• Bulletin of the Korean Chemical Society
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• 제13권2호
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• pp.140-145
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• 1992

The excited state intramolecular proton transfer and physical properties of 7-hydroxyquinoline are studied in various solutions and heterogeneous systems by measuring steady state and time-resolved fluorescence, reflection and NMR spectra. Proton transfer is observed only in protic solvents owing to its requirement of hydrogen-bonded solvent bridge for proton relay transfer. The activation energies of the proton transfer are 2.3 and 5.4 kJ/mol in $CH_3OH$ and in $CH_3OD$, respectively. Dimers of normal molecules are stable in microcrystalline powder form and undergo an extremely fast concerted double proton transfer upon absorption of a photon, consequently forming dimers of tautomer molecules. In the supercage of zeolite NaY, its tautomeric form is stable in the ground state and does not show any proton transfer.

• Journal of Power Electronics
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• 제15권5호
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• pp.1305-1317
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• 2015

Distributed generation systems (DGSs) have been getting more and more attention in terms of renewable energy use and new generation technologies in the past decades. The self-excited induction generator (SEIG) occupies an important role in the area of energy conversion due to its low cost, robustness and simple control. Unlike synchronous generators, the SEIG has to absorb capacitive reactive power from the outer device aiming to stabilize the terminal voltage at load changes. This paper presents a novel static VAR compensator (SVC) called a magnetic energy recovery switch (MERS) to serve as a voltage controller in SEIG powered DGSs. In addition, many small scale SEIGs, instead of a single large one, are applied and devoted to promote the generation efficiency. To begin with, an expandable mathematic model based on a d-q equivalent circuit is created for parallel SEIGs. The control method of the MERS is further improved with the objective of broadening its operating range and restraining current harmonics by parameter optimization. A hybrid control strategy is developed by taking both of the stand-alone and grid-connected modes into consideration. Then simulation and experiments are carried out in the case of single and double SEIG(s) generation. Finally, the measurement results verify that the proposed DGS with SVC-MERS achieves a better stability and higher feasibility. The major advantages of the mentioned variable reactive power supplier, when compared to the STATCOM, include the adoption of a small DC capacitor, line frequency switching, simple control and less loss.

• 에너지공학
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• 제10권4호
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• pp.379-386
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• 2001

본 연구는 산업용 고부하 버너연소에서의 NO$_{x}$ 저감에 관한 실험적 연구이다. 본 연구에서는 NO$_{x}$의 정량적 농도 분포 측정을 위하여 레이저 유동 형광법을 사용하였다. XeCL 엑시머 레이저를 사용하여 NO A-X (0, 0) 진동밴드를 226 nm로 여기하였다. 또한 P$_{21}$+Q$_1$(14.5)/R$_{12}$+Q$_2$(20.5)/P$_1$(23.5) 전이를 여기라인으로 하였으며 다른 간섭의 영향을 최소화 하였다. 본 실험에서 이중선회 확산화염에서의 NO 농도 분포를 측정하였으며, 이 스월버너에서의 화염의 후류에 있어서 NO 농도는 1차/2차 공기비가 증가할 때 감소함을 알수 있었다.

• 대한화학회지
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• 제39권5호
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• pp.338-343
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• 1995

피부에 대한 광증감 효과를 나타내는 소랄렌의 유도체중 8-azapsoralen and 4,4',5'-trimethyl-8-azapsoralen과 티민의 전자상태를 반경험적 분자궤도법으로 고찰하였다. 소랄렌 유도체와 티민 사이의 분자착물 형성에서 가능성 있는 배치를 결정하기 위하여 들뜬 상태의 azapsoralen과 바닥상태의 티민의 전하 이동량을 결정하고, 반응 위치인 3,4-탄소와 4'5'-탄소 이중결합과의 광부가 생성물의 입체구조는 trans-anti형의 Azaps(3,4)<>Thy(5,6) 결합과 4,4',5'-trimethyl-8-azapsoralen (3,4) < > Thymine(5,6) 결합을 형성한다는 사실을 알았다.

• Wind and Structures
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• 제12권2호
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• pp.103-120
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• 2009

Articulated tower platforms due to its compliant nature are more susceptible to the dynamic effects of wind than conventional fixed platforms. Dynamic response analysis of a double hinged articulated tower excited by low frequency wind forces with random waves is presented in this paper. The exposed super structure of the platform, housing the drilling and production facilities is subjected to mean and fluctuating wind loads, while the submerged portion is acted upon by wind driven waves. The fluctuating component of the wind velocity is modeled by Emil Simiu's spectrum, while the sea state is characterized by Pierson-Moskowitz spectrum. Nonlinearities in the system due to drag force, added mass, variable submergence and instantaneous tower orientation are considered in the analysis. To account for these nonlinearities, an implicit time integration scheme (Newmark's-${\beta}$) has been employed which solves the equation of motion in an iterative fashion and response time histories are obtained. The power spectra obtained from random response time histories show the significance of low frequency responses.

