysis of effector protein expression and secretion could be generally used for the study of host-pathogen interactions.

Free-Living Amoeba Vermamoeba vermiformis Induces Allergic Airway Inflammation

  • Lee, Da-In;Park, Sung Hee;Kang, Shin-Ae;Kim, Do Hyun;Kim, Sun Hyun;Song, So Yeon;Lee, Sang Eun;Yu, Hak Sun
    • Parasites, Hosts and Diseases
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    • v.60 no.4
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    • pp.229-239
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    • 2022
  • The high percentage of Vermamoeba was found in tap water in Korea. This study investigated whether Vermamoeba induced allergic airway inflammation in mice. We selected 2 free-living amoebas (FLAs) isolated from tap water, which included Korean FLA 5 (KFA5; Vermamoeba vermiformis) and 21 (an homolog of Acanthamoeba lugdunensis KA/E2). We axenically cultured KFA5 and KFA21. We applied approximately 1×106 to mice's nasal passages 6 times and investigated their pathogenicity. The airway resistance value was significantly increased after KFA5 and KFA21 treatments. The eosinophil recruitment and goblet cell hyperplasia were concomitantly observed in bronchial alveolar lavage (BAL) fluid and lung tissue in mice infected with KFA5 and KFA21. These infections also activated the Th2-related interleukin 25, thymic stromal lymphopoietin, and thymus and activation-regulated chemokines gene expression in mouse lung epithelial cells. The CD4+ interleukin 4+ cell population was increased in the lung, and the secretion of Th2-, Th17-, and Th1-associated cytokines were upregulated during KFA5 and KFA21 infection in the spleen, lung-draining lymph nodes, and BAL fluid. The pathogenicity (allergenicity) of KFA5 and KFA21 might not have drastically changed during the long-term in vitro culture. Our results suggested that Vermamoeba could elicit allergic airway inflammation and may be an airway allergen.

Relationship between Population Growth and Digestive Enzyme Activity of Rotifer Brachionus rotundiformis (Rotifer Brachionus rotundiformis의 개체군 성장과 소화효소 활성의 관계)

  • Kwon, O-Nam;Park, Heum-Gi
    • Journal of Aquaculture
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    • v.21 no.1
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    • pp.47-53
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    • 2008
  • The purpose of this study was to suggest that selecting method of rotifer with high activity of digestive enzymes for the enrichment effect of rotifer and the increasing of digestive enzymes of fish larvae. the populations assayed the activities of the digestive enzymes were randomly selected out of several population communities cultured with freshwater condensed Chlorella. The relationship with the population density and the growth rate of selected populations was shown to RD=5865 SGR-350.08(P<0.001). The relationships with fecundity of the growth rate and the population density were shown to F=-36.147 SGR+61.652(P<0.05) and F=-0.0085 RD+66.38(P<0.001), respectively. The relationships of the growth rate and the individual activities of digestive enzymes in rotifer were assayed to Amyl=-1.6482 SGR+3.2498(P<0.05), TAP=-0.8115 SGR+1.1361(P<0.001) and TGL+0.0055 SGR+0.0079(P=0.239), respectively. But in TG-lipase was not related significantly with the growth rate. Also the relationships of the fecundity and the individual activities of digestive enzymes in rotifer were shown to Amyl=0.0296 F+1.0981(P<0.001), TAP=0.0252 F+0.0975(P<0.001) and TGL=-6E-06 F+0.0113(P=0.915), respectively. But in TG-lipase was not related significantly with the fecundity. And the relationships with the specific activity of TG-lipase of the fecundity, the growth rate and the population density were TGL=-0.024 F+0.2332(P=0.132), TGL=0.1267 SGR+0.005(P<0.01) and TGL=0.0002 F-0.0594(P<0.001), respectively. In this case, specific activity of TG-lipase was shown the significant relationship with the population density and the growth rate, but it was not related significantly with fecundity. Therefore, Because a population shown the high activity of digestive enzymes for increasing a lipid enrichment effect of a rotifers and receiving the many exogenous digestive enzymes to fish larvae was the population of high fecundity than the population of high rotifer density, to select the population of a high fecundity was suggested to benefit than a high growth rate for fish larvae.

Effectiveness of "Picture Book Reading Program for Mothers" for Married Immigrant Women and Their Children (여성결혼이민자와 유아기 자녀를 위한 어머니대상 '그림책 읽기 프로그램'의 효과검증)

  • Hyun, Eun-Ae;Rha, Jong-Hay
    • Korean Journal of Human Ecology
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    • v.21 no.2
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    • pp.165-180
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    • 2012
  • The purpose of the study was to prove the effect of the "Picture Book Reading Program for Mothers" developed to enhance the language competence of married immigrant women and their children. Twenty immigrant mothers with three-year-olds were recruited, and they participated in an 8-week-Picture Book Reading Program developed by the reseacher. The REVT and U-TAP were used to measure linguistic abilities for mothers while PRES was used to measure their children's linguistic abilities. Lee(2004)'s "Effect of dialogic picture book reading teacher training program for toddlers" was used to measure the mother's and children's verbal and non-verbal behaviors. The results of the study were as follows: First, by participating in the PBRPM, the mother's linguistic ability as well as children's vocabulary and receptive language have increased. Second, by participating in the PBRPM in terms of mother-child interaction, mother's verbal behaviors to children (i.e. attention and inquiring) and children's verbal behaviors(i.e. responding and imitation) have increased. In conclusion, "PBRPM" for married immigrant women and their children proved to be effective in enhancing the language competence and verbal interactions between married immigrant women and their children.