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A Study on the Response Technique for Toxic Chemicals Release Accidents - Hydrogen Fluoride and Ammonia - (독성 화학물질 누출사고 대응 기술연구 - 불산 및 암모니아 누출을 중심으로 -)

  • Yoon, Young Sam;Cho, Mun Sik;Kim, Ki Joon;Park, Yeon Shin;Hwang, Dong Gun;Yoon, Jun heon;Choi, Kyung Hee
    • Korean Journal of Hazardous Materials
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    • v.2 no.1
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    • pp.31-37
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    • 2014
  • Since the unprecedented hydrogen fluoride leak accident in 2012, there has been growing demand for customized technical information for rapid response and chemical accident management agencies including the Ministry of Environment, the National Emergency Management Agency, and the National Police Agency need more information on chemicals and accident management. In this regard, this study aims to provide reliable technical data and guidelines to initial response agencies, similar to accident management technical reports of the US and Canada. In this study, we conducted a questionnaire survey and interviews on initial response agencies like fire stations, police stations, and local governments to identify new information items for appropriate initial response and improvements of current guidelines. We also collected and reviewed the Canada's TIPS, US EPA's hydrogen fluoride documents, domestic and foreign literature on applicability tests of control chemicals, and interview data, and then produced items to be listed in the technical guidelines. In addition, to establish database of on-site technical information, we carried out applicability tests for accident control data including ① emergency shut down devide, safety guard, shut down valve, ground connection, dyke, transfer pipe, scrubber, and sensor; ② literature and field survey on distribution type and transportation/storage characteristics (container identification, valve, ground connection, etc.); ③ classification and identification of storage/transportation facilities and emergency management methodslike leak prevention, chemicals control, and cutoff or bypass of rain drainage; ④ domestic/foreign analysis methods and environmental standards including portable detection methods, test standards, and exposure limits; and ⑤ comparison/evaluation of neutralization efficiency of control chemicals on toxic substances.

Morphological and Textural Characteristics of the Beach-dune System in South Korea, with the Possibility of a Dune Type Scheme Based on Grain-size Trend (국내 해안의 해빈-해안사구 지형 및 퇴적물 특성과 입도기반 사구유형 분석)

  • Rhew, Hosahng;Kang, Jihyun
    • Journal of The Geomorphological Association of Korea
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    • v.27 no.3
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    • pp.53-73
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    • 2020
  • Morphology and grain size distribution of coastal dunes should be well documented because they are critical to dune's buffering capacity and resilience against storm surges. The nationwide coastal dune survey produced the dataset, including beach-dune topographic profiles and grain size parameters for frontal beaches, foredunes, and inland dunes. This research investigated the dataset to describe geomorphic and textural properties of coastal dunes: foredune slopes, dune heights above approximately highest high water, mean size, and sorting, together with associated variables of coastal setting that influence coastal dunes. It also explores the possibility of a dune type scheme based on gran size trends. The results are as follows. First, the coast in which dunes are developed is the primary control on foredune morphology and sediment texture. Coastal dunes on the east coast were developed more alongshore rather than inland, with gentler slopes on the higher ground and out of coarser sand. The shore aspect contributes to this pattern because the east coast cannot benefit from prevailing northwesterly. Second, grain size trends from beaches through foredunes to inland dunes were little identified. Third, 12 dune types were identified from 69 dunes, showing the indicative capability for the status of beaches and dunes. We confirmed that the dataset could increase our understanding of the overall characteristics of coastal dune morphology and texture, though there is something to be improved, for example, establishing the refined and comprehensive field survey protocol.

