• Title/Summary/Keyword: Dissolution kinectics

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Effect of Solution Temperature and Bath Concentration on the Kinetics with Dissolution Reaction of Zinc-Ferrite (Zinc-ferrite의 용해 속도론에 미치는 황산 용액의 온도와 농도의 영향)

  • Oh Iee-Sik;Kim Chun-Jo
    • Resources Recycling
    • /
    • v.12 no.4
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    • pp.30-37
    • /
    • 2003
  • A kinetics study on the dissolution reaction of zinc-ferrite has been made with aqueous sulfuric acid in various temperature and concentration. Fraction reacted(R) and apparent rate constant(K) increased with increasing temperature and concentration of sulfuric acid solution. The rate of dissolution is shown by $1-(1-K)^{1/3}=Kt$ for the initial stage of the reaction in aqueous sulfuric acid, where K is apparent rate constant, R is fraction reacted and t is reaction time, respectively. Activation energy associated with reaction was determined to be 16.3 kcal/mole. The dissolution of zinc-ferrite in sulfuric acid solution is dissolved by sto-ichiometric composition, but Fe and Zn did not dissolved, respectively.