• Journal of the Korean institute of surface engineering
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• v.50 no.4
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• pp.231-236
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• 2017

The present work addresses how to measure the amount of dissolved aluminum in phosphoric acid, based on volumetric and gravimetric measurements of the precipitates formed by reaction between the $H_3PO_4$ solution containing dissolved aluminum ions and 10 % KF solution. The volume of the precipitates increased with dilution of the dissolved aluminum-containing $H_3PO_4$ solution up to 1/4 dilution above which it decreased with further dilution. The lowered amounts of the precipitates at low dilution less than 1/4 and high dilution more than 1/4 are attributed to high acidity of the solution and decreased amount of dissolved aluminum in the solution, respectively. Volumetric measurement of the amount of precipitates was found not to be very reliable with the experiments, while weight measurement of the precipitates after drying for 80 min at $60^{\circ}C$ appeared to be very reproducible. In the present work, it is suggested that the amount of Al dissolved in 85 % $H_3PO_4$ solution can be calculated by multiplying 50 to the weight of precipitate obtained by reacting 8 ml of 1/4 diluted $H_3PO_4$ solution containing dissolved aluminum ions with 6 ml of 10 % KF solution.

• KSBB Journal
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• v.27 no.2
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• pp.103-108
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• 2012

The harvesting of microalgae is a critical step that precedes biodiesel conversion. The most widely used harvesting technology is flocculation and floatation. In this study, the efficiency of the flocculants aluminum sulfate and poly aluminum chloride were evaluated for harvesting the alga Dunaliella tertiolecta in conjunction with dissolved air floatation. Using the jar test the optimum concentration range for aluminum sulfate was 1.0~1.5 g/L and for poly aluminium chloride, 1.5~2.0 g/L. The degree of coagulation was visualized by microscopy. Further analysis in combination with dissolved air floatation showed that the optimal concentration for aluminum sulfate was 1.1 g/L and for poly aluminum chloride, 1.6 g/L.

• Journal of Korean Society of Water and Wastewater
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• v.11 no.1
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• pp.42-52
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• 1997

The affection of activated carbon on the dissolved aluminum ion in drinking water has been observed. In addition, the aluminum ion removal capability of activated, alumina, chitosan, and ion exchange resin have been investigated. Experimental results indicated that the coal based activated carbon released considerable amount of aluminum ion to the water while coconut shell based activated carbon didn't. However the release was not continuous. Activated alumina didn't show any recognizable removal capability for aluminum ion in water. Particulate chitosan has removed aluminum ion although dissolved chitosan has not. However it need to development a regeneration process for chitosan to be an effective mean for aluminum ion removal. Ion exchange resin showed a reliable aluminum ion removal capability. The ion exchange capacity was 2.63 meq/g resin for the aluminum ion in drinking water.

• Journal of the Korean Home Economics Association
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• v.38 no.2
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• pp.21-26
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• 2000

Effect of aluminum dissolution from aluminum sauce pans with the kind and concentration of acidity, boiling times and temperature of acidity solution, in new and old sauce pans, and aluminum content in typical food was investigated. As acetic acid concentration increases, aluminum content has increased. But malic acid and citric acid have suddenly increased until acidity concentration would be 0.4%. After that rapidly increasing is not shown. As boiling time and temperature of acidity solution increases, concentration of aluminum dissolved from aluminum sauce pan has increased. Concentration of aluminum by repeated use has increased only a slightly. But aluminum content has dissolved in large quantities from new pan rather than old pan.

• Resources Recycling
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• v.16 no.5
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• pp.3-7
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• 2007

Waste aluminum dross was processed to prepare alum with sulfuric acid, and poly aluminum chloride(PAC) with hydrochloric acid. Metallic aluminum remained in the waste dross was dissolved into the sulfuric acid solution, and the solution could be used as alum for water treatment chemicals after adjusting the required alumina concentration and pH of the solution. Also, it was dissolved into the hydrochloric acid solution and processed to make PAC solution. Compared with the conventional method for preparation of alum and PAC using aluminum hydroxide, material cost could be saved in this method. Also, there is an additional merit in view of recycling of the waste aluminum dross by reducing the amount of waste disposed to landfill.

• Resources Recycling
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• v.18 no.4
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• pp.38-43
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• 2009

The synthesis of aluminum oxalate, one of the aluminum organic compounds, has been performed using aluminum hydroxide as a raw material. For this aim, domestic aluminum hydroxide of 99.7% purity was dissolved by oxalic acid to produce an aqueous aluminum solution. As a result, it was found that aluminum hydroxide could be dissolved almost completely by the reaction with 1.0 mole/l oxalic acid solution at $90^{\circ}C$ for 16 hr. It was strongly required to keep the ratio of ethanol/Al solution more than 2.0 for the synthesis of aluminum oxalate from the aluminum solution. Furthermore, the pH should be controlled to be more than 8.2 in order to obtain the recovery of aluminum oxalate higher than 90%. From the chemical analysis of aluminum oxalate prepared in this work, the content of $NH_4$, Al and C was found to be 14.5, 7.18 and 17.4%, respectively. Accordingly, the aluminum oxalate synthesized from the aluminum solution was confirmed to be $(NH_4)_3Al(C_2O_4)_3$ $3H_2O$.

