• Bulletin of the Korean Chemical Society
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• 제24권4호
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• pp.446-452
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• 2003

Some new nanohybrid materials have been synthesized by intercalating the oxotitanium(IV) meso-tetrakis(4- sulfonatophenyl) porphyrin$(O=Ti^{(IV)} TSPP)$ into the Zn/Al layered double hydroxides (LDHs), and their structures and photophysical properties have been investigated by various laser spectroscopic techniques. According to the XRD pattern of the synthesized nanohybrid materials, the macrocycle plane of $O=Ti^{(IV)}$ TSPP are grafted perpendicular to the LDH layers. The $O=Ti^{(IV)}$ TSPP-intercalated LDH exhibits band broadening of the absorption spectrum and a blue shift of Q-band as compared to that observed in solution. Resonance Raman spectral measurements demonstrate that the positively charged LDHs give rise to a slight decrease of the electronic density of the porphyrin ring accompanying a small change of the electronic distribution of the $O=Ti^{(IV)}$ TSPP. Consequently the LDH environment affects the energies of the two highest occupied molecular orbitals (HOMOs) of the $O=Ti^{(IV)}$) TSPP, $a_{1u}$ and $a_{2u}$, producing a mixed orbital character. Being consistent with these electronic structural changes of $O=Ti^{(IV)}$ TSPP in LDH, both the fluorescence spectral change and the fsdiffuse reflectance transient measurements imply that the photoexcitation of the $O=Ti^{(IV)}$ TSPP intercalated into LDH undergoes fast relaxation to the O=Ti(IV) $TSPP^+-LDH^- $charge transfer (CT) state within a few picoseconds, followed by a photoinduced electron transfer between the O=Ti(IV) TSPP and LDHs with a rate constant greater than %1×10^{10}S^{-1}$. No evidence is found for back electron transfer. In conclusion, the $O=Ti^{(IV)}$ TSPP intercalated LDH seems to be a possible candidate for an artificial reaction center for an efficient solar energy conversion system.

• 한국정보과학회논문지:소프트웨어및응용
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• 제33권12호
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• pp.1022-1030
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• 2006

위치 인식은 유비쿼터스 컴퓨팅 환경상의 중요한 부분이지만 많은 연구에도 불구하고 아직 완벽한 시스템은 존재하지 않는 상황이다. 본 연구에서는 다양한 위치 추적 시스템 중 가장 널리 사용되는 RFID 시스템을 이용하지만 수신된 RSSI 신호는 리더와 태그 안테나의 방향, 각도, 간섭에 매우 민감하여 기존 알고리즘인 파티클 필터를 이용하면 정확한 위치 추정이 힘들다. 이를 극복하기 위해, 본 연구에서는 이중 구조의 파티클 필터를 가진 강인한 위치 추적 시스템을 제안한다. 이 시스템은 하단부에서 회귀분석이나 SVM 분류기법을 이용하여 대략적인 위치를 확인한 다음, 상단부에서 파티클 필터를 이용하여 위치, 속도, 방향을 추정하는 계층적 구조를 갖고 있다. 그리고 계층 구조상에 움직임 특성이 갖는 여러 제약 사항을 반영하여 위치 추정 성능을 향상시킨다. 제안한 위치 추정 시스템을 실제 상황에 적용하고자 리더와 서버간을 스타 메쉬 네트워크로 연결하여 태그를 소지한 사람과 물체의 위치를 제안한 알고리즘을 이용하여 추정하였다. 실험 결과 제안한 위치 추적 시스템이 기존의 파티클 필터를 이용한 시스템보다 정확한 위치 추정 성능을 보임을 확인하였고 지하 시설물이 복잡하게 놓여있는 매우 열악한 운영 환경상에서도 실시간 동작을 통해 그 유용성이 입증되었다.

• International journal of advanced smart convergence
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• 제2권2호
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• pp.16-18
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• 2013

In this paper, we develop a method to design a flexible thin film audio systems utilizing Polyvinylidene fluoride. The system we designed showed the properties of increased transparency and sound pressure levels. As an input terminal transparent oxide thin film is adopted. In order to provide dielectric insulation, a transparent insulating oxide thin film is coated to obtain double -layered structure. In the range of visible light, the output from the output of the system showed an increased and improved sound pressure level. The piezoelectric polymer film of polyvinylidene fluoride (PVDF) is used to produce mechanical vibration due to the applied electrical voltage signal. An analog electric voltage signal is transformed into sound waves in the audio system.

