• 제목/요약/키워드: Dy^{3+}$

검색결과 338건 처리시간 0.025초

조성 변화의 영향에 따른 BSCT 후막의 구조적 특성과 초전 특성 (Influence of composition variation on structural and pyroelectrical properties of BSCT thick films)

  • 노현지;이성갑;이영희
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2007년도 추계학술대회 논문집
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    • pp.246-247
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    • 2007
  • (Ba,Sr,Ca)$TiO_3$ powders, which were prepared by sol-gel method using a solution of Ba-acetate, Sr-acetate and Ca-acetate and Ti iso-propoxide, were mixed with organic vehicle and the BSCT thick films were fabricated by the screen-printing techniques on high purity alumina substrates. The structural and dielectric properties were investigated for various $Dy_2O_3$ doping contents. As a result of thermal analysis, the exothermic peak was observed at around $670^{\circ}C$ due to the formation of the polycrystalline perovskite phase. All BSCT thick films, sintered at $1420^{\circ}C$ for 2h, showed the typical XRD patterns of perovskite polycrystalline structure and no pyrochlore phase was observed. The average grain size of the specimens decreased with.

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토양의 침식과 보존에 관한 이론적 분석 3. 사면 토양의 침식에 관한 이론 (The Theoretical Analyses of the Soil Erosion and Conservation 3. Analytical Theory of Slope Erosion)

  • 장남기
    • 아시안잔디학회지
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    • 제10권1호
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    • pp.41-47
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    • 1996
  • The theory of slope erosion is developed along similar lines to the theory of heat flow in solid added to the correcting factor. if slope erosion in the forest and grassland proceeds according to the hypothesis, it is $\delta$y $\delta^2$y = k $\delta^2$y $\delta$$X^2$+f(s b. t) where 5 is internal properties of slope soil and b is biota on slope. When the variables of the equation of slope erosion are x = -λ the initial elevation=-f(λ), x=λ, x==a, the steady value of the initial elevation=y, and dy dx x=0> =O(t>o), respectively, the houndary condition due to the solution of the equation of slope erosion is y= 2 √$\pi$kt [∫a o λe $(X-λ)^2$4kt dλ- ∫ao- $(x+λ)^2$4kt dλ] + ∫∫∫ f (s.b. t)dtdbds

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볏짚화학펄프의 표백에 관한 연구(제2보) -2단 표백- (Studies on the Bleaching of Rice-Straw Chemical Pulp (II) -Two-Stages Bleaching-)

  • 강진하;박성종;박성철
    • 펄프종이기술
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    • 제33권3호
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    • pp.84-99
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    • 2001
  • This study was carried out to acquire basic data necessary for the use of rice-straw chemical pulp. It investigated the proper bleaching conditions when rice-straw chemical pulp(alkaline sulfite-${Na_2}{S_2}{O_4}$) was bleached using the various kinds of bleaching agents by the two-stages bleaching methods. And, physical properties of pulps bleached with eight kinds of two-stages bleaching methods were tested. The results of this study were as follow; 1. The first-stage bleaching was conducted under the proper conditions with chlorine(C). And then, the proper conditions related to the calcium chlorite(H), hydrogen peroxide(P) and sodium hydrosulfite(Y) bleaching as the second-stage bleaching were investigated. The proper conditions of CH stage were determined to be 0.3% concentration of calcium chlorite, $30^{\circ}C$ of reaction temperature and 20min. of reaction time. For CP stage, the proper conditions of concentration of hydrogen peroxide, reaction temperature and reaction time were 1.5%, $60^{\circ}C$ and 90min., respectively. And for CY stage, the proper conditions were 0.5% concentration of sodium hydrosulfite, $40^{\circ}C$ of reaction temperature and 90min. of reaction time. 2. The first-stage bleaching was conducted under the proper conditions with chlorine dioxide(D). And then, the proper conditions related to the calcium chlorite(H), hydrogen peroxide(P) and sodium hydrosulfite(Y) bleaching as the second-stage bleaching were investigated. The proper conditions of DH stage were determined to be 0.5% concentration of calcium chlorite, $25^{\circ}C$ of reaction temperature and 5min. of reaction time. For DP stage, the proper conditions of concentration of hydrogen peroxide, reaction temperature and reaction time were 1.0%, $70^{\circ}C$ and 90min., respectively. And for DY stage, the proper conditions were 0.3% concentration of sodium hydrosulfite, $50^{\circ}C$ of reaction temperature and 20min. of reaction time. 3. The first-stage bleaching was conducted under the proper conditions with calcium chlorite(H). kAnd then, the proper conditions related to the hydrogen peroxide(P) and sodium hydrosulfite(Y) bleaching as the second-stage bleaching were investigated. The proper conditions of HP stage were determined to be 0.3% concentration of hydrogen peroxide, $30^{\circ}C$ of reaction temperature and 60min. of reaction time. For HY stage, the proper conditions of concentration of sodium hydrosulfite, reaction temperature and reaction time were 2.5%, $60^{\circ}C$ and 30min., respectively. 4. When the rice-straw chemical pulps were bleached with eight kinds of two-stages bleaching methods in the proper conditions mentioned above, respectively, the final brightnesses after CH, CP, CY, DH, DP, DY, HP, and HY bleachings were 62.0, 74.3, 61.4, 58.9, 66.9, 62.9, 50.4 and 60.1, respectively. And strengthes of pulps bleached with DP and DH methods were comparatively higher than those of pulps bleached with other bleaching methods.

