• Title/Summary/Keyword: Distribution weight

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Distribution and Origin of Polycyclic Aromatic Hydrocarbons (PAHs) in Surface Sediments Inside Hallim Harbor of Jeju Island, Korea

  • Moon, Sang-Hee;Lee, Min-Gyu;Kam, Sang-Kyu
    • Journal of Environmental Science International
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    • v.12 no.11
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    • pp.1145-1157
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    • 2003
  • The surface sediments inside Hallim Harbor, one of the major harbors of Jeju Island, were sampled three times (June, September and December, 2001) and analyzed for 16 polycyclic aromatic hydrocarbons (PAHs), recommended by US-EPA as priority pollutants, to assess their distribution levels and to suggest their possible origins. The concentrations of PAHs ranged from 19 to 496 ng/g on a dry weight basis with a mean value of 245 ng/g, and the levels were low to moderate in comparison with other areas in the world. Based on comparisons of individual and total PAH concentrations with effects-based and equilibrium partitioning-based on sediment quality guidelines, the potential for the biological effects were expected to be low. The sedimentary PAHs may be correlated with organic carbon and mud contents to some extent. From the examinations of the four PAH origin indices, such as LMW/HMW (low molecular weight 2-3 ring PAHs over high molecular weight 4-6 ring PAHs), phenanthrene/anthracene ratio, fluoranthene/pyrene ratio, chrysene/benzo〔a〕anthracene ratio, it can be concluded that the sediment PAH contaminations were ascribed to both pyrolytic and petrogenic origins.

Investigation of the heavy-weight floor impact sound field in a testing building with bearing wall structure (벽식구조 표준시험동에서 중량충격음장에 관한 연구)

  • Yoo, Seung-Yup;Lee, Sin-Young;Jeon, Jin-Yong
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2007.05a
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    • pp.969-973
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    • 2007
  • The heavy-weight floor impact sound field of the receiving room in a testing building with bearing wall structure was investigated using bang machine and impact ball. The sound field was investigated through the impact sound pressure level distribution by the field measurement and computational analysis. Predicted sound field using the computational analysis agree with measurement result in the low frequency band. Result shows that standard deviations of the single number rating value are about 2dB in each impact source. Particularly, impact sound pressure level at 120cm height in 63Hz octave band was 5dB lower than spatial averaging value. It was found that receiving positions in the ministry of construction and transportation notice should be reconsidered.

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Distribution of Marine Litters in the Sea Area between Busan and Jeju Island (부산-제주도사이 해역에서 해양폐기물 분포)

  • Kim, Min-Seok
    • Journal of Fisheries and Marine Sciences Education
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    • v.22 no.3
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    • pp.354-361
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    • 2010
  • Author investigated the distribution of debris by a bottom trawler in the eight sea stations over the sea between Busan and Jeju island. 2,118 debris in number and 2,401.5kg in weight were collected. Most of collected debris were fishing gears which seemed to be lost or discarded during operations, and also most of the fishing gears was an eel pot. The densities of debris per hectare in number and weight were 1.21pieces and 2.639kg respectively. Station A was the highest densities compared to other stations, showing 2.7pisces and 4.9kg per hectare in number and weight. The closer to Busan it is, the higher density of debris can be collected.

Strategy for molecular weight distribution control in a batch polymerization reactor system (회분식 중합 반응기에서의 분자량 분포제어 전략)

  • 김인선;유기윤;이현구
    • 제어로봇시스템학회:학술대회논문집
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    • 1993.10a
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    • pp.766-771
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    • 1993
  • A mathematical model is developed to represent the batch reactor for free radical polymerization of PMMA The model is validated by comparing the simulation result with the experimental data. A computational scheme is proposed to determine the trajectory of the reactor temperature that will produce polymer product having the desired molecular weight distribution. For this instantaneous number average chain length and polydispersity are introduced to calculate the reactor temperature. The former is assumed to be a second order polynomial of the sum of the living and dead polymer concentrations. Various reactor temperature, trajectories are observed depending on the reactor conditions and prescribed molecular weight distributions. Fuzzy and PID control algorithms are applied to trace the reactor temperature trajectory. While the PID control gives rise to an overshoot when the trajectory changes its direction, the fuzzy controller yields a more satisfactory performance because it secures information on the trajectory pattern.

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Studies of Purifying Waste Cotton for Esterification & Molecular Weight Distribution Curve of Cellulose Acetate (落綿의 精製 및 이를 原料로 하는 醋酸纖維素의 分子量 分配曲線에 關한 硏究)

  • Kim, Dong-Il;Noh, Ick-Sam
    • Journal of the Korean Chemical Society
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    • v.4 no.1
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    • pp.38-43
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    • 1957
  • Purified cellulosic materials suitable for the production of cellulose esters can be prepared from waste cotton (carding waste from textile mill). The most desirable conditions in purifying waste cotton were obtained. Waxy materials were removed by boiling in 2-3% soda ash solution for more than 30 minutes in open vessel at atmospheric pressure. As for bleaching, it is desirable to use the bleaching powder solution containing 1%, available chlorine for 60 minutes at 35 deg. C. Purified cellulosic material was acetylated to fibrous cellulose triacetate, which was fractionated in the solution of 70% monochloroacetic acid using water as a precipitant, and the degree of polymerizaion and molecular weight of each fraction were measured viscometrically, thereon, molecular weight distribution curve was drawn. Analyzing the shape of this curve, most of the polymers were concentrated on the part of higher degree of polymerization. Purified waste cotton was also analysed, the result was that this cellulosic material can be used as a raw material for cellulose esters and ethers.

