• Bulletin of the Korean Chemical Society
• /
• v.21 no.12
• /
• pp.1222-1226
• /
• 2000

We synthesized the simple triethoxysilanes (SGDR1) bearing a disperse red 1 for thin film fabrication. The thin films were prepared using the solution of SGDR1 after hydrolysis and condensation. The films were annealed at two different temperatures such as $150^{\circ}C$ and $200^{\circ}C$. Trans-to-cis photoisomerization was observed under the exposure of 532 nm light with UV-Vis absorption spectroscopy. The kinetic study of photoisomerization was performed in the film. Reorientation of the polar azobenzene molecules induced optical anisotropy under a linearly polarized light at 532 nm. The effect of aggregation of the chromophores and annealing of the silicon oxide in the matrix were studied on the dynamic properties of isomerization and induced birefringence.

• Korean Chemical Engineering Research
• /
• v.60 no.2
• /
• pp.260-266
• /
• 2022

Average aggregate size in particulate suspensions is estimated with scaling theories based on fractal concept and elasticity of colloidal gel. The scaling theories are used to determine structure parameters of the aggregates, i.e., fractal dimension and power-law exponent for aggregate size reduction with shear stress using scaling behavior of elastic modulus and shear yield stress as a function of particle concentration. The structure parameters are utilized to predict aggregate size which varies with shear stress through rheological modeling. Experimentally rheological measurement is conducted for aqueous suspension of zinc oxide particles with average diameter of 110 nm. The predicted aggregate size is about 1135 nm at 1 s^-1 and 739 nm at 1000 s^-1 on the average over the particle concentrations. It has been found that the predicted aggregate size near 0.1 s^-1 agrees with that the measured one by a dynamic light scattering analyzer operated un-sheared.

• Journal of Microbiology and Biotechnology
• /
• v.16 no.9
• /
• pp.1369-1376
• /
• 2006

Self-organized nanogels were prepared from pullulan/biotin conjugates (PU/Bio) for the development of an effective anticancer drug delivery system. The degree of biotin substitution was 11, 19, and 24 biotin groups per 100 anhydroglucose units of pullulan. The physicochemical properties of the nanogels (PU/Bio1, 2 and 3) in aqueous media were characterized by dynamic light scattering, transmission electron microscopy, and fluorescence spectroscopy. The mean diameter of all the samples was less than 300 nm with a unimodal size distribution. The critical aggregation concentrations (CACs) of the nanoparticles in distilled water were $2.8{\times}10^{-2},\;1.6{\times}10^{-2}$, and $0.7{\times}10^{-2}mg/ml$ for the PU/Bio1, 2, and 3, respectively. The aggregation behavior of the nanogels indicated that biotin can perform as a hydrophobic moiety. To observe the specific interaction with a hepatic carcinoma cell line (HepG2), the conjugates were labeled with rhodamine B isothiocyanate (RITC) and their intensities measured using a fluorescence microplate reader. The HepG2 cells treated with the fluorescence-labeled PU/Bio nanoparticles were strongly luminated compared with the control (pullulan). Confocal laser microscopy also confirmed internalization of the PU/Bio nanogels into the cancer cells. Such results demonstrated that the biotin in the conjugate acted as both a hydrophobic moiety for self-assembly and a tumor-targeting moiety for specific interaction with tumor cells. Consequently, PU/Bio nanogels would appear to be a useful drug carrier for the treatment of liver cancer.

• Journal of the Mineralogical Society of Korea
• /
• v.28 no.2
• /
• pp.95-108
• /
• 2015

Nano-sized iron colloids are formed as acid mine drainage is exposed to surface environments and is introduced into surrounding water bodies. These iron nanomaterials invoke aesthetic contamination as well as adverse effects on aqueous ecosystems. In order to control them, the characteristics of their behaviour should be understood first, but the cumulative research outputs up to now are much less than the expected. Using zero-valent iron (ZVI) and magnetite, this study aims to investigate the behaviour of iron nanomaterials according to the change in the composition and pH of background electrolyte and the concentration of natural organic matter (NOM). The size and surface zeta potential of iron nanomaterials were measured using dynamic light scattering. Characteristic behaviour, such as aggregation and dispersion was compared each other based on the DLVO (Derjaguin, Landau, Verwey, and Overbeek) theory. Whereas iron nanomaterials showed a strong tendency of aggregation at the pH near point of zero charge (PZC) due to electrostatic attraction between particles, their dispersions became dominant at the pH which was higher or lower than PZC. In addition, the behaviour of iron nanomaterials was likely to be more significantly influenced by cations than anions in the electrolyte solutions. Particularly, it was observed that divalent cation influenced more effectively than monovalent cation in electrostatic attraction and repulsion between particles. It was also confirmed that the NOM enhanced the dispersion nanomaterials with increasing the negative charge of nanomaterials by coating on their surface. Under identical conditions, ZVI aggregated more easily than magnetite, and which would be attributed to the lower stability and larger reactivity of ZVI.