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전남지역에서 출토된 고대 도자기의 태토조성과 소성온도 (Body Composition and Firing Temperature of Ancient Pottery Excavated in Chonnam Province)

  • 강경인;정창주
    • 보존과학회지
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    • 제6권1호
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    • pp.15-30
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    • 1997
  • 전남지역 도요지에서 출토된 토기, 시유도편, 녹청자와 청자편의 제조기술과 산지추정은 X선회절분석, 유도결합 플라즈마 발광분석, 열기계적 분석을 통한 물리화학적 성질의 검토로 이루어졌다. 도편의 사용원료는 점토, 석영, 장석광물로 유사하지만 그 함량비는 출토지에 따라 약간의 차이가 있으며, 철분함량에서 토기, 흑갈유, 녹갈유 도편은 $4\~7\%$, 녹청자 및 청자편은 $2\~3\%$로 기종에 따라 두드러진 차이를 나타내고 있다 흑갈유, 녹청자의 구성광물은 $\alpha-Quartz$, mullite와 일부 tridymite, cristobalite로 이루어졌으며, 청자는 $\alpha-Quartz$, mullite만으로 구성되어 있다. 도편의 소성온도는 토기가 $1000\~1100^{\circ}C$, 흑갈유, 녹갈유, 녹청자 청자가 $l130\~1200^{\circ}C$ 정도로 추정되었다. 도편에 대한 출토지의 구분은 분석된 21개의 미량원소중 14개의 원소가 매우 근접되어 불가능하였으며, 도자기제조에 사용된 원료의 지질학적인 특성이 유사한 것으로 판단하였다. 이들 지역에서 출토된 도편의 특성원소는 Rb, Sr, V, Zr, Y, Nd, Sc, La, Ce, Nb, Sm, Eu, Dy, Yb로 14개이다. 영암의 도편은 Zn과 Fe원소에 의해 다른 지역에서 출토된 도편들과 명확히 구분되었고, 출토지가 다른 녹청자, 청자편은 동일한 범위에 군집되는 특징을 나타내어 사용원료가 비슷한 것으로 추정된다.

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불순물이 첨가된 (Ba,Sr) $TiO_3$ 세라믹의 구조 및 유전특성 (Structural and Dielectric Properties of the Doped (Ba,Sr)$TiO_3$ Ceramics)

  • 임성수;한명수;정민석;김태훈;이금성;한석룡;이성갑
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1998년도 추계학술대회 논문집
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    • pp.33-36
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    • 1998
  • BST(66/34) and BSCT(60/30/10) ceramics were prepared by mixed oxide method and studied about the microstructural and dielectric properties with $Y_2$O$_3$, Dy$_2$O$_3$, La$_2$O$_3$, MnCO$_3$. The grain size of undoped BST was 20~30 ${\mu}{\textrm}{m}$, but that of BST, doped content of MnCO$_3$ was 0.1 mol%, was decreased with increasing the contents of $Y_2$O$_3$. As the content of $Y_2$O$_3$ was Increased, Tc was shifted to lower temperature and dielectric constant at Tc was decreased. The dielectric constant of doped BSCT(60/30/10) ceramics ( 0.9 mol% $Y_2$O$_3$. and 0.1 mol% MnCO$_3$) was about 8, 000 at Tc( 22$^{\circ}C$ ).

