• Title/Summary/Keyword: Dy^{3+}$

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REE Mineralization and Geology of Chulmasan Area, Taean, Chungchungnamdo (충남 태안 철마산 일대의 지질 및 희토류 광화작용)

  • Yoo, Bong Chul
    • Journal of the Mineralogical Society of Korea
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    • v.32 no.2
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    • pp.127-143
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    • 2019
  • The geology of the Chulmasan area consists of Precambrain Sogeunri formation, granitic gneiss, foliated biotite granite, foliated mica granite, basic dyke and acidic dyke. REE mineralization in the area occurs at granitic gneiss and foliated mica granite. Minerals with minor amounts of REE and Th from granitic gneiss and foliated mica granite are zircon ($Y_2O_3$ 0.00~1.18 wt.%, $Gd_2O_3$ 0.00~0.59 wt.%, $Er_2O_3$ 0.00~0.22 wt.%, $Yb_2O_3$ 0.00~0.34 wt.%, $Lu_2O_3$ 0.00~0.48 wt.%, $ThO_2$ 0.00~0.33 wt.%), thorianite ($Nd_2O_3$ 0.00~0.24 wt.%, $Lu_2O_3$ 0.00~0.26 wt.%), berthierine ($La_2O_3$ 0.04~0.26 wt.%, $Nd_2O_3$ 0.00~0.20 wt.%, $Tb_2O_3$ 0.04~0.12 wt.%, $Dy_2O_3$ 0.17~0.26 wt.%, $Er_2O_3$ 0.33~0.44 wt.%, $Lu_2O_3$ 0.00~0.19 wt.%, $ThO_2$ 0.61~0.93 wt.%), chlorite ($La_2O_3$ 0.44~0.68 wt.%, $Ce_2O_3$ 0.12~0.13 wt.%, $Nd_2O_3$ 0.31~0.44 wt.%, $Eu_2O_3$ 0.03~0.08 wt.%, $Dy_2O_3$ 0.09~0.21 wt.%, $Ho_2O_3$ 0.04~0.14 wt.%, $Er_2O_3$ 0.18~0.32 wt.%, $Lu_2O_3$ 0.07~0.21 wt.%, $ThO_2$ 0.00~0.97 wt.%), biotite ($Nd_2O_3$ 0.02~0.08 wt.%, $Gd_2O_3$ 0.07~0.08 wt.%, $Tb_2O_3$ 0.02~0.07 wt.%, $Dy_2O_3$ 0.35~0.43 wt.%, $Ho_2O_3$ 0.15~0.26 wt.%, $Er_2O_3$ 0.24~0.28 wt.%, $Yb_2O_3$ 0.06~0.18 wt.%, $ThO_2$ 0.00~0.12 wt.%), orthoclase ($Dy_2O_3$ 0.05~0.12 wt.%, $Ho_2O_3$ 0.05~0.06 wt.%, $Er_2O_3$ 0.28 wt.%, $Yb_2O_3$ 0.06~0.12 wt.%) and plagioclase ($Ho_2O_3$ 0.01~0.03 wt.%, $Er_2O_3$ 0.10~0.27 wt.%, $ThO_2$ 0.11~0.13 wt.%). REE minerals (bastnaesite and fergusonite) were sealed fractures in mainly fledspar, mica, zircon, apatite and ilmenite. Therefore, bastnaesite and fergusonite from the Chulmasan area were formed from redissolution/reconcentration of REE-and Th-bearing minerals from granitic gneiss and foliated mica granite at late stage by several igneous activies and metamorphism.

Electrical Property of $BaTiO_3$ Ceramics(II) ($BaTiO_3$ 세라믹의 전기적성질(II))

  • 윤기현;송효일;윤상옥;이형복
    • Journal of the Korean Ceramic Society
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    • v.18 no.2
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    • pp.75-78
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    • 1981
  • The electrical conductivity of $(M_2O_3)_x (BaTiO_3)_{1-x}$ has been measured over the temperature range of 30 to 27$0^{\circ}C$. The substitution of rare earth oxide such as $La_2O_3$, $Nd_2O_3$, or $Dy_2O_3$ can be represented by $M_2O_3$. The additional mole fraction of the rare earth oxide is ranged over 0.0015 to 0.0030. The electrical conductivity exhibits an anomalous decrease near the tetragonal to cubic transition about 12$0^{\circ}C$. The decrease in the electrical conductivity is observed at the higher impurity concentrations owing to space charge layer. The increase in the electrical conductivity is observed as the impurity ion is varied from $La^{+3}$$Nd^{+3}$ to $Dy^{+3}$, due to overlap of 4f electrons of the inner shell.