• International Journal of Internet, Broadcasting and Communication
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• 제6권1호
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• pp.13-15
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• 2014

We develop a method to fabricate a flexible thin film audio systems using polyvinylidene fluoride(PVDF). The system we designed showed the properties of increased flexibility, transparency, and sound pressure levels. As an input port of two terminals, transparent oxide thin film with a low resistivity is adopted. In order to provide dielectric insulation, a transparent insulating oxide thin film is coated to obtain double-layered structure. In the range of visible light, the output from the output of the system showed a increased and improved sound pressure level. The piezoelectric polymer film of PVDF is used to produce mechanical vibration due to the applied electrical voltage signal. An analog electric voltage signal is transformed into sound waves in the audio system.

• 한국철도학회논문집
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• 제15권4호
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• pp.315-322
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• 2012

터널 내에서 고속철도 차량의 실내소음은 개활지 대비 5dB~7dB정도 증가한다. 그 원인은 터널 내 차체 외부의 음향 인텐시티가 급격히 증가하기 때문인데, 특히, 측면재의 외부에서는 개활지에 비해서 음향 인텐시티의 증가가 가장 크다. 따라서 터널 내에서는 차체의 측면을 통하여 음향파워의 투과 전달이 커질 가능성이 상당히 높다. 본 논문에서는 현재 개발중인 차세대 고속 철도차량의 터널 내 실내소음을 저감시키기 위한 종합적인 차음 전략을 제시하고자 한다. 이를 위하여 차체의 주요 차음재인 바닥 적층재, 측면 적층재 및 복층 유리창의 시편을 제작하여 ASTM E2249-02에 근거하여 투과손실 측정한다. 측정 데이터에 근거하여 차음 성능상의 문제점을 진단하고, 차음성능 향상을 위한 층별 개선 방안과 적층 구조의 개선 방안을 제시한다.

• 한국지하수토양환경학회지:지하수토양환경
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• 제27권4호
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• pp.49-62
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• 2022

The magnesium and iron-based layered double hydroxide (Mg-Fe LDH) was synthesized by the co-precipitation process and the bead type LDH (BLDH, 5~6 mm in diameter) was manufactured by using the Mg-Fe LDH and the starch as a binder. To evaluate the feasibility of the BLDH as the As stabilizer in the soil, various experiments were performed and the As stabilization efficiency of the BLDH was compared to that of powdered type LDH (PLDH, <149 ㎛ in diameter). For the As sorption batch experiment, the As sorption efficiency of both of the PLDH and the BLDH showed higher than 99%. For the stabilization experiment with soil, the As extraction reducing efficiency of the PLDH was higher than 87%, and for the BLDH, it was higher than 80%, suggesting that the BLDH has similar the feasibility of As stabilization for the contaminated soil, compared to the PLDH. From the continuous column experiments, when more than 7% BLDH was added into the soil, the As stabilization efficiency of the column maintained at over 91% for 7 pore volume flushing (simulating about 21 months of rainfall) and slowly decreased down to 64% after that time (to 36 months) under the non-equilibrium conditions. Results suggested that more than 7% of BLDH added in As-contaminated soil could be enough to stabilize As in soil for a long time. The main As fixation mechanisms on the LDH were also identified through the X-ray fluorescence (XRF), the X-ray diffraction (XRD), and the Fourier transform infrared (FT-IR) analyses. Results showed that the LDH has enough of an external surface adsorption capacity and an anion exchange capability at the interlayer spaces. Results of SEM/EDS and BET analyses also supported that the Mg-Fe LDH used in this study has sufficient porous structures and outer surfaces to fix the As. The reduction of carbonate (CO₃^2-) and sulfate (SO₄^2-) anions in the LDH after the reaction between As and the LDH was observed through the FT-IR, the XRF, and the XRD analyses, suggesting that the exchange of some of these anions with the arsenate (H₂AsO₄^- or HAsO₄^2-) occurs at the LDH interlayers during the stabilization process in soil.

