• 방사성폐기물학회지
• /
• 제10권2호
• /
• pp.77-85
• /
• 2012

본 연구는 우라늄-함유 석회침전물로부터 U을 제거(/회수) 하기위하여 탄산염 산화용해-산성화 침전과 질산용해-과산화수소 침전을 각각 고찰하였다. 석회침전물 내 우라늄을 용해하는 관점에서는 질산용해가 유리하나 (약 98% 이상 용해) 이 경우 U과 Al, Ca, Fe, Mg, Si 등의 공존 불순물이 다량 공용해되고, 또한 과산화수소 침전에서도 상당량의 불순물이 U과 함께 공침전 된다. 한편 탄산염 용해에 의한 산성화 침전은 우라늄의 용해가 90% 이하로 방사성 고체페기물의 부피감용 측면에서는 질산용해 보다 덜 효율적이지만, 우라늄과 불순물의 공용해나 산성화 침전에 의한 우라늄과 불순물의 공침전이 거의 일어나지 않아 보다 순수한 U을 회수하는 측면에서는 매우 효과적이다.

• 한국재료학회지
• /
• 제26권5호
• /
• pp.235-240
• /
• 2016

Appropriate thermo-mechanical properties of nickel-based superalloys are achieved by heat treatment, which induces precipitation and solid solution hardening; thus, information on the temperature ranges of precipitation and dissolution of the precipitates is essential for the determination of the heat treatment condition. In this study, thermal analyses of nickel-based superalloys were performed by differential scanning calorimetry method under conditions of various heating rates of 5, 10, 20, or 40K/min in a temperature range of 298~1573K. Precipitation and dissolution temperatures were determined by measuring peak temperatures, constructing trend lines, and extrapolating those lines to the zero heating rate to find the exact temperature under isothermal condition. Determined temperatures for the precipitation reactions were 813, 952, and 1062K. Determined onset, peak, and offset temperatures of the first dissolution reaction were 1302, 1388, and 1406K, respectively, and those values of the second dissolution reaction were 1405, 1414, and 1462K. Determined solvus temperature was 1462K. The study showed that it was possible to use a simple method to obtain accurate phase transition temperatures under isothermal condition.

• 환경위생공학
• /
• 제14권3호
• /
• pp.116-122
• /
• 1999

The purpose of this study is to develop new process named "hydrogen peroxide dissolution method". This process used hydrogen peroxide, which is harmless to human body and oxidize molybdenum wire selectively.The advantages of hydrogen peroxide dissolution method were no discharge of noxious matter when dissolution of molybdenum wire which used as the center supporter, reactions occur in room temperature and easy to recover dissolved molybdenum. This study was aimed at gathering the basic data of molybdenum wire dissolution-recovery process and proposes the reaction condition of molybdenum wire dissolution-recovery process and the factors influencing those reactions. The results were as follows:1. In the dissolution of molybdenum wire, the early condition of reaction was $15^{\circ}C$, and the temperature condition of state was $32^{\circ}C$. 2. 1) In the GSL-60W type, P.W.(Piece weight) was 11.89mg, C.R. was $65.6\Omega$. 2) In the FL-20W type, P.W. was 11.60mg, C.R. was $4.6\Omega$. 3. The molybdenum of process water was treated of a precipitation after dry and after stagnation in the one day, the molybdenum of upper water was treated of precipitation after dry and after congelation.

• 자원환경지질
• /
• 제50권6호
• /
• pp.509-515
• /
• 2017

일반적으로 석영은 지각을 구성하는 광물 가운데 가장 많은 부분을 차지하고 있으며, 이러한 석영의 용해와 침전에 대한 이해는 암석의 풍화 매커니즘과 열수작용 및 변성환경에서의 암석과 물의 관계를 규명하는데 매우 중요한 역할을 한다. 본 논문에서는 석영의 용해와 침전에 영향을 미치는 다양한 물리화학적 환경을 수식을 이용해 재정리하였으며, 이전의 연구자들이 발표한 연구결과를 바탕으로 물리화학적 조건하에서의 석영 용해에 대해 이론적 접근을 실시하였다. 본 논문을 통해서 석영의 용해 및 침전이 다양한 환경에 영향을 받으며, 특히 이론적 접근을 통해서 석영에 작용된 압력보다는 주변의 pH 및 온도 조건에 더 큰 영향을 받는다는 것을 확인하였다.

