• Title/Summary/Keyword: Distance Matrix

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Separating nanocluster Si formation and Er activation in nanocluster-Si sensitized Er luminescence

  • 김인용;신중훈;김경중
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2009년도 제38회 동계학술대회 초록집
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    • pp.109-109
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    • 2010
  • $Er^{3+}$ ion shows a stable and efficient luminescence at 1.54mm due to its $^4I_{13/2}\;{\rightarrow}\;^4I_{15/2}$ intra-4f transition. As this corresponds to the low-loss window of silica-based optical fibers, Er-based light sources have become a mainstay of the long-distance telecom. In most telecom applications, $Er^{3+}$ ions are excited via resonant optical pumping. However, if nanocluster-Si (nc-Si) are co-doped with $Er^{3+}$, $Er^{3+}$ can be excited via energy transfer from excited electrical carriers in the nc-Si as well. This combines the broad, strong absorption band of nc-Si with narrow, stable emission spectra of $Er^{3+}$ to allow top-pumping with off-resonant, low-cost broadband light sources as well as electrical pumping. A widely used method to achieve nc-Si sensitization of $Er^{3+}$ is high-temperature annealing of Er-doped, non-stoichiometric amorphous thin film with excess Si (e.g.,silicon-rich silicon oxide(SRSO)) to precipitate nc-Si and optically activate $Er^{3+}$ at the same time. Unfortunately, such precipitation and growth of nc-Si into Er-doped oxide matrix can lead to $Er^{3+}$ clustering away from nc-Si at anneal temperatures much lower than ${\sim}1000^{\circ}C$ that is necessary for full optical activation of $Er^{3+}$ in $SiO_2$. Recently, silicon-rich silicon nitride (SRSN) was reported to be a promising alternative to SRSO that can overcome this problem of Er clustering. But as nc-Si formation and optical activation $Er^{3+}$ remain linked in Er-doped SRSN, it is not clear which mechanism is responsible for the observed improvement. In this paper, we report on investigating the effect of separating the nc-Si formation and $Er^{3+}$ activation by using hetero-multilayers that consist of nm-thin SRSO or SRSN sensitizing layers with Er-doped $SiO_2$ or $Si_3N_4$ luminescing layers.

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RF 마그네트론 스퍼터링에서 증착거리와 증착온도가 무기 액정 배향막의 물리적 성질에 미치는 영향에 대한 연구 (Influences of Target-to-Substrate Distance and Deposition Temperature on a-SiOx/Indium Doped Tin Oxide Substrate as a Liquid Crystal Alignment Layer)

  • 박정훈;손필국;김기범;박혁규
    • 한국재료학회지
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    • 제18권10호
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    • pp.521-528
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    • 2008
  • We present the structural, optical, and electrical properties of amorphous silicon suboxide (a-$SiO_x$) films grown on indium tin oxide glass substrates with a radio frequency magnetron technique from a polycrystalline silicon oxide target using ambient Ar. For different substrate-target distances (d = 8 cm and 10 cm), the deposition temperature effects were systematically studied. For d = 8cm, oxygen content in a-$SiO_x$ decreased with dissociation of oxygen onto the silicon oxide matrix; temperature increased due to enlargement of kinetic energy. For d = 10 cm, however, the oxygen content had a minimum between $150^{\circ}\;and\;200^{\circ}$. Using simple optical measurements, we can predict a preferred orientation of liquid crystal molecules on a-$SiO_x$ thin film. At higher oxygen content (x > 1.6), liquid crystal molecules on an inorganic liquid crystal alignment layer of a-$SiO_x$ showed homogeneous alignment; however, in the lower case (x < 1.6), liquid crystals showed homeotropic alignment.

세르샤 마모시험을 통한 암석의 마모도 측정에 관한 연구 (Determination of Rock Abrasiveness using Cerchar Abrasiveness Test)

