• Title/Summary/Keyword: Dye-coating

Search Result 114, Processing Time 0.016 seconds

Properties and Application of Azo based Dyes for Detecting Hazardous Acids (유해 산 검출용 아조계 색소의 특성 및 응용 연구)

  • Shin, Seung-Rim;Jun, Kun;An, Kyoung-Lyong;Kim, Sang Woong;Kim, Tae-Hwan;Seo, Dong Sung;Lee, Chang Ick
    • Textile Coloration and Finishing
    • /
    • v.33 no.2
    • /
    • pp.49-63
    • /
    • 2021
  • In this study, a convenient approach for sensitive, quick and simple detection of hazardous acids was investigated. A series of azo dyes were synthesized and applied as a chemosensor for the acid detection both on fibers and in solution. Various aniline, benzothiazole or isoxazole derivatives were used as diazo component and coupled with N-benzyl-N-ethylaniline or 2,2'-(phenylimino)bis-ethanol to give azo based dyes. The acid sensing phenomenon was observed by naked-eye and detection was further confirmed by UV-Vis spectrophotometer and hue difference(ΔH*) evaluation. The developed sensors showed a distinct and quick color change from yellow to magenta by addition of trace amounts of the hazardous acids. The absorption maxima was shifted to a longer wavelength by 70 ~ 150nm and hue difference(ΔH*) was 60 ~ 120°. A cotton fiber coated with Dye 1 exhibited excellent storage stability under various temperature(-30 ~ 43℃) and humidity(30 ~ 80%) conditions without discoloration and fading of the fiber sensors. Also the acid sensing properties were maintained.

Modern Paper Quality Control

  • Olavi Komppa
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
    • /
    • 2000.06a
    • /
    • pp.16-23
    • /
    • 2000
  • The increasing functional needs of top-quality printing papers and packaging paperboards, and especially the rapid developments in electronic printing processes and various computer printers during past few years, set new targets and requirements for modern paper quality. Most of these paper grades of today have relatively high filler content, are moderately or heavily calendered , and have many coating layers for the best appearance and performance. In practice, this means that many of the traditional quality assurance methods, mostly designed to measure papers made of pure. native pulp only, can not reliably (or at all) be used to analyze or rank the quality of modern papers. Hence, introduction of new measurement techniques is necessary to assure and further develop the paper quality today and in the future. Paper formation , i.e. small scale (millimeter scale) variation of basis weight, is the most important quality parameter of paper-making due to its influence on practically all the other quality properties of paper. The ideal paper would be completely uniform so that the basis weight of each small point (area) measured would be the same. In practice, of course, this is not possible because there always exists relatively large local variations in paper. However, these small scale basis weight variations are the major reason for many other quality problems, including calender blacking uneven coating result, uneven printing result, etc. The traditionally used visual inspection or optical measurement of the paper does not give us a reliable understanding of the material variations in the paper because in modern paper making process the optical behavior of paper is strongly affected by using e.g. fillers, dye or coating colors. Futhermore, the opacity (optical density) of the paper is changed at different process stages like wet pressing and calendering. The greatest advantage of using beta transmission method to measure paper formation is that it can be very reliably calibrated to measure true basis weight variation of all kinds of paper and board, independently on sample basis weight or paper grade. This gives us the possibility to measure, compare and judge papers made of different raw materials, different color, or even to measure heavily calendered, coated or printed papers. Scientific research of paper physics has shown that the orientation of the top layer (paper surface) fibers of the sheet paly the key role in paper curling and cockling , causing the typical practical problems (paper jam) with modern fax and copy machines, electronic printing , etc. On the other hand, the fiber orientation at the surface and middle layer of the sheet controls the bending stiffness of paperboard . Therefore, a reliable measurement of paper surface fiber orientation gives us a magnificent tool to investigate and predict paper curling and coclking tendency, and provides the necessary information to finetune, the manufacturing process for optimum quality. many papers, especially heavily calendered and coated grades, do resist liquid and gas penetration very much, bing beyond the measurement range of the traditional instruments or resulting invonveniently long measuring time per sample . The increased surface hardness and use of filler minerals and mechanical pulp make a reliable, nonleaking sample contact to the measurement head a challenge of its own. Paper surface coating causes, as expected, a layer which has completely different permeability characteristics compared to the other layer of the sheet. The latest developments in sensor technologies have made it possible to reliably measure gas flow in well controlled conditions, allowing us to investigate the gas penetration of open structures, such as cigarette paper, tissue or sack paper, and in the low permeability range analyze even fully greaseproof papers, silicon papers, heavily coated papers and boards or even detect defects in barrier coatings ! Even nitrogen or helium may be used as the gas, giving us completely new possibilities to rank the products or to find correlation to critical process or converting parameters. All the modern paper machines include many on-line measuring instruments which are used to give the necessary information for automatic process control systems. hence, the reliability of this information obtained from different sensors is vital for good optimizing and process stability. If any of these on-line sensors do not operate perfectly ass planned (having even small measurement error or malfunction ), the process control will set the machine to operate away from the optimum , resulting loss of profit or eventual problems in quality or runnability. To assure optimum operation of the paper machines, a novel quality assurance policy for the on-line measurements has been developed, including control procedures utilizing traceable, accredited standards for the best reliability and performance.

