• Journal of the Korean Magnetic Resonance Society
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• v.17 no.2
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• pp.81-85
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• 2013

Various fluorine-containing materials are used in electronic devices like LCD display panels and Li-ion batteries. The structural conformation of fluorine in fluorinated materials is an important contributing factor that influences the chemical and physical properties. The conformation can be changed by heat and stress during manufacture or use. Understanding the conformational changes is critical for understanding the performance and durability of electronic devices. Solid-state NMR spectroscopy could be widely used for the analysis of various fluorine-containing materials for electronic devices. However, conventional CPMAS probes cannot be used for in-situ analysis of fluorine-containing electronic devices like LCD panels and Li-ion batteries. In this paper, we show the design, construction, and optimization of a $^{19}F-^{13}C$ double-resonance solid-state NMR probe for a 400MHz wide-bore magnet with a flat square coil for in-situ analysis of fluorine-containing electronic devices without observing fluorine background signals. This custom-built probe does not show any fluorine background signals, and can have higher efficiency for lossy samples.

• Advances in concrete construction
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• v.4 no.1
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• pp.49-69
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• 2016

This work investigates the mechanical properties of conventional concrete (CC) and self compacting concrete (SCC) using fine rubber and silpozz were accompanied by a comparative study between conventional rubberized concrete (CRC) and self compacting rubberized concrete (SCRC). Fine rubber (FR) from scrap tires has replaced the fine aggregate (FA) and Silpozz has been used as a replacement of cement at the proportions of 5, 10 and 15%. Silpozz as a partial replacement of cement in addition of superplasticiser (SP) increases the strength of concrete. Fresh concrete properties such as slump test, compaction factor test for CRC, whereas for SCRC slump flow, $T_{500}$, V-funnel, L-box, U-box, J-ring tests were conducted along with the hardened properties tests like compressive, split tensile and flexural strength test at 7, 28 and 90 days of curing. The durability and microstructural behavior for both CRC and SCRC were investigated. FR used in the present study is 4.75 mm passing with fineness modulus 4.74.M30 grade concrete is used with a mix proportion of 1:1.44:2.91 and w/c ratio as 0.43. The results indicate that as FR quantity increases, workability of both CRC and SCRC decreases. The results also show that the replacement of natural fine aggregate (NFA) with FR particles decreases the compressive strength with the increase of flexural strength observed upto 5% replacement of FR. Also replacement of cement with silpozz resulted enhancement of strength in SCRC.

• Advances in concrete construction
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• v.5 no.1
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• pp.31-48
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• 2017

Supplementary cementitious materials (SCM) have turned out to be a vital portion of extraordinary strength and performance concrete. Metakaolin (MK) is one of SCM material is acquired by calcinations of kaolinite. Universally utilised as pozzolanic material in concrete to enhance mechanical and durability properties. This study investigates the fresh and hardened properties of conventional concrete (CC) and self compacting concrete (SCC) by partially replacing cement with MK in diverse percentages. In CC and SCC, partial replacement of cement with MK varies from 5-20%. Fresh concrete properties of CC are conducted by slump test and compaction factor tests and for SCC, slump flow, T500, J-Ring, L-Box, V-Funnel and U-Box tests. Hardened concrete characteristics are investigated by compressive, split tensile and flexural strengths at age of 7, 28 and 90 days of curing under water. Carbonation depth, water absorption and density of MK based CC and SCC was also computed. Fresh concrete test results indicated that increase in MK replacement increases workability of concrete in a constant w/b ratio. Also, outcomes reveal that concrete integrating MK had greater compressive, flexural and split tensile strengths. Optimum replacement level of MK for cement was 10%, which increased mechanical properties and robustness properties of concrete.

• Advances in concrete construction
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• v.5 no.6
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• pp.659-669
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• 2017

Grouts compared to other material sources, could be highly sensitive to cold weather conditions, especially when the compressive strength is the matter of concern. Grout as one the substantial residential building material used in retaining walls, rebar fixation, sidewalks is in need of deeper investigation, especially in extreme weather condition. In this article, compressive strength development of four different commercial grouts at three temperatures and two humidity rates are evaluated. This experiment is aimed to assess the grout strength development over time and overall compressive strength when the material is cast at low temperatures. Results represent that reducing the curing temperature about 15 degrees could result in 20% reduction in ultimate strength; however, decreasing the humidity percentage by 50% could lead to 10% reduction in ultimate strength. The maturity test results represented the effect of various temperatures and humidity rates on maturity of the grouts. Additionally, the freeze-thaw cycle's effect on the grouts is conducted to investigate the durability factor. The results show that the lower temperatures could be significantly influential on the behavior of grouts compared to lower humidity rates. It is indicated that the maturity test could not be valid and precise in harsh temperature conditions.

• Journal of Drive and Control
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• v.16 no.2
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• pp.43-50
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• 2019

The objective of this study was to reverse engineer a swash plate type piston pump mounted on a wheeled armored vehicle and to analyze the structure of the pump case. From the analysis, the weak parts were identified and corrected in the final design. Each element corresponding to the piston pump case was analyzed. The analytical method was given static boundary conditions, load conditions and confirmed displacement, strain, stress, and safety factor. Plastic deformation and damage were also confirmed and the component elements redesigned through structural analysis Structural analysis and vibration analysis were carried out for the components of the piston pump case. The piston pump model was finally modified by structural analysis and vibration analysis results for each component assembly, and a prototype was designed. Durability test and environmental test were carried out and the test results satisfied all of the requirements. Therefore, the analytical method presented in this study can be utilized as a methodology for element component design in the development of various piston pumps.

