• Clean Technology
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• v.9 no.2
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• pp.87-100
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• 2003

The aim of study was to suggest a methodology for applying cleaner production technology in dyeing & finishing process of textile materials. To accomplish cleaner production, we performed consulting activity in dyeing factory, which composed of following different procedures. First, we organized consulting team with specialists for dyeing, energy and chemicals, and visited dyeing companies for the purpose of doing basic investigation such as analysis of process, chemicals & effluents, condition of equipment and process flow of products. Environmental aspect of raw materials (dyestuff, chemicals) was assessed by TOC, COD, BOD, and effluent of that was assessed by TOC, COD, BOD, TDS and pH. Second, We find out the problems in dyeing&finishing process from the view point of dyeing process, energy, raw materials and process management by utilizing MB (material balance), LCA(Life Cycle Assessment), EB(Energy Balance). Third, we generated the solutions to achieve optimal process condition by brain storming method, and then implemented the solutions to each process. Finally, we determined their effectiveness after considering the results of repeating trials for the solutions. Cleaner production could be achieved by keeping optimal process conditions, equipment modification, improved production management, and on-site reuse or recycling.

• Bulletin of the Korean Chemical Society
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• v.34 no.3
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• pp.863-867
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• 2013

A series of azo disperse dyes having dicyanovinyl groups was synthesized by the Knoevenagel condensation with malononitrile from carbonyl substituted phenylazo disperse dyes which were prepared by conventional diazo coupling reaction of aniline derivatives as diazo components. A variety of coupling components such as anilines, an indole and a pyridone were used. The azo disperse dyes were evaluated for their spectral properties and dyeing assessment on the polyester fabrics. The azo disperse dyes containing dicyanovinyl groups showed bathochromic shifts and darker colors due to increased electron withdrawing strength in their azo components and extended conjugation by dicyanovinyl groups than their parent carbonyl substituted azo dyes. The dyes containing 2-acetylamino-5-methoxy substituent in the coupling component exhibited higher wavelength of maximum absorbance (${\lambda}_{max}$) and significant negative solvatochromism than those of other dyes due to intramolecular hydrogen bonding.

• Journal of Korean Society on Water Environment
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• v.23 no.6
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• pp.881-888
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• 2007

In order to investigate the characteristics of the non-biodegradable material, the $BOD_5/COD_{Cr}$ ratio was used. The average ratio of industrial complex's influent wastewater was 2.29~2.96, the effluent ratio was 4.29~19.0. The removal efficiency of $UV_{254}$ by physicochemical treatment was 22.8~94.7% and 5.3~77.2% by biological treatment, respectively. Of the wastewater removal efficiency for each of the items, the $BOD_5$ treatment efficiency was the greatest at 97.3% and the color & TN treatment efficiency was 40~70%. The study of the economical assessment showed that the complex as well as the individual companies spent 722~1,298 won for each ton of treated wastewater. All of the wastewater treatment facilities spent the most money on chemicals needed to treat the wastewater. The total cost for Nylon manufacturing wastewater treatment plant was the greatest while the total cost for cotton manufacturing wastewater treatment plant turned out to the lowest. As respects of removal efficiency and economocal assessment, Polyester A and Cotton manufacturing wastewater treatment plants were better effective than a dyeing industrial complex wastewater treatment plant.

• Textile Coloration and Finishing
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• v.32 no.4
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• pp.255-264
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• 2020

With the development of synthetic dyes, excellent dyeing properties and massive production became possible. On the other hand, natural dyeing technology has gradually disappeared. However, the international environmental and human safety requirements of the apparel and textile industry are increasing, and there is a growing interest in safer and more environmentally friendly products. Accordingly, the public's interest in natural dyeing is increasing. To meet these demands, it is first necessary to clarify the stages of production and distribution of natural dyes. It is necessary to evaluate whether the product is a natural dye product and study the suitability of the natural dye product through qualitative and quantitative assessment of the indicator components of the natural dye. Typical of three natural dyes did qualitative and quantitative analysis by HPLC-DAD and HPLC-MS. Products dyed using natural dye three products were analyzed, and the presence or absence of detection of each indicator components was confirmed to confirm whether the product was dyed using natural dyes.

• Proceedings of the SAREK Conference
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• 2009.06a
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• pp.996-1001
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• 2009

The purposes of this work were suggested and validated the methods of heat recovery from dyeing wastewater exhausted in Sihwa and Banwol dyeing industrial park. We analyzed the present conditions of heat supplies and demands. So it was made a selection of the system combined heat exchanger for waste heat recovery and the high temperature heat pump. We decided the specifications of the heat recovery facilities. After this, economical assessment is performed to this system. The payback periods are within 4 years, 20 years and 5 years in case of K company, S company and A company. In addition, when they are produced the heat of same capacity, quantities of pollutants from used fuels were calculated.

