• Journal of the Korean Chemical Society
• /
• v.29 no.5
• /
• pp.533-538
• /
• 1985

To investigate the importance of the hydrophobic interaction in the spermine-induced collapse of DNA to a compact structure, the effect of urea on the anomalous absorbance-temperature profile of calf thymus DNA has been investigated. With the increase of the urea concentration, the trough phase of the anomalous absorbance-temperature profile was eliminated eventually. The cooperativity, enthalpy, and the midpoint of the transition to the trough region are more sensitive to urea than those of the Tm-region transition. The present data of the adverse effect of urea, a hydrophobic environmental reagent, on the thermal stabilization of the condensed state of DNA, suggest that hydrophobic interaction may play an important role in the stabilization of the tertiary structure of the collapsed state of DNA.

• Journal of the Korean Society of Manufacturing Process Engineers
• /
• v.14 no.6
• /
• pp.111-121
• /
• 2015

The objective of this study is to develop an automatic object changer unit to improve changing process problems existing in the conventional horizontal machining center. In order to perform this objective, an upward and downward traverse unit was designed. This unit consists of a motor, reducer, chain and sprocket wheel, and an upper and lower base. This automatic object changer unit performs a sliding contact motion in a purpose built and designed frame. Constraint conditions for the upward and downward traverse unit were first designed. Then, an operation mechanism was designed and introduced as the sum of the kinetic energy for the sprocket wheel and the upper and lower base and which was based on the moment of inertia, which is the kinetic energy of the converted upward and downward traverse unit in the side of the reducer. The paper covers the design of th e Automatic Pallet Changer for th e machining center.

• Journal of Soil and Groundwater Environment
• /
• v.25 no.3
• /
• pp.23-31
• /
• 2020

The performance of a downward-irradiation sonoreactor was investigated using calorimetry, KI dosimetry, luminol (Sonochemiluminescence, SCL) method, and aluminium foil erosion method as one of the basic steps for the optimal design of downward-irradiation sonoreactors. The applied frequency was 28 kHz and the input electrical power was 280 - 300 W. The liquid height, from the reactor bottom to the transducer module surface, ranged from 1λ (53.6 mm) to 2λ (107.1 mm). For various liquid heights, the magnitude of calorimetric power and the mass of cavitation-generated I₃^- ion varied significantly. It was found that the additional application of mechanical mixing resulted in higher sonochemical activity, especially in the cavitational active zone, which was induced by violent liquid flow in the reactor. In aluminium foil erosion tests, it was found that less ultrasound energy reached the bottom of the reactor due to the violent liquid flow and no significant sonophysical effect was observed for higher mixing rate conditions (100 and 200 rpm).

• Bulletin of the Korean Chemical Society
• /
• v.32 no.6
• /
• pp.1945-1950
• /
• 2011

The pyridinolysis of methyl phenyl phosphinic chloride is investigated kinetically in acetonitrile at -20.0 $^{\circ}C$. The Hammett and Br${\o}$nsted plots for substituent X variations in the nucleophiles are biphasic concave downwards with a break point at X = H, and unusual positive ${\rho}_X$ (= 2.94) and negative ${\beta}_X$ (= -0.48) values are obtained for the strongly basic nucleophiles. A stepwise mechanism with a rate-limiting step change from bond breaking for the weakly basic pyridines to bond formation for the strongly basic pyridines is proposed on the basis of biphasic concave downward Hammett and Br${\o}$nsted plots. Unusual positive ${\rho}_X$ and negative ${\beta}_X$ values are rationalized by the isokinetic relationship. The pyridinolyses and anilinolyses of four $R_1R_2$P(=O)Cl-type substrates, dimethyl, diethyl, methyl phenyl, and diphenyl phosphinic chlorides in acetonitrile are compared to obtain systematic information on phosphoryl transfer reaction mechanism. The combination of the two ligands, Me and Ph, shows unexpected kinetic results for both the anilinolysis and pyridinolysis: greatest magnitude of $k_H/k_D$ (= 2.10) involving deuterated anilines $[XC_6H_4NH_2(D_2)]$ for the anilinolysis, and exceptionally fast rate and biphasic concave downward free energy correlation for the pyridinolysis.

• Journal of Advanced Marine Engineering and Technology
• /
• v.24 no.2
• /
• pp.57-62
• /
• 2000

The effect of exhaust gas recirculation(EGR) on the characteristics of exhaust gas emissions, and SFC are experimentally investigated by four-cylinder, four-cycle and direct injection marine diesel engine. In order to reduce the soot contents in the recirculated exhaust gas to intake system of the engines, a soot removal system of a cylinderical-type scrubber is specially designed and manufactured for the experimental system. (1) SFC is increased in downward convex curve style with increasing excess air ratio, it is increased with increasing EGR rate at the same excess air ratio. (2) NOx emission is reduced in downward convex curve style with increasing excess air ratio, it is reduced with increasing EGR rate at the same excess air ratio. (3) Soot emission is decreased in downward convex curve style with increasing excess air ratio, it is reduced with increasing EGR rate at the same excess air ratio. (4) CO emission is increased in nearly straight line style with increasing excess air ratio, it is increased with increasing EGR rate at the same excess air ratio. (5) HC emission is not constant tendency with increasing excess air ratio, it is increased with increasing EGR rate at the same excess air ratio.

