• Analytical Science and Technology
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• v.28 no.5
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• pp.317-322
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• 2015

Simultaneous analytical method has developed for the determination of anion biocides in soil by liquid chromatography-tandem mass spectrometry (LC-MS/MS). Chlorite and chlorate in soil were extracted with pure water, and cyanuric acid and sodium dodecylbenzenesulfonate (Na-DBS) were extracted with mobile phase (0.25 mM ammonium formate in 20 mM formic acid : acetonitrile (1:1)). The extract was injected into the LC-MS/MS system after filtration. The method detection limits in this study were 0.04 mg/kg for chlorite, 0.04 mg/kg for chlorate, 0.27 mg/kg for cyanuric acid, and 0.05 mg/kg for Na-DBS, respectively. The method was applied to the analysis of 50 soil samples collected from 40 sites sprayed with biocides and 10 background sites. As a result, anion biocides were not detected in all sites.

• Journal of the Korean Chemical Society
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• v.50 no.3
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• pp.190-195
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• 2006

The critical micelle concentrations (CMC) and the counter ion binding constants (B) in a micellar state of the mixed surfactant systems of sodium dodecylbenzenesulfonate (DBS) with polyoxyethylene(4) lauryl ether (Brij 30) in water were determined as a function of 1 (the overall mole fraction of DBS) by the use of electric conductivity method and surface tensiometer method from 288 K to 308 K. Various thermodynamic parameters (Smo, Hmo, and Gmo) for the micellization of DBS/Brij 30 mixtures were calculated and analyzed from the temperature dependence of CMC values. The measured values of Gomare all negative but the values of Smo are positive in the whole measured temperature region. On the other hand, the values of Hmo are positive or negative, depending on the measured temperature and 1.

• Journal of the Korean Chemical Society
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• v.53 no.5
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• pp.491-498
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• 2009

The critical micelle concentration (CMC) and the counter ion binding constant (B) for the mixed micellizations of DBS (sodium dodecylbenzenesulfonate) with Brij 30 (polyoxyethylene(4) lauryl ether) and Brij 35 (polyoxyethylene (23) lauryl ehter) at 25 ${^{\circ}C}$ in pure water and in aqueous solutions of n-butanol were determined as a function of $\alpha$1 (the overall mole fraction of DBS) by the use of electric conductivity method. Various thermodynamic parameters (Xi, $\gamma$i, Ci, aiM, $\beta$, and ${\Delta}H_{mix}$) were calculated and compared for each mixed surfactant system by means of the equations derived from the nonideal mixed micellar model. There sults show that the molecules of DBS interact more strongly with Brij 35 than Brij 30 and that the DBS/Brij35 mixed system has greater negative deviation from the ideal mixed micellar model than the DBS/Brij 30mixed system.

• Journal of the Korean Ceramic Society
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• v.27 no.1
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• pp.109-117
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• 1990

Magnetite for Water-based ferrofluid was synthesized by air oxidation of aqueous suspension in the pH range 7-12 at $65^{\circ}C$. The optimum condition of magneite formation was delineated by examining various physicochemcial properties such as Fe2+ content, phase characteristics, MHC and $\sigma$max. The point of zero charge of iron oxide powders obtained at various pH conditions were correlated with the oxidation state of Fe in the iron oxide. The magnetite powder prepared at pH 9 ws dispersed using sodium oleate and sodium dodecylbenzenesulfonate (SDBS) as dispersants, and the dispersion characteristics of the magnetite ferrofluid were examined by means of the fraction of solid dispersed, zeta potential data and FT-IR spectrum. A simple calculation on the potential energy of two interacting magnetite particles showed that the dispersion stability was directly correlated with height of the potential energy barrier or the shape of zeta potential.

• The Korean Journal of Rheology
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• v.3 no.2
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• pp.175-185
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• 1991

Sodium octylbenzenesulfonate(SOBS)와 sodium dodecylbenzenesulfonate(SDBS)를 폴리프로필렌(PP) 용융액에 각각 균일하게 서로 다른 함량으로 섞어 넣은 후에 용융압착법 으로 PP 필름을 제조하였다. 저장 점성도(η＇) 저장탄성률(G＇) 및 손실 탄성률(G＂)을 진 동식 레오미터를 사용하여 170~195$^{\circ}C$에서 측정하였다. 실험온도 범위내에서 첨가제를 함유 한 PP와 순PPrks에 Cole-Cole 플롯(G＇에 대한 G＂의 log-log 플롯)에는 차이가 없었다. 그러나 광범위한 전단속도에서 SOBS의 첨가량이 8%를 넘어서면서 η＇과 G＇은 증가하였 다. 이러한 현상은 PP 중에서의 첨가제의 응집효과로 설명되었으며 이것은 SOBS와 SDBS 를 함유하는 PP 필름의 시차 주사열량법 및 주사전자 현미경 관찰결과로 확인되었다. SDBS를 8% 미만 함유하는 PP로부터 섬유의 용융방사가 가능하였으나 SDBS3% 이상 함 유PP 방사섬유는 연신 과정중에 섬유의 절단이 이따금 일어났다. PP 기질내에 있어서의 SDBS의 뜨거운 물에대한 견뢰성을 SDBS와 C. I. Basic blue 41사이의 이온결합 형성 거동 에 바탕을 두어 가시분광법에 의하여 검토하였다.