• 한국광물학회지
• /
• 제9권2호
• /
• pp.71-81
• /
• 1996

Dissolution experiments were conducted to understand chemical nature of weathering of anorthosite from the Hadong area. Anorthosite and plagioclase from it were reacted with HCl or KOH solutions under various conditions concerning such as grain size, initial pH of solutions, and shaking Average composition of plagioclase used in the experiment was Na0.32Ca0.71Al1.71Si2.28O8.Under acidic conditions, solution pH increases rapidly in the initial stage and then gradually to reach palteau. Shaking agitates the reaction rate in the initial stage but does not affect after the system reached steady state. Ca and si concentrations show rapid increase and then gradual increase. Al concentration increases rapidly in the early stage and then decreases. Later decrease was interpreted as the precipitation of an Al-bearing material. Different dissolution rates of different constituents of plagioclase together the with precipitation of al-bearing material might be responsible for the non-stoichiometric dissolution of plagioclase.X-ray diffraction analyses on anorthosite before and after dissolution experiment show dissolution rates differ with different lattice planes of plagioclase. It suggests the crystallographic control on dissolution reaction. X-ray photoelectron spectroscopic result shows that the average composition of plagioclase surface reacted with HCL of initial pH 1.97 for 2000 hours is Na0.20Ca0.26Al1.7Si2.3O8. It means that Na- and Ca-depleted H-feldspar is developed without Al-depleted layer on the surface of plagioclase by reaction with HCl and that dissolution reaction takes place sparsely on the surface of plagioclase. Al and Si are dissolved preferentially over Ca from anorthosite powder in KHO solution. Reaction of acid-reacted anorthosite with KOH solution shows the same Si dissolution behavior as in the fresh anorthosite. This indicates that the Al-depleted and Si-enriched layer does not build up on the acid-reacted surface.

• 열처리공학회지
• /
• 제6권3호
• /
• pp.138-143
• /
• 1993

Effects of aging treatment on the microstructural evolution of a rapidly solidified Al-Li-Cu alloy were investigated by differential scanning calorimetry (DSC) and transmission electron microscopy(TEM). It was found that the precipitation sequence was: supersaturated solid solution ${\alpha}^{\prime}$ ${\rightarrow}$ metastable ${\delta}^{\prime}$ + stable precipitate $T_1$ ${\rightarrow}$ stable precipitates ${\delta}+T_1$. Two exothermic and two endothermic peaks are detected by DSC analysis. The two exothermic and endothermic peaks corresponded to ${\delta}^{\prime}$ and ${\delta}+T_1$ precipitation and dissolution reactions respectively. The enthalpy of ${\delta}^{\prime}$ precipitation decreased with increasing of aging temperature and time until the finishing point of precipitation. The activation energy for precipitation of ${\delta}^{\prime}$ was measured as 80KJ/mol and the energy for dissolution was 93KJ/mol. These values arc higher than those of AI-Li binary alloy. Peak hardness value (Hv 170) was obtamed at $210^{\circ}C$ for 1hr aging treatment which coincided with finishing point of ${\delta}^{\prime}$ precipitation.

• 대한금속재료학회지
• /
• 제49권12호
• /
• pp.917-923
• /
• 2011

Dissolution and precipitation behaviors of complex carbonitrides in austenite of a V-Nb microalloyed steel were quantitatively examined through electrical resistivity measurement and transmission electron microscopy. The electrical resistivity increased with solution treatment temperature up to $1240^{\circ}C$ and then was saturated at $225n{\Omega}m$ for a holding time of 10 min. The electrical resistivity method was also used to quantitatively measure the isothermal precipitation kinetics of the complex carbonitrides in austenite. Nb-rich precipitates were observed in austenite at the early stages of precipitation, but Nb was replaced by V up to the equilibrium amount within the precipitates with further holding time. The time-temperature-precipitation diagram showed a C-type curve; nose temperature and its incubation time were $900^{\circ}C$ and 100 s, respectively.

• 한국재료학회지
• /
• 제30권9호
• /
• pp.474-479
• /
• 2020

The effect of precipitation and dissolution of Si on the thermal diffusivity in the Al-Si alloy system is reported in this study and solution heat treatment followed by aging treatment is carried out to determine the effects of heat treatment on the thermal characteristics. The solution treatment is performed at 535 ℃ for 4 and 10 h and then the specimens are cooled by rapid quenching. The samples are aged at 300 ℃ for 4 h to precipitate Si solute. The addition of 9 wt% silicon contents makes the thermal diffusivity decrease from 78 to 74 mm/s² in the cases of solid solution treated and quenched samples. After quenching and aging, the Si solute precipitates on the Al matrix and increases the thermal diffusivity compared with that after the quenched state. In particular, the increase of the thermal diffusivity is equal to 10 mm/s² without relation to the Si contents in the Al-Si alloy, which seems to corresponded to solute amount of Si 1 wt% in the Al matrix.

• 대한자원환경지질학회:학술대회논문집
• /
• 대한자원환경지질학회 2005년도 춘계 학술발표회 논문집
• /
• pp.34-34
• /
• 2005

• Bulletin of the Korean Chemical Society
• /
• 제19권9호
• /
• pp.1009-1011
• /
• 1998