• 대한화학회지
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• 제38권6호
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• pp.405-410
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• 1994

들뜬상태의 소랄렌 유도체와 바닥상태의 티민 사이에 형성되는 분자착물의 형태를 분자궤도 함수법으로 고찰하였다. PM3-CI-UHF법으로 계산한 결과는 메틸소랄렌 및 하이드록시소랄렌의 C3-C4 이중결합과 C4'-C5' 이중결합과 티민의 C5-C6 이중결합과 광고리화 반응이 일어남을 프론티어궤도의 상호작용으로 설명하고, 이들 화합물의 들뜬상태에서 전자구조를 구조-활성화 관계로 논의하였다.

• 한국전문물리치료학회지
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• 제3권3호
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• pp.32-43
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• 1996

The purpose of this case study was to introduce functional electrical stimulation(FES) for paraplegic patients. FES provides the ability to rise from sitting to standing, maintenance of a standing position, and the ability to walk with a reciprocal gait. Six channels of electrical stimulation are sufficient for synthesis of a simple reciprocal gait pattern in these patients. During the double-stance phase, knee extensor muscles of both knees are stimulated, providing sufficient support for the body. Only one knee extensor muscle group is excited during the single-stance phase. The swing phase of the contralateral lower extremity is accomplished by eliciting the synergic flexor muscle response through electrical stimulation of afferent nerves. The transition from the double-stance phase to the swing phase is controlled by two hand switches used by the therapist or built into the handles of the walking frame for using by the patient. A twenty-five years old male was with a T9/T9 spinal cord injury due to a traffic accident and admitted to Yonsei Rehabilitation Hospital for comprehensive treatment. After 30 days of training using the Parastep(R) he was able to stand for 10 minutes. After 43 days, he was able to walk and at discharged he could walk for 100 meters.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2012년도 제43회 하계 정기 학술대회 초록집
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• pp.340-341
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• 2012

In this work, we investigated the effects of temperature stress on flatband voltage (VFB) shifts of HfO2-SiO2 double gate dielectrics devices. Fig. 1 shows a high frequency C-V of the device when a positive bias for 10 min and a subsequent negative bias for 10 min were applied at room temperature (300 K). Fig. 2 shows the corresponding plot when the same positive and negative biases were applied at a higher temperature (473.15 K). These measurements are based on the BTS (bias temperature stress) about mobile charge in the gate oxides. These results indicate that the positive bias stress makes no difference, whereas the negative bias stress produces a significant difference; that is, the VFB value increased from ${\Delta}0.51$ V (300 K, Fig. 1) to ${\Delta}14.45$ V (473.15 K, Fig. 2). To explain these differences, we propose a mechanism on the basis of oxygen vacancy in HfO2. It is well-known that the oxygen vacancy in the p-type MOS-Cap is located within 1 eV below the bottom of the HfO2 conduction band (Fig. 3). In addition, this oxygen vacancy can easily trap the electron. When heated at 473.15 K, the electron is excited to a higher energy level from the original level (Fig. 4). As a result, the electron has sufficient energy to readily cross over the oxide barrier. The probability of trap about oxygen vacancy becomes very higher at 473.15 K, and therefore the VFB shift value becomes considerably larger.

• Journal of Photoscience
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• 제9권2호
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• pp.379-381
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• 2002

The major electron transfer cofactors in photosystem II have been studied by pulsed EPR, pulsed electron electron double resonance (PELDOR) and laser excited spin polarized electron spin echo envelope modulation (ESEEM) methods, in non-oriented and oriented photosystem II membranes. Distances between radical pairs were determined trom the observed dipole interaction constants to be 27.3 A for P680-QA, 30 A, etc. with the error within 1 A. Angles between the distance vector and membrane normal was determined by orientation dependence of oriented membranes with the accuracy of 5˚ The results were compared with the recent structural data by X-ray analysis.

• Journal of Advanced Marine Engineering and Technology
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• 제10권4호
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• pp.31-40
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• 1986

With the tendency toward high speed and high pressure in centrifugal pumps, the problem of sub-synchronous vibration has arisen, caused by the hydraulic forces of the working fluid, such as wearring, balance piston, impeller, etc.. These forces can drastically alter the rotor critical speeds and stability characteristics, and can be acted significant destabilizing forces. For preventing such self-excited vibration, the desing of the rotor system needs, which would secure the stability of the machine. In this paper, a procedure is presented for dynamic modeling of rotor-bearing-seal-impeller systems which consist of rigid disks, distributed parameter finite rotor elements and discrete bearings, seals and impellers. A finite element model including the effects of rotatory inertia and gyroscopic moments is developed using the consistent matrix approach. The technique of dynamic matrix reduction is applied to the shaft matrices to reduce them to a set of matrices of dynamic of significantly fewer degrees of freedom. The representation of bearing, seal and impeller elements is in term of linearized stiffness and damping matrices by reasonably small perturbations from equilibrium. The stability behavior of a typical double suction centrifugal pump is presented. Results show the influence of clearance and flow conditions on running speeds and stability characteristics.