• 제목/요약/키워드: Dual-Salt

검색결과 36건 처리시간 0.019초

복합조직강의 부식피트 성장특성에 미치는 식염수농도의 영향 (Influence of Salt Solution Concentration on Corrosion Pit Growth Characteristic of Dual Phase Steel)

  • 오세욱;강호민;김태만;도영민
    • 한국해양공학회지
    • /
    • 제2권2호
    • /
    • pp.78-86
    • /
    • 1988
  • In order to investigate the corrosion pit occurrence and growth characteristic of M.E.F.(martensite encapsulated islands of ferrite) dual phase steel was made with a suitable heat treatment of raw material(SS41), a corrosion fatigue test was performed under rotary bending in the salt solution having a concentration from 0.01 wt percent to 3.5 wt percent. The fatigue strength of dual phase steel was remarkably decreased with an increase in concentration of salt solution; approximately from 63% to 80% in case of dual phase steel and from 40% to 71% in case of raw material. Corrosion pit occurred in the martensite phase and fatigue cracks from corrosion pits were selectively propagated in martensite phases. In the observation of corrosion pits at the origin of fatigue cracks, it had been found that corrosion pits were grown into hemispherical pits and a/c(the surface diameter, 2c and the depth, a of corrosion pit)was about 1.0-1.5regardless of the variation of salt solution concentration. The difference of corrosion pit depth growth rate was increased with an increase in concentration of salt solution according to an increase in stress level.

  • PDF

SS41강의 F.E.M.복합조직강에서 노치변화가 부식피로파괴에 미치는 영향 (Influence of Notch Change on Corrosion Fatigue Fracture in F.E.M. Dual phase Steel of SS41 Steel)

  • 도영민;이규천
    • 한국안전학회지
    • /
    • 제16권2호
    • /
    • pp.44-50
    • /
    • 2001
  • The rotated bending fatigue test was conducted in air md in 3.5% NaCl salt solution to investigate the fatigue fracture behaviour of raw material and F.E.M dual phase steel made from raw material(SS41) by a suitable heat treatment. This study has compared the initial microcrack creation of material by tensile test with that by fatigue test. And the rotated bending test of cantilever type under the condition of 3.5% NaCl salt solution and air has investigated the corrosion fatigue fracture behaviour with the variation of stress concentration factor determined by each of notch shapes. The initial microcrack have been developed in fragile grainboundary with general corrosion occurring in raw material : in the pits built up by corrosion in F.E.M. dual phase steel because pits bring out stress concentration. It is small that the degree of decrease in corrosion fatigue life for F.E.M. dual phase steel compared with raw material because the notch sensitivity of F.E.M. dual phase steel is lower than raw material in reason of characteristics with two-phase construction.

  • PDF

열 용해 적층법과 염 침출법을 이용한 3 차원 이중 공 인공지지체 제작에 관한 연구 (A Study on Fabrication of 3D Dual Pore Scaffold by Fused Deposition Modeling and Salt-Leaching Method)

  • 심해리;김종영
    • 대한기계학회논문집A
    • /
    • 제39권12호
    • /
    • pp.1229-1235
    • /
    • 2015
  • 3D 프린터를 이한 인공지지체 제작 기술은 손상된 골 조직 재생을 위해 개발되고 있다. 골 조직 재생에 적하기 위해 인공지지체는 생체적합성, 생분해성 그리고 적절한 기계적 특성을 지녀야 하며, 분한 양의 공극과 내부 연결성을 지닌 구조로 제작되어야 한다. 본 연구에서는 3 차원 이중 공극 인공지지체를 제작하기 위해서 열 해 적층법(fused deposition modeling, FDM) 기반의 폴리머 적층 시스템을 이하였다. 사된 재료는 폴리카프로락톤(polycaprolactone, PCL)과 알긴산 나트륨(sodium alginate, SA)이다. 제작된 3 차원 형상의 인공지지체에 이중 공극을 갖기 위해 염 침출법을 이하였다. 완성된 인공지지체는 주사 전자 현미경과 X 선 검출 분광기(scanning electron microscope-energy dispersive spectroscopy, SEM-EDS)를 통해 관찰하였으며, MG-63 세포를 이하여 in-vitro 평가를 하였다.

