• Title/Summary/Keyword: Dy^{3+}$

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Structure Study of Polycrystalline $Na_3YSi_3O_9$ and Its Substitutes Related to $Na_4CaSi_3O_9,\;Ca_3Al_2O_6$ Structure

  • Kim, Chy-Hyung;Banks, Ephraim
    • Bulletin of the Korean Chemical Society
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    • v.8 no.1
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    • pp.6-9
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    • 1987
  • The study of the $Na_3YSi_3O_9$ structure, by x-ray diffraction and infrared spectrum, showed that $Na_3YSi_3O_9$ is similar to $Na_4CaSi_3O_9$ except for its being pseudo-cubic instead of cubic. The peaks in the x-ray diffraction pattern of $Na_3YSi_3O_9$ could therefore be indexed on the basis of the $Na_4CaSi_3O_9$ cell. Also, modified $Na_3MSi_3O_9$ (M = Lu, Yb, Tm, Er, Y, Ho, Dy, Gd, Eu, and Sm) type compounds were synthesized by introducing excess sodium, decreasing M(III) concentration, and substituting small amount of phosphorus for silicon. The unit cell parameters of the composition $Na_{3.2}M_{0.7}Si_{2.9}P_{0.1}O_{8.7}$ were estimated from x-ray powder diffraction patterns using the Cohen method.

Three Phase Dynamic Current Mode Logic against Power Analysis Attack (전력 분석 공격에 안전한 3상 동적 전류 모드 로직)

  • Kim, Hyun-Min;Kim, Hee-Seok;Hong, Seok-Hee
    • Journal of the Korea Institute of Information Security & Cryptology
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    • v.21 no.5
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    • pp.59-69
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    • 2011
  • Since power analysis attack which uses a characteristic that power consumed by crypto device depends on processed data has been proposed, many logics that can block these correlation originally have been developed. DRP logic has been adopted by most of logics maintains power consumption balanced and reduces correlation between processed data and power consumption. However, semi-custom design is necessary because recently design circuits become more complex than before. This design method causes unbalanced design pattern that makes DRP logic consumes unbalanced power consumption which is vulnerable to power analysis attack. In this paper, we have developed new logic style which adds another discharge phase to discharge two output nodes at the same time based on DyCML to remove this unbalanced power consumption. Also, we simulated 1bit fulladder to compare proposed logic with other logics to prove improved performance. As a result, proposed logic is improved NED and NSD to 60% and power consumption reduces about 55% than any other logics.

Extraction Chromatograph Separation Spark Source Mass Spectrometric Analysis of 14 Rare Earth Impurities in High Purity Rare Earth Oxide

  • Sui, Xiyun;Wang, Zishu;Shao, Baohai
    • Analytical Science and Technology
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    • v.8 no.4
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    • pp.553-559
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    • 1995
  • An extraction chromatographic method of separating rare earth impurities from high purity $Nd_2O_3$, $Sm_2O_3$, $Gd_2O_3$, $Er_2O_3$, $Dy_2O_3$ and $Yb_2O_3$ was studied by using $HCl-NH_4Cl$ as moving phase and P507 as stationary phase. After the impurities were enriched from the eluate by chelant-activated carbon, the active carbon was ashed and the ignited residue was used to prepare the sample electrode for spark source mass spectrometric determination. The impurities in 99.9999% rare earth oxide can be determined by the proposed method with recovery over 80%.

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Capacitance Aging Behavior of Acceptor-Doped BaTiO3 under DC Electrical Field (직류 전계에 의한 Acceptor 첨가 BaTiO3의 유전특성 열화 현상)

  • Hahn, Dong-Woo;Han, Young-Ho
    • Journal of the Korean Ceramic Society
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    • v.46 no.2
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    • pp.219-223
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    • 2009
  • Effects of MgO or $R_2O_3$(R:Dy, Ho, Yb) on the capacitance aging behavior of multilayer ceramic capacitors (MLCCs) based on $BaTiO_3$ dielectrics under DC electrical fields has been studied. At a DC field of 1 $V{/\mu}m$, the capacitance of MLCC specimens dropped immediately in a very short period (<10 s, the first stage) and then decreased continuously with time (the second stage). Mn doping significantly increased the aging rate in the second stage. The addition of MgO or $R_2O_3$ notably decreased the second stage aging rate of Mn-doped specimens. Yb doping gives rise to the lowest aging rate in the second stage, which is due to the larger population of defect dipoles associated with oxygen vacancies.

