• Analytical Science and Technology
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• v.19 no.4
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• pp.290-300
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• 2006

Disinfection by-products(DBPs), such as volatile trihalomethanes and the nonvolatile organochlorine acids, created by chlorination have been extensively studied. However MX which contributes 20-50% of the mutagenic activity in drinking water began to people's attention since 1990. Its chemical name is 3-chloro-4-dichloromethyl-5-hydroxy-2(5H)-furanone. According to WHO guidelines its concentration should be controlled, but its value has not been set up. Due to analytical difficulties in measuring this compound at such a low concentrations and lack of information on toxicity to human. Because concentration (ng/L) of MX in drinking water is low traditional testing methods are ineffective. Therefore this study compared LLE and SPE and have chosen SPE to improve preconcentration. MX has been identified in chlorinated drinking water samples in several countries but not in korea Therefore this study analyzed concentration of MX in different water sources and in spring water. This study examined the causes of changing MX content. Chlorine dosage, seasons, water temperature and distance from the source was all discoverd to be relavant. MX was analyzed in various treatment to find optimum disinfection methods. The outcome was that the concentration of MX was minimized when using biological activated carbon-O3 and granular activated carbon.

• Journal of Environmental Science International
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• v.21 no.11
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• pp.1349-1360
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• 2012

This study presented the phytoplankton communities of the three lakes (Sayeon, Daeam, Hoeya ) using for drinking water in the Ulsan reservoir. The water storage of the Lake Sayeon, Daeam and Hoeya were 25, 13, 21 million ton respectively and most of which were being utilized for industrial and residential purposes. The total precipitation of the Ulsan region in 2010 was 1,162 mm, decreasing 10 % from 1,275 mm of the annual. As for pollutant loads, BOD and TN discharge loads of Daeam was the highest with 3,277 kg/day, 1,931 kg/day and 90 % of them were came from non-point pollutant sources. TP discharge loads showed the highest in the lake Hoeya with 643 kg/day and 97 % of them were came from point sources as household, industry and livestock. We assessed water quality of the lake Sayeon, Daeam and Hoeya using 17 variables. The water quality assessment found that the lake Daeam met the fourth to fifth grade because of high concentration of COD, SS and chlorophyll-a. Eutrophication assessment was conducted by revised Carlson's Index (TSIm, Aizaki) and found that Lake Daeam was more eutrophicated than the other two lakes all the year through as for chlorophyll-a, transparency and the total phosphorus (TP). A total of 95~111 phytoplankton species were identified from the three lake samples. Among them, the largest number of species were Chlorophyceae with 35~51, followed by Bacillariophyceae with 36~45, Cyanophyceae with 9~11, and Cryptophyceae with 6~9 species. The total cell number of phytoplankton was the highest in February (15,254 cells/mL) with Bacillariophyceae in the lake Daeam and the seasonal succession shows that Bacillariophyceae (Stephanodiscus spp.) in the spring, Cyanophyceae (Anabaena spp.) in the summer and the autumn, Bacillariophyceae (Stephanodiscus spp.) in the winter.

• Journal of Microbiology
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• v.45 no.5
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• pp.379-387
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• 2007

A hundred and seventeen antibiotic-resistant Escherichia coli strains were isolated from public tap and spring waters which were polluted by fecal coliforms. There were no significant differences between two water sources as to the coliform pollution level (p> 0.05). All E. coli isolates were detected to be resistant to one or more antibiotics tested. Nearly 42% of the isolates showed multiresistant phenotype. Three (2.5%) of these isolates contained class 1 integron. Sequencing analysis of variable regions of the class 1 integrons showed two gene cassette arrays, dfr1-aadA1 and dhfrA17-aadA5. Resistance to ampicillin, tetracycline or trimethoprim-sulfamethoxazole was transferable according to the results of conjugation experiments. The rate of tetracycline resistance was 15%. tet(A)-mediated tetracycline resistance was widespread among tetracycline-resistant E. coli isolates. Genotyping by BOX-polymerase chain reaction (BOX-PCR) showed that some of the strains were epidemiologically related. This is the first report on the prevalence and characterization of class 1 integron-containing E. coli isolates of environmental origin in Turkey.

