• Title/Summary/Keyword: Disposal system

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Electrolytic Decontamination of the Dismantled Metallic Wastes Contaminated with Uanium Compounds in Neutral Salt Solutions (중성염 용액 내에서 우라늄으로 오염된 금속성 해체폐기물의 전해제염)

  • 최왕규;이성렬;김계남;원휘준;정종헌;오원진
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2004.06a
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    • pp.72-80
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    • 2004
  • Electrolytic dissolution study was carried out to evaluate the applicability of electrochemical decontamination process using a neutral salt electrolyte as a decontamination technology for the recycle or self disposal with authorization of large amount of metallic wastes contaminated with uranium compounds generated by dismantling a retired uranium conversion plant using SUS-304 and Inconel-600 specimen as the main materials of internal system components of the plant. The effects of type of neutral salt as an electrolyte, current density, and concentration of electrolyte on the dissolution of the materials were evaluated. On the basis of the results obtained through the basic inactive experiments, electrochemical decontamination tests using the specimens contaminated with uranium compounds such as $UO_2$, AUC (ammonium uranyl carbonate) and ADU (ammonium diuranate) taken from an uranium conversion plant were peformed in $Na_2SO_4$ and $NaNO_3$ solution. It was verified that the electrochemical decontamination of the dismantled metallic wastes was quite successful in $Na_2SO_4$ and $NaNO_3$ neutral salt electrolyte by reducing $\beta$ radioactivities below the level of self disposal with authorization within 10 minutes regardless of the type of contaminants and the degree of contamination.

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A Study on the Constructing Discrete Fracture Network in Fractured-Porous Medium with Rectangular Grid (사각 격자를 이용한 단열-다공암반내 분리 단열망 구축기법에 대한 연구)

  • Han, Ji-Woong;Hwang, Yong-Soo;Kang, Chul-Hyung
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.4 no.1
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    • pp.9-15
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    • 2006
  • For the accurate safety assessment of potential radioactive waste disposal site which is located in the crystalline rock it is important to simulate the mass transportation through engineered and natural barrier system precisely, characterized by porous and fractured media respectively. In this work the methods to construct discrete fracture network for the analysis of flow and mass transport through fractured-porous medium are described. The probability density function is adopted in generating fracture properties for the realistic representation of real fractured rock. In order to investigate the intersection between a porous and a fractured medium described by a 2 dimensional rectangular and a cuboid grid respectively, an additional imaginary fracture is adopted at the face of a porous medium intersected by a fracture. In order to construct large scale flow paths an effective method to find interconnected fractures and algorithms of swift detecting connectivities between fractures or porous medium and fractures are proposed. These methods are expected to contribute to the development of numerical program for the simulation of radioactive nuclide transport through fractured-porous medium from radioactive waste disposal site.

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The Dissolution Characteristics of Metal Compounds in Soil Application Experiment using Sewage Treatment Sludge mixed with Oyster shells (하수슬러지 및 굴껍질의 토지주입시 금속성분의 용출특성에 관한 연구)

  • Kim, Chul;Moon, Jong-Ik;Shin, Nam-Cheol;Ha, Sang-An;Sung, Nak-Chang;Huh, Mock
    • Journal of the Korea Organic Resources Recycling Association
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    • v.9 no.2
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    • pp.71-76
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    • 2001
  • Recently, sludge disposal becomes one of the most serious environmental problems. Because the landfilling and ocean dumping of sludge materials will be prohibited in the near future, the proper treatment?disposal methods should be investigated. Also, oyster shells, piled at the coast, cause adverse effects in coastal fishery, public water surface, natural landscape, public health and so on. Thus, the purpose of this study is to evaluate the dissolution characteristic of metal compounds during soil application experiment using sewage treatment sludge mixed with oyster shells. The dissolution experiment conducted 100days under artificial rainfall and farming soil, mixed with sewage treatment sludge and oyster shells, was put into the pots(approx. 0.5L). The results from dissolution experiment as follows. 1. K, Na was $5{\sim}20mg/{\ell}$, and Ca was less than $90mg/{\ell}$. 2. Heavy metals such as Cd, Cu, As, Pb, Cr, Hg are dissoluted far less than the soil pollution guideline. The application of sewage sludge mixed with oyster shells increases pH(soil acidity)and buffer capacity(CEC) of farming soil, and heavy metals are thought to be attached to soil as insoluble forms.