  • 이수득;정호영;전석원
    • 터널과지하공간
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    • 제22권4호
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    • pp.284-295
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    • 2012
  • 본 연구에서는 암석 절삭 장비의 마모에 직접적인 영향을 주는 인자인 암석의 마모도(abrasiveness) 측정에 관한 연구를 수행하였다. 몇 가지 방법 중 세르샤 마모 시험(Cerchar abrasiveness test)을 통하여 암석의 마모도에 영향을 미치는 인자를 확인하고 효율적인 시험을 수행하기 위한 조건들을 연구하였다. 국내 19종 암석에 대한 시험 결과를 통하여, 세르샤 마모 지수(CAI, Cerchar Abrasiveness Index)에 영향을 미치는 암석의 역학적 물성(단축압축강도, 간접인장강도, 탄성계수, 포아송비, 공극률, 쇼어경도)과의 상관관계를 찾아보았고 X선 회절 분석을 통하여 암석의 구성 광물 중 마모도에 가장 큰 영향을 미치는 석영 함량, 등가 석영 함량과의 관계도 확인하였다. 그 결과로 암석의 입자 결합 특성보다 광물의 특성이 CAI에 영향을 더 미치는 것으로 관찰되었고, 단축압축강도와 등가 석영함량의 함수로 CAI를 예측하는 모델을 제시하였으며 핀의 경도가 커질수록 CAI값이 선형적으로 작아짐을 확인하였다. 수치해석적 연구를 통해 세르샤 마모 시험을 모사한 결과 초기 긁힘 거리에서 대부분의 마모가 발생함을 확인하였고 하중이 증가할수록 CAI값이 증가함을 확인하였다.

Hyperion 영상의 분류를 위한 밴드 추출 (Feature Selection for Image Classification of Hyperion Data)

  • 한동엽;조영욱;김용일;이용웅
    • 대한원격탐사학회지
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    • 제19권2호
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    • pp.170-179
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    • 2003
  • 다중분광 영상의 정확한 지형지물 분류를 수행할 때 고려해야 할 중요한 요소중에 적절한 분류 클래스의 선정과 선정된 클래스의 분리도가 높아지도록 트레이닝 지역(training fields)을 잡는 것은 특히 중요하다. 최근에 이용되고 있는 위성탑재 하이퍼스펙트럴(hyperspectral) 영상은 많은 밴드를 포함하고 있기 때문에 데이터 처리가 어렵고, 잡음(noise)으로 인하여 다중분광 영상보다 분류 결과가 나쁜 경우도 나타난다. 특히 대상지역의 클래스에 따른 트레이닝 지역의 선정시 일부 클래스에서 하이퍼스펙트럴 밴드수에 비해 상대적으로 적은 수의 트레이닝 샘플로 인하여 공분산 행렬의 계산에 어려움이 따른다. 따라서 본 연구에서는 Hyperion 데이터를 이용한 분류를 수행하기 위하여 밴드 추출 방식을 알아보고, 분류영상의 정확도 평가를 통하여 밴드 추출의 효용성을 시험하였다. 밴드를 줄이는 또 다른 방법인 클래스간 분리도에 따른 최적 밴드를 추출하여 분류정확도를 평가하였다. 실험 결과, 밴드 추출이나 클래스 분리도에 따라 선택된 영상의 분류 정확도는 분류자(classifier)에 상관없이 전체 밴드를 사용한 원영상과 유사하게 나타났지만, 사용된 밴드수와 계산 시간은 단축되었다. 분류자는 MLC, SAM, ECHO의 3종류가 사용되었다.

The Crystal Structure of a Sulfur Sorption Complex of the Dehydrated Partially $Co^{2+}$-Exchanged Zeolite A

  • 염영훈;송성환;김양
    • Bulletin of the Korean Chemical Society
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    • 제16권9호
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    • pp.823-826
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    • 1995
  • The crystal structure of a sulfur sorption complex of the dehydrated partially Co2+ exchanged zeolite A (a=12.058(2) Å) has been determined by single-crystal X-ray techniques. The crystal structure was solved and refined in cubic space group Pm3m at 21(1) ℃. Ion Exchange with aqueous 0.05 M Co(NO3)2 was done by the static method. The crystal of Na4Co4-A was dehydrated at 380 ℃ and 2 × 10-6 Torr for 2 days, followed by exposure to about 100 Torr of sulfur at 330 ℃ for 72 h. Full matrix least-squares refinement converged to R1=0.084 and Rw=0.074 with 102 reflections for which I > 3σ(I). Crystallographic analysis shows that 2.8 Co2+ ions and 4 Na+ ions per unit cell occupy 6-ring sites on the threefold axes. 1.2 Co2+ ions occupy the 8-ring sites on fourfold axes. 2.8 Co2+ ions at Co(1) are recessed 0.66 Å into the large cavity and 4 Na+ ion at Na(1) are recessed 0.77 Å into the sodalite cavity from the (111) plane of O(3)'s. Approximately 16 sulfur atoms were sorbed per unit cell. Two S8 rings, each in a butterfly form, are found in the large cavity. The bond length between S and its adjacent S is 2.27(3) Å. The distance between 6-ring Co2+ ion and its adjacent sulfur is 2.53 (2) Å and that between 8-ring Co2+ ions and its adjacent sulfur is 2.72(9) Å. The angles of S-S'-S and S'-S-S'/ in octasulfur rings are 119.0(2)°and 113.0(2)°, respectively.