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BaTiO$_3$ 세라믹스의 전기저항에 미치는 첨가제와 냉각속도의 영향(I) - TiO$_2$, SiO$_2$ 및 Al2O$_3$ 단미첨가 - (Effect of Additives and Cooling Rates on the Electrical Resistivity of BaTiO3 Ceramics (I))

  • 염희남;하명수;이재춘;정윤중
    • 한국세라믹학회지
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    • 제28권9호
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    • pp.661-666
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    • 1991
  • Microstructure, room temperature resistivity and temperature coefficient of resistance of BaTiO3 ceramics were studied by varying cooling rates and additives such as TiO2, SiO2 and Al2O3. The basic composition of the BaTiO3 ceramics was formed by adding 0.25 mol% Dy2O3 and 0.07 mol% MnO2 to the BaTiO3 composition. Unlike the additives of SiO2 and Al2O3, an addition of 2 mol% TiO2 to the basic composition was effective to control the grain size of the fired specimens. The room temperature resistivity and the temperature coefficient of resistance for the specimen of this particular compostion were measured as about 102 ohm.cm and 16.5%/$^{\circ}C$, respectively. The observed grain boundary phase of the sample with Al2O3 additive was BaTi3O7, while that of the samples with SiO2 additive was confirmed as BaTiSiO5.

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Solubility of Mixed Lanthanide Hydroxide and Oxide Solid Solutions

  • Moniruzzaman, Mohammad;Kobayashi, Taishi;Sasaki, Takayuki
    • 방사성폐기물학회지
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    • 제19권3호
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    • pp.353-366
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    • 2021
  • The solubilities of different multicomponent lanthanide oxide (Ln2O3) solid solutions including binary (Ln1 and Ln2 = La, Nd, Eu, or Tm), ternary (Ln1, Ln2, and Ln3 = La, Nd, Eu, or Tm), and higher systems (Ln = La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu) were studied after aging for four weeks at 60℃. Our recent study revealed that the phase transformations in binary ((La, Nd) and (La, Eu)) and ternary (La, Nd, Eu) systems are responsible for the formation of (La, Nd)(OH)3, (La, Eu)(OH)3, and (La, Nd, Eu)(OH)3 solid solutions, respectively. The variations in the mole fractions of La3+, Nd3+, and Eu3+ in the sample solutions of these hydroxide solid solutions indicated that a thermodynamic equilibrium might account for the apparent La, Nd, and Eu solubilities. Conversely, the binary and ternary systems containing Tm2O3 as the heavy lanthanide oxide retained the oxide-based solid solutions, and their solubility behaviors were dominated by their congruent dissolutions. In the higher multicomponent system, the X-ray diffraction patterns of the solid phases, before and after contact with the aqueous phase indicated the formation of a stable oxide solid solution and their solubility behavior was explained by its congruent dissolution.

Rhizobium japonicum의 생리적(生理的) 특성(特性) 및 Plasmid DNA의 분리(分離) (Isolation of Plasmid DNA and Physiological Characteristics of Rhizobium japonicum)

  • 오세헌;강상재;박우철
    • Current Research on Agriculture and Life Sciences
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    • 제12권
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    • pp.69-82
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    • 1994
  • 6개(個) 품종(品種)의 대두(大豆)로 부터 분리(分離)된 대두(大豆) 근류균(根瘤菌)의 생리적(生理的) 특성(特性) 및 plasmid DNA의 분리(分離)를 조사(調査)한 결과(結果)는 다음과 같다. YEM 배지(培地)에서 S117, S118, 011, DY-1균주(菌株)는 생육속도(生育速度)가 느리고 alkaline 반응(反應)을 나타내었으며, S110, S111, S114, S115, S116, S120, 010균주(菌株)들은 생육속도(生育速度)가 빠르고 산반응(酸反應)을 나타내었다. fast-growing형(型)과 slow-growing형(型) R. japonicum은 모두 극모성 또는 주모성 편모(鞭毛)를 가진 그람 음성(陰性) 간균(桿菌)이며, 한천 평판에서 점액성(粘液性)이 있는 유백색(乳白色) colony를 형성(形成) 하였다. 접종(接種) 7일후(後), fast-growing형(型)의 colony는 직경(直徑)이 2.0-4.0mm였고, slow-growing 형(型)의 colony는 대체로 0.5-1.5였다. fast-growing형(型)은 pH4.5에서 한결같이 감수성(感受性)이 있고, pH9.5에 내성(耐性)이 있는 반면 slow-growing형(型)은 정반대로 나타났다. 조사(調査)된 균주(菌株)들은 모두 생육(生育)을 위한 탄소원(炭素源)으로써 glucose를 이용(利用)하였으며, 010과 321을 제외하고 모든 균주는 starch는 전혀 이용(利用)하지 못하였으며 fast-growing형(型) 만이 sucrose를 이용(利用)하였다. 조사(調査)된 slow-growing R. japonicum은 일반적으로 15-250kb 정도(程度)의 1-3개(個)의 plasmid DNA를 함유하는 반면, fast-growing R. japonicum은 20-250kb정도(程度)의 1-3개(個)의 plamid DNA를 함유(含有)하고 있었다.

