• Title/Summary/Keyword: Dual-Salt

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Influence of Salt Solution Concentration on Corrosion Pit Growth Characteristic of Dual Phase Steel (복합조직강의 부식피트 성장특성에 미치는 식염수농도의 영향)

  • Oh, Sae-Wook;Kang, Ho-Min;Kim, Tae-Man;Do, Yeong-Min
    • Journal of Ocean Engineering and Technology
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    • v.2 no.2
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    • pp.78-86
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    • 1988
  • In order to investigate the corrosion pit occurrence and growth characteristic of M.E.F.(martensite encapsulated islands of ferrite) dual phase steel was made with a suitable heat treatment of raw material(SS41), a corrosion fatigue test was performed under rotary bending in the salt solution having a concentration from 0.01 wt percent to 3.5 wt percent. The fatigue strength of dual phase steel was remarkably decreased with an increase in concentration of salt solution; approximately from 63% to 80% in case of dual phase steel and from 40% to 71% in case of raw material. Corrosion pit occurred in the martensite phase and fatigue cracks from corrosion pits were selectively propagated in martensite phases. In the observation of corrosion pits at the origin of fatigue cracks, it had been found that corrosion pits were grown into hemispherical pits and a/c(the surface diameter, 2c and the depth, a of corrosion pit)was about 1.0-1.5regardless of the variation of salt solution concentration. The difference of corrosion pit depth growth rate was increased with an increase in concentration of salt solution according to an increase in stress level.

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Influence of Notch Change on Corrosion Fatigue Fracture in F.E.M. Dual phase Steel of SS41 Steel (SS41강의 F.E.M.복합조직강에서 노치변화가 부식피로파괴에 미치는 영향)

  • 도영민;이규천
    • Journal of the Korean Society of Safety
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    • v.16 no.2
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    • pp.44-50
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    • 2001
  • The rotated bending fatigue test was conducted in air md in 3.5% NaCl salt solution to investigate the fatigue fracture behaviour of raw material and F.E.M dual phase steel made from raw material(SS41) by a suitable heat treatment. This study has compared the initial microcrack creation of material by tensile test with that by fatigue test. And the rotated bending test of cantilever type under the condition of 3.5% NaCl salt solution and air has investigated the corrosion fatigue fracture behaviour with the variation of stress concentration factor determined by each of notch shapes. The initial microcrack have been developed in fragile grainboundary with general corrosion occurring in raw material : in the pits built up by corrosion in F.E.M. dual phase steel because pits bring out stress concentration. It is small that the degree of decrease in corrosion fatigue life for F.E.M. dual phase steel compared with raw material because the notch sensitivity of F.E.M. dual phase steel is lower than raw material in reason of characteristics with two-phase construction.

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A Study on Fabrication of 3D Dual Pore Scaffold by Fused Deposition Modeling and Salt-Leaching Method (열 용해 적층법과 염 침출법을 이용한 3 차원 이중 공 인공지지체 제작에 관한 연구)

  • Shim, Hae-Ri;Kim, Jong Young
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.39 no.12
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    • pp.1229-1235
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    • 2015
  • Scaffold fabrication technology using a 3D printer was developed for damaged bone tissue regeneration. A scaffold for bone tissue regeneration application should be biocompatible, biodegradable, and have an adequate mechanical strength. Moreover, the scaffold should have pores of satisfactory quantity and interconnection. In this study, we used the polymer deposition system (PDS) based on fused deposition modeling (FDM) to fabricate a 3D scaffold. The materials used were polycaprolactone (PCL) and alginic acid sodium salt (sodium alginate, SA). The salt-leaching method was used to fabricate dual pores on the 3D scaffold. The 3D scaffold with dual pores was observed using SEM-EDS (scanning electron microscope-energy dispersive spectroscopy) and evaluated through in-vitro tests using MG63 cells.