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A Study on the Treatment of Combustible Wastes and the Resource Recovery by Pyrolysis (熱分解에 의한 可燃性 廢棄物의 처리 및 資源回收에 관한 연구)

  • Kim, Sam-Cwan;Zong, Moon-Shik
    • Journal of Environmental Health Sciences
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    • v.13 no.1
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    • pp.17-33
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    • 1987
  • As a result of technical advances and industrialization, the characteristics of domestic and industrial wastes are becoming more complex. Accordingly, improved treatment and disposal systems are being continuously sought to take account of complex characteristics and to comply with economic restrictions. In this study, an application of pyrolysis to the treatment of industrial wastes, including waste scrap rubber, waste raw material used in making the slipper bottom and waste PVC pipe, and the effectiveness of pyrolysis in resource recovery from these wastes were investigated. Batches of wastes were pyrolysed by external heating to a temperature of 400-800$\circ$C in a 32 mm diameter x 0.9 m long silica tube to produce combustible gases, oils and chars. Before the start of pyrolysis runs, the entire system was purged with nitrogen gas to exclude the air. The temperature inside the retort was controlled by the thermocouple in the gas stream, and referred to as the pyrolysis temperature. Under these conditions three products were separately collected and further analyzed. The results were summarized as follows. 1. More gases and less chars were produced with higher pyrolyzing temperature and with higher rates of heating, but the yields of oils tended downwards at temperatures above 700$\circ$C. Accordingly, operating conditions of pyrolysis should be varied with desired material. 2. Calorific values and sulfur contents of produced oils were sufficient and suitable for fuel use. Chars from waste rubber had high heating values with low sulfur contents, but calorific values of chars from waste PVC and waste slipper were as low as 3, 065-4, 273 kcal/kg and 942-2, 545 kcal/kg, respectively. Therefore, char from these wastes are inappropriate for fuel. 3. Soluble contents of Pb, Cd, Cu and Zn in chars from waste rubber and waste slipper were below the Specific Hazardous Waste Treatment Standards. However soluble contents of Pb and Cd in chars from waste PVC were one or two times and five or seven times exceedingly the Specific Hazardous Waste Treatment Standards, respectively. 4. Post high heating is desirable for treatment method of waste PVC which generates toxic hydrogen chloride. 5. The proportions of hydrogen, methane and ethane in produced gases were in the range of 3.99-35.61% V/V, 18.22-32.50% V/V and 5.17-5.87% V/V, respectively. 6. Pyrolysis is a useful disposal method in case of waste slipper, which was hardly combustible, and thus investigations of this kind of materials are required for effective management of industrial waste. 7. Based upon the possible market development for products, overall pyroly economics to take account of treatment values of noncombustible or hazardous materials should be evaluated.

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Performance Evaluation of Karan Fries and Karan Swiss Cattle under Closed Breeding System

  • Singh, M.K.;Gurnani, M.
    • Asian-Australasian Journal of Animal Sciences
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    • v.17 no.1
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    • pp.1-6
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    • 2004
  • The 490 and 380 performance records of Karan Fries and Karan Swiss cows developed through crossbreeding followed by inter-se mating were evaluated for production, reproduction performance and disposal rate. Duration of study (1982-92) was grouped into five periods (1982-83; 1984-85; 1986-87; 1988-89; 1990-92) and each year was divided into four seasons (Winter: Dec.-Jan.; Spring: Feb.-March; Summer: April-June; Rainy: July-Sept.; Autumn: Oct.-Nov). Data were also classified according to sire and level of inbreeding. The least squares means of FLY (first lactation yield -305 days), FLL (first lactation length), FSP (first service period), FDP (first dry period), FCI (first calving interval ), MY/FLL (milk yield per day of first lactation length), MY/FCI (milk yield per day of first calving interval), EBV (expected breeding value) and EBE (expected breeding efficiency) were $3,173{\pm}82$ kg, $34611{\pm}$days, $143{\pm}11$ days, $75{\pm}6$ days, $423{\pm}11$ days, $10.6{\pm}0.2$ kg, $8.9{\pm}0.2$ kg, $3,380{\pm}26$ kg, and $88.2{\pm}1.3$% respectively in Karan Fries. Corresponding estimates in Karan Swiss cows were $2,616{\pm}82$ kg, $328{\pm}8$ days, $148{\pm}12$ days, $103{\pm}9$ days, $435{\pm}13$ days, $8.9{\pm}0.2$ kg, $7.2{\pm}0.3$ kg, $2,924{\pm38}$ kg and $86.0{\pm}3.8$% respectively. The effect of sire was significant on FLY, MY/FLL, MY/FCI and EBV in both the herd (p<0.01). The 10 and 15% sires showed superiority (FLY) over herd average of 11 and 7% in Karan Fries and 32 and 21% in Karan Swiss cattle respectively. Inbreeding has adversely and significantly (p<0.05) affected the FLY, MY/FLL, MY/FCI and survivability of Karan Fries females; FDP and disposal through culling of Karan Swiss heifers. The Karan Fries heifers with inbreeding above 12.5% performed 16% lower FLY to herd average. The effect of season of calving was significant on FLL, FSP and FCI (p<0.05) in Karan Fries. Summer calvers ($361{\pm}12$) were have higher lactation length and autumn calvers ($329{\pm}14$) had minimum. Period of calving significantly influenced the FSP, FCI, MY/FLL and MY/FCI in Karan Fries and FLY, MY/FLL and MY/FCI in Karan Swiss. Production efficiency traits in Karan Fries herd witnessed higher yield in the last two periods whereas, Karan Swiss heifers showed fluctuating performance. The findings suggested judicious use of available genetic variability, keeping of inbreeding under safer level and managemental interventions for the consistent improvement of both herds.