• Applied Biological Chemistry
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• v.37 no.6
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• pp.480-486
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• 1994

The present series of investigations have been undertaken to know the effective removal method of some pesticides, heavy metals and detergent when the doses of oxidants and coagulant were changed in the treatment process of drinking water containing organic material. Three pesticides, IBP, diazinon and CNP, were removed by about 68 to 100% by treatment of oxidant, $Cl_2$. Especially, diazinon was completely removed by treatment of $Cl_2$ and other oxidants such as $Cl_2,\;KMnO_4\;and\;O_3$. However, butachlor removal measured only 20.3 to 26.7% due to treatment of all oxidant used. A detergent, sodium dodecylbenzenesulfonate, was effectively removed by treatment of $O_3$ but remained stable in the presence of other oxidants. The heavy metals of Cd, Pb, Cu and Zn in water were not affected by treatment of all oxidants used. By changing the concentration of humic matter and the dosage of coagulant, the removal of heavy metals was increased according to the increase of coagulant dosage, and decreased when increasing the concentration of humic matter, whereas the pesticides and detergent were not effectively removed.

• Corrosion Science and Technology
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• v.18 no.6
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• pp.243-252
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• 2019

The pitting corrosion and inhibition studies of AZ31B magnesium alloy were investigated in the alkaline solution (pH12) with chloride and inhibitors. The corrosion behavior of passive film with/without Cl^- in the alkaline electrolyte were conducted by polarization curve and immersion tests in the presence of various additives (inhibitors) to clarify the inhibition efficiency of pitting corrosion at higher potential region. Critical concentration of pitting corrosion for Mg alloy was evaluated with 0.005 M NaCl in 0.01 M NaOH on the anodic polarization behavior. Critical pitting of AZ31B Mg alloy in 0.01 M NaOH is a function of chlorides; E_pit = - 1.36 - 0.2 log [Cl^-]. When the Sodium Benzoate (SB) was only used as an inhibitor, a few metastable pits developed on the Mg surface by an immersion test despite no pitting corrosion on the polarization curve meaning that adsorption of SB on the surface is insufficient protection from pitting corrosion in the presence of chloride. The role of SB and Sodium Dodecylbenzenesulfonate (SDBS) inhibitors for the Mg alloy surface in the presence of chloride was suppressed from pitting corrosion to co-adsorb on the Mg alloy surface with strong formation of passive film preventing pitting corrosion.

• Elastomers and Composites
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• v.52 no.4
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• pp.257-265
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• 2017

In this work, CR (Chloroprene Rubber) was emulsified by phase-inversion emulsification with nonionic surfactants (NP-1025, LE-1017, and OP-1019) and an anionic surfactant (SDBS; sodium dodecylbenzenesulfonate), and its stabilization was investigated through a study of its adsorption characteristics, zeta potential, and flow behavior. As the amount of the mixed surfactant increased, the droplet size decreased, resulting in the increase of viscosity. In particular, a CR emulsion with a lower absorbance in the UV spectrum exhibited the highest zeta potential. The results of this experiment showed that the CR emulsion prepared using (LE-1017) and SDBS was the most stable. In this study, calcium hydroxide and aluminum hydroxide were added to enhance the mechanical properties of the CR emulsion, and the relationship between tensile strength, tear strength and surface free energy were investigated. The tensile and tear strengths of the CR emulsion incresed as the amount of calcium hydroxide and aluminum hydroxide increased. The highest tensile and tear strengths and surface free energy were observed for additions of 1.0% calcium hydroxide and 0.80% aluminum hydroxide, respectively. It was concluded that the interfacial bonding strength was improved by the even dispersion of calcium hydroxide and aluminum hydroxide in the CR emulsion.

• Journal of Powder Materials
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• v.24 no.2
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• pp.141-146
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• 2017

$Bi_2Te_3$ powders are recovered by wet chemical reduction for waste n-type thermoelectric chips, and the recovered particles with different morphologies are prepared using various surfactants such as cetyltrimethylammonium bromide (CTAB), sodium dodecylbenzenesulfonate (SDBS), and ethylenediaminetetraacetic acid (EDTA). When citric acid is added as the surfactant, the shape of the aggregated particles shows no distinctive features. On the other hand, rod-shaped particles are formed in the sample with CTAB, and sheet-like particles are synthesized with the addition of SDBS. Further, particles with a tripod shape are observed when EDTA is added as the surfactant. The growth mechanism of the particle shapes depending on the surfactant is investigated, with a focus on the nucleation and growth phenomena. These results help to elucidate the intrinsic formation mechanism of the rod, plate, and tripod structures of the $Bi_2Te_3$ recovered by the wet reduction process.

• Journal of the Korean Chemical Society
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• v.55 no.3
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• pp.379-384
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• 2011

The critical micelle concentration (CMC) and the counter ion binding constant (B) for the mixed micellizations of DBS (sodium dodecylbenzenesulfonate), SDS (sodium dodecylsulfate), and Brij 30 (polyoxyethylene(4) lauryl ether) at $25^{\circ}C$ in pure water were determined by the use of electric conductivity and surface tension measuring methods. Various thermodynamic parameters ($X_i,\;{\gamma}i,\;C_i,\;a_i^M,\;{\beta}$, and ${\Delta}H_{mix}$) were calculated and compared with each other mixed surfactant system by means of the equations derived from the nonideal mixed micellar model. The results show that the SDS molecule interacts more strongly with Brij 30 molecule than DBS molecule and that the SDS/Brij 30 mixed surfactant system has the greatest negative deviation from the ideal mixed micellar model and the SDS/DBS mixed system has followed almost the ideal mixed micellar model.