• 한국해안해양공학회지
• /
• 제3권3호
• /
• pp.126-136
• /
• 1991

본 논문에서는 파랑하중을 받는 Guyed Tower의 비선형 동적거동에 대하여 연구하였다. Guyed Tower를 효율적으로 해석하기 위하여 Tower는 등가의 기둥으로 모형화 하였으며, 계유장치는 수평방향의 비선형 경계요소로 이상화하였다. 또한 파일 기초부는 회전방향의 선형경계요소로 대치하였다. Tower에 작용하는 파랑하중은 Morison 방정식에 의한 산정하였다. 계유장치와 유체의 점성에 기인된 항력 등의 비선형성을 적절히 고려하기 위하여 시간영역에서 해석을 수행하였으며, 비선형 운동방정식을 효율적으로 풀기 위해 Newmark 적분기법에 기초한 모우드 중첩법을 사용하였다. Guyed Tower의 중요한 설계변수인 계유선의 Clump weight 중량 조건과 파일 기초부 조건의 변화에 대한 수치해석을 수행하였다.

• Journal of Microbiology and Biotechnology
• /
• 제11권3호
• /
• pp.369-375
• /
• 2001

Urushiol, a natural monomeric oil, was used to prepare a detergentless micro-emulsion with water and 2-propanol The formation of micro-emulsion was verified by conductivity measurements and dynamic light scattering. The conductivity data showed phase change dynamics, a characteristics of micro-emulsions, and subsequent dynamic light scattering study further confirmed the phenomenon. Average water droplet diameter was 10 nm to 500 nm when the molar ratio of 2-propanol ranged from 0.40 to 0.44 . Earlier studies were performed on toluene and hexane, in which the insoluble substrate in water phase was added to the solvents to be reacted on by enzymes. However, in the present urushiol system, urushiol was used as both solvent and substrate in the laccase polymerization of urushiol. The laccase activity in the system was examined using polymerization of urushiol. The laccase activity in the system was examined using syringaldezine as a substrate, and the activity increased rapidly near the molar ratio of 2-propanol at 0.4, where micro-emulsion started. The activity rose until 0.46 and fell dramatically thereafter. The study of laccase activity in differing mole fractions of 2-propanol showed the existence of an ‘optimal zone’, where the activity of laccase was significantly higher. In order to analyze urushiol polymerization by laccase, a bubble column reactor using a detergentless micro-emulsion system was constructed. Comparative study using other organic solvents systems were conducted and the 2-propanol system was shown to yield the highest polymerization level. The study of laccase activity at a differing mole fraction of 2-propanol showed the existence of an ‘optimal zone’ where the activity was significantly higher. Also, 3,000 cP viscosity was achieved in actual urushi processing, using only 1/100 level of laccase present in urushi.

• 폴리머
• /
• 제36권5호
• /
• pp.628-636
• /
• 2012

폴리(비닐 알코올)(PVA)/디메틸설폭사이드 용액에 폴리스티렌 라텍스 구형입자(직경 범위: 100~300 nm)를 소량 첨가한 뒤, 구형 입자 표면에 형성된 사슬 배제층 두께가 사슬의 농도에 따라 어떻게 의존하는지를 동적 광산란법으로 조사하였다. 묽은 용액 농도에서는 배제층의 두께가 PVA 사슬의 회전반경의 $63{\pm}3%$ 수준에서 일정하게 유지되었었으나 준희박 용액 농도의 초기 영역인 $1.5{\leq}C[{\eta}]{\leq}3$ 범위에서는 배제층 두께 ${\delta}$의 고분자 농도 의존성은 이론치 -0.75와 비슷한 ${\delta}{\sim}C^{-0.8}$로 얻어졌다. 보다 높은 농도 $C[{\eta}]$ >3 이상에서는 배제층의 두께가 급격히 감소하는 것으로 나타났는데 그 이유는 탐침입자간 Oosawa 인력에 의하여 유발된 응집효과가 그 원인인 것으로 설명할 수 있었다.