Effects of Low-Temperature Sintering on Varistor Properties and Stability of VMCDNB-Doped Zinc Oxide Ceramics

  • Nahm, Choon-W.
    • Journal of the Korean Ceramic Society
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    • v.56 no.1
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    • pp.84-90
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    • 2019
  • The varistor properties and stability against dc-accelerated stress of $V_2O_5-Mn_3O_4-Co_3O_4-Dy_2O_3-Nb_2O_5-Bi_2O_3$ (VMCDNB)-doped zinc oxide ceramics sintered at $850-925^{\circ}C$ were investigated. Increasing the sintering temperature increased the average grain size from 4.6 to 8.7 mm and decreased the density of the sintered pellet density from 5.54 to $5.42g/cm^3$. The breakdown field decreased from 5919 to 1465 V/cm because of the increase in the average grain size. Zinc oxide ceramics sintered at $875^{\circ}C$ showed the highest nonlinear coefficient (43.6) and the highest potential barrier height (0.96 eV). Zinc oxide ceramics sintered at $850^{\circ}C$ showed the highest stability: the variation rate of the breakdown field was -2.0% and the variation rate of the nonlinear coefficient was -23.3%, after application of the specified stress (applied voltage/temperature/time).

An analysis of complex permeability of Mn-Zn ferrite doped with rare earth oxide. (희토류가 첨가된 Mn-Zn ferrite의 복소투자율 분석)

  • 김성수;최우성
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • 2000.11a
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    • pp.93-96
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    • 2000
  • In this study, we investigated the electromagnetic properties of Mn-Zn ferrite doped with rare earth oxide (Dy$_2$O$_3$, Er$_2$O$_3$). The main composition is 52mo1% $\alpha$-Fe$_2$O$_3$, 25mo1% Mn$_3$O$_4$23mo1% ZnO and doped with them(0.05wt%~0.25wt%, step:0.05wt%). An experimental process has advanced by conventional ferrimagnetism manufacturing that was prepared by standard ceramic techniques. The XRD pattern of all doped sample were observed spinel and secondary phase. The density of sample were measured nearly constant value. As increased the additive, resistivity, initial permeability and real component of the series complex permeability increased with setting limits each other. In case of Mn-Zn ferrite excess doped with them, resistivity, initial permeability and real component of the series complex permeability decreased and magnetic loss increased in proportion to increasing the additive.

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An analysis of complex permeability of Mn-Zn ferrite doped with rare earth oxide (희토류가 첨가된 Mn-Zn ferrite의 복소투자율 분석)

  • 김성수;최우성
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.11a
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    • pp.93-96
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    • 2000
  • In this study, we investigated the electromagnetic properties of Mn-Zn ferrite doped with rare earth oxide (Dy$_2$O$_3$, Er$_2$O$_3$). The main composition is 52mo1% ${\alpha}$-Fe$_2$O$_3$, 25mol% Mn$_3$O$_4$ 23mo1% ZnO and doped with them(0.05wt% ∼ 0.25wt%, step:0.05wt%). An experimental process has advanced by conventional ferrimagnetism manufacturing that was prepared by standard ceramic techniques. The XRD pattern of all doped sample were observed spinel and secondary phase. The density of sample were measured nearly constant value. As increased the additive, resistivity, initial permeability and real component of the series complex permeability increased with setting limits each other. In case of Mn-Zn ferrite excess doped with them, resistivity, initial permeability and real component of the series complex permeability decreased and magnetic loss increased in proportion to increasing the additive.

