• 한국전자파학회논문지
• /
• 제21권2호
• /
• pp.194-201
• /
• 2010

본 논문에서는 CDMA/RFID 주파수 격리도 향상을 위해 double split ring resonator(DSRR)을 이용한 주파수 선택적 표면(FSS)을 설계하였다. 제안된 FSS의 단위 셀 구조는 외부 SRR과 내부 SRR로 구성되며, 이 두 SRR의 gap은 같은 방향에 위치한다. SRR의 gap 간격 및 line 두께 등을 조절하여 전체적인 크기를 유지하면서 공진 주파수 및 스커트 특성을 조절할 수 있다. 동작 주파수에서 제안된 SRR의 필드는 magneto-dielectric SRR과 다른 방향을 가진다. 한 층은 $9{\times}9$ 단위 셀로 구성되어 있으며, 50 mm 간격을 두고 다른 층이 위치해 있다. 시뮬레이션 결과를 검증하기 위해 패치 안테나 및 FSS를 제작했으며, 측정 결과는 시뮬레이션 결과와 유사한 경향을 보인다. 단위 셀의 저지 대역에서의 전기적 크기는 $0.110\;{\lambda}{\times}0.110\;{\lambda}{\times}0.002\;{\lambda}$로 다이폴 FSS에 비해 소형이며, 지지대를 포함한 2층 FSS의 크기는 $1.058\;{\lambda}{\times}1.058\;{\lambda}{\times}0.153\;{\lambda}$이다. 측정 결과 CDMA 대역의 이득이 유지되며, RFID 대역에서 6.9 dB 이득이 감소하였다.

• 한국소성가공학회:학술대회논문집
• /
• 한국소성가공학회 2006년도 춘계학술대회 논문집
• /
• pp.377-380
• /
• 2006

Manufacturing process of Ti-6Al-4V alloy billet was investigated with FEM simulation and experimental analysis. Before the breakdown process of Ti-6Al-4V alloy ingot, FEM simulation for the breakdown processes of Ti-6Al-4V alloy ingot was used to calculate the forging load and state variables such as strain, strain rate and temperature. In order to breakdown the ingot structure and make an equiaxed structure billet, two different processes were employed for a VAR/VAR processed Ti-6Al-4V alloy ingot. Firstly, the ingot was cogged in single-phase $\beta$ field at the temperature of $1,100^{\circ}C$. In the process, the coarse and inhomogeneous structure developed by the double melting process was broken down. The second breakdown was performed by upsetting and cogging processes in $\alpha+\beta$ phase field to obtain the microstructure of fine equixed $\alpha$ structure in the matrix of transformed $\beta$. Finally, the mechanical properties of Ti-6Al-4V alloy billet made in this work were compared with those of other billet and ring product.

• Bulletin of the Korean Chemical Society
• /
• 제28권6호
• /
• pp.941-946
• /
• 2007

Bacillus halodurans O-methyltransferase (BhOMT) is a S-adenosylmethionine (SAM or AdoMet) dependent methyltransferase. Three dimensional structure of the BhOMT bound to S-adenosyl-L-homocysteine (SAH or AdoHcy) has been determined by comparative homology modeling. BhOMT has 40% sequence identity with caffeoyl-CoA 3-O-methyltransferase (CCoAOMT) from alfalfa. Based on x-ray structure of CCoAOMT, three dimensional structure of BhOMT was determined using MODELLER. The substrate binding sites of these two proteins showed slight differences, but these differences were important to characterize the substrate of BhOMT. Automated docking study showed that four flavonoids, quercetin, fisetin, myricetin, and luteolin which have two hydroxyl groups simultaneously at 3'- and 4'-position in the B-ring and structural rigidity of Cring resulting from the double bond characters between C2 and C3, were well docked as ligands of BhOMT. These flavonoids form stable hydrogen bondings with K211, R170, and hydroxyl group at 3'-position in the Bring has stable electrostatic interaction with Ca2+ ion in BhOMT. This study will be helpful to understand the biochemical function of BhOMT as an O-methyltransferase for flavonoids.

• 한국전자파학회논문지
• /
• 제23권9호
• /
• pp.1058-1064
• /
• 2012

본 논문에서는 기존의 WCDMA 댁내형 중계기 안테나의 격리도를 개선하기 위해 안테나에 적용할 메타 구조 기반의 흡수체를 제안하였다. 제안된 흡수체는 Double Split Ring Resonators(DSRRs) 구조와 Complementary Spiral(CS) 구조로 구성하였다. 메타 구조 기반의 흡수체의 크기는 $9.6mm{\times}9.6mm{\times}1.2mm$이며, 2.2875 GHz에서 약 94 %의 흡수율을 가진다. 제안된 흡수체를 기존의 WCDMA 댁내형 중계기 안테나에 적용한 결과, 85 dB 이상의 격리도 특성을 가지며, 기존의 안테나보다 10 dB 이상 개선하였다. VSWR 특성은 WCDMA 대역 1.92 GHz에서 2.17 GHz 사이에서 2 이하이며, 방사 특성은 E-plane, H-plane 각각 $60^{\circ}{\pm}10^{\circ}$을 가지며, 이득은 6 dBi 이상을 가진다. 제안된 흡수체를 적용한 안테나의 크기는 $90mm{\times}90mm{\times}44.8mm$이다.