• Journal of Broadcast Engineering
• /
• v.19 no.4
• /
• pp.510-520
• /
• 2014

By adopting the MAC(Media Access Control) protocol which enables to pack multiple MPDUs(MAC-level Protocol Data Units) into a single PPDU(Physical Layer Protocol Data Unit), IEEE 802.11n WLAN supports high throughput. Up to now, there have been a lot of existing channel information-based A-MPDU schemes dynamically determining the number of MSDUs according to the wireless channel condition information which is sent from the receiver to sender. However, the channel information-based scheme has a serious drawback having a high system overhead due to the frequent channel feedback information. To reduce the system overhead, the proposed BA-base dynamic A-MPDU scheme simply chooses the number of MSDUs to be retransmitted by not the frequent channel feedback information but the BA signal representing whether MPSUs belonging to the A-MPDU are received or not. Through NS-2(Network Simulator-2), we found that the proposed scheme had higher throughput and lower packet error rate than the existing fixed A-MPDU scheme.

• Journal of the Korean Chemical Society
• /
• v.42 no.2
• /
• pp.156-160
• /
• 1998

Probe diffusion with latex particles in two different types of chemically cross linked gel has been studied. The diffusion of particles in silica gel is decreased by decreasing the gel correlation length but the particles' diffusion in the acrylamide gel still shows the heterogeneity of the gel. By increasing the contents of the gel network the silica gel makes a more homogeneous and compact structure than that of acrylamide gel which has partial heterodyning. Dynamic light scattering study with the probe particles in two different gels reveals the heterogeneity of the gel network. The latex particles trapping in the gel has been investigated by using non-ergodic concepts.

• Journal of the Korea Safety Management & Science
• /
• v.11 no.4
• /
• pp.221-228
• /
• 2009

Electronic Product Code Information Services(EPCIS) is an EPCglobal standard for sharing EPC related information between trading partners. EPCIS provides a new important capability to improve efficiency, security, and visibility in the global supply chain. EPCIS data are classified into two categories, master data (static data) and event data (dynamic data). Master data are static and constant for objects, for example, the name and code of product and the manufacturer, etc. Event data refer to things that happen dynamically with the passing of time, for example, the date of manufacture, the period and the route of circulation, the date of storage in warehouse, etc. There are four kinds of event data which are Object Event data, Aggregation Event data, Quantity Event data, and Transaction Event data. This thesis we propose an event-based data model for EPC Information Service repository in RFID based integrated logistics center. This data model can reduce the data volume and handle well all kinds of entity relationships. From the point of aspect of data quantity, we propose a formula model that can explain how many EPCIS events data are created per one business activity. Using this formula model, we can estimate the size of EPCIS events data of RFID based integrated logistics center for a one day under the assumed scenario.

• Korean Journal of Computational Design and Engineering
• /
• v.9 no.4
• /
• pp.361-372
• /
• 2004

Collaborative and distributed engineering web services are emerging as a viable alternative to the traditional design and engineering process automation. Existing approaches have limitations in supporting long-running engineering transactions, automatic engineering process orchestration and choreography, synchronous and asynchronous conversation, and geometric abstraction for transmission and sharing. In this paper, we present a process-centric engineering web service methodology to overcome these limitations by utilizing BPEL-based (Business Process Execution Language) process templates and coordination broker-based conversation support. This paper discusses the synchronization of engineering web services which can be either peer-centric or process-centric to support long-running engineering transactions and conversation. The process orchestration and choreography broker works as a service dispatching and aggregation mediator for executing process templates, which enables the individual activity or the engineering process to dynamically select and invoke one of the alternative web services through the run-time process brokering. Further, the paper presents how to support collaboration over the running process using conversation policy.

• The Transactions of The Korean Institute of Electrical Engineers
• /
• v.60 no.6
• /
• pp.1112-1121
• /
• 2011

A microgrid is an aggregation of multiple distributed generators (DGs) such as renewable energy sources, conventional generators, and energy storage systems that provide both electric power and thermal energy. Generally, a microgrid operates in parallel with the main grid. However, there are cases in which a microgrid operates in islanded mode, or in a disconnected state. Islanded microgrid can change its operational mode to grid-connected operation by reconnection to the grid, which is referred to as synchronization. Generally, a single machine simply synchronizes with the grid using a synchronizer. However, the synchronization of microgrid that operate with multiple DGs and loads cannot be controlled by a traditional synchronizer, but needs to control multiple generators and energy storage systems in a coordinated way. This is not a simple job, considering that a microgrid consists of various power electronics-based DGs as well as alternator-based generators that produce power together. This paper introduces the results of research examining an active synchronizing control system that consists of the network-based coordinated control of multiple DGs. Consequently, it provides the microgrid with a deterministic and reliable reconnection to the grid. The proposed method is verified by using the test cases with the experimental setup of a microgrid pilot plant.

• Macromolecular Research
• /
• v.16 no.5
• /
• pp.434-440
• /
• 2008

Three-armed, star-shaped molecules containing 4-(N,N-diphenyl)amino-4'-nitroazobenzene chromophores were synthesized to study the diffraction behavior after inscribing surface relief gratings. The two molecules differed in terms of their mode of chromophore attachment to the core. In compound 5, they were bound to the core laterally through alkylene spacers, whereas the chromophores were tethered perpendicularly to the core in compound 4. Although 60 wt% of the polar azobenzene chromophores was comprised of large molecules, no aggregation behavior was observed in the absorption spectra of the thin films. The surface relief gratings were elaborated on the surface of the molecular films by the two-beam interference method. The dynamics of grating formation were studied in terms of the diffraction efficiency using two different film samples made up of two star-shaped molecules. The maximum diffraction efficiency of D-$(ENAZ)_3$, compound 4, was measured to be about 30%, which was significantly high. The mode of chromophore attachment affected the dynamic properties of the diffraction gratings.