• Atmosphere
• /
• v.25 no.3
• /
• pp.461-472
• /
• 2015

The sudden stratospheric warming (SSW), which is characterized by an abrupt increase of polar stratospheric temperature by several tens of degrees in a week, has been known to affect tropospheric weather and climate on sub-seasonal time scale in the boreal winter. Such downward coupling has been often examined in North Atlantic and Europe, but rarely examined in East Asia. In this study, by applying the two definitions of SSW to the reanalysis data, the possible impacts of the SSW events on the surface air temperature (SAT) and tropospheric circulation in East Asia are analyzed. It is found that Eurasian continent, including Siberia and the Northeast Asia, tends to experience anomalously cold SAT for up to sixty days after the SSW events. The resulting SAT anomalies largely resemble those associated with negative Artic Oscillation. However, over East Asia, SSW-related SAT change is weak and not statistically significant. Only during the extreme SSW events when the downward coupling between the stratosphere and troposphere is strong, East Asia exhibits significantly cold SAT anomalies. This relationship is presented by grouping SSW events into those followed by cold SAT anomalies over East Asia and those by warm anomalies for varying threshold values of the SSW events.

• Nuclear Engineering and Technology
• /
• v.38 no.2
• /
• pp.139-146
• /
• 2006

An experimental study was performed to evaluate the effects of surface coating and an enhanced insulation structure on the downward facing boiling process and the critical heat flux on the outer surface of a hemispherical vessel. Steady-state boiling tests were conducted in the Subscale Boundary Layer Boiling (SBLB) facility using an enhanced vessel/insulation design for the cases with and without vessel coatings. Based on the boiling data, CHF correlations were obtained for both plain and coated vessels. It was found that the nucleate boiling rates and the local CHF limits for the case with micro-porous layer coating were consistently higher than those values for a plain vessel at the same angular location. The enhancement in the local CHF limits and nucleate boiling rates was mainly due to the micro-porous layer coating that increased the local liquid supply rate toward the vaporization sites on the vessel surface. For the case with thermal insulation, the local CHF limit tended to increase from the bottom center at first, then decrease toward the minimum gap location, and finally increase toward the equator. This non-monotonic behavior, which differed significantly from the case without thermal insulation, was evidently due to the local variation of the two-phase motions in the annular channel between the test vessel and the insulation structure.

• Nuclear Engineering and Technology
• /
• v.29 no.4
• /
• pp.336-347
• /
• 1997

During postulated severe accidents in Light water Reactors, molten corium which was ejected from the reactor vessel bottom, may erode the concrete basemat of the containment and there by threaten the containment integrity. This study experimentally examines the molten core-concrete interaction (MCC) using 20kg of thermite melt (Fe + $Al_2$O$_3$) and the concrete, used in Yonggwang Nuclear Power Plant Units 3 and 4 (YGN 3 & 4) in Korea. The measured data are the downward heat fluxes, concrete erosion rate, gases and particle generation rates during MCCI. Transient results ore compared with those of TURCIT experiment conducted by SNL in USA. The peak downward heat flux to the concrete was measured to be about 2.1㎿/$m^2$. The initial concrete erosion rate was 175cm per hour, decreasing to 30cm per hour. It was shown from the post-test that the erosion was progressed downward up to 18mm in the concrete slug.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.22 no.12
• /
• pp.1702-1714
• /
• 1998

Removal of spilled oil over the sea and the river has become one of the urgent problems in these days. Removing oil using mechanical devices was recommended because chemical dispersion could cause the secondary contamination in the environment. In the present study a series of experiments were carried out to study the effect of operating conditions, especially, the angle between the belt and the fluid surface on the rate of recovery for the spilled oil using a belt skimmer. Three different types of operation, namely, upward pickup, downward pickup and up-and-downward pickup situations have been investigated for various contact angles, belt speeds and oil thicknesses to find the effects on the recovery rate. The highest rate of oil recovery was found in the case of a contact angle of $45^{\circ}$ and downward pickup. Furthermore, an optimal belt speed was found to reach the saturated recovery rate for a given oil thickness.

• International Journal of Human Ecology
• /
• v.15 no.2
• /
• pp.69-80
• /
• 2014

Guided by the exchange model, altruistic model, intergenerational solidarity theory, and cultural contexts, this study explored the determinants of financial intergenerational transfers between older parents and adult children in South Korea. We examined 18,820 parent-child dyads by using random-effects models on the first wave of the Korean Longitudinal Study of Ageing (KLoSA) data. Findings showed that downward financial intergenerational transfers were consistent with the self-interest exchange model but upward transfers did not support microeconomic theories. Family solidarity theory was generally supported by downward transfers but geographical proximity was not positively associated with upward transfers. Lastly, cultural contextual variables such as marital status, birth order, and sex of a child were found to be significant. Parents tended to both provide and receive more financial support from unmarried children than from married children. Within the same marital status, the hierarchy existed in order of the first-born son, the second or later sons, and daughters when it came to downward financial transfers. Regarding upward financial transfers, the preference in order was more complicated. The findings of this study help in understanding the intergenerational financial transfers in the Korean context.