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THE MAGNETOSTRICTIVE PROPERTIES OF Dy-Fe-B ALLOYS WITH NANOCRYSTALLINE GRAIN STRUCTURE

  • Lim, S.H.;Kim, S.R.;Noh, T.H.;Lee, S.R.;Kang, I.K.
    • Journal of the Korean Magnetics Society
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    • v.5 no.5
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    • pp.795-799
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    • 1995
  • The magnetostriction versus field (${\lambda}-H$) curves for the melt-spun ribbons of $Dy_{x}{(Fe_{1-y}B_{y})}_{1-x}$ (x=0.2, 0.25, 0.3; y=0, 0.05, 0.1, 0.15, 0.2) alloys are measured systematically at various wheel speeds ranging from 10 to 50 m/sec. The ${\lambda}-H$ curves in most cases vary sensitively with the wheel speed and, in the wheel speed range where no amorphous phase is formed, the magnetic softness improves rather continuously with the wheel speed. This result is considered to be due to the reduced grain size with increasing wheel speed, which was confirmed by X-ray diffraction and transmission electron microscopy. In particular, homogeneous and ultrafine grains with size of about 10 nm are formed even in the as-spun state when the $Dy_{0.3}{(Fe_{1-y}B_{y})}_{0.7}$ alloys are quenched at the wheel speed of 30 m/sec (for the alloy with y=0.2) or 40 m/sec (for the alloys with $y{\leq}0.15$) and the ribbons having the nanocrystalline grain structure exhibit good magnetostrictive characteristics.

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An analytical and numerical study of a vertically-discretized wavemaker (수직다열화된 조파장치의 해석해 개발 및 수치모형 실험)

  • Son, Sangyoung;Kim, Yeulwoo;Jung, Taehwa
    • Proceedings of the Korea Water Resources Association Conference
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    • 2021.06a
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    • pp.103-103
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    • 2021
  • 실험실에서의 파랑생성에 흔히 사용되는 피스톤형 조파장치는 수심에 따라 유속이 동일하게 생성된다는 제약이 있어 주로 천해파의 생성에 적합한 것으로 알려져 있다. 본 연구에서는 이러한 제약조건 없이 다양한 유속분포의 파형을 생성하는 수직 다열화된 조파장치가 개발되었다. 우선, 수심방향으로 이산화된 각 패들(paddle)의 스트로크에 대해 선형해석해가 유도되었다. 개발된 해석해는 패들의 수 및 유속분포에 따라 기존의 피스톤형 혹은 플랩형 조파장치 해석해로 근사함이 밝혀짐으로써 포괄적으로 활용될 수 있음이 확인되었다. 즉 개발된 해석해를 활용하면 선택적으로 피스톤형 및 플랩형 조파성능이 구현될 수 있다. 더불어 개발된 해석해는 다상유체의 내부파 생성에도 확정되어 적용가능함이 확인되었다. 다음으로, 개발된 조파장치를 수치적으로 구현하였다. 오픈소스 3차원 수치모형인 OpenFOAM 중, 두 개 이상의 불연속 및 비압축 유체에 대한 Navier-Stokes 방정식을 해결하는 수치 모듈을 사용하여 제안된 수직다열화된 조파장치의 성능이 평가되었다. 이때 동적격자모델(olaDyMFlow)을 결합함으로써 개발된 조파장치 움직임이 물리적 조파장치와 흡사하도록 수치적으로 구현하였다. 모의결과, 여러 개의 다열화된 패들이 층류 흐름 조건에서 심해파를 효율적으로 생성시키고, 중간수심 파랑조건에서는 제안된 조파장치가 상대적으로 덜 유리함을 확인할 수 있었다. 마지막으로 공기, 기름 및 물 등 3상의 흐름조건에서 단 두 개의 패들을 활용하여 각각 내부파 및 표면파를 생성하되었으며, 모의 결과는 해석해과 비교됨으로써 개발된 조파장치의 성능이 검증되었다.

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The effect of tooth bleaching agent contained 35% hydrogen peroxide on the color, microhardness and surface roughness of tooth-colored restorative materials (35% 과산화수소를 함유한 치아미백제가 심미수복재의 색, 미세경도 및 표면 거칠기에 미치는 영향)

  • Shim, Youn-Soo
    • Journal of Korean society of Dental Hygiene
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    • v.12 no.3
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    • pp.533-541
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    • 2012
  • Objectives : The purpose of this study was to evaluate the effects of tooth bleaching agent contained 35% hydrogen peroxide on the color, microhardness and surface roughness of tooth-colored restorative materials. Methods : Four types of tooth-colored restorative materials, including a composite resin(Filtek Z350 ; Z350), a flowable composite resin(Filtek P60 : P60), a compomer(Dyract$^{(R)}$ AP ; DY), and a glass-ionomer cement(KetacTM Molar Easymix ; KM) were used in the study. The specimens($8mm{\times}5mm$) were made by using a customized acrylic mold. Each material was divided into two groups equally(n=40) : experimental group(35% HP) and control group(distilled water). 35% HP group was treated 30 mim/5 days for 15 days. Each 30 minute treatment session consisted of two 15 minute cycles of gel application with 20 second light exposure. The authors measured the color, microhardness, and roughness of the specimens before and after bleaching. The data were analyzed with ANOVA and T-test. Results : 35% HP group showed an apparent color change(${\Delta}E^*$) than control group. In particular, DY and KM showed a noticeable color change and statistically significant differences(p<0.05). 35% HP group showed a reduction in microhardness. Z350 and P60 does not have a statistically significant difference(p>0.05), DY and KM showed a statistically significant difference(p<0.05). Percentage microhardness loss(PML) of control group was 0.6 to 5.5% in the group, 35% HP group was 6.6 to 34.6%. Roughness was increased in 35% HP group after bleaching. Especially DY and KM were significantly increased(p<0.05). Conclusions : Bleaching agents may affect the surface of existing restorations; therefore, they should not be used indiscriminately when tooth-colored restorations are present.