A Study on the Erosion and Sedimentation Traces According to the Sea Level Changes Since the Medieval Warm Period in the Hwaseong Coast (화성 연안의 중세온난기 이후 해수면 변동에 연동된 침식·퇴적 흔적 연구)

  • Yang, Dong-Yoon;Han, Min;Kim, Jin Cheul;Park, Sujeong;Lim, Jaesoo
    • Journal of The Geomorphological Association of Korea
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    • v.26 no.2
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    • pp.39-54
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    • 2019
  • In this paper, based on evidence of coastal sediment, we show that erosion and sedimentation environments are very sensitive to sea level changes during the Medieval Warm Period (MWP) and the Little Ice Age (LIA). We identified four sedimentary units(4.57-3.07m), which formed in the Dark Age Cool Period (DACP), MWP and LIA were classified based on the lithostratigraphy, grain size distribution, magnetic susceptibility and geochemistry of a drilling core taken from the west coast of Hwaseong City. The unconformity surfaces as boundaries of the units were also identified by the lithostratigraphy shown on the drilling core. We propoese that sedimentation was dominant in the area during the periods of sea level rise, whereas erosion prevailed during the periods of sea level fall. Particularly, extreme events, such as floods and typhoons are believed to have accelerated these processes, and we found the associated evidence in sediments of two units. This study provides an example of estimating the relative sea level variation using coastal sediments and may be useful for studying past sea level changes around the Korean Peninsula.

Effect of Elevated Temperature on Physiological and Molecular Responses and Photoassimilate Production of Rice Leaves During Early Seed Development

  • Jung-Il Cho;Yo-Han Yoo;Eun-Ji Kim;Hoejeong Jeong;Jae-Kyeong Baek;Wan-Gyu Sang;Sungyul Chang;Dongwon Kwon
    • Proceedings of the Korean Society of Crop Science Conference
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    • 2022.10a
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    • pp.107-107
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    • 2022
  • The increase in atmospheric temperature due to climate change prolongs the period of exposure to high-temperature environments during rice cultivation. In particular, high-temperature during early seed development greatly affects on the productivity and quality of rice. The high temperature at this time not only affects the transport and distribution of assimilates from leaves to seeds and the accumulation of starch in the seeds, but also affects the leaves, which are the production organs of assimilates, and increases the consumption of assimilation products due to an increase in respiration. Therefore, in this study, rice was grown in temperature gradient chambers(TGC) to analyze the effects of high temperature on physiological responses, assimilate production, and changes in gene expression in rice leaves. Analysis of chlorophyll and sugar contents and RNA-seq experiments were performed using flag leaves collected under normal and elevated temperature conditions, respectively, during the early seed development stage, and then these results were comprehensively discussed.

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Whole-life wind-induced deflection of insulating glass units

  • Zhiyuan Wang;Junjin Liu;Jianhui Li;Suwen Chen
    • Wind and Structures
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    • v.37 no.4
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    • pp.289-302
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    • 2023
  • Insulating glass units (IGUs) have been widely used in buildings in recent years due to their superior thermal insulation performance. However, because of the panel reciprocating motion and fatigue deterioration of sealants under long-term wind loads, many IGUs have the problem of early failure of watertight properties in real usage. This study aimed to propose a statistical method for wind-induced deflection of IGU panels during the whole life service period, for further precise analysis of the accumulated fatigue damage at the sealed part of the edge bond. By the estimation of the wind occurrence regularity based on wind pressure return period, the events of each wind speed interval during the whole life were obtained for the IGUs at 50m height in Beijing, which are in good agreement with the measured data. Also, the wind-induced deflection analysis method of IGUs based on the formula of airspace coefficient was proposed and verified as an improvement of the original stiffness distribution method with the average relative error compared to the test being about 3% or less. Combining the two methods above, the deformation of the outer and inner panes under wind loads during 30 years was precisely calculated, and the deflection and stress state at selected locations were obtained finally. The results show that the compression displacement at the secondary sealant under the maximum wind pressure is close to 0.3mm (strain 2.5%), and the IGUs are in tens of thousands of times the low amplitude tensile-compression cycle and several times to dozens of times the relatively high amplitude tensile-compression cycle environment. The approach proposed in this paper provides a basis for subsequent studies on the durability of IGUs and the wind-resistant behaviors of curtain wall structures.