• Structural Engineering and Mechanics
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• v.83 no.2
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• pp.245-257
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• 2022

As the main lateral load resisting system in high-rise reinforced concrete structures, the mechanical performance of shear wall has a significant impact on the structure, especially for high-rise buildings. Steel corrosion has been recognized as an important factor affecting the mechanical performance and durability of the reinforced concrete structures. To investigate the effect on the seismic behaviour of corroded reinforced concrete shear wall induced by corrosion, analytical investigations and simulations were done to observe the effect of corrosion on the ultimate seismic capacity and drift capacity of shear walls. To ensure the accuracy of the simulation software, several validations were made using both non-corroded and corroded reinforced concrete shear walls based on some test results in previous literature. Thereafter, a parametric study, including 200 FE models, was done to study the influence of some critical parameters on corroded structural shear walls with boundary element. These parameters include corrosion levels, axial force ratio, aspect ratio, and concrete compressive strength. The results obtained would then be used to propose equations to predict the seismic resistance and drift capacity of shear walls with various corrosion levels.

• International conference on construction engineering and project management
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• 2009.05a
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• pp.794-799
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• 2009

The temperature control of in-place concrete is the most important factor for an early age of curing concrete. Heat stress of mass concrete caused by the heat of hydration can induce the crack of concrete, and a frost damage from cold weather casting concrete results defect on compressive strength and degradation of durability. Therefore, success and failure of concrete work is dependant on the measurement and control of concrete temperature. In addition, the compressive strength assessment of in-place concrete obtained from the maturity calculated from the history of temperature make a reduction of construction cycle time, possible. For that purpose, wireless temperature measuring system was developed to control temperature and assess strength of concrete. And, it was possible to monitor the temperature of concrete over 1km apart from site office and to take a proper measure; mesh-type network was developed for wireless sensor. Furthermore, curing control system that contains the program capable to calculate the maturity of concrete from the history of temperature and to assess the compressive strength of concrete was established. In this study, organization and practical method of developed curing control system are presented; base on in-place application case.

• Computers and Concrete
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• v.33 no.2
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• pp.205-216
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• 2024

Self-Curing Self Compacting Concrete (SCSCC), is a special concrete in contemporary construction practice aimed at enhancing the performance of structural concrete. Its primary function is to ensure a sufficient moisture supply that facilitates hydration along with flow, particularly in the context of high-rise buildings and tall structures. This innovative concrete addresses the challenges of maintaining adequate curing conditions in large-scale projects, maintaining requisite workability, contributing to the overall durability and longevity of concrete structures. For implementing such a versatile material in construction, it is imperative to understand the stress-strain (S-S) behaviour. The primary aim of this study is to develop the S-S curves for TCSCSCC and compare through experimental results. Finite element (FE) analysis based ATENA-GiD was employed for the numerical simulation and develop the analytical stress-strain curves by introducing parameters viz., grade of concrete, tie diameter, tie spacing and yield strength. The stress ratio and the strain ratios are evaluated and compared with experimental values. The mean error is 1.2% with respect to stresses and 2.2% in case of strain. Finally, the stress block parameters for tie confined SCSCC are evaluated and equations are proposed for the same in terms of confinement index.

• Applied Chemistry for Engineering
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• v.35 no.2
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• pp.148-153
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• 2024

In this study, a methodology for evaluating impact strength in rollable devices was developed, focusing on measuring impact strength and evaluating rolling and unrolling durability simultaneously, with findings reported from tests on a real demonstration unit. The study utilized a flexible and rollable polyimide (PI) substrate for the evaluations. The chosen parameters for this methodology were a flat-type impactor, weights of 300 g, 500 g, and 1000 g, a rolling shaft ranging from 30 R to 5 R, and the positioning of the impactor. The results revealed that the difference in defect rates when comparing the 300 g and 500 g weights was minimal. However, the adoption of a 1000 g weight markedly increased the defect count due to damage to the PI film's surface. Furthermore, an uptick in rolling and unrolling cycles led to more pronounced surface scratches on the PI film. These methods and findings are poised to make a substantial contribution towards refining reliability testing for a wide array of rollable device applications, including smartphones, watches, pads, and wearable technology.

• Journal of the Korean Applied Science and Technology
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• v.32 no.2
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• pp.339-347
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• 2015

This study is to evaluate moisturizing effect and durability of UV A/B blocking activity with multiple (W/O/W) emulsion system. Most of the sun protective products come to be hot issue having both high SPF and long-lasting activity as using special products when is going out, mountain climbing and sports. Also, many consumers prefer the products which have the excellent waterproofing activity of sun care cosmetics as well as the non-sticky feeling that carried out the study of the sensorial science and texture preference. Therefore, development of the specific formulation using this multiple (W/O/W) emulsion technology, it has O/W type hydro skin feel having soft and moist texture when it is treated on the skin. Finally, this formulation is instantly changed to W/O type feel after adsorbed into the skin. The purpose of this study is to get high SPF lasting effect having high water resistance tactivity with high functional multiple (W/O/W) emulsion cream. We used major ingredients, UV-B absorbers were selected with ethylhexyl methoxycinnamate, isoamyl-p-methoxycinnamate, ethylhexylsalicylate, and octocrylene, UV-A absorbers were selected with butylmethoxydibenzoylmethane, bis-ethylhexyloxyphenol methoxy phenyltriazine. SPF effect of O/W type cream was 34.1. SPF effect of W/O/W type cream was 40.6 (increased about 19%). Water resistance effect after 4 hours, SPF effect of O/W type cream was 3.6 (quickly drop down). SPF effect of W/O/W type cream having 81.0 % waterproofing effect was 32.7 (decreased about SPF 7.9). Moisturizing effect of O/W cream at first was superior comparing multiple emulsion. But after 3 hours quickly was drop-down. Moisturizing effect of multiple emulsion was high comparing O/W type and other sun block creams after 4 hours was constantly maintaining water-content.