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Accuracy Analysis of Point Cloud Data Produced Via Mobile Mapping System LiDAR in Construction Site (건설현장 MMS 라이다 기반 점군 데이터의 정확도 분석)

  • Park, Jae-Woo;Yeom, Dong-Jun
    • Journal of the Korean Society of Industry Convergence
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    • v.25 no.3
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    • pp.397-406
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    • 2022
  • Recently, research and development to revitalize smart construction are being actively carried out. Accordingly, 3D mapping technology that digitizes construction site is drawing attention. To create a 3D digital map for construction site a point cloud generation method based on LiDAR(Light detection and ranging) using MMS(Mobile mapping system) is mainly used. The purpose of this study is to analyze the accuracy of MMS LiDAR-based point cloud data. As a result, accuracy of MMS point cloud data was analyzed as dx = 0.048m, dy = 0.018m, dz = 0.045m on average. In future studies, accuracy comparison of point cloud data produced via UAV(Unmanned aerial vegicle) photogrammetry and MMS LiDAR should be studied.

Studies on the Spectrophotometric Determination, Electrochemical Behavior of Heavy Lanthanide ions in Nonaqueous System and Heavy Chelates Complexes with Bidendate Ligands (Ⅱ) Electrochemical Behavior of Heavy Lanthanide Ions in Acetonitrile (무거운 란탄이온의 분광학적 정량, 비수용액에서의 전기화학적 거동 및 중금속이온과 두자리 리간드 착물에 관한 연구 (제 2 보))

  • Kang Sam-Woo;Park Chong-Min;Kim Il-Kwang;Do Lee-Mi;Lee Jong-Min
    • Journal of the Korean Chemical Society
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    • v.37 no.5
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    • pp.483-490
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    • 1993
  • Voltammetric behavior of heavy lanthanide ions has been investigated by the DC, DPP and CV in acetonitrile solution. The reduction of $Gd^{3+}, Tb^{3+}, Dy^{3+}, Ho^{3+}, Er^{3+}, Tm^{3+} 및 Lu^{3+} proceed by three-electron change to the metallic state with totally irreversibility in 0.1M tetraethylammonium perchlorate. However, the reduction of Yb(Ⅲ) proceeds in two steps $(Yb^{3+} + e^- \Leftrightarrow Yb^{2+} and Yb^{2+} + 2e^- → Yb^0)$. The first reduction of Yb(Ⅲ) showed quasi reversible behavior, but the second reduction was irreversible in cyclic voltammetry. The cathodic peak current showed adsorptive properties in high concentration with lower sweep rate. The electroreduction of heavy lanthanides in water-acetonitrile mixture has been studied. In water-acetonitrile mixture, the negative shift of the peak potential and the decrease peak current were observed increasing water concentration. Also the Yb(Ⅲ) reduction to Yb(Ⅲ) has been deviated from quasi-reversible character with increase water amount. These results drive from the high solvation abilities of water which has high donor number.

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Textural Properties and Cell Wall Components of Dried Persimmon according to Varieties (품종에 따른 건시의 물성적 특성과 세포벽 성분)

  • Sohn, Tae-Hwa;Moon, Kwang-Deok;Lee, Nak-Hoon
    • Journal of the Korean Society of Food Culture
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    • v.6 no.3
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    • pp.229-235
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    • 1991
  • This study is performed to investigate the relation between cell components and hardness which affect to the quality of dried persimmons. Moisture contents of dried persimmons were interrange of 30 to 36%. Enpung Junsi (EJ), Dungsi (Young dong) (DY) and Haman Susi (HS) had higher moisture contents than Dungsi (Sang Ju) (DS), Kojongsi (KS) and Hagakure (HK). Hardness was high in the varieties which has low moisture content such as DS, KS and HK. The significant differences of hardness and fracturability among varieties were appeared conspicuously but those of cohesiveness, adhesiveness and springiness were not appeared. Crude cell wall content, pectin and calcium content of cell wall were high in hard varieties. In the pectin fractions, water soluble pectin content was high in EJ, HS and DY but that of acid and alkali soluble pectin were high in DS, KS and HK. The cell wall of high hardness varieties observed thick and firm than that of low hardness varieties.

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