Impact of Remanent Polarization and Coercive Field on Threshold Voltage and Drain-Induced Barrier Lowering in NCFET (negative capacitance FET) (NCFET (negative capacitance FET)에서 잔류분극과 항전계가 문턱전압과 드레인 유도장벽 감소에 미치는 영향)

  • Hakkee Jung
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.37 no.1
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    • pp.48-55
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    • 2024
  • The changes in threshold voltage and DIBL were investigated for changes in remanent polarization Pr and coercive field Ec, which determine the characteristics of the P-E hysteresis curve of ferroelectric in NCFET (negative capacitance FET). The threshold voltage and DIBL (drain-induced barrier lowering) were observed for a junctionless double gate MOSFET using a gate oxide structure of MFMIS (metal-ferroelectric-metal-insulator-semiconductor). To obtain the threshold voltage, series-type potential distribution and second derivative method were used. As a result, it can be seen that the threshold voltage increases when Pr decreases and Ec increases, and the threshold voltage is also maintained constant when the Pr/Ec is constant. However, as the drain voltage increases, the threshold voltage changes significantly according to Pr/Ec, so the DIBL greatly changes for Pr/Ec. In other words, when Pr/Ec=15 pF/cm, DIBL showed a negative value regardless of the channel length under the conditions of ferroelectric thickness of 10 nm and SiO2 thickness of 1 nm. The DIBL value was in the negative or positive range for the channel length when the Pr/Ec is 25 pF/cm or more under the same conditions, so the condition of DIBL=0 could be obtained. As such, the optimal condition to reduce short channel effects can be obtained since the threshold voltage and DIBL can be adjusted according to the device dimension of NCFET and the Pr and Ec of ferroelectric.

Growth Response, Ecological Niche and Overlap between Quercus variabilis and Quercus dentata under Soil Moisture Gradient (토양수분구배에서 굴참나무와 떡갈나무의 생육반응, 생태 지위 및 중복역)

  • Park, Yeo-Bin;Kim, Eui-Joo
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.26 no.5
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    • pp.47-56
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    • 2023
  • The Quercus variabilis and Quercus dentata, which are said to be relatively drought tolerant among the important genus Quercus that represent deciduous broad-leaved forests in Korea. These two species are widely distributed worldwide in Korea, Japan and China (northern, central, western and eastern subtropical regions). This study compared the ecological niche breadth and overlap according to growth response in 4 soil moisture gradients for the two species and tried to reveal degree of competition and ecological niche characteristics. The ecological niche breadth was 0.977±0.020 for Q. variabilis and 0.979±0.014 for Q. dentata, the latter being slightly wider. And they were similar in 5 traits (stem length, leaf lamina length, leaf width length, stem weight, leaf petiole weight), Q. variabilis was more dominant in 4 traits (leaves number, stem diameter, leaf area, leaf petiole length), and Q. dentata was more dominant in 7 traits (root length, shoot length, plant weight, root weight, shoot weight, leaf weight, leaf petiole weight). The ecological niche overlap for soil moisture between the two species overlapped most in plant structure-related traits and least in photosynthetic organ-related traits such as petiole length. As a result of principal component analysis, degree of competition between the two species for soil moisture was more severe when the soil moisture condition was low than high. Among the measured traits that affect the two-dimensional distribution, 8 traits (Leaves number, Shoot length, Stem length, Plant weight, Root weight, Shoot weight, Stem weight, Leaves weight) were correlated with the factor 1, and 2 traits (Leaf width length, Leaf petiole weight) were correlated with the factor 2 (r>0.5). These results show that the ecological response of the two species to soil moisture is not a few traits involved, but several traits are involved simultaneously.

A Study on the Short-circuit Protection System for Learning Teaching Instruction Using Incandescent Light Bulb (백열전구를 이용한 학습 교구용 단락보호장치에 대한 고찰)

  • Hong-yong Kim
    • Journal of the Society of Disaster Information
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    • v.19 no.4
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    • pp.844-850
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    • 2023
  • Purpose: This paper is about the development of a short-circuit protection power supply device using incandescent bulbs and its application for educational materials. This article, which considers electrical safety and energy conservation at the same time, has many kinds of potential applications for both educational and industrial areas. The above mentioned short-circuit protection power supply device using incandescent bulbs enhances safety and efficiency compared to normal current power supply devices. Additionally, as an educational materials, it can be used for electric safety training, and provides practical electrical safety knowledge on our actual life. Method: Using incandescent bulbs, design new type of short-circuit protection power supply device, and through verifying the function and safety of the device, make new type device, and applying it for an educational tool. Conclusion: This study is to develop new type of power supply device, and verify the possibility of the application for the device as an educational materials. Through this research, show an innovative solution, which contribute to electrical safety and energy conservation, and open the potential possibility on educational and industrial sectors.This kind of research is expected to contributes to enhanced research, and education on electrical safety and energy conservation management.