• 자원환경지질
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• 제56권1호
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• pp.23-53
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• 2023

본 리뷰 논문에서는 지금까지 한국학술지인용색인(KCI)에 발표된 이중층수산화물(LDH) 관련 모든 논문을 조사하여 LDH를 대상으로 한 국내의 연구동향을 분석하였다. LDH를 주제로 한 연구는 2002년 처음 KCI에 발표된 이후 2023년 1월까지 총 160편의 논문이 발표되었으며, 최근 10년 동안 급격히 증가한 특징을 보였다. 총 31개 학문분야 중 상위 5개 분야는 화학공학, 화학, 재료공학, 환경공학, 그리고 물리학 순으로 나타났으며, 이중 화학공학이 71편으로 10편 내외의 다른 분야에 비해 압도적으로 높았다. 각 논문들은 구체적인 소재 응용 연구내용에 기반하여 15개 연구분야로 재분류 되었으며, 그 결과 상위 5개 분야는 환경정화소재, 고분자촉매소재, 배터리소재, 의약의학소재, 그리고 기초 이화학특성 순으로 나타났다. 이러한 조사 결과는 환경정화소재, 고분자촉매, 그리고 배터리 등의 기능 개선을 위한 화학공학 및 화학 분야에서의 LDH 소재 응용 연구가 활발하게 진행되고 있음을 시사한다. 이해 비해 화장품, 환경센서 그리고 농업소재로서의 LDH의 응용은 아직 미비한 단계지만 시장잠재성과 고효율-친환경 트랜드를 고려할 때 향후 떠오르는 연구분야로 주목할 만 하다. 재분류 된 모든 논문들은 응용소재, 핵심연구성과, 사용된 LDH의 특징과 합성법 등의 정보를 포함하여 표와 보충자료에 요약 정리되었다. 본 리뷰 논문에서 최초 제공한 국내 LDH에 대한 전반적인 연구 동향과 관련 세부자료들을 통해 향후 LDH를 활용한 연구방향 설계와 자원·에너지 및 환경분야에서의 효율적인 정책 제안에 도움을 줄 수 있을 것으로 기대한다.

• 생물환경조절학회지
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• 제25권4호
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• pp.270-276
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• 2016

This study analysed overall heat transfer coefficient, heat transmission, and rate of indoor air heating provided by water curtain in order to determine the heat transfer characteristic of double-layered greenhouse equipped with a water curtain system. The air temperatures between the inner and outer layers were determined by the water flow rate and inlet water temperature. Higher water flow rate and inlet water temperature resulted in the increased overall heat transfer coefficient between indoor greenhouse air and water curtain. However, it was found that with higher levels of water flow rate and inlet water temperature, indoor overall heat transfer coefficient was converged about $10W{\cdot}m^{-2}{\cdot}^oC^{-1}$. The low correlation of overall heat transfer coefficient between water curtain and air within double layers was likely because the combination of greenhouse shape, wind speed and outdoor air temperature as well as water curtain affected the heat transfer characteristics. As water flow rate and inlet water temperature increased, the heat transferred into the greenhouse by water curtain also tend to rise. However it was demonstrated that the rate of heat transmission from water curtain into greenhouse with water curtain system using underground water was accounted for 22% to 28% for total heat lost by water curtain. The results of this study which quantify heat transfer coefficient and net heat transfer from water curtain may be a good reference for economical design of water curtain system.

• 한국공간구조학회논문집
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• 제2권2호
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• pp.69-76
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• 2002

The basic systems of spatial structures such as shells, membranes, cable-nets and tensegrity structures have been developed to create the large spaces without column. But there are some difficulties concerning structural stability, surface formation and construction method. Tensegrity systems are flexible structures which are reticulated spatial structures composed of compressive members and cables. The rigidification of tensegrity systems is related to selfstress states which can be achieved only when geometrical and mechanical requirements are simultaneously satisfied. In this paper, the force density method allowing form-finding for tensegrity systems is presented. And various modules of unit-structures are investigated and discussed using the force density method. Also, a model of double-layered single curvature arch with quadruplex using supplementary cable is presented.

• 한국미생물생명공학회:학술대회논문집
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• 한국미생물생명공학회 2003년도 2003 Annual Meeting, BioExhibition and International Symposium
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• pp.129-131
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• 2003

Recombinant bioluminescent bacteria and cultured human cells were applied for toxicogenomic analysis of environmentally hazardous chemicals. Recombinant bioluminescent biosensing cells were used to detect and classify the toxicity caused by various chemicals. Classification of toxicity was realized based upon the chemicals' mode of action using DNA-, oxidative-, protein, and membrane-damage sensitive strains. As well, a simple double-layered cell culture system using Caco-2 cells and Hep G2 cells, which mimic the metabolic processes occurring in humans, such as adsorption through the small intestine and biotransformationin both the small intestine and the liver, was developed to investigate the toxicity of hazardous materials to humans. For a more in-depth analysis, a DNA microarray was used to study the transcriptional responses of Caco-2 and Hep G2 cells to benzo〔a〕pyrene.