Microbiological and Sensory Evaluations on Sesame Leaf of Bio Soybean Paste (깻잎 바이오 된장의 미생물 및 관능평가)

  • Kim, Chang-Ryoul
    • Journal of Food Hygiene and Safety
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    • v.21 no.4
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    • pp.218-222
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    • 2006
  • Microbiological and sensory evaluations of bio soybean paste prepared by sesame leaf and immobilized cells of Bifidobacterium animalis DY 64 were assessed. Bio soybean paste treated with 3.0-5.0% (w/w) of sesame leaf combined with 10% (w/w) immobilized cells increased a consumer acceptance due to enhancing odor and flavor. Aerobic microorganisms in bio soybean paste were significantly (P < 0.05) increased during 15 days of storage and then decreased slightly (P < 0.05) after 30 days of storage at room temperature. Food pathogens of Salmonella spp., Staphylococcus aureus and Escherichia coli were not detected in bio soybean paste during storage. It is concluded that preparation of bio soybean paste using sesame leaf, and immobilized cells of Bifidobacterium animalis DY 64 could be used to industrial application for enhancing consumer acceptance.

The Influence of Re2O3(RDy, Er) on the Electromagnetic Properties of Mn-Zn Ferrite (Re2O3(RDy, Er)가 Mn-Zn ferrite의 전자기적 특성에 미치는 영향)

  • 백승철;최우성
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.15 no.2
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    • pp.178-183
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    • 2002
  • The effects of Dy$_2$O$_3$and Er$_2$O$_3$addition on the electromagnetic properties of Mn-Zn ferrite were investigated in the doping concentration range from 0.05 wt% to 0.25 wt%. All samples were prepared by standard fabrication of ferrite ceramics. The XRD patterns of sample were observed spinel and secondary phase. The densities of sample were showed nearly constant values. As the increased additive, electrical resistivity, initial permeability and real component of the series complex permeability increased with setting limits each other. Excess doped with Dy$_2$O$_3$ and Er$_2$O$_3$, those values decreased. The maximum electrical resistivity was observed with 0.15 we% and initial permeability was observed with 0.05 wt%. Magnetic loss decreased with additive and then increased in proportion to increased.

다양한 활성제 이온이 도핑된 La2WO6 형광체의 제조와 발광 특성

  • Ryu, Hyeon-Tae;Hong, Sun-Gi;Im, Myeong-Hwan;Lee, Eun-Gyeong;Sin, Yu-Hui;Jo, Sin-Ho
    • Proceedings of the Korean Vacuum Society Conference
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    • 2015.08a
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    • pp.191.1-191.1
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    • 2015
  • 최근에 백색 발광다이오드를 개발하기 위한 고효율의 형광체 개발에 많은 연구가 집중되고 있다. 본 연구에서는 $La_2WO_6$ 모체 결정에 다양한 활성제 이온인 $Eu^{3+}$, $Dy^{3+}$, $Sm^{3+}$, $Tb^{3+}$를 각각 도핑하여 다양한 발광 파장을 갖는 고효율의 형광체를 제조하였다. 합성한 형광체 분말은 초기물질 $La_2O_3$, $WO_3$, 희토류 원소 ($Eu_2O_3$, $Dy_2O_3$, $Sm_2O_3$, $Tb_4O_7$)를 각각 화학양론적으로 준비하여 고상반응법으로 제조하였으며, 이때 하소 공정은 $400^{\circ}C$에서 3시간, 소결 공정은 $1050^{\circ}C$에서 5시간 유지하여 합성하였다. $La_2WO_6:Eu^{3+}$ 형광체 분말의 경우에 320, 395, 465 nm에서 강한 흡광 파장이 발생하였으며, 파장 320 nm로 여기 시켰을 때 최대 발광 세기는 618 nm에서 관측되었다. $Sm^{3+}$을 도핑한 형광체의 흡광 스펙트럼은 310, 375, 406, 475 nm에서 발생하였으며, 310 nm로 여기 시켰을 때 602 nm의 강한 주황색 발광 신호가 나타났다. $Dy^{3+}$가 도핑된 $La_2WO_6$ 형광체는 575 nm에 강한 발광 피크를 갖는 황색을 나타내었으며, 흡광 파장은 313 nm 이었다. $Tb^{3+}$를 도핑한 형광체의 주 흡광 스펙트럼은 316 nm에서 발생하였고, 발광 스펙트럼은 545 nm에 피크를 갖는 녹색 발광 신호가 나타났다. 활성제이온의 종류에 따른 형광체의 흡광과 발광, 결정 구조의 특성을 체계적으로 제시하고자 한다.

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