• 폴리머
• /
• 제39권2호
• /
• pp.247-255
• /
• 2015

Poly(1,2-propylene glycol adipate) (PPA) was used as an environmentally friendly plasticizer in flexible poly(vinyl chloride) (PVC). Thermal, mechanical, and rheological properties of the PVC/PPA blends were characterized by differential scanning calorimetry, dynamic mechanical analysis, tensile test, scanning electron microscopy and small amplitude oscillatory shear rheometry. The results showed that PPA lowered the glass transition temperature of PVC. The introduction of PPA could decrease tensile strength and Young's modulus of the PVC/PPA blends; however, elongation-at-break was dramatically increased due to the plastic deformation. The plasticization effect of PPA was also manifested by the decrease of dynamic storage modulus and viscosity in the melt state of the blends. The results indicated that PPA had a good plasticizing effect on PVC.

• Macromolecular Research
• /
• 제12권3호
• /
• pp.282-289
• /
• 2004

We have extensively characterized the fluorescence behavior of unsaturated polyester (UP) resin in the absence and presence of a 1,3-bis-(l-pyrenyl)propane (BPP) fluorescent probe at various dynamic and isothermal cure histories by means of a steady-state fluorescence technique using a front-face illumination equipment. In addition, we explored the effect of the fluorescence intensity on the relaxation of the fluorescent probe in the UP resin by resting the dynamically and isothermally cured resin at ambient temperature and pressure for 24 h. The monomer fluorescence intensity, which has two characteristic peaks at 376 and 396nm, changed noticeably depending on the cure temperature and time and provided important information with respect to the molecular and photophysical responses upon curing. The result of the fluorescence study indicates that the increased local viscosity and restricted molecular mobility of the UP resin surrounding the BPP probe after curing are both responsible for the enhancement of the monomer fluorescence intensity. Our results also demonstrate that once the BPP probe has enough time to rearrange and become isolated prior to fluorescence, a sufficient amount of fluorescence is emitted. Therefore, we note that the fluorescence behavior of this UP resin system is influenced strongly by the relaxation process of the fluorescent probe in the resin as well as process used to cure the resin.

• 한국연소학회:학술대회논문집
• /
• 한국연소학회 2006년도 제33회 KOSCO SYMPOSIUM 논문집
• /
• pp.242-250
• /
• 2006

The impacts of equivalence ratio on the flow structure and flame dynamics in a model gas turbine combustor are investigated using large eddy simulation(LES). Dynamic k-equation model and G-equation flamelet model are employed as LES subgrid model for flow and combustion, respectively. As a result of mean flow field for each equivalence ratio, the increase of equivalence ratio brings about the decrease of swirl intensity through the modification of thermal effect and viscosity, although the same swirl intensity is imposed at inlet. The changes of vortical structure and turbulent intensity etc. near flame surface are occurred consequently. That is, the decrease of equivalence ratio can leads to the increase of heat release fluctuation by the more increased turbulent intensity and fluctuation of recirculation flow. In addition, the effect of inner vortex generated from vortex breakdown on the heat release fluctuation is increased gradually with the decrease of equivalence ratio. Finally, it can be identified that the variations of vortical structure play an important role in combustion instability, even though the small change of equivalence ratio is occurred.

• Structural Engineering and Mechanics
• /
• 제47권5호
• /
• pp.599-622
• /
• 2013

Seismic response of two dimensional liquid tanks is numerically simulated using fully nonlinear velocity potential theory. Galerkin-weighted-residual based finite element method is used for solving the governing Laplace equation with fully nonlinear free surface boundary conditions and also for velocity recovery. Based on mixed Eulerian-Lagrangian (MEL) method, fourth order explicit Runge-Kutta scheme is used for time integration of free surface boundary conditions. A cubic-spline fitted regridding technique is used at every time step to eliminate possible numerical instabilities on account of Lagrangian node induced mesh distortion. An artificial surface damping term is used which mimics the viscosity induced damping and brings in numerical stability. Four earthquake motions have been suitably selected to study the effect of frequency content on the dynamic response of tank-liquid system. The nonlinear seismic response vis-a-vis linear response of rectangular liquid tank has been studied. The impulsive and convective components of hydrodynamic forces, e.g., base shear, overturning base moment and pressure distribution on tank-wall are quantified. It is observed that the convective response of tank-liquid system is very much sensitive to the frequency content of the ground motion. Such sensitivity is more pronounced in shallow tanks.

