• Title/Summary/Keyword: Dy^{3+}$

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Alternating-Current Electrical Conduction Properties of DyCoO3 Ceramics (DyCoO3 세라믹스의 교류전도특성)

  • Jung, Woo-Hwan
    • Korean Journal of Materials Research
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    • v.20 no.3
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    • pp.161-166
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    • 2010
  • The ac, dc conductivity and dielectric properties of $DyCoO_3$ were reported in the temperature range of 77 - 300K and in the frequency range of 20 Hz - 100 kHz. It was observed that at low temperature, ac conductivity is much higher than dc conductivity and the hopping carrier between localized states near the Fermi level was the dominant loss mechanism. A comparison of the measured ac conductivity $\sigma(\omega)$ was made with some of the models of hopping conductivity of the proposed earlier in the literature. It was observed that in $DyCoO_3$ the measured ac conductivity, over the entire frequency and temperature region, can be explained reasonably well by assuming two contributions $\sigma_1(\omega)$ and $\sigma_2(\omega)$ to the measured $\sigma(\omega)$. The first, $\sigma_1(\omega)$, which dominates at low temperature, may be due to impurity conduction in a small polaron; the second, $\sigma_2(\omega)$, which dominates at higher temperatures, depending on the frequency of measurements, may be due to the hopping of a small polaron and is reasonable for the dielectric relaxation peak.

Development of a TL pellet based on $CaSO_4:Dy$ for Neutron Measurement ($CaSO_4:Dy$ 물질 기반 중성자 측정용 TL소자 개발)

  • Yang, Jeong-Seon;Lee, Jeong-Il;Kim, Jang-Lyul;Kim, Bong-Hwan;Sou, Dong-Sup
    • Journal of Radiation Protection and Research
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    • v.31 no.3
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    • pp.129-134
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    • 2006
  • A TL pellet for a neutron dose measurement (KCT-306) by embedding a $^6Li$-compound into a $CaSO_4:Dy$ phohphor was developed based upon the technical information of KCT-300. The KCT-300 is an another kind of $CaSO_4:Dy$ TL detector shich was developed at KAERI, in which small amounts of $NH_4H_2PO_4$ have been emvedded as a binding material. This paper presented the optimized manufacturing condition of KCT-306 and compared its sensitivity with that of the commercialized neutron TL pellets. $CaSO_4:Dy$ Phosphor with grain size ranging less than $45{\mu}m$ are used for the KCT-306. The optimum $CaSO_4:Dy$ TL phosphor, $^6Li$-compounds and P-compound as the binding material are determined as 20-40wt%, 50-70wt% and 20wt%. The TL pellet combination of our KCT-306/KCT-300, TLD-600/TLD-700 and TLD-600H/TLD-700H(Harshaw) have been irradiated in the neutron/gamma mixed fields from a $D_2O$ moderated $^{252}Cf$ neutron source. The KCT-300, TLD-700 and TLD-700H were used at the same time as gamma ray discriminators in the neutron/gamma mixed fields. It was found that the neutron/gamma response ratios of KCT-306/KCT-300, which were developed in this study, were approximately 4 times higher than those of the commercial TLD-600H/TLD-700H.

Solvent Extraction of Light (Pr, Nd) and Medium (Tb, Dy) Rare Earth Elements with PC88A of Rare Earth Chloride Solution from Waste Permanent Magnet (폐 영구자석으로부터 회수한 염화희토류용액에서 PC88A를 이용한 경희토류(Pr, Nd)/중희토류(Tb, Dy) 용매추출)

  • Jeon, Su-Byung;Son, InJoon;Lim, Byung-Chul;Kim, Jeong-Mo;Kim, Yeon-Jin;Ha, Tae-Gyu;Yoon, Ho-Sung;Kim, Chul-Joo;Chung, Kyeong-Woo
    • Resources Recycling
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    • v.27 no.3
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    • pp.8-15
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    • 2018
  • Solvent extraction behavior of light rare earth elements (Pr, Nd) and medium rare erath elements (Tb, Dy) in the HCl-PC88A-kerosene extraction system was investigated in order to separate high-purity light rare earths (Pr, Nd) and medium rare earths (Tb, Dy) in the mixed rare earth chloride solution. In the batch test step, it was confirmed that the separation efficiency was good when the extractant concentration (PC88A) was 0.5 M, the equilibrium pH after extraction was 0.8 to 1.0 (initial pH 1.3 of the feed), the concentrations of hydrochloric acid in scrubbing solution was set as 0.1 M, the concentrations of hydrochloric acid in stripping solution was set as 2.0 M or more. Based on the experimental data obtained from the batch test, the mixer-settler was composed as follows; 4 stages of extraction, 8 stages of scrubbing, 4 stages of stripping, and 3 stages of pickling organic solution. The Mixer-settler was operated for 180 hours, and the operating conditions were continuously adjusted to obtain the high-purity light/medium rare earths. Finally, the purity of light (Pr, Nd) and medium rare earth elements (Tb, Dy) was reached as 3 N class.