A LiPF6-LiFSI Blended-Salt Electrolyte System for Improved Electrochemical Performance of Anode-Free Batteries

  • Choi, Haeyoung;Bae, YeoJi;Lee, Sang-Min;Ha, Yoon-Cheol;Shin, Heon-Cheol;Kim, Byung Gon
    • Journal of Electrochemical Science and Technology
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    • v.13 no.1
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    • pp.78-89
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    • 2022
  • ANODE-free Li-metal batteries (AFLMBs) operating with Li of cathode material have attracted enormous attention due to their exceptional energy density originating from anode-free structure in the confined cell volume. However, uncontrolled dendritic growth of lithium on a copper current collector can limit its practical application as it causes fatal issues for stable cycling such as dead Li formation, unstable solid electrolyte interphase, electrolyte exhaustion, and internal short-circuit. To overcome this limitation, here, we report a novel dual-salt electrolyte comprising of 0.2 M LiPF6 + 3.8 M lithium bis(fluorosulfonyl)imide in a carbonate/ester co-solvent with 5 wt% fluoroethylene carbonate, 2 wt% vinylene carbonate, and 0.2 wt% LiNO3 additives. Because the dual-salt electrolyte facilitates uniform/dense Li deposition on the current collector and can form robust/ionic conductive LiF-based SEI layer on the deposited Li, a Li/Li symmetrical cell exhibits improved cycling performance and low polarization for over 200 h operation. Furthermore, the anode-free LiFePO4/Cu cells in the carbonate electrolyte shows significantly enhanced cycling stability compared to the counterparts consisting of different salt ratios. This study shows an importance of electrolyte design guiding uniform Li deposition and forming stable SEI layer for AFLMBs.

Conceptual design of a dual drum-controlled space molten salt reactor (D2 -SMSR): Neutron physics and thermal hydraulics

  • Yongnian Song;Nailiang Zhuang;Hangbin Zhao;Chen Ji;Haoyue Deng;Xiaobin Tang
    • Nuclear Engineering and Technology
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    • v.55 no.6
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    • pp.2315-2324
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    • 2023
  • Space nuclear reactors are becoming popular in deep space exploration owing to their advantages of high-power density and stability. Following the fourth-generation nuclear reactor technology, a conceptual design of the dual drum-controlled space molten salt reactor (D2-SMSR) is proposed. The reactor concept uses molten salt as fuel and heat pipes for cooling. A new reactivity control strategy that combines control drums and safety drums was adopted. Critical physical characteristics such as neutron energy spectrum, neutron flux distribution, power distribution and burnup depth were calculated. Flow and heat transfer characteristics such as natural convection, velocity and temperature distribution of the D2-SMSR under low gravity conditions were analyzed. The reactivity control effect of the dual-drums strategy was evaluated. Results showed that the D2-SMSR with a fast spectrum could operate for 10 years at the full power of 40 kWth. The D2-SMSR has a high heat transfer coefficient between molten salt and heat pipe, which means that the core has a good heat-exchange performance. The new reactivity control strategy can achieve shutdown with one safety drum or three control drums, ensuring high-security standards. The present study can provide a theoretical reference for the design of space nuclear reactors.

Simultaneous Dual-Enzyme Immunoassays in a Solid Phase

  • 백세환;박순재
    • Bulletin of the Korean Chemical Society
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    • v.18 no.1
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    • pp.44-50
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    • 1997
  • A method of dual-signal generation from two different enzymes was developed and utilized to simultaneously perform dual immunoassays in a single microwell. Two enzymes selected as tracers were horseradish peroxidase (HRP) and β-galactosidase (GAL). 3, 3', 5, 5'-Tetramethylbenzidine (TMB) and chlorophenolred-β-galactopyranoside (CPRG) as chromogenic substrates for the respective enzyme were used. Although the two enzymes showed their maximum activities at distinct pH conditions (pH 5.1 for HRP and 7.5 for GAL), the enzyme reactions were able to be concurrently carried out at pH 5.75 in a dual-substrate solution without signal loss. This performance was achieved by increasing TMB concentration two-fold, introducing potassium salt as activator of GAL reaction, and extending total reaction time 50%. The signal generation method was then used for dual-enzyme immunoassays to detect antibodies with co-immobilized Hepatitis C virus antigens (core and NS5) and a Hepatitis B virus antigen (PreS(2)) in a microwell. Dose-response curves of the assays revealed cooperativity between different antigen-antibody complex formation, which suggested that dual immunoassays can only be used for qualitative screening tests unless the antigens immobilized were spatially separated.