Developing Advanced Total Recycling Method of FRP Boats (FRP선박의 일괄 재처리 방법의 개선)

  • Lee, Seung Hee;Yoon, Koo Young
    • Journal of the Korean Society for Marine Environment & Energy
    • /
    • v.16 no.1
    • /
    • pp.53-59
    • /
    • 2013
  • Since 1990s, the major recycling methods for mechanical recycling of FRP(Fiber Reinforced Plastics)boats has involved shredding and grinding of the scrap FRP in a new recycled product. But still it leads to secondary problem such as air pollution, unacceptable shredding noise level and few limited applications. This study is to propose a newly advanced method which is more efficient and environment friendly waste FRP regenerating system. As extracting FRP layer and making the recycled fiber for recycled-fiber reinforced concrete(RFRC) from waste FRP, the recycling process has some merits in a sense of the recycling energy and the environmental effects. In this study, for those tasks, spectro-chemical differentiation method and coloring water-soluble dye treatment makes the roving layer more distinguishable photophysically. Also that has remarkably reduced safety hazards and energy. Using the mechanical properties of polymers and composite, FRP with the orthotropic and laminated plastic structure has been easily separated in the new extracting system. Also the new method has introduced five kind of separating manuals for the some different compositions of FRP boats. The roving fiber of laminated glass-fiber layer is as good as the polyvinyl fiber which is cost-high commercial fiber to increasing strength of concrete products. The early study has shown the effectiveness of laminated glass-fiber layer which also is chemical-resistant due to the resin coating. These results imply that more efficient and environment friendly recycled glass fiber can be better applied to the fiber reinforced concrete(FRC) substitute and this study also has shown wide concrete applications with RFRC from the waste FRP boat.

Selective Pattern Growth of Silica Nanoparticles by Surface Functionalization of Substrates (기판 표면 기능화에 의한 실리카 나노입자의 선택적 패턴 성장)

  • Kim, Ki-Chul
    • Journal of the Korea Academia-Industrial cooperation Society
    • /
    • v.21 no.4
    • /
    • pp.20-25
    • /
    • 2020
  • As nanoscience and nanotechnology advance, techniques for selective pattern growth have attracted significant attention. Silica nanoparticles (NPs) are used as a promising nanomaterials for bio-labeling, bio-imaging, and bio-sensing. In this study, silica NPs were synthesized by a sol-gel process using a modified Stöber method. In addition, the selective pattern growth of silica NPs was achieved by the surface functionalization of the substrate using a micro-contact printing technique of a hydrophobic treatment. The particle size of the as-synthesized silica NPs and morphology of selective pattern growth of silica NPs were characterized by FE-SEM. The contact angle by surface functionalization of the substrate was investigated using a contact angle analyzer. As a result, silica NPs were not observed on the hydrophobic surface of the OTS solution treatment, which was coated by spin coating. In contrast, the silica NPs were well coated on the hydrophilic surface after the KOH solution treatment. FE-SEM confirmed the selective pattern growth of silica NPs on a hydrophilic surface, which was functionalized using the micro-contact printing technique. If the characteristics of the selective pattern growth of silica NPs can be applied to dye-doped silica NPs, they will find applications in the bio imaging, and bio sensing fields.