• Bulletin of the Korean Chemical Society
• /
• 제30권2호
• /
• pp.445-448
• /
• 2009

This study examined the effect of the uptake of one and two electrons on the atomic structure of three isomers of $C_{20}$ clusters, namely the ring, bowl (corannulene like), and cage (the smallest fullerene). Geometry optimizations were performed using the hybrid density functional (B3LYP) methods for neutral, singly and doubly charged $C_{20},\;{C_{20}}^-,and\;{C_{20}}^{2-}$. These results show that the symmetry of the lowest energies for ring and bowl isomers were not changed, whereas the increasing order of energy for the cage (the smallest fullerene) isomers was changed from $D_{2h}\;<\;C_{2h}\;{\leq}\;C_2\;of\;C_{20}\;through\;Ci\;<\;C_{2h}\;<\;C_2\;<\;D_{2h}\;of\;{C_{20}}^-\;to\;Ci\;<\;C_2\;<\;D_{2h}\;<\;C_{2h}\;of\;{C_{20}}^{2-}$. The reduced symmetry isomers of the cage have comparative energy and the ground state symmetry of the neutral and single and double charged $C_{20}$ decreased with increasing number of electrons taken up in the point of energetics. Interestingly, the difference in energy between the ground state and the next higher energy state of ${C_{20}}^{2-}$ was 3.5kcal/mol, which is the largest energy gap of the neutral, single anion and double anion of the cage isomers examined.

• Journal of Electrical Engineering and Technology
• /
• 제12권1호
• /
• pp.385-395
• /
• 2017

A new digitized decoupled dual-axis micro dynamically tuned gyroscope with three equilibrium rings (TMDTG) is proposed which can eliminate the constant torque disturbance (CTD) caused by the double rotation frequency of a driving shaft with a micro dynamically tuned gyroscope with one equilibrium ring (MDTG). A mechanical and kinematic model of the TMDTG is theoretically analyzed and the structure parameters are optimized in ANSYS to demonstrate reliability. By adjusting the thickness of each equilibrium ring, the CTD can be eliminated. The digitized model of the TMDTG system is then simulated and examined using MATLAB. Finally, a digitized prototype based on FPGA is created. The gyroscope can be dynamically tuned by adjusting feedback voltage. Experimental results show the TMDTG has good performance with a scale factor of $283LSB/^{\circ}/s$ in X-axis and $220LSB/^{\circ}/s$ in Y-axis, respectively. The scale factor non-linearity is 0.09% in X-axis and 0.13% in Y-axis. Results from analytical models, simulations, and experiments demonstrate the feasibility of the proposed TMDTG.

• Archives of Pharmacal Research
• /
• 제19권3호
• /
• pp.246-247
• /
• 1996

In the previous reports (Park et al., 1991, and 1993), we described the synthesis and analgesic effects of various homovanillic amides as analogs of capsaicin. In the study, we tried to enhance the analgesic actvity of capsaicin by structural modification. Our study has been performed in three directions. First, the amide bond of capsaicin was transposed. Second, a phenyl ring was introduced to replace a double bond of capsaicin. Finally, aminoethylation was performed on 4-hydroxy group of capsaicin to improve oral bioavailability. These studies have led to N-(3-phenylpropyl)homovanillic amide 2 which has high analgesic activity. Our continuing efforts in this area have focused on the introduction of various substituents on the phenyl ring of 2 as well as their pharmacological studies. We report herein the synthesis of homovanillic amide derivatives and their analgesic activity.

• Bulletin of the Korean Chemical Society
• /
• 제29권7호
• /
• pp.1311-1314
• /
• 2008

Bacillus halodurans O-methyltransferase (BhOMT) is an S-adenosylmethionine dependent methyltransferase. In our previous study, three dimensional structure of the BhOMT has been determined by comparative homology modeling and automated docking study showed that two hydroxyl groups at 3'- and 4'-position in Bring and structural rigidity of C-ring resulting from the double bond characters between C2 and C3 of flavonoid, were key factors for interaction with BhOMT. In the present study, BhOMT was cloned and expressed. Binding assay was performed on purified BhOMT using fluorescence experiments and binding affinity of luteolin, quercetin, fisetin, and myricetin were measured in the range of $10^7$. Fluorescence quenching experiments indicated that divalent cation plays a critical role on the metal-mediated electrostatic interactions between flavonoid and substrate binding site of BhOMT. Fluorescence study confirmed successfully the data obtained from the docking study and these results imply that hydroxyl group at 7-position of luteolin, quercetin, fisetin, and myricetin forms a stable hydrogen bonding with K211 and carboxyl oxygen of C-ring forms a stable hydrogen bonding with R170. Hydroxyl group at 3'-and 4'-position in the B-ring also has strong $Ca^{2+}$ mediated electrostatic interactions with BhOMT.

• Bulletin of the Korean Chemical Society
• /
• 제34권9호
• /
• pp.2640-2644
• /
• 2013

The all-hydrocarbon i,i+4 stapling system using an oct-4-enyl crosslink is one of the most widely employed chemical tools to stabilize an ${\alpha}$-helical conformation of a short peptide. This crosslinking system has greatly extended our ability to modulate intracellular protein-macromolecule interactions. The helix-inducing property of the i,i+4 staple has shown to be highly dependent on the length and the stereochemistry of the oct-4-enyl crosslink. Here we show that changing the double bond position within the i,i+4 staple has a considerable impact not only on the formation of the crosslink but also on ${\alpha}$-helix induction. The data further increases the understanding of the structure-activity relationships of this valuable chemical tool.

• ETRI Journal
• /
• 제39권1호
• /
• pp.69-75
• /
• 2017

This study presents a dual-band 3D frequency selective surface that provides a large degree of freedom in frequency and bandwidth adjustability. The proposed structure is evaluated in terms of its structural parameters, and prototypes are fabricated. The radius of the copper rings and the height of the cylinders are considered, and are shown through full-wave electromagnetic simulations to have a significant effect on the frequency characteristics of the frequency selective surface. The measurement results of the fabricated samples are compared with the simulation results, and a satisfactory agreement is obtained.