• Journal of Environmental Impact Assessment
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• v.25 no.3
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• pp.209-221
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• 2016

The section from water source to 2.6km upper stream of Hantan River is protected as the drinking water quality protection area according to guidelines of Ministry of Environment, because water source of the Gwanin water intake plant has been known the river. However, opinions were consistently brought up that the standard of water source protection zone must be changed with using underground water as water source because of contribution possibility of underground water as the water source of Gwanin water intake facility. In this regard, hydrogeologic investigation including resistivity survey and hydrogeochemical investigation were carried out to assess water source and infiltration of contaminant for the plant. Quaternary basaltic rocks (50m thick with four layers) covered most of the study area on the granite basement. As the result of the resistivity survey, it is revealed that permeable aquifer is distributed in the boundary of two layers: the basaltic layer with low resistivity; and the granite with high resistivity. Considering of outflow from Gwanin water intake facility, the area possessing underground water was estimated at least $5.7km^2$. The underground water recharged from Cheorwon plain was presumed to outflow along the surface of unconformity plane of basalt and granite. Based on field parameters and major dissolved constituents, groundwater and river water clearly distinguished and the spring water was similar to groundwater from the basaltic aquifer. Temporal variation of $SiO_2$, Mg, $NO_3$, and $SO_4$ concentrations indicated that spring water and nearby groundwater were originated from the basaltic aquifer and other groundwater from granitic aquifer. In conclusion, the spring of the Gwanin water intake plant was distinguished from river water in terms of hydrogeochemical characteristics and mainly contributed from the basaltic aquifer.

• Journal of Korean Society on Water Environment
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• v.29 no.6
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• pp.832-841
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• 2013

In recent years, eutrophication in the Paldang Lake has become one of the major environmental problems in Korea as it may threaten drinking water safety and human health. Thus it is important to understand the phenomena and predict the time and magnitude of algal blooms for applying adequate algal reduction measures. This study performed seasonal water quality assessment and chlorophyll-a prediction using Bayseian simple/multiple linear regression analysis. Bayseian regression analysis could be a useful tool to overcome limitations of conventional regression analysis. Also it can consider uncertainty in prediction by using posterior distribution. Generally, chlorophyll-a of a P2(Paldang Dam 2) site showed high concentration in spring and it was similar to that of P4(Paldang Dam 4) site. For the development of Bayseian model, we performed seasonal correlation. As a result, chlorophyll-a of a P2 site had a high correlation with P5(Paldang Dam 5) site in spring (r = 0.786, p<0.05) and with P4 in winter (r = 0.843, p<0.05). Based on the DIC (Deviance Information Criterion) value, critical explanatory variables of the best fitting Bayesian linear regression model were selected as a $PO_4-P$ (P2), Chlorophyll-a (P5) in spring, $NH_3-N$ (P2), Chlorophyll-a (P4), $NH_3-N$ (P4) in summer, DTP (P2), outflow (P2), TP (P3), TP (P4) fall, COD (P2), Chl-a (P4) and COD (P4) in winter. The results of chlorophyll-a prediction showed relatively high $R^2$ and low RMSE values in summer and winter.

• Korean Chemical Engineering Research
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• v.44 no.2
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• pp.216-226
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• 2006

Total trihalomethanes (THMs), dichloroacetic acid (DCAA) and trichloroacetic acid (TCAA) that are the major disinfection byproducts (DBPs) are monitored continuously in drinking water in Seoul. Study on characteristics of DBPs is crucial to judge the safety of drinking water in Seoul. Analysis of THMs, haloacetonitriles (HANs), chloral hydrate (CH), and haloacetic acids (HAAs) was carried out in several distribution systems from January 2002 to December 2004. The concentration of THMs was 0.015 mg/L in purified water, 0.019 mg/L in tapwater by direct service, and 0.023 mg/L in tapwater through watertank, respectively. It might be due to the increased contact time with chlorine by a process of the distribution system. And the other DBPs show a tendency to increase in its concentration by a process of the distribution system. Also, in summer, the concentration of DBPs was higher than in spring and winter. It might be due to the higher temperature of water in summer. In all cases, the quantities of detected DBPs were 4-6 times lower than those of regulation limits of drinking water in Seoul. In view of these results, the tapwater in Seoul is good to drink it all the times.

• Analytical Science and Technology
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• v.21 no.5
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• pp.383-391
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• 2008

International Agency for Research on Cancer (IARC) has classified it as a possible carcinogen and World Health Organization (WHO) has suggested 50 ng/mL as a guideline value for 1,4-dioxane. Considering the toxicity of 1,4-dioxane and ingestion rate of drinking water, the monitoring of 1,4-dioxane in drinking water in Nakdong river is very important. We analyzed 1,4-dioxane four times per year for the 12 samples of treated water and 4 samples of raw water in Nakdong river in Korea from 2000 to 2007 and surveyed the trend of concentrations of 1,4-dioxane. As a results of analysis, 1,4-dioxane was detected from 0.24 to 240.2 ng/mL in treated water and from 0.39 to 81.9 ng/mL in raw water from 2000 to 2007. The average concentrations are 22.68 ng/mL and 19.15 ng/mL in treated water and raw water, respectively. The detected concentrations was decreased but frequency of detection was not changed since establishment of regulation in 2004. Results of comparison of 95 percentile excessive cancer risk of 1,4-dioxane in treated and raw water were each $6.63{\times}10^{-6}$, $3.17{\times}10^{-6}$ before 2004 and $2.10{\times}10^{-6}$, $1.22{\times}10^{-6}$ after 2004. Also, comparing the detected concentration and frequency for each season, these were more detected the concentration and frequency for 1,4-dioxane in treated and raw water from winter to spring.