Combination of Brain Cancer with Hybrid K-NN Algorithm using Statistical of Cerebrospinal Fluid (CSF) Surgery

  • Saeed, Soobia;Abdullah, Afnizanfaizal;Jhanjhi, NZ
    • International Journal of Computer Science & Network Security
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    • 제21권2호
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    • pp.120-130
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    • 2021
  • The spinal cord or CSF surgery is a very complex process. It requires continuous pre and post-surgery evaluation to have a better ability to diagnose the disease. To detect automatically the suspected areas of tumors and symptoms of CSF leakage during the development of the tumor inside of the brain. We propose a new method based on using computer software that generates statistical results through data gathered during surgeries and operations. We performed statistical computation and data collection through the Google Source for the UK National Cancer Database. The purpose of this study is to address the above problems related to the accuracy of missing hybrid KNN values and finding the distance of tumor in terms of brain cancer or CSF images. This research aims to create a framework that can classify the damaged area of cancer or tumors using high-dimensional image segmentation and Laplace transformation method. A high-dimensional image segmentation method is implemented by software modelling techniques with measures the width, percentage, and size of cells within the brain, as well as enhance the efficiency of the hybrid KNN algorithm and Laplace transformation make it deal the non-zero values in terms of missing values form with the using of Frobenius Matrix for deal the space into non-zero values. Our proposed algorithm takes the longest values of KNN (K = 1-100), which is successfully demonstrated in a 4-dimensional modulation method that monitors the lighting field that can be used in the field of light emission. Conclusion: This approach dramatically improves the efficiency of hybrid KNN method and the detection of tumor region using 4-D segmentation method. The simulation results verified the performance of the proposed method is improved by 92% sensitivity of 60% specificity and 70.50% accuracy respectively.

Using Taguchi design of experiments for the optimization of electrospun thermoplastic polyurethane scaffolds

  • Nezadi, Maryam;Keshvari, Hamid;Yousefzadeh, Maryam
    • Advances in nano research
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    • 제10권1호
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    • pp.59-69
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    • 2021
  • Electrospinning is a cost-effective and versatile method for producing submicron fibers. Although this method is relatively simple, at the theoretical level the interactions between process parameters and their influence on the fiber morphology are not yet fully understood. In this paper, the aim was finding optimal electrospinning parameters in order to obtain the smallest fiber diameter by using Taguchi's methodology. The nanofibers produced by electrospinning a solution of Thermoplastic Polyurethane (TPU) in Dimethylformamide (DMF). Polymer concentration and process parameters were considered as the effective factors. Taguchi's L9 orthogonal design (4 parameters, 3 levels) was applied to the experiential design. Optimal electrospinning conditions were determined using the signal-to-noise (S/N) ratio with Minitab 17 software. The morphology of the nanofibers was studied by a Scanning Electron Microscope (SEM). Thereafter, a tensile tester machine was used to assess mechanical properties of nanofibrous scaffolds. The analysis of DoE experiments showed that TPU concentration was the most significant parameter. An optimum combination to reach smallest diameters was yielded at 12 wt% polymer concentration, 16 kV of the supply voltage, 0.1 ml/h feed rate and 15 cm tip-to-distance. An empirical model was extracted and verified using confirmation test. The average diameter of nanofibers at the optimum conditions was in the range of 242.10 to 257.92 nm at a confidence level 95% which was in close agreement with the predicted value by the Taguchi technique. Also, the mechanical properties increased with decreasing fibers diameter. This study demonstrated Taguchi method was successfully applied to the optimization of electrospinning conditions for TPU nanofibers and the presented scaffold can mimic the structure of Extracellular Matrix (ECM).