• Fashion & Textile Research Journal
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• v.20 no.6
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• pp.752-758
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• 2018

Due to environmental pollution and human hazards of some synthetic dyes, the global fashion companies are increasingly interested in eco-friendly products, especially natural dye. For the globalization of natural dyeing industry based on this concern, however, there are some deficiencies of standardization, specification, and conformity assessment on natural dyestuffs as well as natural dyeing process. These obstacles should be not only studied but also defined for a commercial transaction. Accordingly, a study for conformity assessment on commercialized natural dyestuffs (red) was conducted by HPLC analysis in this study. As the results of HPLC analysis, alizarin and purpurin, representative index ingredients, were detected in most of the samples, but the index ingredient content in each sample was different. In addition, some samples showed the variety of peaks including the index ingredients and others. It was inferred that the representative index ingredients could be used on the traceability of natural sourced dyestuffs. These results are related to the index ingredient consistency, standardization, and reproducibility of natural dyed products including such as yarns, fabrics, garments, and so on. Therefore, the present study was demonstrated that in order to determine the conformity assessment system for the satisfaction of all stakeholders, the offering of information on the origin, manufacturing process, and index ingredient content of natural dyes should be prioritized.

• Journal of the Korea Fashion and Costume Design Association
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• v.13 no.1
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• pp.47-57
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• 2011

As the development of denim products using new differentiated materials plays an important role regardless of their target age groups, there is an increasing need for the development of premium denim designs for senior women using various materials. As part of the strategy to develop such a design for the senior generation, a market survey was performed regarding commercially available premium denim products in the market, and the current trends in the denim market were researched and analyzed to make use of the results in design development. In addition, a differentiated material, hybrid yarn using conjugated dyeing (HYCD) was applied to use several washing techniques capable of highlighting the unique features of denim clothing. The design of four items including a jacket, vest, capri pants and long pants were suggested. These items were differentiated from other products by emphasizing their details such as stitching and pockets. In light of the current consumer trend to select denim jeans on the basis of their fashion-ability (e.g., silhouette or color) rather than practicality or price, it is considered meaningful to develop high value added, premium jean products for the senior generation using diverse materials and details. At the same time, performing further studies designed to demonstrate the stability and reliability of the developed products through consumers' comparative assessment is required.

• Journal of the Korean Chemical Society
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• v.56 no.3
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• pp.348-356
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• 2012

In an attempt to find a new class of bisazo disperse dyes with better dyeing properties, a series of novel bisazo dyestuffs based on 4-arylhydrazono-3-(2'-hydroxyphenyl)-1-phenyl-2-pyrazolin-5-ones $\mathbf{3a-f}$ were prepared by diazocoupling of p-nitrophenyl diazonium chloride with 4-arylhydrazono-3-(2'-hydroxyphenyl)-1-phenyl-2-pyrazolin-5-ones $\mathbf{2a-f}$. Compounds $\mathbf{3a-f}$ were subsequently reacted with acetic anhydride in the presence of p-toluenesulfonic acid afford the corresponding O-acetyl derivatives $\mathbf{4a-f}$. The latter products as well as spectral data indicated that compounds $\mathbf{3a-f}$ exist predominantly in the azo-hydrazone tautomeric form (H) as the ZE-configuration. Additionally, two series of the synthesized dyes $\mathbf{3a-f}$ and $\mathbf{4a-f}$ were applied as disperse dyes for dyeing polyester fabrics and their fastness properties were evaluated. Also the position of color in CIELAB coordinates ($L^*$, $a^*$, $b^*$, $H^*$, $C^*$*) was assessed.

• Journal of the Korean Wood Science and Technology
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• v.49 no.2
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• pp.134-141
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• 2021

This study was conducted to investigate the potential of the neutral extract (NE) prepared by treating P. radiata bark with aqueous NaHCO3 solution as a natural dyestuff. Silk and cotton fabrics were dyed at four different NE concentrations, 0.5%, 1.0%, 1.5%, and 2.0% o.w.b. (on the weight of bath). The fabric to liquid ratio of 1 : 50, dyeing temperature of 90℃, and dyeing time of 90 min were used as the fixed condition. The appropriate NE dyeing concentration of silk and cotton fabrics was 1.5% o.w.b. Colors of the dyed silk and cotton fabrics were brown and light brown, respectively. From colorfastness assessment, both dyed silk and cotton showed good washing and rubbing fastness, but poor light fastness. NE dyed fabrics exhibited excellent ammonia deodorization property and antibacterial activity against Staphylococcus aureus and Klebsiella pneumoniae. Therefore, NE of P. radiata bark could have the potential for use as a functional brown dyestuff.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.13 no.2
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• pp.485-491
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• 2012

Due to increase in production of the domestic textile industry, energy consumption in textile industry is still growing. Traditional dyeing machine has high temperature and pressure. Accordingly, it uses an indirect cooling system that utilize a heat exchanger to cool after the dyeing. However, this indirect cooling system consumes a great deal of water, takes prolonged periods of time to process and, most importantly, because of the condensing of the dye at the cooling stage requires further energy in reduction cleaning and washing process. Therefore, in this paper, we propose a direct cooling washing machine that replaces the traditional indirect cooling system to provide coolant into the dyeing machine. The newly proposed direct cooling washing machine will still use parts of the traditional dying but will be able to skip the cooling as well as the reduction cleaning and washing process, resulting in less processing time and lower energy consumption. Also, we made a prototype. The prototype was applied to dyeing machine to test the direct cooling washing machine's ability and dyeing property. Additionally, we compared indirect cooling washing machine with direct cooling washing machine about ability, material and energy saving assessment.