Radionuclides Transport from the Hypothetical Disposal Facility in the KURT Field Condition on the Time Domain (KURT 부지 환경에 위치한 가상의 처분 시설에서 누출되는 방사성 핵종의 이동을 Time Domain에서 해석하는 방법에 관한 연구)

  • Hwang, Youngtaek;Ko, Nak-Youl;Choi, Jong Won;Jo, Seong-Seock
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.10 no.4
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    • pp.295-303
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    • 2012
  • Based on the data observed and analyzed on a groundwater flow system in the KURT (KAERI Underground Research Tunnel) site, the transport of radionuclides, which were assumed to be released at the supposed position, was calculated on the time-domain. A groundwater pathway from the release position to the surface was identified by simulating the groundwater flow model with the hydrogeological characteristics measured from the field tests in the KURT site. The elapsed time when the radionuclides moved through the pathway is evaluated using TDRW (Time Domain Random Walk) method for simulating the transport on the time-domain. Some retention mechanisms, such as radioactive decay, equilibrium sorption, and matrix diffusion, as well as the advection-dispersion were selected as the factors to influence on the elapsed time. From the simulation results, the effects of the sorption and matrix diffusion, determined by the properties of the radionuclides and underground media, on the transport of the radionuclides were analyzed and a decay chain of the radionuclides was also examined. The radionuclide ratio of the mass discharge into the surface environment to the mass released from the supposed repository did not exceed $10^{-3}$, and it decreased when the matrix diffusion were considered. The method used in this study could be used in preparing the data on radionuclide transport for a safety assessment of a geological disposal facility because the method could evaluate the travel time of the radionuclides considering the transport retention mechanism.

Development on Glass Formulation for Aluminum Metal and Glass Fiber (유리섬유 및 알루미늄 금속 혼합물 유리조성 개발)

  • Cho, Hyun-Je;Kim, Cheon-Woo
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.10 no.4
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    • pp.247-254
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    • 2012
  • Vitrification technology has been widely applied as one of effective processing methods for wastes generated in nuclear power plants. The advantage of vitrifying for low- and intermediate-level radioactive wastes has a large volume reduction and good durability for the final products. Recently, a filter using on HVAC(Heating Ventilating & Air Conditioning System) is composed with media (glass fiber) and separator (aluminum film) has been studied the proper treatment technology for meeting the waste disposal requirement. Present paper is a feasibility study for the filter vitrification that developing of the glass compositions for filter melting and melting test for physicochemical characteristic evaluation. The aluminum metal of film type is preparing with 0.5 cm size for proper mixing with glass frit, glass fiber is also preparing with 1 cm size within crucible. The glass compositions should be developed considering molten glass are related with wastes reduction. Glass compositions obtained from developing on glass formulation are mainly composed of $SiO_2$ and $B_2O_3$ for aluminum metal. A variety of factors obtained from the glass formulation and melting test are reviewed, which is feeding rate and glass characteristics of final products such as durability for implementing the wastes disposal requirement.