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Photo-induced Living Cationic Polymerization of Tetrahydrofuran. III. Synthesis of Poly(THF-co-3-MTHF)

  • Soukil Mah;Choi, Jia;Lee, Hansup;Choi, Soonja
    • Fibers and Polymers
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    • v.1 no.1
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    • pp.1-5
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    • 2000
  • Poly(3-methyltetrahydrofuran)(3-MTHF) and poly(tetrahydrofuran-co-3-MTHF), having very narrow molecular weight distribution were successfully synthesized via photo-induced living cationic polymerization in the presence of diphenyliodonium hexafluorophosphate. Linear relationship between % conversion and number average molecular weight of resulting poly(3-MTHF) in the polymerization of 3-MTHF, carried out at -22$^{\circ}C$, indicates that the 5-membered cyclic oxonium ion, being responsible for the cationic propagation is stabilized by ion pall formation with hexafluorophosphate anion, supplied from the salt. The linear relationship between two parameters, mentioned above was also observed in the copolymerization of 3-MTHF with THF, carried out at 0 and -22$^{\circ}C$. The molecular structures including the copolymer composition and average molecular weight and its distribution is determined by reaction parameters such as monomer feed ratio and reaction temperature.

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MWD of Fractionated Polystyrene in Ultrasound Induced High Pressure Reactor (초음파가 조사된 고압반응기에서 분획된 Polystyrene의 분자량 분포특성)

  • Kim, H.H.;Lee, S.B.;Hong, I.K.
    • Elastomers and Composites
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    • v.32 no.3
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    • pp.173-178
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    • 1997
  • In this study, the ultrasonic irradiation in elevated pressure was used to alter the molecular weight and MWD of polystyrene. The high pressure reactor was filled with 0.5w/v% polystyrene solution, and then it was pressurized from 500psi to 4000psi. The ultrasound was irradiated in 10 minutes at each pressure, and the extract was collected and analyzed by GPC. Molecular weight distribution was predicted by log-normal and Schulz distribution function. The average molecular weight and polydispersity of polystyrene were decreased, as the pressure applied during the ultrasonic irradiation was increase. It was able to fractionate polymer material and control polydispersity by adjusting pressure in the ultrasonic irradiation.

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Analysis of nonionic surfactants and silicone polymers in cosmetic products using Matrix - assisted Laser Desorption/Ionization Time-of- flight Mass Spectrometry

  • Lee, Myoung-Hee;Lee, Gae-Ho;Yoo, Jong-Shin
    • Proceedings of the SCSK Conference
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    • 2003.09b
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    • pp.480-507
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    • 2003
  • A rapid and efficient method for analyzing the nonionic surfactants and silicone polymers, which control the shape and characteristics of cosmetic products and give influence on product quality, has been developed using Matrix-Assisted Laser Desorption Ionization Time of Flight Mass Spectrometry (MALDI- TOF IMS). The MALDI-TOF/MS could easily and effectively determine the molecular weight distribution and monomer units of nonionic surfactants. As a result, creating a library of mass spectrum data of surfactants used in cosmetic products using MALDI-TOF/MS and analyzing surfactants extracted from the products may become a useful method for detailed structural characterization of the surfactants. Furthermore, the MALDI-TOF/MS analysis was effective in obtaining the spectrum of silicone polymers from which the molecular weight distribution could be determined. The repetition units and structural data could also be obtained through molecular mass peaks. Additionally, the monomer ratio and terminal groups as properties of silicone copolymers could be determined

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Effects of Purposeful Exercise Training Program on Symmetrical Posture in Persons with Hemiplegia (목적있는 운동훈련이 편마비 환자의 좌우 대칭적 서기자세에 미치는 영향)

  • Kim, Myoung-Jin
    • Physical Therapy Korea
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    • v.4 no.1
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    • pp.63-69
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    • 1997
  • Asymmetrical posture during static stance has been identified as a common problem in persons with hemiplegia. This study examined the effect of a purposeful exercise training program on symmetrical weight bearing in three adult persons with hemiplegia. Multiple baseline design was used. The intervention program, including ball throwing and catching, rolling ball catching and throwing, and Swiss ball pulling and stopping was introduced for 15 minutes each day during each intervention phase. Quantitative measurement of the weight distribution was taken with the Limloader. Visual inspection and mean of data revealed a significant improvement in symmetrical weight distribution. This result suggests that a purposeful exercise training program can be effective in helping persons with hemiplegia achieve symmetric stances.

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Statistical Analysis of Irrigation Reservoir Water Supply Index (관개용저수지 용수공급지수(IRWSI)의 확률통계 분석)

  • 김선주;이광야;강상진
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.40 no.4
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    • pp.58-66
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    • 1998
  • Irrigation Reservoir Water Supply Index(IRWSI), which can be applied to the effective supply and management of the irrigation water resources, was developed. IRWSI was formulated as resealed nonexceedance probabilities of two hydrologic components : reservoir storage ratio and precipitation. To generate nonexceedance probability of hydrologic component, it was important to define the optimal one among the various probability distribution function in the state of nature. To define an optimal probability distribution, in this study, four types of probability distribution function were tested by the K-S fitting, and for the calculation of IRWSI, reservoir storage ratio(%) and precipitation used Normal distribution & Gamma distribution, respectively. In this study, the weight coefficients of a and b for each hydrologic component, which is precipitation and reservoir storage ratio, was decided as 0.8 and 0.2, respectively. While some studies changed weight coefficients according to the size of basin area, this study used same values without considering that. From the analysis of drought characteristics, it was found that the IRWSI was sensitive to the size of irrigation area rather than the size of basin area, and the south-eastern region of Korea had been suffered from severe drought damage.

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