Influence of complex geological structure on horizontal well productivity of coalbed methane

  • Qin, Bing;Shi, Zhan-Shan;Sun, Wei-Ji;Liang, Bing;Hao, Jian-Feng
    • Geomechanics and Engineering
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    • 제29권2호
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    • pp.145-154
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    • 2022
  • Complex geological conditions have a great influence on the mining of coalbed methane (CBM), which affects the extraction efficiency of CBM. This investigation analyzed the complicated geological conditions in the Liujia CBM block of Fuxin. A geological model of heterogeneities CBM reservoirs was established to study the influence of strike direction of igneous rocks and fault structures on horizontal well layout. Subsequently, the dual-porosity and dual-permeability mathematical model was established, which considers the dynamic changes of porosity and permeability caused by gas adsorption, desorption, pressure change. The results show that the production curve is in good agreement with the actual by considering gas seepage in matrix pores in the model. Complicated geological structures affect the pressure expansion of horizontal wells, especially, the closer to the fault structure, the more significant the effect, the slower the pressure drop, and the smaller the desorption area. When the wellbore extends to the fault, the pressure expansion is blocked by the fault and the productivity is reduced. In the study area, the optimal distance to the fault is 70 m. When the horizontal wellbore is perpendicular to the direction of coal seam igneous rock, the productivity is higher than that of parallel igneous rock, and the horizontal well bore should be perpendicular to the cleat direction. However, the well length is limited due to the dense distribution of igneous rocks in the Liujia CBM block. Therefore, the horizontal well pumping in the study area should be arranged along the direction of igneous rock and parallel plane cleats. It is found that the larger the area surrounded by igneous rock, the more favorable the productivity. In summary, the reasonable layout of horizontal wells should make full use of the advantages of igneous rock, faults and other complex geological conditions to achieve the goal of high and stable production.

Optimised neural network prediction of interface bond strength for GFRP tendon reinforced cemented soil

  • Zhang, Genbao;Chen, Changfu;Zhang, Yuhao;Zhao, Hongchao;Wang, Yufei;Wang, Xiangyu
    • Geomechanics and Engineering
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    • 제28권6호
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    • pp.599-611
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    • 2022
  • Tendon reinforced cemented soil is applied extensively in foundation stabilisation and improvement, especially in areas with soft clay. To solve the deterioration problem led by steel corrosion, the glass fiber-reinforced polymer (GFRP) tendon is introduced to substitute the traditional steel tendon. The interface bond strength between the cemented soil matrix and GFRP tendon demonstrates the outstanding mechanical property of this composite. However, the lack of research between the influence factors and bond strength hinders the application. To evaluate these factors, back propagation neural network (BPNN) is applied to predict the relationship between them and bond strength. Since adjusting BPNN parameters is time-consuming and laborious, the particle swarm optimisation (PSO) algorithm is proposed. This study evaluated the influence of water content, cement content, curing time, and slip distance on the bond performance of GFRP tendon-reinforced cemented soils (GTRCS). The results showed that the ultimate and residual bond strengths were both in positive proportion to cement content and negative to water content. The sample cured for 28 days with 30% water content and 50% cement content had the largest ultimate strength (3879.40 kPa). The PSO-BPNN model was tuned with 3 neurons in the input layer, 10 in the hidden layer, and 1 in the output layer. It showed outstanding performance on a large database comprising 405 testing results. Its higher correlation coefficient (0.908) and lower root-mean-square error (239.11 kPa) were obtained compared to multiple linear regression (MLR) and logistic regression (LR). In addition, a sensitivity analysis was applied to acquire the ranking of the input variables. The results illustrated that the cement content performed the strongest influence on bond strength, followed by the water content and slip displacement.

Quantitative analysis of retained austenite in Nb added Fe-based alloy

  • Kwang Kyu Ko;Jin Ho Jang;Saurabh Tiwari;Hyo Ju Bae;Hyo Kyung Sung;Jung Gi Kim;Jae Bok Seol
    • Applied Microscopy
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    • 제52권
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    • pp.5.1-5.10
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    • 2022
  • The use of Pipelines for long-distance transportation of crude oil, natural gas and similar applications is increasing and has pivotal importance in recent times. High specific strength plays a crucial role in improving transport efficiency through increased pressure and improved laying efficiency through reduced diameter and weight of line pipes. TRIP-based high-strength and high-ductility alloys comprise a mixture of ferrite, bainite, and retained austenite that provide excellent mechanical properties such as dimensional stability, fatigue strength, and impact toughness. This study performs microstructure analysis using both Nital etching and LePera etching methods. At the time of Nital etching, it is difficult to distinctly observe second phase. However, using LePera etching conditions it is possible to distinctly measure the M/A phase and ferrite matrix. The fraction measurement was done using OM and SEM images which give similar results for the average volume fraction of the phases. Although it is possible to distinguish the M/A phase from the SEM image of the sample subjected to LePera etching. However, using Nital etching is nearly impossible. Nital etching is good at specific phase analysis than LePera etching when using SEM images.