A LiPF6-LiFSI Blended-Salt Electrolyte System for Improved Electrochemical Performance of Anode-Free Batteries

  • Choi, Haeyoung;Bae, YeoJi;Lee, Sang-Min;Ha, Yoon-Cheol;Shin, Heon-Cheol;Kim, Byung Gon
    • Journal of Electrochemical Science and Technology
    • /
    • 제13권1호
    • /
    • pp.78-89
    • /
    • 2022
  • ANODE-free Li-metal batteries (AFLMBs) operating with Li of cathode material have attracted enormous attention due to their exceptional energy density originating from anode-free structure in the confined cell volume. However, uncontrolled dendritic growth of lithium on a copper current collector can limit its practical application as it causes fatal issues for stable cycling such as dead Li formation, unstable solid electrolyte interphase, electrolyte exhaustion, and internal short-circuit. To overcome this limitation, here, we report a novel dual-salt electrolyte comprising of 0.2 M LiPF6 + 3.8 M lithium bis(fluorosulfonyl)imide in a carbonate/ester co-solvent with 5 wt% fluoroethylene carbonate, 2 wt% vinylene carbonate, and 0.2 wt% LiNO3 additives. Because the dual-salt electrolyte facilitates uniform/dense Li deposition on the current collector and can form robust/ionic conductive LiF-based SEI layer on the deposited Li, a Li/Li symmetrical cell exhibits improved cycling performance and low polarization for over 200 h operation. Furthermore, the anode-free LiFePO4/Cu cells in the carbonate electrolyte shows significantly enhanced cycling stability compared to the counterparts consisting of different salt ratios. This study shows an importance of electrolyte design guiding uniform Li deposition and forming stable SEI layer for AFLMBs.

Conceptual design of a dual drum-controlled space molten salt reactor (D2 -SMSR): Neutron physics and thermal hydraulics

  • Yongnian Song;Nailiang Zhuang;Hangbin Zhao;Chen Ji;Haoyue Deng;Xiaobin Tang
    • Nuclear Engineering and Technology
    • /
    • 제55권6호
    • /
    • pp.2315-2324
    • /
    • 2023
  • Space nuclear reactors are becoming popular in deep space exploration owing to their advantages of high-power density and stability. Following the fourth-generation nuclear reactor technology, a conceptual design of the dual drum-controlled space molten salt reactor (D2-SMSR) is proposed. The reactor concept uses molten salt as fuel and heat pipes for cooling. A new reactivity control strategy that combines control drums and safety drums was adopted. Critical physical characteristics such as neutron energy spectrum, neutron flux distribution, power distribution and burnup depth were calculated. Flow and heat transfer characteristics such as natural convection, velocity and temperature distribution of the D2-SMSR under low gravity conditions were analyzed. The reactivity control effect of the dual-drums strategy was evaluated. Results showed that the D2-SMSR with a fast spectrum could operate for 10 years at the full power of 40 kWth. The D2-SMSR has a high heat transfer coefficient between molten salt and heat pipe, which means that the core has a good heat-exchange performance. The new reactivity control strategy can achieve shutdown with one safety drum or three control drums, ensuring high-security standards. The present study can provide a theoretical reference for the design of space nuclear reactors.

Simultaneous Dual-Enzyme Immunoassays in a Solid Phase

  • 백세환;박순재
    • Bulletin of the Korean Chemical Society
    • /
    • 제18권1호
    • /
    • pp.44-50
    • /
    • 1997
  • A method of dual-signal generation from two different enzymes was developed and utilized to simultaneously perform dual immunoassays in a single microwell. Two enzymes selected as tracers were horseradish peroxidase (HRP) and β-galactosidase (GAL). 3, 3', 5, 5'-Tetramethylbenzidine (TMB) and chlorophenolred-β-galactopyranoside (CPRG) as chromogenic substrates for the respective enzyme were used. Although the two enzymes showed their maximum activities at distinct pH conditions (pH 5.1 for HRP and 7.5 for GAL), the enzyme reactions were able to be concurrently carried out at pH 5.75 in a dual-substrate solution without signal loss. This performance was achieved by increasing TMB concentration two-fold, introducing potassium salt as activator of GAL reaction, and extending total reaction time 50%. The signal generation method was then used for dual-enzyme immunoassays to detect antibodies with co-immobilized Hepatitis C virus antigens (core and NS5) and a Hepatitis B virus antigen (PreS(2)) in a microwell. Dose-response curves of the assays revealed cooperativity between different antigen-antibody complex formation, which suggested that dual immunoassays can only be used for qualitative screening tests unless the antigens immobilized were spatially separated.

Application of single-well push-drift-pull tests using dual tracers (SF6 and salt) for designing CO2 leakage monitoring network at the environmental impact test site in Korea

  • Kim, Hong-Hyun;Lee, Seong-Sun;Ha, Seung-Wook;Lee, Kang-Kun
    • Geosciences Journal
    • /
    • 제22권6호
    • /
    • pp.1041-1052
    • /
    • 2018
  • A single-well push-drift-pull tracer test using two different tracers ($SF_6$ and salt) was performed at the Environmental Impact Test (EIT) site to determine suitable locations for monitoring wells and arrange them prior to artificial $CO_2$ injection and leak tests. Local-scale estimates of hydraulic properties (linear groundwater velocity and effective porosity) were obtained at the study site by the tracer test with two tracers. The mass recovery percentage of the volatile tracer ($SF_6$) was lower than that of the non-volatile tracer (salt) and increased drift time may make degassing of $SF_6$ intensified. The $CO_2$ leakage monitoring results for both unsaturated and saturated zones suggest that the $CO_2$ monitoring points should be located near points at which a high concentration gradient is expected. Based on the estimated hydraulic properties and tracer mass recovery rates, an optimal $CO_2$ monitoring network including boreholes for monitoring the unsaturated zone was constructed at the study site.