Development and Cost-effective Evaluation of Grass Blocks Minimizing Construction Waste (건설폐기물을 최소화한 비용 효율적 잔디 블록 기법 개발 및 평가)

  • Jeon, Minsu;Hong, Jungsun;Jeon, Jechan;Kim, Lee-Hyung
    • Journal of Wetlands Research
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    • v.19 no.3
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    • pp.359-365
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    • 2017
  • Impermeable surfaces such as transportation land uses including roads and parking lots accumulate high heavy metals and particulate matters concentration especially during dry season which worsens the river water quality and distort the water circulation system during rainfall events. Recently, the government has been promoting policies to install Low Impact Development (LID) facilities such as permeable pavements or grass blocks in parking lots or pavements. However, transition of asphalt-paved surfaces to permeable pavement generated asphalt wastes which are detrimental to the environment and has cost implications due to its removal and disposal. Therefore this study was conducted to provide a method of constructing a cost-effective permeable pavement to reduce waste generation and cost. In this study, comparative analysis of the water circulation capacity and economic efficiency of the traditional construction method and new method proposed in this study through the lab-scale experiment. The proposed method was to make holes in existing asphalt pavements, layout geotextile fabric and permeable base media such as sand before compaction. After compaction, layout grass blocks on the compacted base media then layout sand in between each grass blocks before compaction. Apparently, there was no significant difference between the traditional installation method of permeable pavement and the proposed method in this study considering surface runoff, infiltrated volume, stored volume, and rainfall-runoff delay time. The proposed method in this study generated 86% less wastes compared to the traditional installation method and has 70% cost reduction considering asphalt removal and disposal. The construction method proposed in this study yielded similar performance compared to the traditional installation method and water circulation effect, but was proven to be less complicated and economical.

Numerical simulation of groundwater flow in LILW Repository site:I. Groundwater flow modeling (중.저준위 방사성폐기물 처분 부지의 지하수 유동에 대한 수치 모사: 1. 지하수 유동 모델링)

  • Park, Kyung-Woo;Ji, Sung-Hoon;Kim, Chun-Soo;Kim, Kyung-Su;Kim, Ji-Yeon
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.6 no.4
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    • pp.265-282
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    • 2008
  • Based on the site characterization works in a low and intermediate level waste(LILW) repository site, the numerical simulations for groundwater flow were carried out in order to understand the groundwater flow system of repository site. To accomplish the groundwater flow modeling in the repository site, the discrete fracture network(DFN) model was constructed using the characteristics of fracture zones and background fractures. At result, the total 10 different hydraulic conductivity(K) fields were obtained from DFN model stochastically and K distributions of constructed mesh were inputted into the 10 cases of groundwater flow simulations in FEFLOW. From the total 10 numerical simulation results, the simulated groundwater levels were strongly governed by topography and the groundwater fluxes were governed by locally existed high permeable fracture zones in repository depth. Especially, the groundwater table was predicted to have several tens meters below the groundwater table compared with the undisturbed condition around disposal silo after construction of underground facilities. After closure of disposal facilities, the groundwater level would be almost recovered within 1 year and have a tendency to keep a steady state of groundwater level in 2 year.

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Optimum Dumping Rate of Biodegradable Liquid Waste in Ocean Disposal (분해성 액상폐기물의 해양처리시 최적 투기율)

  • LEE Suk-Mo
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.23 no.3
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    • pp.198-207
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    • 1990
  • Among the biodegradable liquid waste treatment and disposal methods, ocean dumping is a cost-effective and productive manner considering reuse point of view However, when biodegradable liquid waste is dumped in the ocean, oxygen consumption by the decomposition of organic matter must be considered. The purpose of this study is to determine the maximum allowable concentration and dumping rate in the southern waters of the East Sea based on dissolved oxygen level. Streeter and Phelps' model has been used to determine the maximum allowable concentration. Factors in this model, deoxygenation constants and reaeration coefficients, have been determined by appling oxygen consumption method and closed system model. Deoxygenation constants and reaeration coefficients from surface to each standard depth are $0.24\~0.29/day\;and\;0.03\~0.39/day$ in summer, $0.17\~0.20/day\;and\;0.04\~0.56/day$ in winter, respectively. The allowable organic matter concentration($mgBOD/\iota$) to the dissolved oxy-gen sag value of $5mg/{\iota}$ is represented $17.23\times(H)^{-0.37}$ in summer, and $64.96\times(H)^{-0.52}$ in winter by mixing depth(H, m). Csanady's experiment has been applied to estimate the optimum dumping rate. The optimum dumping rate($R,\;m^3/sec$) can be written as a product of the beam(b, m) and the draft(h, m) of vessel, and biochemical oxygen demand of waste($L_n,\;mg/{\iota}$) $R=275{\times}bh^{0.63}L_n^{-1}$ in summer $=745{\times}bh^{0.48}L_n^{-1}$ in winter. The difference of dumping rate between in summer and winter is due to the oxygen distribution.

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