• 제어로봇시스템학회:학술대회논문집
• /
• 제어로봇시스템학회 2004년도 ICCAS
• /
• pp.296-300
• /
• 2004

A new MR cylinder with built-in valves using MR fluid (MR valve) is proposed for fluid power control systems. The MR or Magneto-Rheololgical fluid is a newly developed functional fluid whose obvious viscosity is controlled by the applied magnetic field intensity. The MR cylinder is composed of cylinder with small clearance and piston with electromagnet. The differential pressure is controlled by the applied magnetic field intensity. It has the characteristics of simple, compact and reliable structure. The size of MR cylinder and piston has ${\varphi}$60mm${\times}$259mm and ${\varphi}$58mm${\times}$136.5mm in face size respectively and 0.8mm in gap length. Through experiments on the static characteristics, it is found that the differential pressure is controlled by the applied magnetic field intensity under little influence of the flow rate, which corresponds to a pressure control valve. Effectiveness of the MR cylinder is demonstrated through the position control of one link MR manipulator.

• International Journal of Industrial Entomology and Biomaterials
• /
• 제40권1호
• /
• pp.28-32
• /
• 2020

Recently, many studies have been undertaken on the wet spinning and electrospinning of silk because wet-spun fibers and electrospun webs of silk can be applied in the biomedical and cosmetic fields owing to the good biocompatibility of silk. The rheological properties of silk solution are important because they strongly affect the spinning performance of the silk solution and the structures of resultant fibrous materials. Therefore, as a preliminary study on the effect of solvent composition on the rheological properties of silk fibroin (SF) solution and structure of the resultant film, in the reported work, methanol was added to the SF formic acid solution. A small amount of methanol (i.e. 2%) added to the SF formic acid solution significantly altered the rheological properties of the solution: its shear viscosity increased by 10 folds at low shear and decreased on increasing the shear rate, demonstrating shear thinning behavior of the SF solution. Dynamic tests for the SF solution indicated that the addition of 2% methanol altered the viscous state of the SF formic acid solution to elastic. However, the molecular conformation (i.e. β-sheet conformation) of the regenerated SF film cast from formic acid remained unchanged on the addition of 2% methanol.

• 대한전기학회논문지:전기물성ㆍ응용부문C
• /
• 제55권8호
• /
• pp.417-422
• /
• 2006

This paper presents the effect of driving waveform for piezoelectric bend mode inkjet printhead with optimized mechanical design. Experimental and theoretical studies on the applied driving waveform versus jetting characteristics were performed. The inkjet head has been designed to maximize the droplet velocity, minimize voltage response of the actuator and optimize the firing frequency to eject ink droplet. The head design was carried out by using mechanical simulation. The printhead has been fabricated with Si(100) and SOI wafers by MEMS process and silicon direct bonding method. To investigate how performance of the piezoelectric ceramic actuator influences on droplet diameter and droplet velocity, the method of stroboscopy was used. Also we observed the movement characteristics of PZT actuator with LDV(Laser Doppler Vibrometer) system, oscilloscope and dynamic signal analyzer. Missing nozzles caused by bubbles in chamber were monitored by their resonance frequency. Using the water based ink of viscosity of 4.8 cps and surface tension of 0.025 N/m, it is possible to eject stable droplets up to 20 kHz, 4.4 m/s and above 8 pl at the different applied driving waveforms.