Flour Characteristics and End-Use Quality of Korean Wheats with 1Dx2.2+1Dy12 Subunits in High Molecular Weight Glutenin

  • Park, Chul-Soo;Baik, Byung-Kee;Kang, Moon-Seok;Park, Jong-Chul;Park, Jae-Gun;Yu, Chang-Yeon;Choung, Myoung-Gun;Lim, Jung-Dae
    • Preventive Nutrition and Food Science
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    • v.11 no.3
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    • pp.243-252
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    • 2006
  • White salted noodles and pan bread were prepared from Korean wheats with 1Dx2.2+1Dy12 subunits in high molecular weight glutenin subunits (HMW-GS) to evaluate the suitability for end-use products through the comparison with US wheats with various classes and commercial wheat flours. Korean wheat flours with 1Dx2.2+1Dy12 subunits showed higher SDS sedimentation volume than US wheat flours with similar protein content. Compared to wheat flours with similar protein content and SDS sedimentation volume, water absorption percent of Korean wheat flours using a mixograph was higher than that of US wheat flours, but similar to commercial wheat flours. Mixograph mixing time was similar to hard wheat flours and commercial noodle flours. Optimum water absorption percent of noodle dough from Korean wheat flours was higher than that of US wheat flours. Noodle sheets from Korean wheat flours with 1Dx2.2+ 1Dy12 subunits showed lower L values, higher a values and similar b values compared to commercial noodle flours. Hardness of cooked noodles from Korean wheat flours 1Dx2.2+1Dy12 subunits correlated positively with protein content, NIRS hardness, mixograph water absorption and gluten yield of flours. Korean wheat flours with 1Dx2.2+1Dy12 subunits showed lower loaf volume and harder crumb firmness than hard wheat flours and commercial bread wheat flours in spite of similar protein quantity and quality to hard wheat flours.

Development and Application of Dynamic Water Quality Model in Nakdong River (동적수질해석모형의 개발과 낙동강에의 적용)

  • Kwon, Na-Young;Choi, Hyun-Gu;Yu, Jae-Jung;Han, Kun-Yeun
    • Journal of Korea Water Resources Association
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    • v.43 no.3
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    • pp.283-294
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    • 2010
  • The objective of this study is to develop an accurate and stable dynamic water quality model which is capable of reflecting various flows and irregular cross sections and handling numerical oscillations under the low flow conditions. In order to solve the oscillation problem under the low flow conditions, diffusive wave method was applied to the low flow condition in developing a hydraulic model, DyHYD. DyQUAL is also developed as a water quality model to calculate up to 12 water quality variables including autochthonous BOD, water temperature, DO, TN and TP. The developed model is applied to both hypothetical river channels and actual Nakdong river watershed. Additionally, the applicability and reliability of the models are verified by comparing simulation results with observed values. Nash-Sutcliffe coefficients are estimated by comparison between simulation results and observed values. In the calibration and verification process, the coefficients varies from 0.391 to 0.591 and 0.704 to 0.902 for discharge, BOD, TN and TP, respectively.

A 3-D Measuring System of Thermoluminescence Spectra and Thermoluminescence of CaSO4 : Dy, P (열자극발광 스펙트럼의 3차원 측정 장치와 CaSO4 : Dy, P의 열자극발광)

  • Lee, Jung-Il;Moon, Jung-Hak;Kim, Douk-Hoon
    • Journal of Korean Ophthalmic Optics Society
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    • v.6 no.2
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    • pp.71-75
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    • 2001
  • In this paper, a three-dimensional measuring system of thermoluminescence(TL) spectra based on temperature, wavelength and luminescence intensity was introduced. The system was composed of a spectrometer, temperature control unit for thermal stimulation, photon detector and personal computer for control the entire system. Temperature control was achieved by using feedback to ensure a linear-rise in the sample temperature. Digital multimeter(KEITHLEY 195A) measures the electromotive force of Copper-Constantan thermocouple and then transmits the data to the computer through GPIB card. The computer converts this signal to temperature using electromotive force-temperature table in program, and then control the power supply through the D/A converter. The spectrometer(SPEX 1681) is controlled by CD-2A, which is controlled by the computer through RS-232 communication port. For measuring the luminescence intensity during the heating run, the electrometer(KEITHLEY 617) measures the anode current of photomultiplier tube(HAMAMATSU R928) and transmits the data to computer through the A/D converter. And, we measured and analyzed thermoluminescence of $CaSO_4$ : Dy, P using the system. The measuring range of thermoluminescence spectra was 300K-575K and 300~800 nm, $CaSO_4$ : Dy. P was fabricated by the Yamashita's method in Korea Atomic Energy Research Institute(KAERI) for radiation dosimeter. Thermoluminesce spectra of the $CaSO_4$ : Dy, P consist of two main peak at temperature of $205^{\circ}C$, wavelength 476 nm and 572 nm and with minor ones at 658 nm and 749 nm.

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