• Advances in environmental research
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• v.5 no.2
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• pp.141-151
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• 2016

Large amounts of aluminum hydroxide ($Al(OH)_3$) exist in water purification sludge (WPS) because of the added aluminum coagulant in water treatment process. Notably, $Al(OH)_3$ is an amphoteric compound, can be dissolved in its basic condition using sodium hydroxide to form aluminate ions ($Al(OH)_4{^-}$). However, in a process in which pH is increasing, the humid acid can be dissolved easily from WPS and will inhibit the recovery and reuse of the dissolved aluminate ions. This study attempts to fix this problem by a novel approach to separate $Al(OH)_4{^-}$ ions using nanofiltration (NF) technology. Sludge impurity in a alkaline solution is retained by the NF membrane, such that the process recovers $Al(OH)_4{^-}$ ions, and significantly decreases the organic matter or heavy metal impurities in the permeate solution. The $Al(OH)_4{^-}$ ion is an alkaline substance. Experimental results confirm that a recovered coagulant of $Al(OH)_4{^-}$ ion can effectively remove kaolin particles from slightly acidic synthetic raw water.

• Journal of Korean Society of Environmental Engineers
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• v.35 no.1
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• pp.17-22
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• 2013

In this study, a pH control method by carbon dioxide ($CO_2$) was applied to coagulation process in water treatment plant (WTP) to investigate the coagulation efficiency and residual dissolved aluminum when high pH raw water is flowing into the plant during algal blooming. Existing coagulant dose (1 mg/L in raw water) resulted in the pH reduction of 0.0384 by LAS, 0.0254 by PAC, 0.0201 by A-PAC, and 0.0135 by PACS2, respectively. And then the concentration of dissolved aluminum was 0.02 mg/L at pH 7.44, 0.07 mg/L at pH 7.96, 0.12 mg/L at pH 8.16, 0.39 mg/L at pH 8.38 showing the concentration increase with pH in the coagulation process. It was noteworthy that rapid increase was observed at pH above 8.0 next the rapid mixing. Therefore it is necessarily required to control pH below 7.8 in the coagulation process in order to meet drinking water quality standard of aluminum for high pH raw water into WTP, $CO_2$ injection could control pH successfully at about 7.3 even for the raw water of high pH above 8.0. In addition it was found that the pH control by $CO_2$ injection was significantly effective for coagulation in terms of turbidity removal, coagulant dosage, and residual dissolved aluminum concentration.

• Proceedings of the Korean Sanitation Conference
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• 2004.11a
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• pp.54-65
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• 2004

Use of aluminum salts as coagulants In water treatment may lead to increased concentrations of aluminum in finished water. Aluminum is a suspected causative agent of neurological disorders such as Alzheimer's disease. The objective of this study was to examine variation and minimizing in residual aluminum concentration during water treatment process. The aluminum sources at Bokjeong Water Plant were present naturally aluminum in the raw water and derived due to use of PACS as a coagulant. Much of the raw water total aluminum were in particulate and suspended aluminum. In this study was compared the optimize condition to minimize the concentration of residual aluminum using Jar-test with the various coagulants such as alum, PAC, PACS. The results indicated that PACS was more effective than alum, PAC and insufficient or excessive alum, PAC, PACS addition led to increase residual aluminum. Adjustment raw water pH $6.5\~7.0$ before coagulation using PACS was capable of minimizing total and dissolved aluminum. Thus it is important that the optimal dosage of coagulant and the optimal pH adjustment before coagulation can decided to minimize the concentration of residual aluminum in treated water.

• Proceedings of the IEEK Conference
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• 2001.10a
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• pp.472-477
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• 2001

Spent catalysts containing platinum were generated in petroleum refinery and other chemical industries. The reclamation of precious metals from such wastes has long been attempted in view of their rare, expensive and indispensable nature. In this study, the recovery of platinum from petroleum catalysts was attempted by a method consisting mainly of dissolving alumina substrate with sulfuric acid thereby concentrating insoluble platinum. Also, platinum dissolved partially in sulfuric acid was recovered by a cementation method using aluminum metal as a reductive agent. The effect of temperature, time, concentration of sulfuric acid. and pulp density on the dissolution of substrate was investigated. When the substrate of platinum catalyst was ${\gamma}$-AI$_2$O$_3$ about 95% alumina was dissolved in 6.0M sulfuric acid at 10$0^{\circ}C$ for 2 hours. When the substrate was the mixture of ${\gamma}$-A1$_2$O$_3$and $\alpha$-A1$_2$O$_3$about 92% was dissolved after 4 hours. As a result, more than 99% of platinum could be recovered by this method and aluminum sulfate was obtained as byproduct.