A Simulation Study on Transcranial Direct Current Stimulation Using MRI in Alzheimer's Disease Patients (알츠하이머병 환자의 MRI를 활용한 경두개 직류 전기 자극 시뮬레이션에 관한 연구)

  • Chae-Bin Song;Cheolki Lim;Jongseung Lee;Donghyeon Kim;Hyeon Seo
    • Journal of Biomedical Engineering Research
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    • v.44 no.6
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    • pp.377-383
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    • 2023
  • Purpose: There is increasing attention to the application of transcranial direct current stimulation (tDCS) for enhancing cognitive functions in subjects to aging, mild cognitive impairment (MCI), and Alzheimer's disease (AD). Despite varying treatment outcomes in tDCS which depend on the amount of current reaching the brain, there is no general information on the impacts of anatomical features associated with AD on tDCS-induced electric field. Objective: The objective of this study is to examine how AD-related anatomical variation affects the tDCS-induced electric field using computational modeling. Methods: We collected 180 magnetic resonance images (MRI) of AD patients and healthy controls from a publicly available database (Alzheimer's Disease Neuroimaging Initiative; ADNI), and MRIs were divided into female-AD, male-AD, female-normal, and male-normal groups. For each group, segmented brain volumes (cerebrospinal fluid, gray matter, ventricle, rostral middle frontal (RMF), and hippocampus/amygdala complex) using MRI were measured, and tDCS-induced electric fields were simulated, targeting RMF. Results: For segmented brain volumes, significant sex differences were observed in the gray matter and RMF, and considerable disease differences were found in cerebrospinal fluid, ventricle, and hippocampus/amygdala complex. There were no differences in the tDCS-induced electric field among AD and normal groups; however, higher peak values of electric field were observed in the female group than the male group. Conclusions: Our findings demonstrated the presence of sex and disease differences in segmented brain volumes; however, this pattern differed in tDCS-induced electric field, resulting in significant sex differences only. Further studies, we will adjust the brain stimulation conditions to target the deep brain and examine the effects, because of significant differences in the ventricles and deep brain regions between AD and normal groups.

Variations in electrode characteristics through simplification of phosphorus-doped NiCo2O4 electrode manufacturing process (인이 도핑된 NiCo2O4 전극 제조 공정의 간소화를 통한 전극 특성의 변화)

  • Seokhee-Lee;Hyunjin Cha;Jeonghwan Park;Young Guk Son;Donghyun Hwang
    • Journal of Surface Science and Engineering
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    • v.56 no.5
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    • pp.299-308
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    • 2023
  • In this study, phosphorus (P)-doped nickel cobaltite (P-NiCo2O4) and nickel-cobalt layered double hydroxide (P-NiCo-LDH) were synthesized on nickel (Ni) foam as a conductive support using hydrothermal synthesis. The thermal properties, crystal structure, microscopic surface morphology, chemical distribution, electronic state of the constituent elements on the sample surface, and electrical properties of the synthesized P-NiCo2O4 and P-NiCo-LDH samples were analyzed using thermogravimetric analysis-differential scanning calorimetry (TGA-DSC), X-ray diffraction (XRD), field-emission scanning electron microscopy (FE-SEM), energy dispersive X-ray spectroscopy (EDS), X-ray photoelectron spectroscopy (XPS), cyclic voltammetry (CV), galvanostatic charge-discharge (GCD), and electrochemical impedance spectroscopy (EIS). The P-NiCo2O4 electrode exhibited a specific capacitance of 1,129 Fg-1 at a current density of 1 Ag-1, while the P-NiCo-LDH electrode displayed a specific capacitance of 1,012 Fg-1 at a current density of 1 Ag-1. When assessing capacity changes for 3,000 cycles, the P-NiCo2O4 electrode exhibited a capacity retention rate of 54%, whereas the P-NiCo-LDH electrode showed a capacity retention rate of 57%.