3.5% NaCl 수용액의 pH변화가 복합조직강의 부식피로파괴에 미치는 영향 (Influence of pH in 3.5% NaCl aqueous solution on corrosion fatigue-fracture of dual phase steel)

  • 오세욱;안호민;도영문
    • 한국해양공학회지
    • /
    • 제1권2호
    • /
    • pp.123-129
    • /
    • 1987
  • Corrosion fatigue fracture of dual phase steel(SS41) and raw material steel(SS41) were investigated in 3.5% NaCl aqueous solution at PH 4,6,9 and 11. The fatigue limit of dual phase steel is increased approximately 1.8 times larger than that of raw material in air. The corrosion fatigue life of dual phase steel is about 5-10 times larger than that of raw material in 3.5% NaCl aqueous solution. The reduction of fatigue life is larger for the acidsalt solution than for the alkali salt solution. The reduction of stress level on the reduction ratio of corrosion fatigue life is large as pH 6-11. The reduction ratio of corrosion fatigue life of dual phase steel and raw material is nearly coincided at pH 2. While at pH4-2 the reduction ratio of corrosion fatigue life only depends on the corrosion effect. It has been found that the corrosion resistance effect of dual phase steel is smaller than that of raw material in corrosion fatigue crack propagation rate. As pH below 6 is changed, it can be clearly observed from raw material that the brittle intergranular fracture is characterized, and from the above result, the influence of corrosion of dual phase steel is small.

  • PDF

압출 적층 조형법과 입자 추출법을 결합한 이중 공극 BCP/Silica 인공지지체의 제작 (Fabrication of BCP/Silica Scaffolds with Dual-Pore by Combining Fused Deposition Modeling and the Particle Leaching Method)

  • 사민우;김종영
    • 대한기계학회논문집A
    • /
    • 제40권10호
    • /
    • pp.865-871
    • /
    • 2016
  • 조직 공학에서는 전통적인 인공지지체 제작 방식인 가스 발포, 염 침출, 스폰지 복제 그리고 동결주조 법 등이 이용되고 있다. 하지만 다양한 공극 형태 및 크기를 가지고 있어서 세포 상호 작용 효과 및 충분한 기계적 특성에 한계가 있다. 그러나 열 용해 적층 법은 조직공학에서 폴리머 재료를 이용하여 다양한 3차원 인공지지체를 제작할 수 있는 가장 적절한 기술이다. 따라서 본 연구에서는 PCL 몰드를 제작하고 실리카와 알긴산 나트륨 염을 포함하는 세라믹 슬러리를 제조하여 몰드에 주입시켰으며, 1일 동안 자연 건조를 시켰다. 제작된 3차원 슬러리 몰드는 PCL 몰드의 제거 및 슬러리를 경화시키기 위해 $100^{\circ}C$의 오븐에서 2시간 열처리 되었고, 열처리 후에 $1100^{\circ}C$에서 소결되었다. 제작된 인공지지체는 주사전자현미경을 통해 관찰되었고, 압축 시험을 통해 알긴산 나트륨 염의 혼합량에 따른 인공지지체의 기계적 특성은 평가되었다.

다결점 AMBISM/SIMULINK 모델을 이용한 AMBIDEXTER 계측제어 시스템 개념 설계에 관한 연구 (A Design Concept study for the AMBIDEXTER Control System through Developing a Multi-node System Model, AMBISM/SIMULINK)

  • 유영진;김진성;이영준;오세기
    • 한국에너지공학회:학술대회논문집
    • /
    • 한국에너지공학회 2002년도 추계 학술발표회 논문집
    • /
    • pp.89-103
    • /
    • 2002
  • 기존 원자력 발전 기술이 안고 있는 문제점들을 해결함과 동시에 장기적으로 기존의 경ㆍ중수형 원자로를 대체 또는 보완할 수 있을 것으로 기대되는 새로운 원자력에너지시스템으로서 토륨ㆍ우라늄ㆍ플루토늄 혼합 핵주기에 기초한 용융염원자로(Molten Salt Reactor)의 일종인 AMBIDEXTER (Advanced Molten-salt Break-even Inherently-safe Dual-missioning EXperimental and TEst Reactor) 원자력에너지 복합시스템의 개념설계 연구가 진행중이다.(중략)

  • PDF