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Fabrication of Bismuth- and Aluminum-Substituted Dysprosium Iron Garnet Films for Magneto-Optic Recording by Pyrolysis and Their Magnetic and Magneto-Optic Properties

  • Cho, Jae-Kyong
    • The Korean Journal of Ceramics
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    • 제1권2호
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    • pp.91-95
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    • 1995
  • Polycrystalline bismuth- and aluminum- substituted dysporsium and yttrium iron garnet (Bi2R3-xAlyFe5-yO12, R=Dy or Y, $0\leqx\leq3, \; 0\leqy\leq3$) films have been prepared by pyrolysis. The crystallization temperatures, the solubility limit of bismuth ions into the garnet phase, and magnetic and magneto-optic properties of the films have been investigated as a function of bismuth and aluminum concentration. It was found that the crystallization temperatures as a function of bismuth and aluminum concentration. It was found that the crystallization temperatures of these films rapidly decreased as bismuth concentration. It was found that the crystallization temperatures of these films rapidly decreased as bismuth concentration (x) increased up to x=1.5 and then remained temperatures of these films rapidly decreased as bismuth concentration (x) increased up to x=1.5 and then remained unchanged at x>1.5, whereas, showed no changes as aluminum concentration (y) increased up to y=1.0 and then gradually increased at y>1.0. The solubility limit of bismuth ions was x=1.8 when y=0 but increased to x=2.3 when y=1.0. It was demonstrated that the magnetic and magneto-optic properties of the dysprosium iron garnet films could be tailored by bismuth and aluminum substitution suitable for magneto-optic recording as follows. The saturation magnetization and coercivity data obtained for the films indicated that the film composition at which the magnetic compensation temperature became room temperature was y=1.2 when x=1.0. Near this composition the coercivity and the squareness of the magnetic hysteresis loop of the films were several kOe and unit, respectively. The Curie temperatures of the films increased with the increase of x but decreaed with the increase of y, and was 150-$250^{\circ}C$ when x=1.0 and y=0.6-1.4. The Faraday rotation at 633 nm of the films increased as x increased but decreased as y increased, and was 1 deg/$\mu\textrm{m}$ when x=1.0 and y=1.0. Based on the data obtained, the appropriate film composition for magneto-optic recording was estimated as near x=1.0 and y=1.0 or $BiDy_2AlFe_4O_{12}$.

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UAV 기반 열적외선 센서를 이용한 태양광 셀의 발열 검출 (The Detection of Heat Emission to Solar Cell using UAV-based Thermal Infrared Sensor)

  • 이근상;이종조
    • 대한공간정보학회지
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    • 제25권1호
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    • pp.71-78
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    • 2017
  • 최근 널리 보급되고 있는 태양광 발전소의 유지관리를 위해 다양한 연구들이 시도되고 있다. 본 연구에서는 unmanned aerial vehicle(UAV)기반 열적외선 센서를 이용하여 태양광 셀의 발열을 분석하는 것으로서 주요 결론은 다음과 같다. 먼저 UAV 기반 RGB 센서를 이용하여 정사영상과 digital surface model(DSM) 자료를 구축하였으며, 이를 통해 태양광 셀의 발열 분석에 필요한 태양광 모듈 레이어를 생성하였다. 또한 태양광 모듈 레이어의 위치정확도를 평가하기 위해 virtual reference service(VRS) 측량을 이용하여 검정점에 대한 수평오차를 분석한 결과, 표준오차가 $dx={\pm}2.4cm$, $dy={\pm}3.2cm$로 높은 위치정확도를 확보할 수 있었다. 그리고 태양광 셀의 발열 실험을 위해 고무패치를 설치한 후 UAV 열적외선 센서를 이용하여 발열이 생기는 고무패치의 위치를 효과적으로 분석할 수 있었다. 또한 고무패치 셀 비율과 UAV 열적외선 센서에 의한 셀 비율의 표준오차는 ${\pm}3.5%$로 나타났으며, 따라서 UAV 기반 열적외선 센서를 이용하여 태양광 셀의 발열을 효과적으로 분석할 수 있었다. 아울러 발열이 생기는 셀이 위치하고 있는 태양광 모듈의 코드를 자동으로 추출함으로서 효과적인 태양광발전소 유지보수가 가능하게 되었다.