• Journal of Food Hygiene and Safety
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• v.14 no.3
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• pp.227-232
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• 1999

A total of 136 coliform bacteria isolated from spring water (112 strains) and ground water (24 strains), submitted to Seoul Health and Environmental Research Institute from June to July in 1997, were characterized biochemically and microbiologically. Colonical characteristics of each isolate were also noted, including color and texture on EMB agar. Among the 136 isolates, 50.7% were greenish metallic sheen color, 44.2% were pink and 5.1% were violet. The sixty four percent were smooth, 34.6% were mucoid and 0.7%. were rough. Twenty three bacterial species were identified by IMViC and API 20E test. Among the 136 coliform bacteria known to species, 39 isolates (28.6%) were Escherichia spp., 32 isolates (23.5%) were Klebsiella ssp., 30 isolates (22.1%) were Enterobacter spp., 19 isolates (14.0%) were Serratia spp., 6 isolates (4.4%) were Citrobacter spp., 4 isolates (3.0%) were Kluyvera spp. and 7 isolates (5.1%) were other bacterial species. Strains, which were gas-positive in lactose broth but gas-negative in Kligler Iron Agar were Ent. intermedium, Ser. liquefaciens, Ser. marcescenes and Salmonella arizoae. Strains, which were H2S production were also Kleb. pneumoniae, Kleb. oxytoca, Kleb. ornithinolytica, Ent. sahazahii, Ent. cloacae, Ser. liquefaciens, Ser. fica ria, Cit. freundii and Sal. arizoae. In the present study, most of coliform isolated from spring and ground water were E. coli, Klebsiella spp. and Enterobacter spp. Since coliform with pink colony in EMB agar was isolated as frequent as coliform with greenish metallic sheen colony, coliform with pink colony should be considered as important colony. Our results suggested that new coliform strains may be emerging on the basis of biochemical and microbiological testes.

• Journal of Environmental Health Sciences
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• v.44 no.3
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• pp.227-237
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• 2018

Objectives: This study was investigated the characteristics of small-scale water works (SWW) in Gyeongnam area and conduct a health risk assessment of water-quality inspection items unfitted for water-quality standards (WQS). Methods: The characteristics of SWW in Gyeongnam province were analyzed using the data of SWW in the last three years (2014~2016) published in National Waterworks Information System. In addition, the health risk assessment for inspection items unfitted for WQS was carried out in four steps: hazard identification, dose-response assessment, exposure assessment, and risk characterization. Results: The total number of SWW in Gyeongnam area was gradually decreased from 2014 to 2016. In addition, drinking water sources of SWW were in the order of ground water, valley water, spring water, surface water, and river-bed water. The number of points unfitted for WQS in SWW by year was 22, 45, and 18 in 2014, 2015, and 2016, respectively, and a total of 112 points were found to unfit for WQS in SWW during 2014~2016. The hazard quotient (HQ) for fluoride, nitrate nitrogen, boron in the unfitted points for WQS was more than 1.0, and the mean values for turbidity and color in points unfitted for WQS were 2.38 nephelometric turbidity unit and 16.25 color unit, respectively. Conclusions: The HQ for fluorine, nitrate nitrogen and boron was more than 1.0 in points unfitted for WQS among SWW in Gyeongnam area, and the turbidity and the color degree exceeded WQS, which mean that there is a possibility of harmful impacts on the human health.

• Journal of Korean Society on Water Environment
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• v.35 no.6
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• pp.557-566
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• 2019

Paldang is a river reservoir in the Midwest of Korea, which is a drinking water source for the metropolitan area. Since the Paldang Reservoir is shallow, and has a short hydraulic residence time, its water quality is directly impacted by two incoming rivers, the north Han River (NHR) and the south Han River (SHR). The NHR has different seasonal patterns of water temperature from the SHR because the NHR is greatly impacted by the discharge water from upstream dams. The electrical conductivity (EC) and other material concentrations of the SHR are usually higher than those of the NHR because its basin is limestone-based. The difference in water temperature in the two rivers causes density flow, and the distribution of the EC within the reservoir can be an indicator for monitoring density flow. From the vertical gradient of the EC at the dam site, from spring to fall, it was confirmed that the SHR flowed into the upper layer, and the NHR flowed into the lower layer, and vice versa at other times. The relative difference (RD) of the EC between the upper layer and the lower layer at the dam site was used as an indicator for density flow. The RD of the EC showed a very significant correlation with the RD of total organic carbon (r = 0.70, p < 0.001) and the RD of total nitrogen (r = 0.58, p < 0.01). This relationship is based on the assumption that the difference in electrical conductivity and water quality between the SHR and the NHR is constant. However, in many cases this assumption is inconsistent. Thus, further study is needed on more suitable indicators to evaluate the impact of density flow on water quality.