Application of single-well push-drift-pull tests using dual tracers (SF6 and salt) for designing CO2 leakage monitoring network at the environmental impact test site in Korea

  • Kim, Hong-Hyun;Lee, Seong-Sun;Ha, Seung-Wook;Lee, Kang-Kun
    • Geosciences Journal
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    • v.22 no.6
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    • pp.1041-1052
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    • 2018
  • A single-well push-drift-pull tracer test using two different tracers ($SF_6$ and salt) was performed at the Environmental Impact Test (EIT) site to determine suitable locations for monitoring wells and arrange them prior to artificial $CO_2$ injection and leak tests. Local-scale estimates of hydraulic properties (linear groundwater velocity and effective porosity) were obtained at the study site by the tracer test with two tracers. The mass recovery percentage of the volatile tracer ($SF_6$) was lower than that of the non-volatile tracer (salt) and increased drift time may make degassing of $SF_6$ intensified. The $CO_2$ leakage monitoring results for both unsaturated and saturated zones suggest that the $CO_2$ monitoring points should be located near points at which a high concentration gradient is expected. Based on the estimated hydraulic properties and tracer mass recovery rates, an optimal $CO_2$ monitoring network including boreholes for monitoring the unsaturated zone was constructed at the study site.

Influence of pH in 3.5% NaCl aqueous solution on corrosion fatigue-fracture of dual phase steel (3.5% NaCl 수용액의 pH변화가 복합조직강의 부식피로파괴에 미치는 영향)

  • 오세욱;안호민;도영문
    • Journal of Ocean Engineering and Technology
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    • v.1 no.2
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    • pp.123-129
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    • 1987
  • Corrosion fatigue fracture of dual phase steel(SS41) and raw material steel(SS41) were investigated in 3.5% NaCl aqueous solution at PH 4,6,9 and 11. The fatigue limit of dual phase steel is increased approximately 1.8 times larger than that of raw material in air. The corrosion fatigue life of dual phase steel is about 5-10 times larger than that of raw material in 3.5% NaCl aqueous solution. The reduction of fatigue life is larger for the acidsalt solution than for the alkali salt solution. The reduction of stress level on the reduction ratio of corrosion fatigue life is large as pH 6-11. The reduction ratio of corrosion fatigue life of dual phase steel and raw material is nearly coincided at pH 2. While at pH4-2 the reduction ratio of corrosion fatigue life only depends on the corrosion effect. It has been found that the corrosion resistance effect of dual phase steel is smaller than that of raw material in corrosion fatigue crack propagation rate. As pH below 6 is changed, it can be clearly observed from raw material that the brittle intergranular fracture is characterized, and from the above result, the influence of corrosion of dual phase steel is small.

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Fabrication of BCP/Silica Scaffolds with Dual-Pore by Combining Fused Deposition Modeling and the Particle Leaching Method (압출 적층 조형법과 입자 추출법을 결합한 이중 공극 BCP/Silica 인공지지체의 제작)

  • Sa, Min-Woo;Kim, Jong Young
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.40 no.10
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    • pp.865-871
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    • 2016
  • In recent years, traditional scaffold fabrication techniques such as gas foaming, salt leaching, sponge replica, and freeze casting in tissue engineering have significantly limited sufficient mechanical property and cell interaction effect due to only random pores. Fused deposition modeling is the most apposite technology for fabricating the 3D scaffolds using the polymeric materials in tissue engineering application. In this study, 3D slurry mould was fabricated with a blended biphasic calcium phosphate (BCP)/Silica/Alginic acid sodium salt slurry in PCL mould and heated for two hours at $100^{\circ}C$ to harden the blended slurry. 3D dual-pore BCP/Silica scaffold, composed of macro pores interconnected with micro pores, was successfully fabricated by sintering at furnace of $1100^{\circ}C$. Surface morphology and 3D shape of dual-pore BCP/Silica scaffold from scanning electron microscopy were observed. Also, the mechanical properties of 3D BCP/Silica scaffold, according to blending ratio of alginic acid sodium salt, were evaluated through compression test.

A Design Concept study for the AMBIDEXTER Control System through Developing a Multi-node System Model, AMBISM/SIMULINK (다결점 AMBISM/SIMULINK 모델을 이용한 AMBIDEXTER 계측제어 시스템 개념 설계에 관한 연구)

  • 유영진;김진성;이영준;오세기
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
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    • 2002.11a
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    • pp.89-103
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    • 2002
  • 기존 원자력 발전 기술이 안고 있는 문제점들을 해결함과 동시에 장기적으로 기존의 경ㆍ중수형 원자로를 대체 또는 보완할 수 있을 것으로 기대되는 새로운 원자력에너지시스템으로서 토륨ㆍ우라늄ㆍ플루토늄 혼합 핵주기에 기초한 용융염원자로(Molten Salt Reactor)의 일종인 AMBIDEXTER (Advanced Molten-salt Break-even Inherently-safe Dual-missioning EXperimental and TEst Reactor) 원자력에너지 복합시스템의 개념설계 연구가 진행중이다.(중략)

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